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RESEARCH PAPER · Inorganic Chemistry · 2017

Five-Fold Ordering in High-Pressure Perovskites RMn3O6 (R = Gd–Tm and Y)

Lei Zhang, Yoshitaka Matsushita, Kazunari Yamaura, Alexei А. Belik

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Five-Fold Ordering in High-Pressure Perovskites RMn3O6 (R = Gd–Tm and Y)OriginalStructural and Magnetic Transitions in CaCo3V4O12 Perovskite at Extreme Conditions13Complex Ferrimagnetism and Magnetoresistance Switching in Ca-Based Double Double and Triple Double Perovskites34Rise of A-site columnar-ordered A 2 A′A′′B 4 O 12 quadruple perovskites with intrinsic triple order52Mn Self-Doping of Orthorhombic RMnO3 Perovskites: (R0.667Mn0.333)MnO3 with R = Er–Lu17High-Pressure Synthesis, Structures, and Properties of Trivalent A-Site-Ordered Quadruple Perovskites RMn7O12 (R = Sm, Eu, Gd, and Tb)26Intrinsic Triple Order in A‐site Columnar‐Ordered Quadruple Perovskites: Proof of Concept22Displacive structural phase transitions and the magnetic ground state of quadruple perovskite YMn7O1214Valence Variations by B-Site Doping in A-Site Columnar-Ordered Quadruple Perovskites Sm2MnMn(Mn4–xTix)O12 with 1 ≤ x ≤ 320Magnetic structure and spin-flop transition in the A -site columnar-ordered quadruple perovskite TmMn3O619Crystal structures of cation non-stoichiometric RMn3O6 (R = Gd, Er, and Tm) manganites belonging to A-site columnar-ordered quadruple perovskite family6Centrosymmetry Breaking and Ferroelectricity Driven by Short-Range Magnetic Order in the Quadruple Perovskite (YMn 3 )Mn 4 O 1212Spin-Glass Magnetic Properties of A-Site Columnar-Ordered Quadruple Perovskites Y2MnGa(Mn4–xGax)O12 with 0 ≤ x ≤ 311Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure9Spontaneous Rotation of Ferrimagnetism Driven by Antiferromagnetic Spin Canting29High-Pressure Synthesis, Crystal Structures, and Properties of A‑Site Columnar-Ordered Quadruple Perovskites NaRMn2Ti4O12 with R = Sm, Eu, Gd, Dy, Ho, Y13Magnetic properties and ferrimagnetic structures of Mn self-doped perovskite solid solutions (Ho1−xMnx)MnO38Effects of magnetic dilution in the ferrimagnetic columnar ordered Sm2MnMnMn4−xTixO12 perovskites8A plethora of structural transitions, distortions and modulations in Cu-doped BiMn 7 O 12 quadruple perovskites7Structural Stability and Properties of Marokite-Type γ-Mn3O411Synthesis of Ilmenite-type ε-Mn2O3 and Its Properties10Improving carrier separation at the TiO 2 /CsPbIBr 2 interface by gradient Sn-doping1Triple A-Site Cation Ordering in the Ferrimagnetic Y2CuGaMn4O12 Perovskite14High pressure studies of transition metal oxides5Dielectric and Spin-Glass Magnetic Properties of the A-Site Columnar-Ordered Quadruple Perovskite Sm2CuMn(MnTi3)O125CaFeFeNbO 6 – an iron-based double double perovskite16Realization of triple A-site cation ordering through the Dy/Mn/Zn combination in the ferrimagnetic Dy2MnZnMn4−Ti O12 perovskites7Magnetic inhomogeneities in the quadruple perovskite manganite [Y2−xMnx]Mn6O122Anisotropic Thermal Expansion and a Second-Order Charge Order Transition in the Ferrimagnetic Dy2CuZnMn4O12 Perovskite with Triple A-Site Cation Ordering3Gd2CuZnMn4O12: A-site columnar-ordered perovskite with anisotropic thermal expansion and a gradual charge-order transition1Research progress on quadruple perovskite oxides16Near zero thermal expansion and electrocatalysis for quadruple perovskite oxides CaCu3Fe4−xMnxO123Ferrimagnetic structures with rare-earth induced spin-reorientation in the Mn self-doped perovskite (Er0.7Mn0.3)MnO31Negative Magnetization Phenomena in A-Site Columnar-Ordered Quadruple Perovskites Ce2MnM(Mn2Sb2)O12 with M = Mn and Zn1Critical role of magnetic rare-earth cations in enhancing magnetic transition temperatures of A-site columnar-ordered quadruple perovskites R2MnZn(MnZnSb2)O12 with R = La, Pr, Nd, and Sm1Magnetic Structures and Magnetic Phase Diagram of the Mixed-Valence Iron Phosphate Fe 7 (PO 4 ) 60

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  1. Structural and Magnetic Transitions in CaCo3V4O12 Perovskite at Extreme Conditions

    Inorganic Chemistry · 2017-05-18

    Sergey V. Ovsyannikov, Elena A. Bykova, Anna Pakhomova, Denis P. Kozlenko, Maxim Bykov, Sergey E. Kichanov, Natalia V. Morozova, Igor V. Korobeinikov, F. Wilhelm, Andreï Rogalev, Alexander A. Tsirlin, Alexander Kurnosov, Yury G. Zainulin, Nadezda I. Kadyrova, Alexander P. Tyutyunnik, Leonid Dubrovinsky

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  2. Complex Ferrimagnetism and Magnetoresistance Switching in Ca-Based Double Double and Triple Double Perovskites

    Chemistry of Materials · 2017-09-25

    Graham McNally, Ángel M. Arévalo‐López, Padraig S. Kearins, Fabio Orlandi, Pascal Manuel, John Paul Attfield

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  3. Rise of A-site columnar-ordered A 2 A′A′′B 4 O 12 quadruple perovskites with intrinsic triple order

    Dalton Transactions · 2018-01-01

    Alexei А. Belik

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  4. Mn Self-Doping of Orthorhombic RMnO3 Perovskites: (R0.667Mn0.333)MnO3 with R = Er–Lu

    Inorganic Chemistry · 2018-02-12

    Lei Zhang, D Gerlach, Andreas Dönni, Toyohiro Chikyow, Yoshio Katsuya, Masahiko Tanaka, Shigenori Ueda, Kazunari Yamaura, Alexei А. Belik

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  5. High-Pressure Synthesis, Structures, and Properties of Trivalent A-Site-Ordered Quadruple Perovskites RMn7O12 (R = Sm, Eu, Gd, and Tb)

    Inorganic Chemistry · 2018-05-03

    Lei Zhang, Noriki Terada, JOHNSON Roger Douglas, Dmitry D. Khalyavin, Pascal Manuel, Yoshio Katsuya, Masahiko Tanaka, Yoshitaka Matsushita, Kazunari Yamaura, Alexei А. Belik

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  6. Intrinsic Triple Order in A‐site Columnar‐Ordered Quadruple Perovskites: Proof of Concept

    ChemPhysChem · 2018-06-25

    Alexei А. Belik, Dmitry D. Khalyavin, Lei Zhang, Yoshitaka Matsushita, Yoshio Katsuya, Masahiko Tanaka, JOHNSON Roger Douglas, Kazunari Yamaura

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  7. Displacive structural phase transitions and the magnetic ground state of quadruple perovskite YMn7O12

    Physical review. B./Physical review. B · 2019-01-16

    JOHNSON Roger Douglas, Dmitry D. Khalyavin, Pascal Manuel, Yoshio Katsuya, M. M. Tanaka, Yoshitaka Matsushita, Ling Zhang, Kazunari Yamaura, Alexei А. Belik

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  8. Valence Variations by B-Site Doping in A-Site Columnar-Ordered Quadruple Perovskites Sm2MnMn(Mn4–xTix)O12 with 1 ≤ x ≤ 3

    Inorganic Chemistry · 2019-02-15

    Alexei А. Belik, Lei Zhang, Ran Liu, Dmitry D. Khalyavin, Yoshio Katsuya, Masahiko Tanaka, Kazunari Yamaura

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  9. Magnetic structure and spin-flop transition in the A -site columnar-ordered quadruple perovskite TmMn3O6

    Physical review. B./Physical review. B · 2019-03-21

    Anuradha M. Vibhakar, Dmitry D. Khalyavin, Pascal Manuel, Ling Zhang, Kazunari Yamaura, Paolo G. Radaelli, Alexei А. Belik, JOHNSON Roger Douglas

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  10. Crystal structures of cation non-stoichiometric RMn3O6 (R = Gd, Er, and Tm) manganites belonging to A-site columnar-ordered quadruple perovskite family

    Journal of Solid State Chemistry · 2019-04-03

    Alexei А. Belik, Lei Zhang, Yoshitaka Matsushita, Yoshio Katsuya, Masahiko Tanaka, Kazunari Yamaura

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  11. Centrosymmetry Breaking and Ferroelectricity Driven by Short-Range Magnetic Order in the Quadruple Perovskite (YMn 3 )Mn 4 O 12

    Inorganic Chemistry · 2019-10-08

    Marine Verseils, Francesco Mezzadri, Davide Delmonte, Riccardo Cabassi, Benoı̂t Baptiste, Yannick Klein, G. Calestani, F. Bolzoni, E. Gilioli, Andrea Gauzzi

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  12. Spin-Glass Magnetic Properties of A-Site Columnar-Ordered Quadruple Perovskites Y2MnGa(Mn4–xGax)O12 with 0 ≤ x ≤ 3

    Inorganic Chemistry · 2019-10-22

    Ran Liu, Dmitry D. Khalyavin, Naoki Tsunoda, Yu Kumagai, Fumiyasu Oba, Yoshio Katsuya, Masahiko Tanaka, Kazunari Yamaura, Alexei А. Belik

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  13. Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure

    Journal of Materials Chemistry C · 2020-01-01

    Yalin Ma, Мaxim S. Моlokeev, Chuanhui Zhu, Shuang Zhao, Yifeng Han, Meixia Wu, Sizhan Liu, Trevor A. Tyson, Mark Croft, Man‐Rong Li

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  14. Spontaneous Rotation of Ferrimagnetism Driven by Antiferromagnetic Spin Canting

    arXiv (Cornell University) · 2020-01-01

    Anuradha M. Vibhakar, Dmitry D. Khalyavin, Pascal Manuel, J. Liu, Alexei А. Belik, JOHNSON Roger Douglas

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  15. High-Pressure Synthesis, Crystal Structures, and Properties of A‑Site Columnar-Ordered Quadruple Perovskites NaRMn2Ti4O12 with R = Sm, Eu, Gd, Dy, Ho, Y

    Inorganic Chemistry · 2020-06-09

    Ran Liu, Rebecca Scatena, Dmitry D. Khalyavin, JOHNSON Roger Douglas, Yoshiyuki Inaguma, Masahiko Tanaka, Yoshitaka Matsushita, Kazunari Yamaura, Alexei А. Belik

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  16. Magnetic properties and ferrimagnetic structures of Mn self-doped perovskite solid solutions (Ho1−xMnx)MnO3

    Journal of Alloys and Compounds · 2020-12-13

    Andreas Dönni, Vladimir Pomjakushin, Lei Zhang, Kazunari Yamaura, Alexei А. Belik

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  17. Effects of magnetic dilution in the ferrimagnetic columnar ordered Sm2MnMnMn4−xTixO12 perovskites

    Physical review. B./Physical review. B · 2020-12-22

    Anuradha M. Vibhakar, Dmitry D. Khalyavin, Pascal Manuel, Ran Liu, Kazunari Yamaura, Alexei А. Belik, JOHNSON Roger Douglas

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  18. A plethora of structural transitions, distortions and modulations in Cu-doped BiMn 7 O 12 quadruple perovskites

    Journal of Materials Chemistry C · 2021-01-01

    Alexei А. Belik, Yoshitaka Matsushita, Masahiko Tanaka, JOHNSON Roger Douglas, Dmitry D. Khalyavin

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  19. Structural Stability and Properties of Marokite-Type γ-Mn3O4

    Inorganic Chemistry · 2021-08-16

    Sergey V. Ovsyannikov, Andrey Aslandukov, Andrey Aslandukov, Stella Chariton, Alexander A. Tsirlin, Igor V. Korobeinikov, Natalia V. Morozova, Timofey Fedotenko, Saiana Khandarkhaeva, Leonid Dubrovinsky

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  20. Synthesis of Ilmenite-type ε-Mn2O3 and Its Properties

    Inorganic Chemistry · 2021-08-20

    Sergey V. Ovsyannikov, Alexander A. Tsirlin, Igor V. Korobeinikov, Natalia V. Morozova, Andrey Aslandukov, Gerd Steinle‐Neumann, Stella Chariton, Saiana Khandarkhaeva, Konstantin V. Glazyrin, F. Wilhelm, Andreï Rogalev, Leonid Dubrovinsky

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  21. Improving carrier separation at the TiO 2 /CsPbIBr 2 interface by gradient Sn-doping

    Physical Chemistry Chemical Physics · 2022-01-01

    Yingfeng Li, Bingxin Wang, Yingjian Liu, Wenxiang Gao, Meicheng Li

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  22. Triple A-Site Cation Ordering in the Ferrimagnetic Y2CuGaMn4O12 Perovskite

    Inorganic Chemistry · 2022-08-31

    Alexei А. Belik, Dmitry D. Khalyavin, Yoshitaka Matsushita, Kazunari Yamaura

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  23. High pressure studies of transition metal oxides

    Elsevier eBooks · 2022-09-24

    Masaki Azuma, Ikuya Yamada, Kazunari Yamaura, Alexei А. Belik, Takafumi Yamamoto, Masayuki Fukuda

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  24. Dielectric and Spin-Glass Magnetic Properties of the A-Site Columnar-Ordered Quadruple Perovskite Sm2CuMn(MnTi3)O12

    Materials · 2022-11-23

    Alexei А. Belik, Ran Liu, Kazunari Yamaura

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  25. CaFeFeNbO 6 – an iron-based double double perovskite

    Chemical Communications · 2023-01-01

    Kunlang Ji, J. R. Bedward, Qingchan Li, Pascal Manuel, C. Ritter, John Paul Attfield

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  26. Realization of triple A-site cation ordering through the Dy/Mn/Zn combination in the ferrimagnetic Dy2MnZnMn4−Ti O12 perovskites

    Ceramics International · 2023-01-04

    Alexei А. Belik, Ran Liu, Kazunari Yamaura

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  27. Magnetic inhomogeneities in the quadruple perovskite manganite [Y2−xMnx]Mn6O12

    Physical review. B./Physical review. B · 2023-08-03

    Anuradha M. Vibhakar, Dmitry D. Khalyavin, Pascal Manuel, N. J. Steinke, Lei Zhang, Kazunari Yamaura, Alexei А. Belik, JOHNSON Roger Douglas

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  28. Anisotropic Thermal Expansion and a Second-Order Charge Order Transition in the Ferrimagnetic Dy2CuZnMn4O12 Perovskite with Triple A-Site Cation Ordering

    Inorganic Chemistry · 2023-11-27

    Alexei А. Belik

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  29. Gd2CuZnMn4O12: A-site columnar-ordered perovskite with anisotropic thermal expansion and a gradual charge-order transition

    Journal of Solid State Chemistry · 2024-01-01

    Alexei А. Belik

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  30. Research progress on quadruple perovskite oxides

    Journal of Materials Chemistry C · 2024-01-01

    Jie Feng Ding, Xinhua Zhu

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  31. Near zero thermal expansion and electrocatalysis for quadruple perovskite oxides CaCu3Fe4−xMnxO12

    Journal of the Ceramic Society of Japan · 2024-05-31

    Manami Goto, Ikuya Yamada, Shunsuke Yagi, Kenta Kimura

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  32. Ferrimagnetic structures with rare-earth induced spin-reorientation in the Mn self-doped perovskite (Er0.7Mn0.3)MnO3

    Ceramics International · 2024-08-12

    Andreas Dönni, Vladimir Pomjakushin, Martin Rotter, Lei Zhang, Kazunari Yamaura, Alexei А. Belik

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  33. Negative Magnetization Phenomena in A-Site Columnar-Ordered Quadruple Perovskites Ce2MnM(Mn2Sb2)O12 with M = Mn and Zn

    Inorganic Chemistry · 2025-05-16

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  34. Critical role of magnetic rare-earth cations in enhancing magnetic transition temperatures of A-site columnar-ordered quadruple perovskites R2MnZn(MnZnSb2)O12 with R = La, Pr, Nd, and Sm

    Journal of Alloys and Compounds · 2025-11-17

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  35. Magnetic Structures and Magnetic Phase Diagram of the Mixed-Valence Iron Phosphate Fe 7 (PO 4 ) 6

    Inorganic Chemistry · 2026-03-26

    Andreas Dönni, L. Keller, Vladimir Pomjakushin, Naohito Tsujii, Alexei А. Belik

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