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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2019

Fe/Ru Oxide as a Versatile and Effective Cocatalyst for Boosting Z-Scheme Water-Splitting: Suppressing Undesirable Backward Electron Transfer

Akinobu Nakada, Hajime Suzuki, Junie Jhon M. Vequizo, Kanta Ogawa, Masanobu Higashi, Akinori Saeki, Akira Yamakata, Hiroshi Kageyama, Ryu Abe

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Fe/Ru Oxide as a Versatile and Effective Cocatalyst for Boosting Z-Scheme Water-Splitting: Suppressing Undesirable Backward Electron TransferOriginalHybrid cocatalysts in semiconductor-based photocatalysis and photoelectrocatalysis160Photocatalytic Oxygen Evolution from Water Splitting255A new lead-free Sillén–Aurivillius oxychloride Bi5SrTi3O14Cl with triple-perovskite layers for photocatalytic water splitting under visible light19Particulate photocatalytic reactors with spectrum-splitting function for artificial photosynthesis4Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis109Z-Scheme Overall Water Splitting Using ZnxCd1–xSe Particles Coated with Metal Cyanoferrates as Hydrogen Evolution Photocatalysts49Crystal Facet-Dependent Intrinsic Charge Separation on Well-Defined Bi 4 TaO 8 Cl Nanoplate for Efficient Photocatalytic Water Oxidation23Light-induced electron transfer/phase migration of a redox mediator for photocatalytic C–C coupling in a biphasic solution5Water oxidation of visible-light-responsive bismuth-yttrium oxychloride promoted by a dual-ion doping strategy for assembly of Z-scheme overall water splitting25Electronic Engineering of ABO3 Perovskite Metal Oxides Based on d0 Electronic‐Configuration Metallic Ions toward Photocatalytic Water Splitting under Visible Light44Artificial Photosynthesis for H2 Generation and CO2 Conversion0Band engineering of layered oxyhalide photocatalysts for visible-light water splitting42Recent advances and perspectives on iron-based photocatalysts63Z-scheme water splitting utilizing CuLi 1/3 Ti 2/3 O 2 as a hydrogen-evolving photocatalyst with photo-response up to 600 nm6Boosting Z-Scheme-Type Water Splitting by Controlling FeIII/FeII Redox Potential in Metal Hexacyanoferrate Modifiers Loaded on H2-Evolving Photocatalyst8Highly dispersed Fe–Ru dual cocatalysts derived from a Prussian blue analogue for boosting O 2 evolution on an oxyiodide photocatalyst0Interfacial heterophase BaTa 2 O 6 :N with spatial CoO x /Pt cocatalysts for stable water oxidation in pH-unadjusted Fe 3+ redox media toward solar energy storage1Vanadium-based oxyhalide photocatalysts for visible-light-driven Z-scheme water splitting: advancing conduction band engineering0Flux Synthesis of Sillén–Aurivillius Oxyiodide for Visible Light Water Splitting Photocatalysis12Magnetically Enhanced Electrodes for Oxygen Evolution Reaction Using Ruthenium–Iron Oxide Nanocomposites2Core–Shell Structured Cocatalysts for Enhancing Redox-Mediated Z-Scheme Photocatalytic Water Splitting and Producing H2 and O2 Separately16Phase-Migrating Z-Scheme Charge Transportation Enables Photoredox Catalysis Harnessing Water as an Electron Source9Enhanced Photocatalytic O2 Evolution over Layered Perovskite Oxyiodide Ba2Bi3Nb2O11I through Flux Synthesis and Surface Modifications7Interface Engineering between Photocatalyst and Cocatalyst: A Strategy for Enhancing Interfacial Charge Transfer and Water Oxidation of Layered Oxyhalides22Doubling Charge Transport in Z‐Scheme Water Splitting: Di‐Vanadium‐Substituted Polyoxometalate as Shuttle Redox Mediator for Boosting Visible‐Light‐Induced Water Splitting1Bimetallic cocatalyst for synergistic enhancement of Bi4TaO8Cl/Ti3C2 −MXene@PtPd Ohm junctions photocatalytic hydrogen evolution performance16Self-regulating Electron Redistribution, by Ru and Fe Towards Optimal Electronic Structure of β-MnO2 for Oxygen Evolution Reaction in Alkaline Medium1Active control of forward/backward charge transfer in Z-scheme water splitting: manipulating electrostatic affinity/repulsion between photocatalyst surface and electron mediator2Polyoxometalate hole reservoir unlocks visible-light-driven overall water splitting with a single photocatalyst via external catalytic water oxidation1S-scheme Bi4TaO8Cl/g-C3N4 heterostructure accelerates photocatalytic CO2 reduction to CH3OH4Interfacial Electrostatic Interaction Overcomes Backward Electron Transfer without CrO x -Based Core–Shell Cocatalyst for Efficient Z-Scheme Water Splitting4

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  1. Hybrid cocatalysts in semiconductor-based photocatalysis and photoelectrocatalysis

    Journal of Materials Chemistry A · 2020-01-01

    Shuxian Zhong, Yamin Xi, Shijie Wu, Qian Liu, Leihong Zhao, Song Bai

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  2. Photocatalytic Oxygen Evolution from Water Splitting

    Advanced Science · 2020-11-18

    Sen Lin, Hongwei Huang, Tianyi Ma, Yihe Zhang

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  3. A new lead-free Sillén–Aurivillius oxychloride Bi5SrTi3O14Cl with triple-perovskite layers for photocatalytic water splitting under visible light

    Journal of Photochemistry and Photobiology A Chemistry · 2020-12-10

    Daichi Ozaki, Hajime Suzuki, Osamu Tomita, Yoshiyuki Inaguma, Kouichi Nakashima, Hiroshi Kageyama, Ryu Abe

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  4. Particulate photocatalytic reactors with spectrum-splitting function for artificial photosynthesis

    Physical Chemistry Chemical Physics · 2021-01-01

    Yasuhiko Takeda, Tomiko M. Suzuki, Shunsuke Sato, Takeshi Morikawa

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  5. Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis

    Journal of the American Chemical Society · 2021-01-08

    Akinobu Nakada, Daichi Kato, Ryky Nelson, Hikaru Takahira, Masayoshi Yabuuchi, Masanobu Higashi, Hajime Suzuki, Maria A. Kirsanova, Naoji Kakudou, Cédric Tassel, Takafumi Yamamoto, Craig M. Brown, Richard Dronskowski, Akinori Saeki, Artem M. Abakumov, Hiroshi Kageyama, Ryu Abe

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  6. Z-Scheme Overall Water Splitting Using ZnxCd1–xSe Particles Coated with Metal Cyanoferrates as Hydrogen Evolution Photocatalysts

    ACS Catalysis · 2021-06-17

    Yosuke Kageshima, Yui Gomyo, Hikaru Matsuoka, Hiroto Inuzuka, Hajime Suzuki, Ryu Abe, Katsuya Teshima, Kazunari Domen, Hiromasa Nishikiori

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  7. Crystal Facet-Dependent Intrinsic Charge Separation on Well-Defined Bi 4 TaO 8 Cl Nanoplate for Efficient Photocatalytic Water Oxidation

    Energy Material Advances · 2022-01-01

    Abraham Adenle, Ming Shi, Xiaoping Tao, Yüe Zhao, Bin Zeng, Na Ta, Rengui Li

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  8. Light-induced electron transfer/phase migration of a redox mediator for photocatalytic C–C coupling in a biphasic solution

    Dalton Transactions · 2022-01-01

    Ren Itagaki, Shin‐ya Takizawa, Ho‐Chol Chang, Akinobu Nakada

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  9. Water oxidation of visible-light-responsive bismuth-yttrium oxychloride promoted by a dual-ion doping strategy for assembly of Z-scheme overall water splitting

    Journal of Materials Chemistry A · 2022-01-01

    Mingxu Hu, Shiwen Du, Beibei Dong, Yu Qi, Zhaochi Feng, Fuxiang Zhang

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  10. Electronic Engineering of ABO3 Perovskite Metal Oxides Based on d0 Electronic‐Configuration Metallic Ions toward Photocatalytic Water Splitting under Visible Light

    Small Structures · 2022-02-22

    Yunfeng Bao, Fuxiang Zhang

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  11. Artificial Photosynthesis for H2 Generation and CO2 Conversion

    Journal of The Surface Finishing Society of Japan · 2023-12-01

    Ryu Abe, Akinobu Nakada, Hajime Suzuki

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  12. Band engineering of layered oxyhalide photocatalysts for visible-light water splitting

    Chemical Science · 2024-01-01

    Daichi Kato, Hajime Suzuki, Ryu Abe, Hiroshi Kageyama

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  13. Recent advances and perspectives on iron-based photocatalysts

    Journal of Materials Chemistry C · 2024-01-01

    Nayab Arif, Muhammad Nadeem Zafar, Maria Batool, Muhammad Humayun, Muhammad Ahsan Iqbal, Muhammad Younis, Luyan Li, Kui Li, Y. J. Zeng

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  14. Z-scheme water splitting utilizing CuLi 1/3 Ti 2/3 O 2 as a hydrogen-evolving photocatalyst with photo-response up to 600 nm

    Sustainable Energy & Fuels · 2024-01-01

    Shunya Yoshino, Tanya Kurutach, Qingshan Liu, Toshiki Yamanaka, Shunsuke Nozawa, Makoto Kobayashi, Hiromu Kumagai, Hideki Kato

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  15. Boosting Z-Scheme-Type Water Splitting by Controlling FeIII/FeII Redox Potential in Metal Hexacyanoferrate Modifiers Loaded on H2-Evolving Photocatalyst

    ACS Materials Letters · 2024-05-21

    Harutaka Ninomiya, Osamu Tomita, Hajime Suzuki, Akinobu Nakada, Ryu Abe

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  16. Highly dispersed Fe–Ru dual cocatalysts derived from a Prussian blue analogue for boosting O 2 evolution on an oxyiodide photocatalyst

    Chemical Communications · 2025-01-01

    Reiya Takahashi, Hajime Suzuki, Harutaka Ninomiya, Makoto Ogawa, Osamu Tomita, Akinobu Nakada, Shunsuke Nozawa, Akinori Saeki, Ryu Abe

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  17. Interfacial heterophase BaTa 2 O 6 :N with spatial CoO x /Pt cocatalysts for stable water oxidation in pH-unadjusted Fe 3+ redox media toward solar energy storage

    Journal of Materials Chemistry A · 2025-01-01

    Danfeng Xiao, Huihui Li, Hao Fu, Xiaofei Chen, Zelong Li, Yuhua Wang

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  18. Vanadium-based oxyhalide photocatalysts for visible-light-driven Z-scheme water splitting: advancing conduction band engineering

    Journal of Materials Chemistry A · 2025-01-01

    Hajime Suzuki, Ryuki Tomita, Yusuke Ishii, Osamu Tomita, Akinobu Nakada, Akinori Saeki, Ryu Abe

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  19. Flux Synthesis of Sillén–Aurivillius Oxyiodide for Visible Light Water Splitting Photocatalysis

    Chemistry of Materials · 2025-01-21

    Makoto Ogawa, Hajime Suzuki, Kanta Ogawa, Hiroki Ubukata, Osamu Tomita, Akinobu Nakada, Shunsuke Nozawa, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

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  20. Magnetically Enhanced Electrodes for Oxygen Evolution Reaction Using Ruthenium–Iron Oxide Nanocomposites

    ACS Applied Nano Materials · 2025-02-10

    Miguel D. R. Junior, Artur Luís Hennemann, Luca M. Sihn, Marcelo Nakamura, Kalil Cristhian Figueiredo Toledo, Henrique E. Toma, Fernando Menegatti de Melo

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  21. Core–Shell Structured Cocatalysts for Enhancing Redox-Mediated Z-Scheme Photocatalytic Water Splitting and Producing H2 and O2 Separately

    ACS Catalysis · 2025-03-07

    Hajime Suzuki, Yuya Okada, Suguru Kise, Xinru Sui, Shunsuke Nozawa, Osamu Tomita, Ryu Abe

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  22. Phase-Migrating Z-Scheme Charge Transportation Enables Photoredox Catalysis Harnessing Water as an Electron Source

    Journal of the American Chemical Society · 2025-04-19

    Ren Itagaki, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Ho‐Chol Chang, Ryu Abe

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  23. Enhanced Photocatalytic O2 Evolution over Layered Perovskite Oxyiodide Ba2Bi3Nb2O11I through Flux Synthesis and Surface Modifications

    Inorganic Chemistry · 2025-04-25

    Reiya Takahashi, Makoto Ogawa, Hajime Suzuki, Osamu Tomita, Akinobu Nakada, Shunsuke Nozawa, Akinori Saeki, Ryu Abe

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  24. Interface Engineering between Photocatalyst and Cocatalyst: A Strategy for Enhancing Interfacial Charge Transfer and Water Oxidation of Layered Oxyhalides

    Journal of the American Chemical Society · 2025-06-19

    Hajime Suzuki, Kengo Minamimoto, Yusuke Ishii, Osamu Tomita, Akinobu Nakada, Shunsuke Nozawa, Akira Yamakata, Ryu Abe

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  25. Doubling Charge Transport in Z‐Scheme Water Splitting: Di‐Vanadium‐Substituted Polyoxometalate as Shuttle Redox Mediator for Boosting Visible‐Light‐Induced Water Splitting

    Advanced Functional Materials · 2025-07-22

    Osamu Tomita, Kento Tachizawa, Takuro Kido, Hajime Suzuki, Akinobu Nakada, Ryu Abe

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  26. Bimetallic cocatalyst for synergistic enhancement of Bi4TaO8Cl/Ti3C2 −MXene@PtPd Ohm junctions photocatalytic hydrogen evolution performance

    Separation and Purification Technology · 2025-09-10

    Qi Zhuang He, Kailong Gao, Kailong Gao, Peigen Ding, Liuna Zhang, Jiarui Yang, Xiaoming Gao, Xuan Jian

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  27. Self-regulating Electron Redistribution, by Ru and Fe Towards Optimal Electronic Structure of β-MnO2 for Oxygen Evolution Reaction in Alkaline Medium

    Catalysis Letters · 2025-12-18

    B. N. Divya, P. Shiva Keshava Kumar, H. M. Veereshappa, S. Mahima, K.S. Manjunatha Kumara, Srinivasa Budagumpi, D. H. Nagaraju

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  28. Active control of forward/backward charge transfer in Z-scheme water splitting: manipulating electrostatic affinity/repulsion between photocatalyst surface and electron mediator

    Chemical Science · 2026-01-01

    Ren Itagaki, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Ryu Abe

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  29. Polyoxometalate hole reservoir unlocks visible-light-driven overall water splitting with a single photocatalyst via external catalytic water oxidation

    Chemical Science · 2026-01-01

    Harutaka Ninomiya, Osamu Tomita, Hajime Suzuki, Akinobu Nakada, Rie Haruki, Shunsuke Nozawa, Ryu Abe

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  30. S-scheme Bi4TaO8Cl/g-C3N4 heterostructure accelerates photocatalytic CO2 reduction to CH3OH

    Colloids and Surfaces A Physicochemical and Engineering Aspects · 2026-01-06

    Yating Zhang, Liang Dai, Xin Wang, Jia Jia, Keke Li, Chen Meng, Qiang Zhang, Jianglong Mu, Yuling Song

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  31. Interfacial Electrostatic Interaction Overcomes Backward Electron Transfer without CrO x -Based Core–Shell Cocatalyst for Efficient Z-Scheme Water Splitting

    Journal of the American Chemical Society · 2026-02-16

    Ren Itagaki, Akinobu Nakada, Hajime Suzuki, Osamu Tomita, Ryu Abe

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