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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2019

Evaluating Thermal Quenching Temperature in Eu 3+ -Substituted Oxide Phosphors via Machine Learning

Ya Zhuo, Shruti Hariyani, Edward Armijo, Zainab Abolade Lawson, Jakoah Brgoch

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Evaluating Thermal Quenching Temperature in Eu 3+ -Substituted Oxide Phosphors via Machine LearningOriginalDesign of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 418Double perovskite Ca2MgTeO6:Eu3+ red-emitting phosphors with high thermal stability for near UV/blue excited white LEDs81Recent progress on discovery and properties prediction of energy materials: Simple machine learning meets complex quantum chemistry62A red phosphor LaSc3(BO3)4:Eu3+ with zero-thermal-quenching and high quantum efficiency for LEDs251Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors76Machine learning 5d-level centroid shift of Ce3+ inorganic phosphors31Synthesis and optical properties of novel double perovskite Ca2MgTeO6:Dy3+,Na+ phosphors for white LEDs28Delayed Concentration Quenching of Luminescence Caused by Eu3+-Induced Phase Transition in LaSc3(BO3)4114Exploiting the diverse photoluminescence behaviors of NaLuF4:xEu3+ nanoparticles and g-C3N4 to realize versatile applications in white light-emitting diode and optical thermometer161Deep-red photoluminescence from enhanced 5D0-7F4 transition in Eu3+ doped Ca2Ga2GeO7 phosphors36Effect of charge compensators (Li+, Na+, K+) on the luminescence properties of Sr3TeO6:Eu3+ red phosphor42Highly efficient blue-emitting phosphor of Sr[B 8 O 11 (OH) 4 ]:Eu 2+ prepared by a self-reduction method19Opportunities for Next-Generation Luminescent Materials through Artificial Intelligence85Measuring the impact of novelty, bibliometric, and academic-network factors on citation count using a neural network42Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Charge compensation effects of alkali metal ions M+ (Li+, Na+, K+) on luminescence enhancement in red-emitting Ca3Si2O7:Eu3+ phosphors51Highly efficient and thermally stable Eu3+ activated phosphate based phosphors for wLEDs: An experimental and DFT study53A mini review of machine learning in inorganic phosphors10A novel red-emitting phosphor K 2 MgGeO 4 :Eu 3+ for WLEDs: zero-thermal quenching induced by heterovalent substitution27The Local Symmetry of Eu3+-Activated Li4ca2b8o16 Red-Emitting Phosphors with High Color Purity and Excellent Thermal Stability0How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Enhancing the photoluminescence performance of Ca5(PO4)2SiO4:Re3+ (Re = Eu, Sm) phosphors with A3+ (A = La, Bi) codoping and white light-emitting diode application28Multiobjective Machine Learning-Assisted Discovery of a Novel Cyan–Green Garnet: Ce Phosphors with Excellent Thermal Stability73Self‐Trapped Exciton Emission with High Thermal Stability in Antimony‐Doped Hybrid Manganese Chloride84Photoluminescence properties of Ba3In2WO9: Eu3+: a novel red-emitting phosphor for WLEDs24Preparation and luminescence behaviour of perovskite LaAlO3:Tb3+ nanophosphors for innovative displays71Machine Learning for Harnessing Thermal Energy: From Materials Discovery to System Optimization85Synthesis and luminescence properties of double perovskite red-emitting NaSrLaTeO6:Sm3+ phosphors with high thermal stability and color purity for w-LEDs38Luminescence in the solid state7Data-driven materials discovery and synthesis using machine learning methods14Spectroscopic characterization of Eu3+-doped KSrYSi2O7 phosphor for NUV LEDs: Estimation of the Judd Ofelt parameter16Machine learning the peak emission wavelength of Mn 4+ -activated inorganic phosphors6Recent progress in phosphor technology1Ultra-bright and thermally stable deep red emitting doped yttrium zirconate nanoparticles for tunable white LEDs and indoor plant growth28Preparation, characterization, and application of a red phosphor Ca2InTaO6:Eu3+ in w-LEDs and latent fingerprint detection56Lattice dynamics, core–shell electron structure and Judd − Ofelt analysis on europium-doped Gd2O3 micro phosphors2Site-selective occupation of Eu3+, high-quenching concentration, and enhanced luminescence via Mg2+ co-doping in a borophosphate phosphor30Novel Red-Emitting Eu3+-Doped Y2(WxMo1−xO4)3 Phosphor with High Conversion Efficiency for Lighting and Display Applications5Needs, Trends, and Advances in Scintillators for Radiographic Imaging and Tomography98Structurally stable Mn4+-doped oxide phosphor with improved thermal stability for agricultural lighting22Photoluminescence Color Prediction for Eu3+‐Doped Perovskite Red Phosphors Using Machine Learning3A guide to comprehensive phosphor discovery for solid-state lighting245Developing and optimizing novel Cr 3+ -activated inorganic NIR phosphors by combining triple-objective optimization and crystal field engineering25Structural, optical and photoluminescence properties of BaLa2ZnO5: Eu3+ phosphor: A prospective red-emitting phosphor for LED applications27Cation vacancy-boosted BaZnB 4 O 8 : x Eu 3+ phosphors with high quantum yield and thermal stability for pc-WLEDs17Detection of sulphur( ii ) of carbon dots synthesized from Gardenia residue5Thermal stability and quantum efficiency improvement of Cr 3+ -activated garnet phosphors via regulating A/B sites for near-infrared LED applications9One-shot heterogeneous transfer learning from calculated crystal structures to experimentally observed materials5Charge compensation effect of alkali metal ions on luminescence enhancement and negative thermal quenching of Sr1-xLaNaTeO6:xEu3+ red phosphors18Advancements of Lanthanide-doped Phosphors in Solid-state Lighting Applications27Application of Eu(III) activated tungstates in solid state lighting15Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers3Optical Phenomena in Molecule-Based Magnetic Materials154A novel orange-red emitting K5Y(MoO4)4:Sm3+ phosphor with excellent color purity for temperature sensing and high CRI WLEDs19Detection of Ferric Ion by Fluorescent Carbon Nano Dots Synthesized from Forsythia Residue3Hierarchical Symbolic Regression Modeling and Physical Mechanism Study of Stokes Shift of Cr³⁺-Activated Double Perovskite Phosphors0Modulating anti-thermal and concentration quenching for enhanced dysprosium emission6Activator – host structure relations of applied optical materials: a review7Computational investigation of Eu3+ doping effects on the mechanical and thermodynamic properties of Na2MSiO4 (M = Mg, Zn)4Explainable machine learning-enabled discovery for high-efficiency red-emitting phosphor under data constraints5Prediction of luminescence lifetimes of Mn4+/Eu3+ doped phosphors based on interpretable machine learning3Atomistic Modeling of Rare Earth Ions in Photonic Materials4Machine-Learning-Assisted Discovery of Cr3+-Based Near-Infrared Phosphors16Hierarchical symbolic regression modeling and physical mechanism study of Stokes shift of Cr3+-activated double perovskite phosphors4Enhanced Thermal Stability in Eu 3+ -Doped Phosphors by Red-Shifting the Charge Transfer Band8Composition-based machine learning for predicting and designing Mn 4+ -doped phosphors3Data-Driven Advances in Rare-Earth Substituted Inorganic Phosphors for Solid-State Lighting and Display Applications: A 6G Perspective0Thermally stable near-infrared light-emitting materials2Intrinsically Thermally Robust Nanocrystals for High‐Flux Photonics9Highly efficient La2(Li, Mg)(Nb, Al)O6: Mn4+ far-red phosphor realized by crystal-field engineering for plant growth lighting6Structural evolution and photoluminescence modulation by Gd3+ in Tb3+-doped Ga2O31Structural analysis and JO theory calculations on color-tunable phosphor LiCaSiO3:Sm3+,Eu3+2Data-driven approaches for functional ceramics3The effects of Bi3+ and surfactants on the luminescence properties of orange-red light emitting phosphor CaSiO3: Eu3+, Bi3+, Sm3+, Li+1Data-Driven Discovery of Ce 3+ -Activated Phosphors with Target Excitation Energies for Solid-State Lighting2Machine learning prediction of luminescence concentration quenching of Tb3+-doped inorganic phosphors0Structural Engineering of Rare‐Earth Nanomaterials0Ultra‐Robust (>700 K) Vacuum‐Ultraviolet Radiography Enabled by Nano‐Polycrystalline hBN0Machine Learning‐Triggered Auto‐Discovery and Promotion of Luminescent Materials: From Predictive Modeling to Autonomous Laboratories0First-principles insights into the cation-dependent electronic and optical properties of Na2MSiO4 (M = Mg, Zn) compounds0From Phosphor Ceramics to Intelligent Light‐Conversion Materials: High‐Flux Luminescence, Glassy Composite Interface, and Machine‐Learning‐Guided Design0

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  7. Synthesis and optical properties of novel double perovskite Ca2MgTeO6:Dy3+,Na+ phosphors for white LEDs

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  8. Delayed Concentration Quenching of Luminescence Caused by Eu3+-Induced Phase Transition in LaSc3(BO3)4

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  10. Deep-red photoluminescence from enhanced 5D0-7F4 transition in Eu3+ doped Ca2Ga2GeO7 phosphors

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  11. Effect of charge compensators (Li+, Na+, K+) on the luminescence properties of Sr3TeO6:Eu3+ red phosphor

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  19. A novel red-emitting phosphor K 2 MgGeO 4 :Eu 3+ for WLEDs: zero-thermal quenching induced by heterovalent substitution

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