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RESEARCH PAPER · Nanoscale · 2019

New lead-free perovskite Rb 7 Bi 3 Cl 16 nanocrystals with blue luminescence and excellent moisture-stability

Jie‐Ling Xie, Zhao‐Qian Huang, Bin Wang, Weijun Chen, Wen-Xiu Lu, Xin Liu, Jun‐Ling Song

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New lead-free perovskite Rb 7 Bi 3 Cl 16 nanocrystals with blue luminescence and excellent moisture-stabilityOriginalLuminescent perovskites: recent advances in theory and experiments259Bleifreie Halogenid‐Perowskit‐Nanokristalle: Kristallstrukturen, Synthese, Stabilitäten und optische Eigenschaften28Lead‐Free Halide Perovskite Nanocrystals: Crystal Structures, Synthesis, Stabilities, and Optical Properties460Synthetic Evolution of Colloidal Metal Halide Perovskite Nanocrystals66Lead-Free Halide Perovskites and Perovskite Variants as Phosphors toward Light-Emitting Applications159Charge-Carrier Dynamics of Lead-Free Halide Perovskite Nanocrystals234Lead-Free Perovskites for Lighting and Lasing Applications: A Minireview42Can perovskite inspired bismuth halide nanocrystals outperform their lead counterparts?21Prospects of lead-free perovskite-inspired materials for photovoltaic applications86Ionic Liquid-Assisted Exfoliation of Two-Dimensional Metal–Organic Frameworks for Luminescent Sensing41Efficient and Reabsorption‐Free Radioluminescence in Cs 3 Cu 2 I 5 Nanocrystals with Self‐Trapped Excitons489All‐Inorganic Lead‐Free 0D Perovskites by a Doping Strategy to Achieve a PLQY Boost from <2 % to 90 %75All‐Inorganic Lead‐Free 0D Perovskites by a Doping Strategy to Achieve a PLQY Boost from <2 % to 90 %247Synthesis and Localized Photoluminescence Blinking of Lead‐Free 2D Nanostructures of Cs3Bi2I6Cl3 Perovskite44Synthesis and Localized Photoluminescence Blinking of Lead‐Free 2D Nanostructures of Cs3Bi2I6Cl3 Perovskite8Recent Advancements and Challenges for Low-Toxicity Perovskite Materials182The Rb7Bi3−3xSb3xCl16 Family: A Fully Inorganic Solid Solution with Room‐Temperature Luminescent Members87The Rb7Bi3−3xSb3xCl16 Family: A Fully Inorganic Solid Solution with Room‐Temperature Luminescent Members18Room Temperature Synthesis of Stable, Printable Cs3Cu2X5 (X = I, Br/I, Br, Br/Cl, Cl) Colloidal Nanocrystals with Near-Unity Quantum Yield Green Emitters (X = Cl)201Low-dose real-time X-ray imaging with nontoxic double perovskite scintillators483Lead Halide Perovskite Nanocrystals: Room Temperature Syntheses toward Commercial Viability89Highly-stable tin-based perovskite nanocrystals produced by passivation and coating of gelatin39Identification of Halogen-Associated Active Sites on Bismuth-Based Perovskite Quantum Dots for Efficient and Selective CO2‑to-CO Photoreduction522Blue electroluminescent metal halide perovskites6Recent advances of lead-free metal halide perovskite single crystals and nanocrystals: synthesis, crystal structure, optical properties, and their diverse applications74Development of structure and tuning ability of the luminescence of lead-free halide perovskite nanocrystals (NCs)43Recent Advances and Opportunities of Lead-Free Perovskite Nanocrystal for Optoelectronic Application95Recent progress of zero-dimensional luminescent metal halides879Room-temperature synthesis of blue-emissive zero-dimensional cesium indium halide quantum dots for temperature-stable down-conversion white light-emitting diodes with a half-lifetime of 186 h45Zero-dimensional Sb3+ doped Rb7Bi3Cl16 metal halides with triplet self-trapped exciton emission4Lead‐Free Halide Perovskites for Light Emission: Recent Advances and Perspectives337All‐Inorganic Lead‐Free Perovskite(‐Like) Single Crystals: Synthesis, Properties, and Applications108Halide Perovskite Light‐Emitting Diode Technologies167Progresses on Novel B‐Site Perovskite Nanocrystals21Atomically Thin Sheets of Lead‐Free 1D Hybrid Perovskites Feature Tunable White‐Light Emission from Self‐Trapped Excitons38Activation of Self‐Trapped Emission in Stable Bismuth‐Halide Perovskite by Suppressing Strong Exciton–Phonon Coupling154Advances in Lead-Free Perovskite Single Crystals: Fundamentals and Applications124Emerging new‐generation white light‐emitting diodes based on luminescent lead‐free halide perovskites and perovskite derivatives23Microwave-assisted synthesis of blue-emitting cesium bismuth bromine perovskite nanocrystals without polar solvent21Investigations on caesium-incorporated rubidium tin chloride-defect perovskite nanomaterial as highly efficient ultraviolet photocatalysts8Quasi-Zero Dimensional Halide Perovskite Derivates: Synthesis, Status, and Opportunity170D Perovskites: Unique Properties, Synthesis, and Their Applications388Recent Advances in Blue Perovskite Quantum Dots for Light‐Emitting Diodes105All-inorganic perovskite nanocrystals: next-generation scintillation materials for high-resolution X-ray imaging129Antimony and bismuth cooperation to enhance the broad yellow photoluminescence of zero-dimensional hybrid halide14Metal Halide Perovskite-Based Phosphors and Their Applications in LEDs3Highly Luminescent and Multifunctional Zero‐Dimensional Cesium Lanthanide Chloride (Cs 3 LnCl 6 ) Colloidal Nanocrystals34Lead‐Free Metal Halide Perovskite Nanocrystals: From Fundamentals to Applications38Recent progress and future prospects on halide perovskite nanocrystals for optoelectronics and beyond48Recent Progress of Bismuth Effect on All‐Inorganic Lead‐Free Metal Halide Derivatives: Crystals Structure, Luminescence Properties, and Applications70Progress in all-inorganic heterometallic halide layered double perovskites26Light Emission from Low‐Dimensional Pb‐Free Perovskite‐Related Metal Halide Nanocrystals37Dynamically tunable multicolor emissions from zero-dimensional Cs 3 LnCl 6 (Ln: europium and terbium) nanocrystals with wide color gamut23Advances of metal halide perovskite large-size single crystals in photodetectors: from crystal materials to growth techniques21Influence of halogen substitution in double perovskite Rb2Sn(Br0.75I0.25)6 on the photocatalytic degradation of methylene blue dye under visible light irradiation15Recent developments in lead-free bismuth-based halide perovskite nanomaterials for heterogeneous photocatalysis under visible light49Structure, composition, and stability of metal halide perovskites4A Mechanochemically Synthesized Hybrid Bismuth Halide as Highly Efficient Red Phosphor for Blue Chip‐Based WLED32Recent developments of lead-free halide-perovskite nanocrystals: Synthesis strategies, stability, challenges, and potential in optoelectronic applications59Cerium Ion Promoting the Emission of Self-Trapped Excitons of Quasi-2D Europium Halide Perovskites for Self-Activated White Light-Emitting10Water‐Dispersable Silica‐Supported Nanocrystalline Pb‐Free Perovskite Rb 7 Bi 3 Cl 16 @SiO 2 for ATP‐Responsive Bio‐Imaging3Prospects for lead free perovskite for photovoltaic applications and biological impacts: Challenges and opportunities30Stable Broadband Bright Green Emission of Self‐trapped Excitons Triggered by Sb3+ Doping in Zero‐Dimensional Cs3BiCl68Environmentally Friendly Perovskite‐Based Photovoltaics and Luminescence: Lead Less or Lead Free15Observation on structural and optical features of new nanostructured lead-free methylammonium zinc or cobalt iodide perovskites for solar cells applications16Antimony Doping Enabled Photoluminescence Quantum Yield Enhancement in 0D Inorganic Bismuth Halide Crystals22Non‐lead Metal Halide Perovskite Materials0Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications5Highly efficient blue luminescence from stable lead-free Cu-doped Rb 2 LiBiBr 6 double perovskites4Recent advances in lead-free halide perovskites: from synthesis to applications69Room temperature synthesis of nanocomposite thin films with embedded Cs 2 AgIn 0.9 Bi 0.1 Cl 6 lead-free double perovskite nanocrystals with long-term water stability, wide range pH tolerance, and high quantum yield3Advantageous occupation of Cu2+ in the B site of double-perovskite Rb2BB'Br6 (B = K; B′ = Bi) framework for white-light-emission7Visual and rapid fluorescence sensing for hexavalent chromium by hydroxypropyl chitosan passivated bismuth-based perovskite quantum dots18Blue Lead‐Free Perovskite Derivatives: Structural Diversity, Luminescence Properties and Light‐Emitting Diode Applications27Bismuth-based quantum dots pioneering transformative breakthroughs in environment and energy sectors6Lead-free metal–halide perovskite nanocrystals: synthesis and optical properties [Review]0A Bi( iii )-based halide with near-unity photoluminescence quantum yield as a blue-light-excited red phosphor for WLEDs8Methods of synthesis for metal halide perovskite photocatalysts0Mechanochemical Synthesis of Phase-Pure CsCu2I3 and Cs3Cu2I5 Phosphors Regulated by Polar Solvents and Their Application in Tunable Chromaticity LEDs10Scalable synthesis of Sb-doped Rb3InCl6 nanocrystals for high-resolution X-ray imaging screen9Eco-friendly synthesis of Cs3Bi2Br9 perovskite quantum dots using castor oil as solvent and ligand for leather anti-counterfeiting9Polarization‐Dependent Multiphoton‐Excited Self‐Trapped Emission in Alloyed 0D Rb7Bi3Cl16 Metal Halides via Sb3+ Doping5Research Progress on Zero-dimensional Metal Halide Scintillators towards Radiation Detection Applications3Engineering the optoelectronic properties of lead-free Rb2B’BiCl6 (B = K, Li) double perovskites: highly efficient blue light emission1Boron-pnictogen donor-acceptor bonding as a perovskite design principle: DFT case study of quasi 0D A(BX3)2 (A=BeBH3, MgBH3; B=Sb, Bi; X=I)2Designing Stable Nanoarchitectonics of Metal Halide Perovskite‐Based Materials for Aqueous Electrocatalysis3Advances and Current Progress of Dopant Engineering on All‐Inorganic Halide Perovskites Toward High‐Performance Scintillating Materials0The Rise of Perovskitoid for Photoelectric Device: From Preparation to Applications1Protocol for luminescent nanocrystal synthesis via modified ligand-assisted precipitation and X-ray scintillation film fabrication0High PLQY and Ultra‐Stable Cs 2 ZnCl 4 /SiO 2 Nano‐Composite Particles From Lead‐Free Perovskite Colloidal Quantum Dots0

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