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RESEARCH PAPER · ACS Catalysis · 2018

Effects of Interfacial Electron Transfer in Metal Complex–Semiconductor Hybrid Photocatalysts on Z-Scheme CO2 Reduction under Visible Light

Akinobu Nakada, Ryo Kuriki, Keita Sekizawa, Shunta Nishioka, Junie Jhon M. Vequizo, Tomoki Uchiyama, Nozomi Kawakami, Daling Lu, Akira Yamakata, Yoshiharu Uchimoto, Osamu Ishitani, Kazuhiko Maeda

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Effects of Interfacial Electron Transfer in Metal Complex–Semiconductor Hybrid Photocatalysts on Z-Scheme CO2 Reduction under Visible LightOriginalFacile fabrication of oxygen and carbon co-doped carbon nitride nanosheets for efficient visible light photocatalytic H 2 evolution and CO 2 reduction27Cocatalysts for Selective Photoreduction of CO 2 into Solar Fuels23011．金属錯体光触媒を用いた二酸化炭素還元と複合系への展開0From molecular metal complex to metal-organic framework: The CO2 reduction photocatalysts with clear and tunable structure297Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO2 Reduction Driven by Visible Light280Oxygen‐Doped Ta3N5 Nanoparticles for Enhanced Z‐Scheme Carbon Dioxide Reduction with a Binuclear Ruthenium(II) Complex under Visible Light13Photocathode Characteristics of a Spray-Deposited Cu2ZnGeS4 Thin Film for CO2 Reduction in a CO2-Saturated Aqueous Solution45A facile approach for the synthesis of ZnxCd1-xS/C nanocomposite to enhance photocatalytic activity10The photocatalytic phenol degradation mechanism of Ag-modified ZnO nanorods193Synthesis of Copolymerized Carbon Nitride Nanosheets from Urea and 2‐Aminobenzonitrile for Enhanced Visible Light CO2 Reduction with a Ruthenium(II) Complex Catalyst16Recent advances in engineering active sites for photocatalytic CO 2 reduction144Photocatalytic CO2 Reduction under Visible‐Light Irradiation by Ruthenium CNC Pincer Complexes31Z‐Schema‐Photokatalysesysteme für die Kohlendioxidreduktion: Wo stehen wir heute?40Z‐Scheme Photocatalytic Systems for Carbon Dioxide Reduction: Where Are We Now?667Artificial Trees for Artificial Photosynthesis: Construction of Dendrite-Structured α-Fe2O3/g-C3N4 Z-Scheme System for Efficient CO2 Reduction into Solar Fuels87Recent advances on visible-light-driven CO2 reduction: Strategies for boosting solar energy transformation17An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding71Selective CO2 reduction into formate using Ln–Ta oxynitrides combined with a binuclear Ru(II) complex under visible light18Effective Suppression of O2 Quenching of Photo-Excited Ruthenium Complex Using RNA Aptamer3Recent Progress in Mixed‐Anion Materials for Solar Fuel Production58All-solid-state Z-scheme systems for photocatalytic CO2 reduction0Metal–Organic Framework Decorated Cuprous Oxide Nanowires for Long‐lived Charges Applied in Selective Photocatalytic CO2 Reduction to CH4230Metal–Organic Framework Decorated Cuprous Oxide Nanowires for Long‐lived Charges Applied in Selective Photocatalytic CO2 Reduction to CH415Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO 2 reduction in water208In situ construction of a 2D/2D heterostructured ZnIn 2 S 4 /Bi 2 MoO 6 Z -scheme system for boosting the photoreduction activity of Cr( vi )53Photochemical reduction of carbon dioxide to formic acid115Plasmonic photocatalysis1New Visible‐Light‐Responsive Photocatalysts for Water Splitting Based on Mixed Anions1Molecule/Semiconductor Hybrid Materials for Visible-Light CO 2 Reduction: Design Principles and Interfacial Engineering99Organic terpyridine molecule as an efficient cocatalyst for metal–free CO2 photoreduction mediated by mesoporous graphitic carbon nitride27Engineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels112CO2 Reduction Using Molecular Photocatalysts2Ag-based photocatalytic heterostructures: Construction and photocatalytic energy conversion application71Photocatalytic Reduction of Cr(VI) and Degradation of Organic Pollutants by Z-Scheme g-C3N4/Bi2S3 Heterojunction8Multi anion-based materials: Synthesis and catalytic applications30Advances in Z‐scheme semiconductor photocatalysts for the photoelectrochemical applications: A review281Fabrication and Characterization of Inverse-Opal Titania Films for Enhancement of Photocatalytic Activity9Photocatalytic materials applications for sustainable agriculture29Emerging Dual-Functional 2D transition metal oxides for carbon capture and Utilization: A review47Toward Excellence in Photocathode Engineering for Photoelectrochemical CO2 Reduction: Design Rationales and Current Progress104Comprehensive Review for an Efficient Charge Transfer in Single Atomic Site Catalyst/Organic Polymers toward Photocatalytic CO2 Reduction26Structure-Dependent Surface Molecule-Modified Semiconductor Photocatalysts: Recent Progress and Future Challenges29Tailoring the electronic structure of In 2 O 3 /C photocatalysts for enhanced CO 2 reduction39Nickel Single-Atom Catalyst-Mediated Efficient Redox Cycle Enables Self-Checking Photoelectrochemical Biosensing with Dual Photocurrent Readouts32Fabrication of Ti-doped Bi2S3/NiO p-n heterojunction with enhanced visible-light–driven photocatalytic activity21Unique Thermal Structural Phase Transitions Exhibited by Unsymmetrical Organometallic Gold(III)‐Dithiolene Complexes with Pentylthio and Hexylthio Groups3Surface-Specific Modification of Graphitic Carbon Nitride by Plasma for Enhanced Durability and Selectivity of Photocatalytic CO2 Reduction with a Supramolecular Photocatalyst48Photocatalysts for CO2 reduction and computational insights41Epitaxially grown silicon-based single-atom catalyst for visible-light-driven syngas production32Morphology, Energy Level Alignment, and Charge Transfer at the Protoporphyrin IX–Semiconductor Interface3Relationships between Compositional Heterogeneity and Electronic Spectra of (Ga1–xZnx)(N1–xOx) Nanocrystals Revealed by Valence Electron Energy Loss Spectroscopy3Photocatalytic water splitting603Mesoporous Mixed-Metal–Organic Framework Incorporating a [Ru(Phen)3]2+ Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines29Polyoxometalate-based hybrid materials with electronic interaction boosting photocatalytic H2 evolution coupled with alcohol oxidation11Synergism of the Plasmonic Effect and Schottky Junction to Effectively Facilitate Photocatalytic CO2 Reduction of Bi4O5I2@Cu43A triple tandem reaction for the upcycling of products from poorly selective CO2 photoreduction systems108Recent Progress in All‐Solid‐State Z‐Scheme Heterostructures for Photoreduction of CO 230Synergetic Effect of Ligand Modification of a Ru(II) Complex Catalyst and Ag Loading for Constructing a Highly Active Hybrid Photocatalyst Using C3N4 for CO2 Reduction11Metal-free carbazole–thiophene photosensitizers designed for a dye-sensitized H2-evolving photocatalyst in Z-scheme water splitting6Na-Ru bimetallic functional sites promote photo-driven CO2 directed conversion into CH415Charge Transport Approaches in Photocatalytic Supramolecular Systems Composing of Semiconductor and Molecular Metal Complex for CO2 Reduction15Molecular Terpyridine–Lanthanide Complexes Modified Carbon Nitride for Enhanced Photocatalytic CO2 Reduction6How can heteroatoms boost the performance of photoactive nanomaterials for wastewater purification?16Mechanistic study on photocatalysis properties of Cu3N/TiO2 heterojunction nanorods1Novel environmentally-friendly 0D/3D TiO2@FeMoO4 binary composite with boosted photocatalytic performance: Structural analysis and Z-scheme interpretations25Modeling heterojunctions: a computational chemistry perspective9Photocatalytic CO2 reduction in aqueous media using a silver-loaded conjugated polymer and a Ru(II)-Ru(II) supramolecular photocatalyst6Tantalum oxynitride (TaON): synthesis routes, structural diversity, and solar water splitting activity2Artificial Photosynthesis via Photocatalytic, Electrocatalytic, and Photoelectrocatalytic CO2 Conversion0Design Strategy for Heteroleptic Ir(III) Photosensitizers with Spatially Separated Excited Electrons toward Efficient CO 2 Reduction1Strategies to activate conjugated polymers by molecular catalysts for light-driven CO2 conversions1

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  1. Facile fabrication of oxygen and carbon co-doped carbon nitride nanosheets for efficient visible light photocatalytic H 2 evolution and CO 2 reduction

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  2. Cocatalysts for Selective Photoreduction of CO 2 into Solar Fuels

    Chemical Reviews · 2019-02-14

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  3. 1．金属錯体光触媒を用いた二酸化炭素還元と複合系への展開

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  4. From molecular metal complex to metal-organic framework: The CO2 reduction photocatalysts with clear and tunable structure

    Coordination Chemistry Reviews · 2019-04-15

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  5. Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO2 Reduction Driven by Visible Light

    Advanced Materials · 2019-05-08

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  6. Oxygen‐Doped Ta3N5 Nanoparticles for Enhanced Z‐Scheme Carbon Dioxide Reduction with a Binuclear Ruthenium(II) Complex under Visible Light

    ChemPhotoChem · 2019-05-28

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  7. Photocathode Characteristics of a Spray-Deposited Cu2ZnGeS4 Thin Film for CO2 Reduction in a CO2-Saturated Aqueous Solution

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  8. A facile approach for the synthesis of ZnxCd1-xS/C nanocomposite to enhance photocatalytic activity

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  9. The photocatalytic phenol degradation mechanism of Ag-modified ZnO nanorods

    Journal of Materials Chemistry C · 2019-11-29

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  10. Synthesis of Copolymerized Carbon Nitride Nanosheets from Urea and 2‐Aminobenzonitrile for Enhanced Visible Light CO2 Reduction with a Ruthenium(II) Complex Catalyst

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  11. Recent advances in engineering active sites for photocatalytic CO 2 reduction

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  12. Photocatalytic CO2 Reduction under Visible‐Light Irradiation by Ruthenium CNC Pincer Complexes

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  13. Z‐Schema‐Photokatalysesysteme für die Kohlendioxidreduktion: Wo stehen wir heute?

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  14. Z‐Scheme Photocatalytic Systems for Carbon Dioxide Reduction: Where Are We Now?

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  15. Artificial Trees for Artificial Photosynthesis: Construction of Dendrite-Structured α-Fe2O3/g-C3N4 Z-Scheme System for Efficient CO2 Reduction into Solar Fuels

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  16. Recent advances on visible-light-driven CO2 reduction: Strategies for boosting solar energy transformation

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  17. An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding

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  18. Selective CO2 reduction into formate using Ln–Ta oxynitrides combined with a binuclear Ru(II) complex under visible light

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  19. Effective Suppression of O2 Quenching of Photo-Excited Ruthenium Complex Using RNA Aptamer

    Bulletin of the Chemical Society of Japan · 2020-10-12

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  20. Recent Progress in Mixed‐Anion Materials for Solar Fuel Production

    Solar RRL · 2020-10-24

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  21. All-solid-state Z-scheme systems for photocatalytic CO2 reduction

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  22. Metal–Organic Framework Decorated Cuprous Oxide Nanowires for Long‐lived Charges Applied in Selective Photocatalytic CO2 Reduction to CH4

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  23. Metal–Organic Framework Decorated Cuprous Oxide Nanowires for Long‐lived Charges Applied in Selective Photocatalytic CO2 Reduction to CH4

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  24. Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO 2 reduction in water

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  25. In situ construction of a 2D/2D heterostructured ZnIn 2 S 4 /Bi 2 MoO 6 Z -scheme system for boosting the photoreduction activity of Cr( vi )

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  28. New Visible‐Light‐Responsive Photocatalysts for Water Splitting Based on Mixed Anions

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  29. Molecule/Semiconductor Hybrid Materials for Visible-Light CO 2 Reduction: Design Principles and Interfacial Engineering

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  30. Organic terpyridine molecule as an efficient cocatalyst for metal–free CO2 photoreduction mediated by mesoporous graphitic carbon nitride

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  31. Engineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels

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  32. CO2 Reduction Using Molecular Photocatalysts

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  33. Ag-based photocatalytic heterostructures: Construction and photocatalytic energy conversion application

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  34. Photocatalytic Reduction of Cr(VI) and Degradation of Organic Pollutants by Z-Scheme g-C3N4/Bi2S3 Heterojunction

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  35. Multi anion-based materials: Synthesis and catalytic applications

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  36. Advances in Z‐scheme semiconductor photocatalysts for the photoelectrochemical applications: A review

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  38. Photocatalytic materials applications for sustainable agriculture

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  40. Toward Excellence in Photocathode Engineering for Photoelectrochemical CO2 Reduction: Design Rationales and Current Progress

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  41. Comprehensive Review for an Efficient Charge Transfer in Single Atomic Site Catalyst/Organic Polymers toward Photocatalytic CO2 Reduction

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  42. Structure-Dependent Surface Molecule-Modified Semiconductor Photocatalysts: Recent Progress and Future Challenges

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  43. Tailoring the electronic structure of In 2 O 3 /C photocatalysts for enhanced CO 2 reduction

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  45. Fabrication of Ti-doped Bi2S3/NiO p-n heterojunction with enhanced visible-light–driven photocatalytic activity

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  47. Surface-Specific Modification of Graphitic Carbon Nitride by Plasma for Enhanced Durability and Selectivity of Photocatalytic CO2 Reduction with a Supramolecular Photocatalyst

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  48. Photocatalysts for CO2 reduction and computational insights

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  49. Epitaxially grown silicon-based single-atom catalyst for visible-light-driven syngas production

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