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RESEARCH PAPER · The Journal of Physical Chemistry Letters · 2019

Sb3+ Doping-Induced Triplet Self-Trapped Excitons Emission in Lead-Free Cs2SnCl6 Nanocrystals

Yuyu Jing, Ying Liu, Jing Zhao, Zhiguo Xia

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Sb3+ Doping-Induced Triplet Self-Trapped Excitons Emission in Lead-Free Cs2SnCl6 NanocrystalsOriginalRevising care to meet maternal needs post birth: an overview of the hospital to home postnatal study.02D layered all-inorganic halide perovskites: recent trends in their structure, synthesis and properties75Antimony doped lead-free double perovskites (Cs 2 NaBi 1−x Sb x Cl 6 ) with enhanced light absorption and tunable emission79Crystal structure and luminescence properties of lead-free metal halides (C 6 H 5 CH 2 NH 3 ) 3 MBr 6 (M = Bi and Sb)123High-efficiency blue photoluminescence in the Cs 2 NaInCl 6 :Sb 3+ double perovskite phosphor198Tunable photoluminescence in Sb 3+ -doped zero-dimensional hybrid metal halides with intrinsic and extrinsic self-trapped excitons67Highly Tunable Emission by Halide Engineering in Lead-Free Perovskite-Derivative Nanocrystals: The Cs2SnX6 (X = Cl, Br, Br/I, I) System55Recent processes on light-emitting lead-free metal halide perovskites99Sb 3+ Dopant and Halogen Substitution Triggered Highly Efficient and Tunable Emission in Lead-Free Metal Halide Single Crystals331Bright Blue and Green Luminescence of Sb(III) in Double Perovskite Cs2MInCl6 (M = Na, K) Matrices372Supramolecular Approach for Fine-Tuning of the Bright Luminescence from Zero-Dimensional Antimony(III) Halides179Efficient Thermally Activated Delayed Fluorescence from All‐Inorganic Cesium Zirconium Halide Perovskite Nanocrystals222Efficient Thermally Activated Delayed Fluorescence from All‐Inorganic Cesium Zirconium Halide Perovskite Nanocrystals48Rb3InCl6: A Monoclinic Double Perovskite Derivative with Bright Sb3+-Activated Photoluminescence103Density functional study on electronic properties of transition metal-based vacancy-ordered halide perovskites3Synthesis and luminescence properties of apatite-type red-emitting Ba2La8(GeO4)6O2:Eu3+ phosphors32Development of structure and tuning ability of the luminescence of lead-free halide perovskite nanocrystals (NCs)43Boosting triplet self-trapped exciton emission in Te(IV)-doped Cs2SnCl6 perovskite variants239Efficient Emission in Halide Layered Double Perovskites: The Role of Sb 3+ Substitution in Cs 4 Cd 1– x Mn x Bi 2 Cl 12 Phosphors48ns2 Electron (Bi3+ and Sb3+) Doping in Lead-Free Metal Halide Perovskite Derivatives329Colloidal BaZrS 3 chalcogenide perovskite nanocrystals for thin film device fabrication98All-inorganic lead-free metal halide perovskite quantum dots: progress and prospects55Alloying Cs + into Rb 2 ZrCl 6 :Te 4+ toward highly efficient and stable perovskite variants37An ultraviolet excitation anti-counterfeiting material of Sb 3+ doped Cs 2 ZrCl 6 vacancy-ordered double perovskite55Bulk assembly of a 0D organic antimony chloride hybrid with highly efficient orange dual emission by self-trapped states85Co-luminescence in a zero-dimensional organic–inorganic hybrid antimony halide with multiple coordination units67Excitation wavelength tunable white light emission in vacancy-ordered double perovskite30Photoconductive Detectors Based on Perovskite Quantum Dots or Nanocrystals: From Lead-Based System to Lead-Free System0Recent Advances and Opportunities of Lead-Free Perovskite Nanocrystal for Optoelectronic Application95Self-trapped exciton emission in an Sn( ii )-doped all-inorganic zero-dimensional zinc halide perovskite variant46Self-trapped exciton to dopant energy transfer in Sb 3+ -doped Cs 2 ZrCl 6 perovskite variants45Zero-dimensional Sb3+ doped Rb7Bi3Cl16 metal halides with triplet self-trapped exciton emission4Hybrid 0D Antimony Halides as Air‐Stable Luminophores for High‐Spatial‐Resolution Remote Thermography150Lead‐free metal halide perovskites for light‐emitting diodes38Efficient Energy Transfer in Te4+-Doped Cs2ZrCl6 Vacancy-Ordered Perovskites and Ultrahigh Moisture Stability via A-Site Rb-Alloying Strategy241Photoluminescence of Singlet/Triplet Self‐Trapped Excitons in Sb3+‐Based Metal Halides293Lead‐Free Halide Double Perovskite Nanocrystals for Light‐Emitting Applications: Strategies for Boosting Efficiency and Stability200Reversible Luminescent Vapochromism of a Zero-Dimensional Sb3+-Doped Organic–Inorganic Hybrid88Tailoring the Broadband Emission in All‐Inorganic Lead‐Free 0D In‐Based Halides through Sb3+ Doping123Large-scale room-temperature synthesis of high-efficiency lead-free perovskite derivative (NH4)2SnCl6:Te phosphor for warm wLEDs66Polarons and Charge Localization in Metal‐Halide Semiconductors for Photovoltaic and Light‐Emitting Devices110Sb-Doped Metal Halide Nanocrystals: A 0D versus 3D Comparison168Morphological and Optical Tuning of Lead-Free Cs2SnX6 (X = I, Br) Perovskite Nanocrystals by Ligand Engineering14Cs2Zr1−xTexCl6 Perovskite Microcrystals with Ultrahigh Photoluminescence Quantum Efficiency of 79.46% for High Light Efficiency White Light Emitting Diodes64Synthesis of a Bi3+-Doped Cs2HfCl6 Double Perovskite with Highly Efficient Blue Light Emission at Room Temperature54Sb 3+ ‐Doping in Cesium Zinc Halides Single Crystals Enabling High‐Efficiency Near‐Infrared Emission370(INVITED) Revisiting Duffy's model for Sb3+ and Bi3+ in double halide perovskites: Emergence of a descriptor for machine learning1Uncovering Halogen Mixing and Octahedral Dynamics in Cs 2 SnX 6 by Multinuclear Magnetic Resonance Spectroscopy25Transformation between the Dark and Bright Self-Trapped Excitons in Lead-Free Double-Perovskite Cs 2 NaBiCl 6 under Pressure70ns2-containing vacancy-ordered double perovskites for optoelectronic applications: A first-principles investigation4Controlling Photoluminescence and Photocatalysis Activities in Lead‐Free Cs2PtxSn1−xCl6 Perovskites via Ion Substitution92Controlling Photoluminescence and Photocatalysis Activities in Lead‐Free Cs2PtxSn1−xCl6 Perovskites via Ion Substitution16Modulation of the optical bandgap and photoluminescence quantum yield in pnictogen (Sb3+/Bi3+)-doped organic–inorganic tin(IV) perovskite single crystals and nanocrystals35Efficient White Photoluminescence from Self-Trapped Excitons in Sb 3+ /Bi 3+ -Codoped Cs 2 NaInCl 6 Double Perovskites with Tunable Dual-Emission285Tuning the luminous properties and optical thermometry of Cs2SnCl6 phosphor microcrystals via Bi and Sb codoping30Pressure-Driven Reverse Intersystem Crossing: New Path toward Bright Deep-Blue Emission of Lead-Free Halide Double Perovskites144White-light emission lead-free perovskite phosphor Cs2ZrCl6:Sb3+63Origin of Luminescence in Sb3+- and Bi3+-Doped Cs2SnCl6 Perovskites: Excited State Relaxation and Spin–Orbit Coupling107Efficient, Stable, and Tunable Cold/Warm White Light from Lead‐Free Halide Double Perovskites Cs2Zr1‐xTexCl654Bright Triplet Self-Trapped Excitons to Dopant Energy Transfer in Halide Double-Perovskite Nanocrystals95Multiexcitonic Emission in Zero-Dimensional Cs2ZrCl6:Sb3+ Perovskite Crystals275Role of organic cation orientation in formamidine based perovskite materials36Cyan Emission in Two-Dimensional Colloidal Cs2CdCl4:Sb3+ Ruddlesden–Popper Phase Nanoplatelets67Isolated [SbCl6]3– Octahedra Are the Only Active Emitters in Rb7Sb3Cl16 Nanocrystals29Toward a General Understanding of Exciton Self-Trapping in Metal Halide Perovskites93Multi-Dopant Engineering in Perovskite Cs2SnCl6: White Light Emitter and Spatially Luminescent Heterostructure58Crystallization Dynamics of Sn‐Based Perovskite Thin Films: Toward Efficient and Stable Photovoltaic Devices197Recent Advances in All‐Inorganic Zero‐Dimensional Metal Halides28Te 4+ -doped zero-dimensional Cs 2 ZnCl 4 single crystals for broadband yellow light emission50Broadband multimodal emission in Sb-doped CaZnOS-layered semiconductors25Nonradiative Energy Transfer from CsPbBr3 Nanocrystals to CdSe/CdS Nanocrystals for Efficient Light Down Conversion9Robust dual cationic ligand for stable and efficient warm-white light emission in lead-free double perovskite nanocrystals9Colloidal Synthesis and Tunable Multicolor Emission of Vacancy‐Ordered Cs2HfCl6 Perovskite Nanocrystals74Te4+/Bi3+ Co-Doped Double Perovskites with Tunable Dual-Emission for Contactless Light Sensor, Encrypted Information Transmission and White Light Emitting Diodes91Water-Molecule-Induced Emission Transformation of Zero-Dimension Antimony-Based Metal Halide79Toward eco‐friendly and stable halide perovskite‐inspired materials for light‐emitting devices applications by dimension classification: Recent advances and opportunities21Antimony doping to enhance luminescence of tin( iv )-based hybrid metal halides35Bright tunable luminescence of Sb 3+ doping in zero-dimensional lead-free halide Cs 3 ZnCl 5 perovskite crystals26Doped 0D Cs 4 PbCl 6 single crystals featuring full-visible-region colorful luminescence17High quality lead-free perovskites toward white light emitting diodes and X-ray imaging24Lead-free perovskite Rb 2 Sn 1− x Te x Cl 6 with bright luminescence for optical thermometry and tunable white light emitting diodes23Triplet–triplet energy transfer from Bi 3+ to Sb 3+ in zero-dimensional indium hybrids via a B-site co-doping strategy toward white-light emission34Ultra-stable blue-emitting lead-free double perovskite Cs 2 SnCl 6 nanocrystals enabled by an aqueous synthesis on a microfluidic platform21White light emission from lead-free mixed-cation doped Cs 2 SnCl 6 nanocrystals47Stoichiometry‐Controlled Phase Engineering of Cesium Bismuth Halides and Reversible Structure Switch46Component Engineering to Tailor the Structure and Optical Properties of Sb-Doped Indium-Based Halides86Novel Insights into Sb-Cu Catalysts for Electrochemical Reduction of CO250(C16H28N)2SbCl5: A new lead-free zero-dimensional metal-halide hybrid with bright orange emission111Structural, Morphological and Raman Characteristics of Cs2SnCl6 Double-Perovskite Crystals0Light Emission of Self‐Trapped Excitons in Inorganic Metal Halides for Optoelectronic Applications260Magnetic Transitions and Energy Transfer Processes in Sb-Based Zero-Dimensional Metal Halide Nanocrystals Doped with Manganese34Tunable Dual Emission in Bi3+/Te4+-Doped Cs2HfCl6 Double Perovskites for White Light-Emitting Diode Applications56Unraveling the triplet excited-state dynamics of Bi3+ in vacancy-ordered double perovskite Cs2SnCl6 nanocrystals76Efficient Yellow Self-Trapped Exciton Emission in Sb3+-Doped RbCdCl3 Metal Halides72Cryogenic Scintillation Performance of Cs4PbI6 Perovskite Single Crystals8Regulating the Singlet and Triplet Emission of Sb3+ Ions to Achieve Single-Component White-Light Emitter with Record High Color-Rendering Index and Stability145Large Spectral Shift of Mn2+ Emission Due to the Shrinkage of the Crystalline Host Lattice of the Hexagonal CsCdCl3 Crystals and Phase Transition30Recent progress of triplet state emission in organic-inorganic hybrid metal halides28Bright Green Emission from Self-Trapped Excitons Triggered by Sb3+ Doping in Rb4CdCl6145Centimeter-Sized Na-Doped CsPb2Br5 Single Crystals with Efficient Self-Trapped Exciton Emission8Efficient Self-Trapped Exciton Emission in Ruddlesden–Popper Sb-Doped Cs3Cd2Cl7 Perovskites49Fast HCl-free Synthesis of Lead-free Rb2ZrCl6:xSb3+ Perovskites15Origin of Broadband Emission and Large Stokes Shift in Antimony Trisulfide11Green Triplet Self-Trapped Exciton Emission in Layered Rb3Cd2Cl7:Sb3+ Perovskite: Comparison with RbCdCl3:Sb3+44Emission Mechanism of Self-Trapped Excitons in Sb 3+ -Doped All-Inorganic Metal-Halide Perovskites104Zero-dimensional rubidium zinc halide blue-emitting quantum dots for X-ray imaging9Factors influencing self-trapped exciton emission of low-dimensional metal halides115Highly Stable and Panchromatic Light Absorbing Cs2OsX6 (X = Cl−, Br−, I−) Vacancy Ordered Perovskites as Photoanodes for Solar Water Oxidation19All-inorganic non-perovskite copper halides for light emission33Light Emission from Low‐Dimensional Pb‐Free Perovskite‐Related Metal Halide Nanocrystals37Orange/cyan emissive sensors of Sb 3+ for probing water via reversible phase transformation in rare-earth-based perovskite crystals24Turn‐on Circularly Polarized Luminescence in Chiral Indium Chlorides by 5s2 Metal Centers56Turn‐on Circularly Polarized Luminescence in Chiral Indium Chlorides by 5s2 Metal Centers12Admirable stability achieved by ns 2 ions Co-doping for all-inorganic metal halides towards optical anti-counterfeiting17Antimony doped tin( iv ) hybrid metal halides with high-efficiency tunable emission, WLED and information encryption31Controlled growth of lead-free cesium zirconium halide double perovskite nanocrystals through a microfluidic reactor8Effect of Mn 2+ doping on exciton recombination and carrier trapping in the Cs 2 CdCl 4 metal halide24Highly emissive Sb 3+ -doped Rb 2 InCl 5 ·H 2 O perovskites: cost-effective synthesis, luminescence, and its application11Manipulating the sublattice distortion induced by Mn 2+ doping for boosting the emission characteristics of self-trapped excitons in Cs 4 SnBr 619Metal halides RbCdCl 3 :Sb 3+ and Rb 4 CdCl 6 :Sb 3+ with yellow and cyan emissions obtained via a facile hydrothermal process7Opportunity of lead-free metal halide perovskites for electroluminescence39Sn 2+ doping-induced large extra vibrational energy of an excited state for efficient blue emission in Cs 2 SnCl 6 :Bi1Zero-dimensional cadmium-based metal halide with near-unity photoluminescence quantum efficiency21Exploring the Links between Photoluminescence and Microstructure in Cs2InBr5·H2O Samples Doped with Pb2+8Doping Strategies for Promising Organic–Inorganic Halide Perovskites24Enhanced free-exciton luminescence in Cs2SnBr6−I : A first-principles study13Effect of the Host Lattice Environment on the Expression of 5s2 Lone-Pair Electrons in a 0D Bismuth-Based Metal Halide34Chemical doping of lead-free metal-halide-perovskite related materials for efficient white-light photoluminescence61Excitation-Wavelength-Dependent Emission Behavior in (NH4)2SnCl6 via Sb3+ Dopant41Luminescence Mechanism of ns2 Ions in Cs2(Sn/Hf)Cl6 Revealed by First-Principles Calculations15Surface Effects on Anisotropic Photoluminescence in One‐Dimensional Organic Metal Halide Hybrids12Precise Hue Control in a Single‐Component White‐Light Emitting Perovskite Cs2SnCl6 through Defect Engineering Based on La3+ Doping31Multimodal Luminescent Low-Dimension Cs2ZrCl6:xSb3+ Crystals for White Light-Emitting Diodes and Information Encryption22Realize intelligent anti-counterfeiting and efficient near-infrared emission of indium-based perovskite through crystal phase and energy band engineering5Synthesis of Pb‐free Double‐Perovskite Heterojunction (Cs2SnCl6‐Bi3+&Te4+/Cs2GeF6‐Mn4+) with White Emission for LED Application8Bromide ions substitution-induced photoluminescence tuning in Cs2NaInCl6:Sb3+ double perovskite10Efficient Near-Infrared Luminescence Based on Double Perovskite Cs2SnCl620Excited-State Dopant–Host Energy-Level Alignment: Toward a Better Understanding of the Photoluminescence Behaviors of Doped Phosphors18Modulating Nonluminous 0D (NH4)2SnCl6 Perovskites by Metal Ion Doping12Near room temperature synthesis of Cs2InCl5-xBrx·H2O (x = 0–5) perovskites with tunable yellow to red emissions3Mn2+‐Based Luminescent Metal Halides: Syntheses, Properties, and Applications155Photoluminescence Emission Studies on a Lanthanum-Doped Lead Free Double Halide Perovskite, La:Cs2SnCl652Synthesis and Improved Photoluminescence of SnF2-Derived CsSnCl3-SnF2:Mn2+ Perovskites via Rapid Thermal Treatment5Confocal mapping of stable room-temperature emission centers in gadolinium doped vacancy-ordered double halide perovskite, Gd:Cs2SnCl647Carriers, Quasi-particles, and Collective Excitations in Halide Perovskites109Ligand Engineering in Tin-Based Perovskite Solar Cells49Zero‐Dimensional Gua3SbCl6 Crystals as Intrinsically Reabsorption‐Free Scintillators for Radiation Detection44Ultrahigh PLQY Lead‐Free Organic–Inorganic Hybrid Zirconium‐Based Perovskites in Anticounterfeiting Applications43Optimization of the optical properties of lead-free 0D Cs3Cu2I5 perovskite films via hydroiodic acid8Dimension Tuning of All‐Inorganic Ag‐Based Metal Halides by Solvent Engineering7

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  41. Polarons and Charge Localization in Metal‐Halide Semiconductors for Photovoltaic and Light‐Emitting Devices

    Advanced Materials · 2021-05-06

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  42. Sb-Doped Metal Halide Nanocrystals: A 0D versus 3D Comparison

    ACS Energy Letters · 2021-05-27

    Dongxu Zhu, Matteo L. Zaffalon, Juliette Zito, Francesca Cova, Francesco Meinardi, Luca De Trizio, Ivan Infante, Sergio Brovelli, Liberato Manna

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  43. Morphological and Optical Tuning of Lead-Free Cs2SnX6 (X = I, Br) Perovskite Nanocrystals by Ligand Engineering

    Frontiers in Electronics · 2021-06-21

    Alessandro Veronese, Carlo Ciarrocchi, Marcello Marelli, Paolo Quadrelli, M. Patrini, Lorenzo Malavasi

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  44. Cs2Zr1−xTexCl6 Perovskite Microcrystals with Ultrahigh Photoluminescence Quantum Efficiency of 79.46% for High Light Efficiency White Light Emitting Diodes

    Advanced Optical Materials · 2021-06-25

    Zhilin Li, Zhihui Rao, Qiaoqiao Li, Liujiang Zhou, Xiujian Zhao, Xiao Nan Gong

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  45. Synthesis of a Bi3+-Doped Cs2HfCl6 Double Perovskite with Highly Efficient Blue Light Emission at Room Temperature

    Inorganic Chemistry · 2021-06-28

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  46. Sb 3+ ‐Doping in Cesium Zinc Halides Single Crystals Enabling High‐Efficiency Near‐Infrared Emission

    Advanced Functional Materials · 2021-07-10

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  47. (INVITED) Revisiting Duffy's model for Sb3+ and Bi3+ in double halide perovskites: Emergence of a descriptor for machine learning

    Optical Materials X · 2021-07-21

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  48. Uncovering Halogen Mixing and Octahedral Dynamics in Cs 2 SnX 6 by Multinuclear Magnetic Resonance Spectroscopy

    Chemistry of Materials · 2021-07-26

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  49. Transformation between the Dark and Bright Self-Trapped Excitons in Lead-Free Double-Perovskite Cs 2 NaBiCl 6 under Pressure

    The Journal of Physical Chemistry Letters · 2021-07-28

    Jutao Jiang, Guangming Niu, Laizhi Sui, Xiaowei Wang, Yutong Zhang, Li Che, Guorong Wu, Kaijun Yuan, Xueming Yang

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  50. ns2-containing vacancy-ordered double perovskites for optoelectronic applications: A first-principles investigation

    Solid State Communications · 2021-07-30

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