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RESEARCH PAPER · Inorganic Chemistry · 2020

Transition-Metal Monofluorophosphate Ba2M2(PO3F)F6 (M = Mn, Co, and Ni): Varied One-Dimensional Transition-Metal Chains and Antiferromagnetism

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Transition-Metal Monofluorophosphate Ba2M2(PO3F)F6 (M = Mn, Co, and Ni): Varied One-Dimensional Transition-Metal Chains and AntiferromagnetismOriginalMonofluorophosphates—New Examples and a Survey of the PO3F2− Anion6Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M2(SeO3)F2 (M = Mn2+, Ni2+)4Open-framework transition metal fluorophosphates with one-dimensional antiferromagnetic chains7New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O3Open-Framework Iron Fluoride Phosphates Based on Chain, Trinuclear, and Tetranuclear Chain FeIII Building Units: Crystal Structures and Magnetic Properties8MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains16KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units16Structure and magnetic properties of an amine-templated one-dimensional cobalt-fluoro-sulfate containing Co 4 F 4 cubane and hydrogen evolution reaction (HER) performance of its derived carbon-wrapped CoSe 2 nanorods5Three new fluoride phosphates and fluorophosphates Ba3Fe(PO4)F6, Ba3Ga(PO3.5F0.5)O0.5F5.5 and Ba3Fe(PO3F)F7: Combinations of varied building blocks and two-dimensional [Ba3F2]4+ layers derived from fluorine-centred tetrahedra0Syntheses, structures, and magnetism of new vanadium and iron fluoride phosphates Ax(NH4)3-xM4(PO4)2F7(OH)2 (A=K, Rb, Cs, and M= V, Fe) containing novel structural motifs3Fluorination strategy toward chemical and functional modification66Crystal structure of KMnPO 4 F with short- and long-range order inside the layered magnetic system0Analogous Chain Selenite Chlorides Ba 2 M(SeO 3 ) 2 Cl 2 (M = Cu 2+ , Ni 2+ , Co 2+ , Mn 2+ ) and Pb 2 Cu(SeO 3 ) 2 Cl 2 with Tunable Spin S : Syntheses and Characterizations7Synthesis and characterization of a two-dimensional antiferromagnet KNiB4O6F3 with triangular spin lattice5Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal10Synthesis, structures, and magnetic properties of alkali metal manganese( iii ) fluorophosphates containing low-dimensional S = 2 spin structures1Fluorinated Phosphates, BaMPO4F (M = Mn, Fe), with One-Dimensional Channels: Structure and Magnetism1Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions1Fe(II)/Fe(III) Mixed-Valence Fluorophosphate Frameworks and Their Magnetic Characterization0

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  1. Monofluorophosphates—New Examples and a Survey of the PO3F2− Anion

    Chemistry · 2021-01-07

    Matthias Weil

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  2. Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M2(SeO3)F2 (M = Mn2+, Ni2+)

    Inorganic Chemistry · 2021-07-26

    Tianyu Zhu, Olivier Mentré, Haoming Yang, Yong Jin, Xinan Zhang, Ángel M. Arévalo‐López, C. Ritter, Kwang‐Yong Choi, Minfeng Lü

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  3. Open-framework transition metal fluorophosphates with one-dimensional antiferromagnetic chains

    Journal of Solid State Chemistry · 2021-09-01

    Yong Jin, Xinan Zhang, Tianyu Zhu, Haoming Yang, Olivier Mentré, Claire Minaud, Minfeng Lü

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  4. New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O

    Journal of Solid State Chemistry · 2022-06-05

    Xinan Zhang, Yanling Jin, Wenxuan Zhu, Dan Chen, Qingqing Huang, Yaping Li, Minfeng Lü

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  5. Open-Framework Iron Fluoride Phosphates Based on Chain, Trinuclear, and Tetranuclear Chain FeIII Building Units: Crystal Structures and Magnetic Properties

    Inorganic Chemistry · 2022-06-07

    Yong Jin, Suheon Lee, Tianyu Zhu, Xinan Zhang, Haoming Yang, Dan Chen, Wenxuan Zhu, Kwang‐Yong Choi, Minfeng Lü

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  6. MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains

    Inorganic Chemistry · 2022-10-26

    Hang Liu, Yanhong Wang, Ya-Dong Zhou, Shuang Li, Yaling Dou, Tao Wang, Hongcheng Lu

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  7. KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units

    Dalton Transactions · 2023-01-01

    Yanhong Wang, Shuang long Li, Yaling Dou, Hui Li, Hongcheng Lu

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  8. Structure and magnetic properties of an amine-templated one-dimensional cobalt-fluoro-sulfate containing Co 4 F 4 cubane and hydrogen evolution reaction (HER) performance of its derived carbon-wrapped CoSe 2 nanorods

    Dalton Transactions · 2023-01-01

    Malaya K. Sahoo, J. N. Behera

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  9. Three new fluoride phosphates and fluorophosphates Ba3Fe(PO4)F6, Ba3Ga(PO3.5F0.5)O0.5F5.5 and Ba3Fe(PO3F)F7: Combinations of varied building blocks and two-dimensional [Ba3F2]4+ layers derived from fluorine-centred tetrahedra

    Journal of Solid State Chemistry · 2023-02-03

    Dan Chen, Yanling Jin, Wenxuan Zhu, Qingqing Huang, Yaping Li, Minfeng Lü

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  10. Syntheses, structures, and magnetism of new vanadium and iron fluoride phosphates Ax(NH4)3-xM4(PO4)2F7(OH)2 (A=K, Rb, Cs, and M= V, Fe) containing novel structural motifs

    Journal of Solid State Chemistry · 2023-05-31

    Xinan Zhang, Yanling Jin, Wenxuan Zhu, Dan Chen, Qingqing Huang, Yaping Li, Olivier Mentré, Claire Minaud, Minfeng Lü

    Read original paper ↗ ·
  11. Fluorination strategy toward chemical and functional modification

    Fundamental Research · 2023-12-19

    Haotian Qiu, Shilie Pan, Miriding Mutailipu

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  12. Crystal structure of KMnPO 4 F with short- and long-range order inside the layered magnetic system

    Dalton Transactions · 2024-01-01

    Olga V. Yakubovich, Larisa Victorovna Shvanskaya, Galina V. Kiriukhina, Sergey V. Simonov, Anatoly S. Volkov, Olga V. Dimitrova, Vladimir V. Korolev, E. A. Ovchenkov, Alexander N. Vasiliev

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  13. Analogous Chain Selenite Chlorides Ba 2 M(SeO 3 ) 2 Cl 2 (M = Cu 2+ , Ni 2+ , Co 2+ , Mn 2+ ) and Pb 2 Cu(SeO 3 ) 2 Cl 2 with Tunable Spin S : Syntheses and Characterizations

    Inorganic Chemistry · 2024-07-26

    Alimujiang Yalikun, Yanhong Wang, Yun Lv, Yaling Dou, Hyun‐Joo Koo, Jiaojiao Cao, Wei Qi, Keke Huang, Myung‐Hwan Whangbo, Zhongwen Ouyang, Hongcheng Lu

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  14. Synthesis and characterization of a two-dimensional antiferromagnet KNiB4O6F3 with triangular spin lattice

    Journal of Solid State Chemistry · 2024-10-18

    Hui Li, Shuang Li, Yanhong Wang, Yaling Dou, Hongcheng Lu

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  15. Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal

    Inorganic Chemistry · 2024-10-28

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Qian Wu, Mingjun Xia

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  16. Synthesis, structures, and magnetic properties of alkali metal manganese( iii ) fluorophosphates containing low-dimensional S = 2 spin structures

    Dalton Transactions · 2025-01-01

    Xiedong Cheng, Feifan Li, Qingqing Huang, Laura C. J. Pereira, Rui Cui, Yaping Li, Minfeng Lü

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  17. Fluorinated Phosphates, BaMPO4F (M = Mn, Fe), with One-Dimensional Channels: Structure and Magnetism

    Inorganic Chemistry · 2025-06-04

    Qingqing Huang, Xiedong Cheng, Claire Minaud, Olivier Mentré, Bruno J. C. Vieira, Joao Carlos Waerenborgh, Feifan Li, Yaping Li, Minfeng Lü

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  18. Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions

    Journal of Solid State Chemistry · 2025-12-24

    Shuaikun Li, Yanhong Wang, Haibo Li, Hang Liu, Yun Lv, Hongcheng Lu

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  19. Fe(II)/Fe(III) Mixed-Valence Fluorophosphate Frameworks and Their Magnetic Characterization

    Inorganic Chemistry · 2026-07-13

    Feifan Li, Xiedong Cheng, Laura C. J. Pereira, Bruno J. C. Vieira, Joao Carlos Waerenborgh, Rui Cui, Qingqing Huang, Yaping Li, Shoushuang Li, Mingming Hang, Zhenglong Zhu, Zirui Zuo, Hexiang Liu, Minfeng Lü

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