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RESEARCH PAPER · Nano Energy · 2018

Ferroelectric polarization promoted bulk charge separation for highly efficient CO2 photoreduction of SrBi4Ti4O15

Shuchen Tu, Yihe Zhang, A.H. Reshak, S. Auluck, Liqun Ye, Xiaopeng Han, Tianyi Ma, Hongwei Huang

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Ferroelectric polarization promoted bulk charge separation for highly efficient CO2 photoreduction of SrBi4Ti4O15OriginalBand structure engineering of boron–oxygen-based materials for efficient charge separation12Fabricating ferromagnetic MoS 2 -based composite exposed to simulated sunlight for sodium storage8The Role of Polarization in Photocatalysis930The Role of Polarization in Photocatalysis60Two dimensional bismuth-based layered materials for energy-related applications140Enhanced photocatalytic property of Ag loaded on well-defined ferroelectric Na3VO2B6O11 crystals under visible light irradiation24Self-powered ferroelectric NTC thermistor based on bismuth titanate51Unprecedented Eighteen‐Faceted BiOCl with a Ternary Facet Junction Boosting Cascade Charge Flow and Photo‐redox314Unprecedented Eighteen‐Faceted BiOCl with a Ternary Facet Junction Boosting Cascade Charge Flow and Photo‐redox25Synthesis of high efficient and stable plasmonic photocatalyst Ag/AgNbO3 with specific exposed crystal-facets and intimate heterogeneous interface via combustion route39Size-dependent selectivity and activity of CO2 photoreduction over black nano-titanias grown on dendritic porous silica particles49Dielectric, ferroelectric, impedance and photocatalytic water splitting study of Y3+ modified SrBi2Ta2O9 ferroelectrics38Efficient band structure engineering and visible-light response in ZrS2/GaS heterobilayer by electrical field or external strains13Strong tribocatalytic dye decomposition through utilizing triboelectric energy of barium strontium titanate nanoparticles185Charge Coupling Enhanced Photocatalytic Activity of BaTiO3/MoO3 Heterostructures98Plasmonic Ag@TiO2 Core–Shell Nanoparticles for Enhanced CO2 Photoconversion to CH4117Charge steering in ultrathin 2D nanomaterials for photocatalysis65Ferroelectric polarization and thin-layered structure synergistically promoting CO 2 photoreduction of Bi 2 MoO 6164Ferroelectric semiconductors for photocatalytic energy and environmental applications5Integrating CuInSe 2 nanocrystals with polymeric carbon nitride nanorods for photocatalytic water splitting9Research progress and prospects of photocatalytic devices with perovskite ferroelectric semiconductors11Silver-Based Plasmonic Catalysts for Carbon Dioxide Reduction32Recent Advances of Ferro-, Piezo-, and Pyroelectric Nanomaterials for Catalytic Applications332Piezopotential augmented photo- and photoelectro-catalysis with a built-in electric field143Photocatalytic mineralization of disperse red 167.1 by cubic Cu2O nanoparticles: Experimental and theoretical approach8Construction of Infrared‐Light‐Responsive Photoinduced Carriers Driver for Enhanced Photocatalytic Hydrogen Evolution250TBAOH assisted synthesis of ultrathin BiOCl nanosheets with enhanced charge separation efficiency for superior photocatalytic activity in carbamazepine degradation63Advances in Piezo‐Phototronic Effect Enhanced Photocatalysis and Photoelectrocatalysis619CO adsorption, reduction and oxidation on Pb(Zr,Ti)O3(001) surfaces associated with negatively charged gold nanoparticles8Assembling ultrafine TiO2 nanoparticles on UiO-66 octahedrons to promote selective photocatalytic conversion of CO2 to CH4 at a low concentration172Enhancement of pyroelectric catalysis of ferroelectric BaTiO3 crystal: The action mechanism of electric poling70Novel CaMoO4@GO Nanocomposite: Synthesis, Characterization, and Investigation its Photocatalytic Properties6Theoretical insights into the origin of highly efficient photocatalyst NiO/NaTaO3 for overall water splitting20Piezocatalysis and Piezo‐Photocatalysis: Catalysts Classification and Modification Strategy, Reaction Mechanism, and Practical Application986Pyroelectric catalysis157Nano-Au-modified TiO2 grown on dendritic porous silica particles for enhanced CO2 photoreduction32Engineering the Band-Edge of Fe2O3/ZnO Nanoplates via Separate Dual Cation Incorporation for Efficient Photocatalytic Performance83Inside‐and‐Out Semiconductor Engineering for CO 2 Photoreduction: From Recent Advances to New Trends411Photocatalysis Within Intrinsic Spontaneous Polarization Electric Field47Coupling ferroelectric polarization and anisotropic charge migration for enhanced CO2 photoreduction119Local-interaction-field-coupled semiconductor photocatalysis: recent progress and future challenges74Highly efficient synergetic piezo/photocatalytic degradation in novel M0.5Bi2.5Nb2O9 (M=Li, Na, K) ferroelectric nanosheets18Synergistic effect of surface coated and bulk doped carbon on enhancing photocatalytic CO2 reduction for MgIn2S4 microflowers37Interface engineering in low-dimensional bismuth-based materials for photoreduction reactions42All-in-one polarized Cd/CdS/halloysite ferroelectric hybrid for exceptional photocatalytic hydrogen evolution38Catalysis based on ferroelectrics: controllable chemical reaction with boosted efficiency62Facet-selective charge separation in two-dimensional bismuth-based photocatalysts31First principles calculation of optical absorption and polarization properties of In doped h-LuFeO31Polarisation tuneable piezo-catalytic activity of Nb-doped PZT with low Curie temperature for efficient CO 2 reduction and H 2 generation87Preparation and piezoelectric catalytic performance of flexible inorganic Ba 1− x Ca x TiO 3 via electrospinning28Synergetic polarization effect of protonation and Fe-doping on g-C 3 N 4 with enhanced photocatalytic activity14Promoting carrier separation efficiently by macroscopic polarization charges and interfacial modulation for photocatalysis57Ferroelectric polarization effect promoting the bulk charge separation for enhance the efficiency of photocatalytic degradation64Fabrication of PVDF-based piezocatalytic active membrane with enhanced oxytetracycline degradation efficiency through embedding few-layer E-MoS2 nanosheets168Effect of ferroelectric Ba0.8Sr0.2TiO3 on the charge carrier separation of BiOBr at different temperature21Recyclable 0D/2D ZnFe2O4/Bi5FeTi3O15 S-scheme heterojunction with bismuth decoration for enhanced visible-light-driven tetracycline photodegradation49Crystal face-selective Bi4Ti3O12/BiOI heterojunction constructed for enhanced visible ligtht-driven photocatalytic activity37Recent advances in CdS-based photocatalysts for CO2 photocatalytic conversion204Review on Bismuth‐Based Photocatalyst for CO2 Conversion50Millimeter-level nitrogen modified activated carbon spheres assisted Bi4Ti3O12 composites for bifunctional adsorption/photoreduction of CO260Dynamic Internal Field Engineering in BaTiO3-TiO2 Nanostructures for Photocatalytic Dye Degradation30Role of transition metal oxides in g-C3N4-based heterojunctions for photocatalysis and supercapacitors230Enhanced photocatalytic activity of ferroelectric-based Ag2O/Bi4Ti3O12 hybrids by piezoelectric effect37Synergistic Polarization Engineering on Bulk and Surface for Boosting CO 2 Photoreduction306Synergistic Polarization Engineering on Bulk and Surface for Boosting CO2 Photoreduction21Facile one-step redox synthesis of Bi2O2CO3/Bi2O3/Bi ternary photocatalyst without additional carbon source11CuS -mediated two reaction systems enable biomimetic photocatalysis in CO2 reduction with visible light19Enhanced photocatalytic performance of ferroelectric-based SrBi4Ti4O15/SnS2 hybrids by piezoelectric effect38A roadmap towards the development of superior photocatalysts for solar- driven CO2-to-fuels production43Uji Aktivitas Fotokatalis Senyawa Aurivillius Lapis EmpaT SrBi4Ti4O15 dalam Mendegradasi Rhodamine-B3Crystal-structure dependent reaction pathways in photocatalytic formaldehyde mineralization on BiPO434Synergy of ferroelectric polarization and oxygen vacancy to promote CO2 photoreduction407Essential effect of proton coupled electron sequent transfer on photocatalytic water complete dissociation: A DFT study13Advances in structural modification of perovskite semiconductors for visible light assisted photocatalytic CO2 reduction to renewable solar fuels: A review92Sc2CF2/Janus MoSSe heterostructure: A potential Z-scheme photocatalyst with ultra-high solar-to-hydrogen efficiency89Spontaneous polarisation of ferroelectric BaTiO3/ZnO heterostructures with enhanced performance in a Fenton-like catalytic reaction24Versatile Titanates: Classification, Property, Preparation, and Sustainable Energy Catalysis40Solar fuels: research and development strategies to accelerate photocatalytic CO 2 conversion into hydrocarbon fuels805Ferroelectrics in Photocatalysis47Green Production of Solar Fuels Using Formaldehyde Pollutant as a Carbon Feedstock Achieving Conversion of Waste into Energy2Cation vacancy activating surface neighboring sites for efficient CO 2 photoreduction on Bi 4 Ti 3 O 12 nanosheets35Cocatalyst engineering to weaken the charge screening effect over Au–Bi 4 Ti 3 O 12 for piezocatalytic pure water splitting34Construction of Bi2O3 quantum Dots/SrBi4Ti4O15 S-scheme heterojunction with enhanced photocatalytic CO2 reduction: Role of Bi2O3 quantum dots and mechanism study46Ferroelectric ceramics and glass ceramics for photocatalysis8Ferroelectric Heterojunction and Bi-Ti-In Trimetallic Sites Mediated Co2 Coordination Model on the Indium-Doped Bi4ti3o12-Cuin5s8 for Controlling the Selectivity of Photoreduction of Co20Ferroelectric-assisted charge carrier separation over Bi 2 MoO 6 nanosheets for photocatalytic dye degradation16High-efficiency photoreduction of CO 2 in a low vacuum4Piezoelectric induced reverse photocatalytic performances of carbon nitride with different structures18Underlying physics and chemistry of ferroic-photocatalysis: a critical review20Atomically thin Bi/Bi4Ti3O12 heterojunction mediated increasing active photogenerated carriers for boosting photocatalytic activity47Piezoelectric catalysis for efficient reduction of CO2 using lead-free ferroelectric particulates113Multi-field driven hybrid catalysts for CO2 reduction: Progress, mechanism and perspective39Oxygen Vacancies Promoted Piezoelectricity toward Piezo-Photocatalytic Decomposition of Tetracycline over SrBi 4 Ti 4 O 15104Built in electric field boosted photocatalytic performance in a ferroelectric layered material SrBi2Ta2O9 with oriented facets: Charge separation and mechanism insights59Near-infrared responsive Z-scheme heterojunction with strong stability and ultra-high quantum efficiency constructed by lanthanide-doped glass89Layered bismuth-based photocatalysts300Direct Z-scheme MoSe2/TiO2 heterostructure with improved piezoelectric and piezo-photocatalytic performance48Progress on Emerging Ferroelectric Materials for Energy Harvesting, Storage and Conversion187Hierarchical Bi2WO6/BiFeWO6 n-n heterojunction as an efficient photocatalyst for water splitting under visible light40Ferroelectric polarization promotes the excellent CO2 photoreduction performance of Bi4Ti3O12 synthesized by molten salt method30Improving charge separation efficiency and piezo-photodegradation properties in Na0.5Bi0.5TiO3 via lattice engineering14Bi-Ti-In trimetallic sites in the Indium-doped Bi4Ti3O12-CuIn5S8 S-scheme heterojunction for controlling the selectivity of CO2 photoreduction25Enhanced internal field of Bi4NbO8Cl ferroelectric photocatalyst to promote charge separation via constructing crystal plane-dependent BiOI dielectric layer15A dual optimization approach for photoreduction of CO2 to alcohol in g-C3N4/BaTiO3 system: Heterojunction construction and ferroelectric polarization35Insights into highly efficient piezocatalytic molecule oxygen activation over Bi2Fe4O9: Active sites and mechanism58Symmetry breaking for semiconductor photocatalysis46The spontaneous polarization of In-doped κ-Ga2O3 by first-principles calculation8Enhanced photocatalytic hydrogen evolution by piezoelectric effects based on MoSe2/Se-decorated CdS nanowire edge-on heterostructure54High‐Performance Photocatalytic Reduction of Nitrogen to Ammonia Driven by Oxygen Vacancy and Ferroelectric Polarization Field of SrBi 4 Ti 4 O 15 Nanosheets61Synergy‐Compensation Effect of Ferroelectric Polarization and Cationic Vacancy Collaboratively Promoting CO2 Photoreduction37Superior photopiezocatalytic performance by enhancing spontaneous polarization through post-synthesis structure distortion in ultrathin Bi2WO6 nanosheet polar photocatalyst58Eco-Friendly Synthesis and Characterization of Plate-Like Fe doped SrBi4Ti4O15 by Molten Salt Method0Highly transparent Bi 4 Ti 3 O 12 thin-film electrodes for ferroelectric-enhanced photoelectrochemical processes6Lead-Free Piezoelectric Ceramics6Synthesis and characterization of plate-like vanadium doped SrBi4Ti4O15 prepared via KCl molten salt method3Highly efficient photocatalytic hydrogen production by platinum modified ferroelectric SrBi4Ti4O1522Advances in ultrasound-assisted photocatalyst synthesis and piezo-photocatalysts58Eco-friendly Synthesis of SrBi4Ti3,95Fe0,05O15 via Molten Salt Method0The Catalysts for an Environmental Remediation0The Construction of Heterojunction Realizes the Coupling Effect of Piezoelectric Effect on Photocatalysis0Molten Salt Synthesis of Photocatalyst Material SrBi4Ti4O15 for Methylene Blue Degradation2A (Bi2O2)2+ layer as a significant carrier generator and transmission channel in CaBi2Nb2O9 platelets for enhanced piezo-photo-catalytic performance50Interfacial Chemical Bond Engineering in a Direct Z-Scheme g-C3N4/MoS2 Heterojunction82Rapid Identification of Efficient Photocatalysts by Visualizing the Spatial Distribution of Photoinduced Charge Carriers9Hydrothermal synthesis of layered perovskite Sr2Bi4Ti5O18 for efficient photocatalytic degradation of organic pollutants15Multifunctional ferroelectric catalysis for water splitting: classification, synergism, strategies and challenges33Recent advances in 2D semiconductor nanomaterials for photocatalytic CO2 reduction30Advances in bismuth-based non-centrosymmetric materials as polarization-enhanced photocatalysts for environmental remediation and energy conversion43Nano-ferroelectric oxidase mimics for colorimetric detection of glutathione31High photocatalytic performance of ferroelectric AgNbO3 in a doping state14Construction of a Z-scheme Cu2O/SrBi4Ti4O15 p–n heterojunction for enhanced visible light photocatalytic performance for doxycycline degradation20Multimodal energy harvesting and catalysis of piezoelectric nanosheets for efficient and round-the-clock wastewater treatment16Preparation and Characterization of ZnTiO 3 /g‐C 3 N 4 Heterojunction Composite Catalyst with Highly Enhanced Photocatalytic CO 2 Reduction Performance10Synthesis of novel flower-like Bi4Ti3O12/BiOCl heterojunctions with excellent piezoelectric photocatalytic performance29A review on the recent development of bismuth-based catalysts for CO2 photoreduction24Enhanced catalytic activity of Molar-like BaTiO3 by oxygen vacancies20Piezoelectric charges promote FeS2 regeneration for efficient catalytical seawater splitting H2 evolution9Synthesis of plate-like Fe-doped SrBi4Ti4O15 using Na2SO4/K2SO4 molten salt method: XRD, Raman spectroscopy, SEM, and UV–VIS DRS studies3Research progress on photocatalytic reduction of CO 2 based on ferroelectric materials21Natural polymer/wide-bandgap inorganic hybrids for visible-light-driven CO2 photoreduction: Unraveling the multiple effects of interfacial chemical bonding7The unique spontaneous polarization property and application of ferroelectric materials in photocatalysis40Advancements in Catalytic Reduction of CO2 at Ambient Conditions for Enhanced Value-Added Product Synthesis2Green and efficient piezocatalytic hydrogen production achieved by modifying SrBi 4 Ti 4 O 15 with CdSe19Recent Progress in Charge Separation of Photocatalysts Facilitated by Polarization1Surface oxygen vacancy engineering in weak Bi–O bonded ferroelectric bismuth sodium titanate for boosting the photocatalytic CO 2 reduction reaction56Piezo‐catalysis in BiFeO 3 @In 2 Se 3 Heterojunction for High‐Efficiency Uranium Removal42Emerging polynary bismuth-based photocatalysts: Structural classification, preparation, modification and applications16Pyroelectric Photocatalysis: Polarization mechanism insight, in situ characterizations and challenges19Doping engineering in S–scheme composite for Regulating the selectivity of photocatalytic CO2 reduction13Mechanisms of noble metal-enhanced ferroelectric spontaneous polarized photocatalysis45

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