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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2019

Li4SrCa(SiO4)2:Eu2+: A Potential Temperature Sensor with Unique Optical Thermometric Properties

Rui Shi, Lixin Ning, Yan Huang, Ye Tao, Lirong Zheng, Zhibing Li, H. Liang

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Li4SrCa(SiO4)2:Eu2+: A Potential Temperature Sensor with Unique Optical Thermometric PropertiesOriginalLithium ion doping triggered splendid quantum efficiency and thermal stability in Li 2 SrSiO 4 : x Eu 2+ phosphors for optical thermometry and high luminous efficiency white-LED31Detecting Variable Resistance by Fluorescence Intensity Ratio Technology2An optical thermometry based on abnormal negative thermal quenching of the charge transfer band edge35A ratiometric optical thermometer with multi-color emission and high sensitivity based on double perovskite LaMg0.402Nb0.598O3: Pr3+ thermochromic phosphors212Systemic development of a Bismuth-containing multifunctional phosphate for field emission displays and thermochromic applications18Synergistic effect from the dual oxidation states of europium in the color-tuning of Ca3Mg3(PO4)4:Eu2+, Eu3+ thermometric phosphor30Non-stoichiometry in Ca2Al2SiO7 enabling mixed-valent europium toward ratiometric temperature sensing61NaLa(MoO4)2: Sm3+, Tb3+ phosphor: Optical temperature sensing material with a wide change range of luminescence color35Ratiometric Optical Thermometer with High Sensitivity Based on Site-Selective Occupancy of Mn2+ Ions in Li5Zn8Al5Ge9O36 under Controllable Synthesis Atmosphere40Huge enhancement of Sm 2+ emission via Eu 2+ energy transfer in a SrB 4 O 7 pressure sensor50The stability of coordination polyhedrons and distribution of europium ions in Ca 6 BaP 4 O 177Dual-Mode Optical Thermometry Design in Lu3Al5O12:Ce3+/Mn4+ Phosphor189Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs99Controllable hydrothermal synthesis and morphology evolution of Zn4B6O13:Tb/Eu phosphors with tunable luminescent properties28A promising temperature sensing strategy based on highly sensitive Pr3+-doped SrRE2O4 (RE = Sc, Lu and Y) luminescent thermometers72Luminescence and temperature sensing abilities of zincate phosphors co-doped bismuth Bi3+ and lanthanide Eu3+/Sm3+81Ratiometric thermal sensing based on dual emission of YBO3:Ce3+, Tb3+34Photoluminescence and ratiometric optical thermometry in Mn4+/Eu3+ dual-doped phosphor via site-favorable occupation83A spatial/temporal dual-mode optical thermometry based on double-sites dependent luminescence of Li4SrCa(SiO4)2: Eu2+ phosphors with highly sensitive luminescent thermometer116Enhancing thermometric performance via improving indicator signal in Bi3+-doped CaNb2O6:Ln3+ (Ln = Eu/Sm/Dy/Tb) phosphors143Self-activated luminescence in AZn4(BO3)3 (A = K, Rb, Cs) and oxygen-defects-related photoluminescence tuning28Preparation, luminescence properties and electronic structure of RE (RE=Eu3+,Sm3+,Dy3+)-doped multi-color silico-phosphate Ca15(PO4)2(SiO4)6 phosphors31Deep-Tissue Temperature Sensing Realized in BaY2O4:Yb3+/Er3+ with Ultrahigh Sensitivity and Extremely Intense Red Upconversion Luminescence130Thermal‐couple levels of 4 S 3/2 and 2 H 11/2 in Na(Ca, Sr)La(VO 4 ) 2 :Er 3+ phosphors for potential optical thermometers36A review on fluorescence intensity ratio thermometer based on rare-earth and transition metal ions doped inorganic luminescent materials440Cation sites modification enhanced luminescence and thermal quenching characteristic in the blue light-emitting Na3Sc2-xZnx(PO4)3:0.03Eu2+ phosphors10Highly Sensitive Dual-Mode Optical Thermometry in Double-Perovskite Oxides via Pr3+/Dy3+ Energy Transfer106Electrospun fibers embedded with microcrystal for optical temperature sensing8ZnGa2–yAlyO4:Mn2+,Mn4+ Thermochromic Phosphors: Valence State Control and Optical Temperature Sensing83Site Occupancies, VUV-UV–vis Photoluminescence, and X‑ray Radioluminescence of Eu2+-Doped RbBaPO419Optical thermometry of Er 3+ in electrospun yttrium titanate nanobelts4Temperature dependent luminescent characterization of BaMgSiO4:Eu2+ phosphor4Two-Site Occupancy Induced a Broad-Band Emission in Phosphor K2YZr(PO4)3:Eu2+ for White-Light-Emitting Diode Applications47Site preference and the optical thermometry strategy by different temperature response from two sites environment of Mn2+ in K7ZnSc2B15O3075Constructing sensitive luminescent thermometers via energy transfer in Ce 3+ and Eu 2+ co-doped Ca 8 Mg 3 Al 2 Si 7 O 28 phosphors23Design of white-emitting optical temperature sensor based on energy transfer in a Bi 3+ , Eu 3+ and Tb 3+ doped YBO 3 crystal44Improving the temperature-dependent sensitivity of Ca 9 Y(PO 4 ) 7 :Ce 3+ ,Mn 2+ and g-C 3 N 4 composite phosphors by mechanical mixing19Negative thermal expansion triggered anomalous thermal upconversion luminescence behaviors in Er 3+ /Yb 3+ -codoped Y 2 Mo 3 O 12 microparticles for highly sensitive thermometry71Recent advances on metal oxide-based luminescence thermometry118Regulation of double luminescence centers based on the evolution of disordered local structure for ratiometric temperature sensing applications9Trap Depth Engineering in Mgga2o4: Bi3+ for Muticolor Dynamic Anti-Counterfeiting, Encryption And Optical Temperature Sensing Applications142Photocatalytic, thermometric and internal heating multifunctional properties of Er3+/Yb3+-codoped MoO3 upconverting microparticles16Exploiting novel optical thermometry near room temperature with a combination of phase-change host and luminescent Pr3+ ion39Synthesis and design of NaYF 4 microprisms via a microwave‐assisted approach for highly sensitive optical thermometry applications6Solid‐State Synthesis of (Ph4P)MI3 (M=Eu2+, Sr2+, Sn2+) and Investigation of Photoluminescence Properties of Green Emitting Phosphor3Understanding the Stabilization and Tunability of Divalent Europium 2.2.2B Cryptates34Tuning Emission from Greenish to Blue via Chemical Composition Modulation in Solid Solutions (Sr 1– y Ca y ) 2 Sb 2 O 7 :Bi 3+ under near-UV Light Excitation63Dual-Feedbacked Temperature Sensing of Er3+ in Fusiform-Polycrystalline-Implanted BaYF5/PAN Electrospun Fibers2Warm white light emission, thermochromic property and long persistent luminescence derived from multi-sites of Eu2+/Eu3+ in host lattice71Dual-ratiometric thermometry of Erbium(Ⅲ) in electrospun fibers inlaid with BaMgF4 microcrystals8Influence of Dy3+ ion concentration on photoluminescence and energy transfer mechanism of promising KBaScSi3O9 phosphors for warm white LEDs57Design and Directional Growth of (Mg1−xZnx)(Al1−yCry)2O4 Single‐Crystal Fibers for High‐Sensitivity and High‐Temperature Sensing Based on Lattice Doping Engineering and Acoustic Anisotropy18Suppression of Eu2+ Luminescence Loss14A review and outlook of ratiometric optical thermometer based on thermally coupled levels and non-thermally coupled levels232Sensitive optical thermometer via efficient energy transfer in dual-emitting thermochromic YNbO4:Bi3+, Eu3+ phosphor45Multifunctional Ca9NaZn1-Mg (PO4)7:Eu2+ phosphor for full-spectrum lighting, optical thermometry and pressure sensor applications112A dual-ratiometric optical thermometry based on Sr 2 LaF 7 :Er 3+ crystal-implanted pliable fibers13Demonstration of temperature-sensitive paints with rigorously controlled thickness applied to variously shaped metal substrates with a highly stable connection based on a demulsification-induced fast solidification strategy2Tunable concentration/excitation-dependent deep-red and white light emission in single-phase Eu 2+ -activated Sc-based oxide phosphors for blue/UV-LEDs32Tunable emission of Li 4 SrCaSi 2 O 4− y N 2 y / 3 :Eu 2+ phosphors based on anion substitution induction for WLEDs and optical thermometry12Toward Opto-Structural Correlation to Investigate Luminescence Thermometry in an Organometallic Eu(II) Complex73Regulation of Local Site Structures to Stabilize Mixed-Valence Eu2+/3+ under a Reducing Atmosphere for Multicolor Photoluminescence23New Structural Design Strategy: Optical Center VO4-Activated Broadband Yellow Phosphate Phosphors for High-Color-Rendering WLEDs38Luminescent properties of Eu3+-doped NaLaCaWO6 red phosphors and temperature sensing derived from the excited state of charge transfer band35Temperature-dependent photoluminescence and optical thermometry performance in Ca3Bi(PO4)3:Er3+ phosphors28Color-tunable emissions in Bi3+/Eu3+ activated phosphors for multi-mode optical thermometers35A new optical temperature sensor based on the fluorescence intensity ratio of Mn 2+ and Mn 4+19Ratiometric optical thermometer with high-sensitive temperature sensing based on tunable luminescence of Ce3+-Eu2+ in KSr4B3O9 phosphors17Manganese activated narrowband red-emitting Cs2KInF6:Mn4+ phosphor with high colour purity for backlight display16Design of highly sensitive ratiometric thermometry with time-gated technique7Fluorescence modulation in Pr3+-doped MGd2O4 (M = Sr, Ba) by the site engineering strategy4Strain-Negligible Eu2+ Doping Enabled Color-Tunable Harsh Condition-Resistant Perovskite Nanocrystals for Superior Light-Emitting Diodes31Ceramics phosphor powders4Suitable selection of high-energy state excitation to enhance the thermal stability of Eu 3+ and the sensitivity of La 2 CaSnO 6 :Eu 3+ ,Mn 4+ temperature measuring materials14Eu2+/Ce3+ emission structural unit revolution and Eu2+/Ce3+ energy transfer in Ca2Mg0·75Al0·5Si1·75O7 melilite based on high alumina blast furnace slags7Thermally Triggered Multilevel Diffractive Optical Elements Tailored by Shape-Memory Polymers for Temperature History Sensors21A novel Tb3+ and Eu3+ co-doped dual-emitting phosphate K3SrBi(P2O7)2 phosphor for application in FIR thermometers65Recent Advances in Multi-Site Luminescent Materials: Design, Identification and Regulation20MgGa2O4:Mn2+, Mn4+: A dual-emitting phosphors with unique optical temperature sensing41Pr3+ doped Y3GaO6 luminescent thermometer for high temperature conditions15Luminescence‐Based Infrared Thermal Sensors: Comprehensive Insights26Thermally stable illuminating characteristics of Tb3+/Sm3+ ions activated BaO–SrO–Al2O3–B2O3–SiO2 glasses for photonic applications8Luminescence and optical thermometry strategy based on emission spectra of Li2Ba5W3O15:Pr3+ phosphors42Insight into the electron transfer and anti-thermal quenching of europium doped Li 4 SrCa(SiO 4 ) 23Utilizing diametrically opposite thermal quenching luminescence to achieve highly sensitive temperature measurement and anti-counterfeiting24Thermal sensitivity of Ho3+ fluorescence in oxyfluoride nanocrystals and derivative embedded fibers3A post-reduction strategy to enhance near-infrared-II emission from Li 4 SrCa(SiO 4 ) 2 :Cr 4+ phosphors11Luminescence analysis of heavily Mn 2+ -doped LaMgAl 11 O 19 phosphors: crystallographic site occupation and the formation of Mn 2+ –Mn 2+ dimers18Realizing a broad-scope and high-sensitivity optical thermometer based on dual-emission centers with structure confinement effect-related energy transfer7Tunable emission and thermal sensitivity via energy transfer from Bi 3+ to Eu 3+ in BaY 2 Al 2 Ga 2 GeO 122Heterostructure anion-groups guided design enabling customizable Eu2+ spectrum behavior in borophosphate7Modulation of components toward blue light emission and scintillation properties of Eu2+ activated Sr1-xLaxMgxAl12-xO19 crystal1Persistent Photoluminescence and Mechanoluminescence of a Highly Sensitive Pressure and Temperature Gauge in Combination with a 3D‐Printable Optical Coding Platform51Temperature responsive behaviour of SrAl2O4(Eu, Dy):ZnGa2O4(Cr) phosphor-glass composite12Ca2HfSi4O12:Eu2+: A novel blue phosphor with excellent temperature sensitivity for temperature sensor and cathodoluminescence properties for field-emission displays7Integrating unwonted photoluminescence and anti-thermal quenching in Ba 2 MgTeO 6 double perovskites for high-performance optical thermometers9Ligand Effects on the Emission Characteristics of Molecular Eu(II) Luminescence Thermometers21A novel negative-thermal quenching Ca 9 ZnK(VO 4 ) 7 :Sm 3+ phosphor for a sensitive optical thermometer2Bi3+-doping enhanced ZnWO4: Eu3+ phosphors energy transfer and its high FIR optical thermometry characteristics9Eu3+ doping induces asynchronous tuning of luminescence and afterglow in self-activated LiZnSbO4 host for multiple applications51Time- and temperature-dependent dynamic fluorescence of non-stoichiometric induced defective phosphors and multiple applications33Anomalous Antithermal Quenching and Enhanced Thermal Sensitivity in Fractal‐Structured Cs 2 NaHoBr 6 Perovskite5Defect engineering to develop a green-emitting Eu2+-doped sulphide phosphor for water-resistant LED backlighting11Unraveling acoustic anisotropy and lattice engineering strategy in GdxSc2-xO3 perovskite single-crystal fibers: Paving the way for high-sensitivity and robust ultrasonic thermometry beyond 2000 °C1Luminescence properties of multi-site Eu2+ emission in Ca9MgNa(PO4)7 phosphors with cation substitution5Dual green and red emission of novel Mn doped Mg 0.3 Zn 0.7 Al 2 O 4 phosphors synthesized by a solid-state method for high-sensitivity temperature sensor applications0Doping-induced phase transition and tunable luminescence of Sr9Tm(VO4)7:Eu3+ phosphor for multifunctional applications0Synthesis and Characterization of Orange-Red Emitting Li4SrCa(SiO4)2: Sm3+ Phosphor for Solid- State Lighting and Dosimetry Application0Photoluminescent Thermal Response Regulation in Zinc Metal Halide Materials Through Sn 2+ Alloying‐Induced Carrier Localization for Visualization‐Enabled Temperature Sensor1Bandwidth-tailored high-sensitivity thermometry in Mn4 + -doped Mg3Ga2GeO8: Coexistence of strong/weak crystal field sites1Dual-mode optical thermometry and mechanoluminescence in defect-engineered ZnGa2O4:Pr3 + phosphors0

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  5. Systemic development of a Bismuth-containing multifunctional phosphate for field emission displays and thermochromic applications

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  6. Synergistic effect from the dual oxidation states of europium in the color-tuning of Ca3Mg3(PO4)4:Eu2+, Eu3+ thermometric phosphor

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  7. Non-stoichiometry in Ca2Al2SiO7 enabling mixed-valent europium toward ratiometric temperature sensing

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  8. NaLa(MoO4)2: Sm3+, Tb3+ phosphor: Optical temperature sensing material with a wide change range of luminescence color

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  9. Ratiometric Optical Thermometer with High Sensitivity Based on Site-Selective Occupancy of Mn2+ Ions in Li5Zn8Al5Ge9O36 under Controllable Synthesis Atmosphere

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  10. Huge enhancement of Sm 2+ emission via Eu 2+ energy transfer in a SrB 4 O 7 pressure sensor

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  11. The stability of coordination polyhedrons and distribution of europium ions in Ca 6 BaP 4 O 17

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  32. Temperature dependent luminescent characterization of BaMgSiO4:Eu2+ phosphor

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  34. Site preference and the optical thermometry strategy by different temperature response from two sites environment of Mn2+ in K7ZnSc2B15O30

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  44. Synthesis and design of NaYF 4 microprisms via a microwave‐assisted approach for highly sensitive optical thermometry applications

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  48. Dual-Feedbacked Temperature Sensing of Er3+ in Fusiform-Polycrystalline-Implanted BaYF5/PAN Electrospun Fibers

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  49. Warm white light emission, thermochromic property and long persistent luminescence derived from multi-sites of Eu2+/Eu3+ in host lattice

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  50. Dual-ratiometric thermometry of Erbium(Ⅲ) in electrospun fibers inlaid with BaMgF4 microcrystals

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