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RESEARCH PAPER · Chemistry of Materials · 2014

High-Pressure Synthesis of A-Site Ordered Double Perovskite CaMnTi2O6 and Ferroelectricity Driven by Coupling of A-Site Ordering and the Second-Order Jahn–Teller Effect

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High-Pressure Synthesis of A-Site Ordered Double Perovskite CaMnTi2O6 and Ferroelectricity Driven by Coupling of A-Site Ordering and the Second-Order Jahn–Teller EffectOriginalChemInform Abstract: High‐Pressure Synthesis of A‐Site Ordered Double Perovskite CaMnTi2O6 and Ferroelectricity Driven by Coupling of A‐Site Ordering and the Second‐Order Jahn—Teller Effect.0Synthesis, structure and dielectric properties of new ordering perovskites LnPbMgSbO 6 (Ln = La, Pr, Nd)6Atomic-scale control of TiO6 octahedra through solution chemistry towards giant dielectric response94High pressure and multiferroics materials: a happy marriage52Synthesis, structures and magnetic properties of the dimorphic Mn 2 CrSbO 6 oxide48Linear coordination polymers based on aluminum phosphates: synthesis, crystal structure and morphology7Double Double Cation Order in the High‐Pressure Perovskites MnRMnSbO668Double Double Cation Order in the High‐Pressure Perovskites MnRMnSbO68Characterization of Ordering in A-Site Deficient Perovskite Ca1– x La2 x /3TiO3 Using STEM/EELS16High‐Pressure Synthesis and Magnetic Behavior of A‐Site Columnar‐Ordered Double Perovskites, LnMn(Ga0.5Ti0.5)2O6 (Ln = Sm, Gd)13Unprecedented phase transition sequence in the perovskite Li0.2Na0.8NbO312Five-Fold Ordering in High-Pressure Perovskites RMn3O6 (R = Gd–Tm and Y)36High‐Pressure Perovskite: Synthesis, Structure, and Phase Relation5Ambient-temperature high-pressure-induced ferroelectric phase transition in CaMnTi2O618A ‑Site Ordered Double Perovskite CaMnTi2O6 as a Multifunctional Piezoelectric and Ferroelectric–Photovoltaic Material80Complex Ferrimagnetism and Magnetoresistance Switching in Ca-Based Double Double and Triple Double Perovskites34Pr 2 FeCrO 6 : A Type I Multiferroic79[Am]Mn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand86An overview of double perovskites A2B′B″O6 with small ions at A site: Synthesis, structure and magnetic properties206Broad-band emission of A 3 B′B′′ 2 O 9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder14Rise of A-site columnar-ordered A 2 A′A′′B 4 O 12 quadruple perovskites with intrinsic triple order52New Mechanism for Ferroelectricity in the Perovskite Ca 2– x Mn x Ti 2 O 6 Synthesized by Spark Plasma Sintering45Improper ferroelectric polarization in a perovskite driven by intersite charge transfer and ordering23Nonswitchable polarization and magnetoelectric coupling in the high-pressure synthesized doubly ordered perovskites NaYMnWO6 and NaHoCoWO636Magnetic and electronic properties of the ferroelectric-photovoltaic ordered double perovskite CaMnTi2O6 investigated by x-ray absorption spectroscopies12Intrinsic Triple Order in A‐site Columnar‐Ordered Quadruple Perovskites: Proof of Concept22A group-theoretical approach to enumerating magnetoelectric and multiferroic couplings in perovskites39Spin freezing into a disordered state in CaFeTi2O6 synthesized under high pressure5The new ordered double perovskite SrLaCuIrO611Ferri- and ferro-magnetism in CaMnMReO 6 double double perovskites of late transition metals M = Co and Ni26Valence Variations by B-Site Doping in A-Site Columnar-Ordered Quadruple Perovskites Sm2MnMn(Mn4–xTix)O12 with 1 ≤ x ≤ 320Tuning of multiferroic order with Co doping in CuCr2O4 : Interplay between structure and orbital order15Calculation and Comparison of Electronic, Vibrational, Polarization, and Magnetic Properties of Double Perovskites CaMnTi2O6 and CaFeTi2O61Development of an Automatic, High-Throughput Structural Refinement Method Using Rietveld Analysis28Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure9Solid-state crystal growth of lead-free ferroelectrics49Above-Room-Temperature LiNbO3-Type Polar Magnet Stabilized by Chemical and Physical Pressure10Electronic structure and x-ray magnetic circular dichroism in ferroelectric CaMnTi2O65High-Pressure Synthesis, Crystal Structures, and Properties of A‑Site Columnar-Ordered Quadruple Perovskites NaRMn2Ti4O12 with R = Sm, Eu, Gd, Dy, Ho, Y13Enhanced Spontaneous Polarization by V4+ Substitution in a Lead-Free Perovskite CaMnTi2O67Charge Disproportionation and Complex Magnetism in a PbMnO3 Perovskite Synthesized under High Pressure9Ferrimagnetic and relaxor ferroelectric properties of R 2 MnMn(MnTi 3 )O 12 perovskites with R = Nd, Eu, and Gd11A combinatory ferroelectric compound bridging simple ABO3 and A-site-ordered quadruple perovskite117Doubling the Stakes: The Promise of Halide Double Perovskites159Doubling the Stakes: The Promise of Halide Double Perovskites55Effect of B-Site Order–Disorder in the Structure and Magnetism of the New Perovskite Family La2MnB′O6 with B′ = Ti, Zr, and Hf13Double Double to Double Perovskite Transformations in Quaternary Manganese Oxides25Double Double to Double Perovskite Transformations in Quaternary Manganese Oxides2Pressure Dependence of Structural Behavior and Electronic Properties in Double Perovskite Ba 2 SmSbO 69Structural principles of cation ordering and octahedral tilting in A-site ordered double perovskites: ferroelectric CaMnTi 2 O 6 as a model system19Modulation of ionic arrangement in polar magnet by chemical pressure2Linear dichroism and polarization controllable persistent spin helix in two-dimensional ferroelectric ZrOI2 monolayer17Double and double double perovskites in the RMnMnTaO6 series11High-pressure A-site manganites: Structures and magnetic properties11Triple A-Site Cation Ordering in the Ferrimagnetic Y2CuGaMn4O12 Perovskite14High pressure studies of transition metal oxides5Dielectric and Spin-Glass Magnetic Properties of the A-Site Columnar-Ordered Quadruple Perovskite Sm2CuMn(MnTi3)O125CaFeFeNbO 6 – an iron-based double double perovskite16An overview of the recent developments in the structural correlation of magnetic and electrical properties of PrNiMnO double perovskite28Hydrogen anion as a strong magnetic mediator for obtaining high-temperature ferromagnetic semiconductors: The case of hydride double perovskites10A-Site Columnar-Ordered Perovskite CaZnV2O6 as a Pauli-Paramagnetic Metal2Hybrid Improper Ferroelectricity in Columnar (NaY)MnMnTi4O125Hybrid Improper Ferroelectricity in Columnar (NaY)MnMnTi4O120Switching of Hybrid Improper Ferroelectricity in Oxide Double Perovskites9Room temperature magnetoelectric effect in Sr2FeNbO6 perovskite: A theory supported experimental investigation10High-pressure synthesis of half-doped perovskites MnV 0.5 Nb 0.5 O 3 and MnV 0.5 Ta 0.5 O 3 with unusual A-site small Mn 2+ cations0Anisotropic Thermal Expansion and a Second-Order Charge Order Transition in the Ferrimagnetic Dy2CuZnMn4O12 Perovskite with Triple A-Site Cation Ordering3Centrosymmetric to non-centrosymmetric transition in the Ca 2− x Mn x Ti 2 O 6 double perovskite system studied through structural analysis and dielectric properties1Diffuse Ferroelectricity and Atypical Magnetism in Quadruple Perovskite Oxide Bi2/3Sr1.5Ba1.5 Ti4O120Research progress on quadruple perovskite oxides16Ferroelectric anomaly of perovskite layer structured Pb 2+ ‐doped Sr 2 Nb 2 O 7 ceramics2Magnetism in Cation-Ordered Multicomponent Oxide Perovskites2Data-driven physics-informed descriptors of cation ordering in multicomponent perovskite oxides17(Ca0.5Mn0.5)2MnTeO6 – An Anomalously Stable High‐Pressure Double Perovskite2Design of magnetic polar double-double perovskite oxides through cation ordering3Near zero thermal expansion and electrocatalysis for quadruple perovskite oxides CaCu3Fe4−xMnxO123Effect of structural, magnetic, magnetocaloric, and electrical polarization properties for multiferroic double perovskite Lu2CoCrO6 compound6Metal-Ordered Arsenides M2MnAs3 (M = Zr, Hf) with a NaCl/NiAs Intergrowth Structure0Low‐Temperature Single‐Crystal Structure and Phonon Properties of A‐Site Ordered Double Perovskite CaMnTi 2 O 62Jahn–Teller distortion induced two-dimensional ferroelasticity in Mn 2 CuO 6 monolayers with antiferromagnetic ordering2Intrinsic electronic phase separation and competition between G -type, C -type, and C E -type charge and orbital ordering modes in Hg 1 − x Na x Mn 3 Mn 4 O 123Strategies for obtaining CaMn3Ti4O12-related materials and enhancing intrinsic dielectric constant of such A-site-ordered quadruple perovskites0Emergence of insulating ferro- and ferrimagnetism with enhanced optical properties in double-double perovskite oxides1Cryogenic magnetocaloric properties of zinc-based perovskite Nd2ZnZn(Zn2Sb2)O12 with A-site columnar-type and B-site rock-salt-type orders2Recent advances in quadruple perovskite oxide-based electrocatalysts for oxygen evolution reactions: a review2Stabilization of high-pressure metastable states by chemical approaches0Octahedral-rigidity-engineered linear dielectrics for harsh-temperature energy storage capacitors2Emergent in-plane polar vortex state in a perovskite superlattice0Review on the applications of perovskite oxides in hydrogen storage and batteries1Automation of Rietveld Analysis for the Reduction of Analytical Bias and High-throughput Analysis0

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  1. ChemInform Abstract: High‐Pressure Synthesis of A‐Site Ordered Double Perovskite CaMnTi2O6 and Ferroelectricity Driven by Coupling of A‐Site Ordering and the Second‐Order Jahn—Teller Effect.

    ChemInform · 2014-06-26

    Akihisa Aimi, Daisuke Mori, K. Hiraki, Toshihiro Takahashi, Yue Jin Shan, Yuichi Shirako, Jianshi Zhou, Yoshiyuki Inaguma

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  2. Synthesis, structure and dielectric properties of new ordering perovskites LnPbMgSbO 6 (Ln = La, Pr, Nd)

    Solid State Sciences · 2014-07-18

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  3. Atomic-scale control of TiO6 octahedra through solution chemistry towards giant dielectric response

    Scientific Reports · 2014-10-10

    Wanbiao Hu, Liping Li, Guangshe Li, Yun Liu, Ray Leslie Withers

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  4. High pressure and multiferroics materials: a happy marriage

    IUCrJ · 2014-10-31

    E. Gilioli, Lars Ehm

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  5. Synthesis, structures and magnetic properties of the dimorphic Mn 2 CrSbO 6 oxide

    Dalton Transactions · 2015-01-01

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  6. Linear coordination polymers based on aluminum phosphates: synthesis, crystal structure and morphology

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  7. Double Double Cation Order in the High‐Pressure Perovskites MnRMnSbO6

    Angewandte Chemie International Edition · 2016-06-17

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  8. Double Double Cation Order in the High‐Pressure Perovskites MnRMnSbO6

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  9. Characterization of Ordering in A-Site Deficient Perovskite Ca1– x La2 x /3TiO3 Using STEM/EELS

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    Mohsen Danaie, Demie M. Kepaptsoglou, Quentin Mathieu Ramasse, Colin Ophus, Karl Rhys Whittle, Sebastian M. Lawson, S. Pedrazzini, Neil P. Young, Paul A.J. Bagot, Philip D. Edmondson

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  10. High‐Pressure Synthesis and Magnetic Behavior of A‐Site Columnar‐Ordered Double Perovskites, LnMn(Ga0.5Ti0.5)2O6 (Ln = Sm, Gd)

    European Journal of Inorganic Chemistry · 2017-01-06

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  11. Unprecedented phase transition sequence in the perovskite Li0.2Na0.8NbO3

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  12. Five-Fold Ordering in High-Pressure Perovskites RMn3O6 (R = Gd–Tm and Y)

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  13. High‐Pressure Perovskite: Synthesis, Structure, and Phase Relation

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  14. Ambient-temperature high-pressure-induced ferroelectric phase transition in CaMnTi2O6

    Physical review. B./Physical review. B · 2017-09-05

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  15. A ‑Site Ordered Double Perovskite CaMnTi2O6 as a Multifunctional Piezoelectric and Ferroelectric–Photovoltaic Material

    Inorganic Chemistry · 2017-09-11

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  16. Complex Ferrimagnetism and Magnetoresistance Switching in Ca-Based Double Double and Triple Double Perovskites

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  17. Pr 2 FeCrO 6 : A Type I Multiferroic

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  18. [Am]Mn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand

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  19. An overview of double perovskites A2B′B″O6 with small ions at A site: Synthesis, structure and magnetic properties

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  20. Broad-band emission of A 3 B′B′′ 2 O 9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder

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  21. Rise of A-site columnar-ordered A 2 A′A′′B 4 O 12 quadruple perovskites with intrinsic triple order

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  22. New Mechanism for Ferroelectricity in the Perovskite Ca 2– x Mn x Ti 2 O 6 Synthesized by Spark Plasma Sintering

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  23. Improper ferroelectric polarization in a perovskite driven by intersite charge transfer and ordering

    Physical review. B./Physical review. B · 2018-04-05

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  24. Nonswitchable polarization and magnetoelectric coupling in the high-pressure synthesized doubly ordered perovskites NaYMnWO6 and NaHoCoWO6

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  25. Magnetic and electronic properties of the ferroelectric-photovoltaic ordered double perovskite CaMnTi2O6 investigated by x-ray absorption spectroscopies

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  26. Intrinsic Triple Order in A‐site Columnar‐Ordered Quadruple Perovskites: Proof of Concept

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  27. A group-theoretical approach to enumerating magnetoelectric and multiferroic couplings in perovskites

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  28. Spin freezing into a disordered state in CaFeTi2O6 synthesized under high pressure

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  29. The new ordered double perovskite SrLaCuIrO6

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  30. Ferri- and ferro-magnetism in CaMnMReO 6 double double perovskites of late transition metals M = Co and Ni

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  31. Valence Variations by B-Site Doping in A-Site Columnar-Ordered Quadruple Perovskites Sm2MnMn(Mn4–xTix)O12 with 1 ≤ x ≤ 3

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  32. Tuning of multiferroic order with Co doping in CuCr2O4 : Interplay between structure and orbital order

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  33. Calculation and Comparison of Electronic, Vibrational, Polarization, and Magnetic Properties of Double Perovskites CaMnTi2O6 and CaFeTi2O6

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  34. Development of an Automatic, High-Throughput Structural Refinement Method Using Rietveld Analysis

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  37. Above-Room-Temperature LiNbO3-Type Polar Magnet Stabilized by Chemical and Physical Pressure

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  39. High-Pressure Synthesis, Crystal Structures, and Properties of A‑Site Columnar-Ordered Quadruple Perovskites NaRMn2Ti4O12 with R = Sm, Eu, Gd, Dy, Ho, Y

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  40. Enhanced Spontaneous Polarization by V4+ Substitution in a Lead-Free Perovskite CaMnTi2O6

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  41. Charge Disproportionation and Complex Magnetism in a PbMnO3 Perovskite Synthesized under High Pressure

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  42. Ferrimagnetic and relaxor ferroelectric properties of R 2 MnMn(MnTi 3 )O 12 perovskites with R = Nd, Eu, and Gd

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  44. Doubling the Stakes: The Promise of Halide Double Perovskites

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  45. Doubling the Stakes: The Promise of Halide Double Perovskites

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  46. Effect of B-Site Order–Disorder in the Structure and Magnetism of the New Perovskite Family La2MnB′O6 with B′ = Ti, Zr, and Hf

    Inorganic Chemistry · 2021-03-11

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  47. Double Double to Double Perovskite Transformations in Quaternary Manganese Oxides

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  48. Double Double to Double Perovskite Transformations in Quaternary Manganese Oxides

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  49. Pressure Dependence of Structural Behavior and Electronic Properties in Double Perovskite Ba 2 SmSbO 6

    The Journal of Physical Chemistry C · 2021-11-08

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  50. Structural principles of cation ordering and octahedral tilting in A-site ordered double perovskites: ferroelectric CaMnTi 2 O 6 as a model system

    Dalton Transactions · 2022-01-01

    Elisabeth K. Albrecht, Antti J. Karttunen

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