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RESEARCH PAPER · Dalton Transactions · 2018

Enhanced luminescence of a Ba 2 GdSbO 6 :Mn 4+ red phosphor via cation doping for warm white light-emitting diodes

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Enhanced luminescence of a Ba 2 GdSbO 6 :Mn 4+ red phosphor via cation doping for warm white light-emitting diodesOriginalHighly efficient rare-earth-free deep red emitting phosphor La 2 Li 1−y Sb 1−x O 6 : x Mn 4+ , y Mg 2+ : application in high-power warm w-LEDs63Novel far-red-emitting SrGdAlO 4 :Mn 4+ phosphors with excellent responsiveness to phytochrome P FR for plant growth lighting39Photoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer78Preparation, characterization, and luminescence properties of double perovskite SrLaMgSbO 6 :Mn 4+ far-red emitting phosphors for indoor plant growth lighting29Synthesis and photoluminescence properties of novel far-red-emitting BaLaMgNbO 6 :Mn 4+ phosphors for plant growth LEDs106Synthesis, structure, and luminescence characteristics of far-red emitting Mn 4+ -activated LaScO 3 perovskite phosphors for plant growth15Thermally stable La 2 LiSbO 6 :Mn 4+ ,Mg 2+ far-red emitting phosphors with over 90% internal quantum efficiency for plant growth LEDs57Tunable Optical Properties and Enhanced Thermal Quenching of Non-Rare-Earth Double-Perovskite (Ba1–xSrx)2YSbO6:Mn4+ Red Phosphors Based on Composition Modulation135Enhanced luminescence performances of Mn4+:Y3Al5O12 red phosphor by ions of Rn2+ (Be2+, Mg2+, Sr2+, Ba2+)19Room-temperature synthesis, optimized photoluminescence and warm-white LED application of a highly efficient non-rare-earth red phosphor33Luminescence properties of a non-rare-earth doped oxyfluoride LiAl4O6F:Mn4+ red phosphor for solid-state lighting72A novel rare-earth free red-emitting Li3Mg2SbO6:Mn4+ phosphor-in-glass for warm w-LEDs: Synthesis, structure, and luminescence properties101Synthesis and luminescence properties of Mn4+-activated Ba2LaSbO6 deep-red phosphor38Synthesis and photoluminescence properties of novel Ca2LaSbO6:Mn4+ double perovskite phosphor for plant growth LEDs115Near-ultraviolet excited Tm3+ and Dy3+ ions co-doped barium lanthanum silica oxide phosphors for white-light applications38A novel red-emitting La 2 CaHfO 6 :Mn 4+ phosphor based on double perovskite structure for pc-WLEDs lighting27Double perovskite A 2 LaNbO 6 :Mn 4+ ,Eu 3+ (A = Ba, Ca) phosphors: potential applications in optical temperature sensing121Enhanced photoluminescence and thermal properties due to size mismatch in Mg 2 Ti x Ge 1−x O 4 :Mn 4+ deep-red phosphors44Highly efficient red-emitting Ca 2 YSbO 6 :Eu 3+ double perovskite phosphors for warm WLEDs48Luminescent perovskites: recent advances in theory and experiments259Mn 4+ -activated BaLaMgSbO 6 double-perovskite phosphor: a novel high-efficiency far-red-emitting luminescent material for indoor plant growth lighting42Mn 4+ -activated Li 3 Mg 2 SbO 6 as an ultrabright fluoride-free red-emitting phosphor for warm white light-emitting diodes95Review—Tanabe−Sugano Energy-Level Diagram and Racah Parameters in Mn4+-Activated Red and Deep Red-Emitting Phosphors78Synthesis and luminescence properties of a novel dazzling red-emitting phosphor NaSr 3 SbO 6 :Mn 4+ for UV/n-UV w-LEDs37Simultaneously enhanced far-red luminescence and thermal stability in Ca3Al4ZnO10:Mn4+ phosphor via Mg2+ doping for plant growth lighting69CaYAlO4:Mn4+,Mg2+: An efficient far-red-emitting phosphor for indoor plant growth LEDs58Novel Mn 4+ doped Ca 2 GdSbO 6 red–emitting phosphor: A potential color converter for light‐emitting diodes54A novel red phosphor Ba2La4Y4(SiO4)6O2:Eu3+ with high quantum yield and thermal stability for warm white LEDs81Synthesis and photoluminescence properties of novel Sr3LiSbO6:Mn4+ red phosphor for indoor plant growth51Ultra-fast synthesis and photoluminescence properties of red-emitting NaBiF4:Eu3+ nanophosphors by various NH4F concentrations12Low temperature synthesis and photoluminescence properties of Mn4+-doped La2MgTiO6 deep-red phosphor with a LiCl flux24Cyan-emitting Ba3Y2B6O15:Ce3+,Tb3+ phosphor: A potential color converter for near-UV-excited white LEDs56Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation89Novel Ca2GdTaO6:Mn4+,M (M = Li+, Na+, K+, and Mg2+) red phosphors for plant cultivation light-emitting diodes: Synthesis and luminescence properties47Non-radiative processes and luminescence quenching in Mn4+ doped phosphors27Deep-red-emitting Ca2LuSbO6:Mn4+ phosphors for plant growth LEDs: Synthesis, crystal structure, and photoluminescence properties69Synthesis and photoluminescence properties of a novel high-efficiency red-emitting Ca2LuSbO6:Eu3+ phosphor for WLEDs69Synthesis and Research of rare earth-doped color tunable Sr3Gd(PO4)3 phosphors6Synthesis and photoluminescence properties of a novel Ca2LaNbO6:Mn4+ double perovskite phosphor for plant growth LEDs20Synthesis, Crystal Structure, and Photoluminescence Characteristics of High-Efficiency Deep-Red Emitting Ba2GdTaO6:Mn4+ Phosphors60Green route, room-temperature synthesis and luminescence properties of a non-rare-earth doping Zn2+ based narrow-band red phosphor for WLEDs16Review—Mn 4+ -Activated Red and Deep Red-Emitting Phosphors193Luminescence properties of double perovskite Gd2MgTiO6:Tb3+ phosphors by solid-state reaction method7Sm3+-activated Y2Mo4O15 red-emitting microparticles with admirable luminescent performance for indoor illumination25Highly efficient and thermally stable CaMgLaSbO6:Mn4+ red phosphor for indoor plant growth17Highly thermal-sensitive robust LaTiSbO6:Mn4+ with a single-band emission and its topological architecture for single/dual-mode optical thermometry93Engineering cation vacancies to improve the luminescence properties of Ca 14 Al 10 Zn 6 O 35 : Mn 4+ phosphors for LED plant lamp42Luminescence and Energy-Transfer Properties in Bi 3+ /Mn 4+ -Codoped Ba 2 GdNbO 6 Double-Perovskite Phosphors for White-Light-Emitting Diodes111Synthesis and luminescence properties of CaLaMgNbO6:Mn4+ red phosphor for UV-based w-LEDs3NaLa2SbO6:Mn4+ far-red phosphor: Synthesis, luminescence properties and emission enhancement by Al3+ ions15Luminescence and self-referenced optical temperature sensing performance in Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors263Tunable white light emission of rare earth ions doped single matrix SrAl2Si2O8 phosphors9Comparative investigation on luminescence properties of Mn4+ doped Ba6Y2W3O18 and Ba6Gd2W3O18 phosphors24A New Co-Substitution Strategy as a Model to Study a Rare-Earth-Free Spinel-Type Phosphor with Red Emissions and Its Application in Light-Emitting Diodes33Highly efficient near-UV-excitable Ca 2 YHf 2 Al 3 O 12 :Ce 3+ ,Tb 3+ green-emitting garnet phosphors with potential application in high color rendering warm-white LEDs175Far red-emitting double perovskite phosphors Ca2(1-x)Sr2xGdSbO6:Mn4+: Luminescence improvement based on composition modulation39Effects of Ti4+- and W6+-substitution on photoluminescence properties of Sr2GdSbO6:Mn4+ phosphor for plant cultivation41Obtaining Efficiently Tunable Red Emission in Ca3-δLnδWO6:Mn4+ (Ln = La, Gd, Y, Lu, δ = 0.1) Phosphors Derived from Nearly Nonluminescent Ca3WO6:Mn4+ via Ionic Substitution Engineering for Solid-State Lighting46Ba3Y2WO9:Mn4+: A near-UV and yellow-green light excited red phosphor for greenhouse cultivation42A red phosphor LaSc3(BO3)4:Eu3+ with zero-thermal-quenching and high quantum efficiency for LEDs251Multicolor-tunable Ca8MgBi(PO4)7: Ce3+, Tb3+, Mn2+ phosphors under dual-channel excitation6NaCaTiTaO6:Sm3+: A novel orange-red-emitting tantalate phosphor with excellent thermal stability and high color purity for white LEDs63A novel efficient Mn4+-activated Ba2YTaO6 far-red emitting phosphor for plant cultivation LEDs: Preparation and photoluminescence properties26Ultra-high color rendering warm-white light-emitting diodes based on an efficient green-emitting garnet phosphor for solid-state lighting276Luminescence properties of color-tunable YNbO4: Dy3+, Tm3+ phosphors21Localized Charge Accumulation Driven by Li+ Incorporation for Efficient LED Phosphors with Tunable Photoluminescence77Glass-ceramic phosphors for solid state lighting: A review117Tunable photoemission and energy transfer of heavily Bi3+,Eu3+ co-doped Y4GeO8 phosphors40Enhanced luminescence properties of Ca 1+x Sr 2−x Al 2 O 6 :Eu 3+ (0 ≤ x ≤ 1) red phosphors based on composition modulation6Enhancement of Mn 4+ Emission by Means of Energy Transfer in Mg 2 Al 4 Si 5 O 18 :Dy 3+ , Mn 4+ Phosphors5Bright red luminescence from Mn4+ ions doped Sr2LuTaO6 double-perovskite phosphors43Luminescent properties of Na2GdMg2(VO4)3:Eu3+ red phosphors for NUV excited pc-WLEDs59Synthesis, crystal structure and photoluminescence properties of novel far-red-emitting SrLaZnSbO6:Mn4+ double-perovskite phosphors for plant cultivation LEDs33Dual-mode dichromatic SrBi4Ti4O15: Er3+ emitting phosphor for anti-counterfeiting application111Enhanced luminescence performances of Sr2YTaO6:Mn4+ narrow red phosphor by Rn+ (Li+,Na+,Ca2+,Mg2+) ions31A novel far-red emitting phosphor activated Ba2LuTaO6:Mn4+: Crystal structure, optical properties and application in plant growth lighting37Luminescence and Energy Transfer of Li 2 Y 4 (MoO 4 ) 7 : Ln 3+ (Ln = Dy, Eu) Phosphors5Realizing a Novel Red-Emitting Ca0.99MoO4:0.01Eu3+, Al3+ Phosphor: Charge Compensation, Molten Salt Synthesis0Finding a novel Ca2M3(SiO4)2(PO4)O (M = La, Y):Eu3+ red-emitting phosphor with positive responsiveness to phytochrome: Application in plant cultivation11Using an excellent near-UV-excited cyan-emitting phosphor for enhancing the color rendering index of warm-white LEDs by filling the cyan gap81A review: X‐ray excited luminescence of gadolinium based optoelectronic phosphors7Turning on the luminescence of Sr5(PO4)3Cl: Eu2+ by doping of La, Gd and Lu ions for full-spectrum lighting application18Utilizing energy transfer strategy to produce efficient green luminescence in Ca2LuHf2Al3O12:Ce3+,Tb3+ garnet phosphors for high-quality near-UV-pumped warm-white LEDs52Local structure and luminescent properties of Cs2KGaF6:Mn4+ phosphor for backlight white LEDs32Novel double‐perovskite Mg 2 InSbO 6 :Sm 3+ phosphor with excellent heat‐resistant performance and high color purity used in white LEDs23Novel non-rare-earth red-emitting phosphor Li4AlSbO6:Mn4+ for plant growth: Crystal structure, luminescence properties and its LED device61Finding an efficient far-red-emitting CaMg2La2W2O12:Mn4+ phosphor toward indoor plant cultivation LED lighting91Optical and Magnetic Properties of Cubic Double Perovskites Ba2RSbO6(R= Dy, Gd) Coordinated to Lattice Dynamical and Crystal‐Field Computations4Deep‐red‐emitting Ca 2 ScSbO 6 :Mn 4+ phosphors with a double perovskite structure: Synthesis, characterization and potential in plant growth lighting27Analysis of crystal-field effect on luminescence spectra of Mn 4+ (3d 3 ) ion-doped double perovskite La 2 ZnTiO 6 phosphor by semiempirical computations: exchange charge model and superposition model19Photoluminescence and thermal properties of a red-emitting LnNbO4:Pr3+ (Ln = La, Gd, and Y) phosphor for warm WLEDs2Novel deep‐red‐emitting double‐perovskite type Ca 2 ScNbO 6 :Mn 4+ phosphor: Structure, spectral study, and improvement by NaF flux16A tunable blue–cyan dual emission phosphor in Ca 4− x Lu 2 x Hf 1− x Ge 3 O 12 :Bi 3+ via forming segregation structure for WLEDs13Luminescence properties, crystal field and nephelauxetic effect on (NH4)2NaMF6: Mn4+ (M = Al, Ga and In) red phosphors for warm white light-emitting diodes22Excellent Quantum Efficiency and Superior Color Purity Red-Emitting CaAl12O19–CaAl4O7–MgAl2O4:Mn4+ Phosphors for Plant Growth and High Color Rendering Index White Light-Emitting Diode Applications37Rare-earth-free Mn4+ ions activated Ba2YSbO6 phosphors for solid-state lighting, flexible display, and anti-counterfeiting applications50Green synthesis and luminescent properties of seven coordination K3ZrF7:Mn4+ red phosphor for warm WLEDs7Fluorescence Lifetime-Based Luminescent Thermometry Material with Lifetime Varying over a Factor of 5044Monodisperse CaAl12O19:Mn4+ microspheres for full-spectrum white LEDs8Analysis of crystal-field effects on the energy levels of Mn4+ ions doped in different photoluminescent host lattices, exhibiting lowering of site symmetry: Exchange charge and superposition model calculations, for potential applications21Synthesis and optical properties of Mn4+ activated double-perovskite niobate deep red phosphors for WLEDs and plant cultivation19Luminescence and Energy Transfer of Li2Y4(MoO4)7:Ln (Ln = Dy, Tb) Phosphors2A novel yellow-emitting CaGdSbWO8:Dy3+ single-phase phosphor with high thermal stability and application in w-LEDs25Equivalent chemical substitution in double–double perovskite-type ALaLiTeO 6 :Mn 4+ (A = Ba 2+ , Sr 2+ , Ca 2+ ) phosphors enabling wide range crystal field strength regulation and efficient far-red emission17Spectroscopic Properties and Thermal Stability of a Mn4+-Doped Polyfluoride Phosphor for Solid-State Lighting0A dual-functional platform for plant cultivation and wide-range optical thermometry based on vibration sidebands13An efficient double-perovskite CaLaLiTeO6:Mn4+ far-red phosphor towards indoor plant lighting application57Structural, electronic, magnetic, and optical properties of a novel double perovskite Ba2GdRuO615Photoluminescence and temperature dependent properties of Bi3+, Sm3+ co-doped Ca2YSbO6 phosphor for dual-emitting optical thermometer18Realizing multicolor tunable photoluminescence in La2MgTiO6: Tb3+, Eu3+ phosphors via energy transfer and application for white light-emitting diodes23Design and fabrication of a bimodal emitting phosphor by co-doping two different activators for high sensitivity temperature sensing12Mn4+ activated phosphors in photoelectric and energy conversion devices56Highly efficient and thermally robust phosphor-in-glass ceramic (PiGc) for high-brightness laser-driven lighting13Photoluminescence properties of Sb3+-activated Ca2YTaO6 dual color emitting phosphors for plant growth LEDs applications11Analysis of crystal-field effects on the energy levels of Mn4+ ions doped in Gd2MgTiO6 phosphor using exchange charge model and superposition model1Double perovskite La2LiNb(1-)O6: xMn4+ red phosphors with excellent humidity stability and high thermal stability for plant growth LEDs11Photoluminescence properties of double perovskite Ca2LuTaO6:Bi3+/Sm3+ white light emitting phosphors23The nephelauxetic function he: A tool to locate the emission of Mn4+ in oxides and fluorides3Optimized Mn4+ doped Sr9Y2W4O24 perovskite for enhanced far-red-emitting luminescent material30Review—Structural and Optical Interpretations on Phosphor-Based Optical Thermometry9A novel luminescent material with good luminescent thermal stability1Preparation and luminescence properties of broadband red-emitting Sr3LiSbO6: Mn4+, Sm3+ phosphor5Self-luminescence properties of Zn3(VO4)2 phosphors and the effect of Eu3+ ions doping9A novel Mn4+-doped Li2Mg4TiO7 red-emitting phosphor for warm white light-emitting diodes8Synthesis, Structure and Luminescence Properties of Mn-doped MgAl2O4 Red-Emitting Phosphors with Varying Sintering Temperature5Valence compensation strategy-driven emission and thermal stability enhancement for dual-mode wide-range optical thermometry9Structural, Electronic, and Magnetic Properties of Ferrimagnetic Double‐Perovskite Ba 2 GdRuO 6 : Density Functional Theory and Monte Carlo Simulation20Spectroscopic, photometric properties and energy transfer mechanism of white light emitting Li2SiO3:Tb3+, Eu3+, Mn4+ phosphors2Broadband near-infrared phosphor LiTi 2 (PO 4 ) 3 : x Cr 3+ realized via multi-site occupation8Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application11Tuning structural, spectroscopic and electronic properties of Mn4+ doped Y2GaSbO7 phosphor for optoelectronics and phototherapy applications10Red-emitting Mn 4+ -doped CaAl 4 O 7 phosphors for applications in high color rendering index warm white light-emitting diodes and plant growth LEDs responsive to red phytochrome and all of chlorophyll3Fabrication and luminescent properties of Ca2YSbO6: Sm3+, Dy3+ double-perovskite phosphors2Boosting luminescence of Ca2GdTaO6: Mn4+ red phosphors via Li+ charge compensation for plant growth LEDs1Ca2GdTi0.5W0.5O6:Mn4+ deep-red phosphor with high thermal stability for application in plant growth lighting1Highly efficient La2(Li, Mg)(Nb, Al)O6: Mn4+ far-red phosphor realized by crystal-field engineering for plant growth lighting6Solid solution-assisted local coordination modulation: A facile strategy for high-performance Mn4 + -doped SrLaMgTi0.5W0.5O6 red phosphors0Design and investigation of Ca2YZr0.5W0.5O6:Mn4+ deep-red phosphor with good thermal stability for plant growth lighting5Design of Ca2LaZr0.5W0.5O6 double perovskites: Tailoring Mn4+ luminescent centers for high efficiency and thermal quenching resistance0Luminescence properties of Mn4+-doped Sr2GdZr0.5W0.5O6 regulated by local coordination environment0Sr3LiSbO6: Mn4+/Eu3+ phosphors for plant growth: Luminescence enhancement and light-converting film demonstration1Structure regulation of transition metal ion-activated double perovskite phosphors: performance optimization of Sr2YZr0.5W0.5O6:Mn4+0Dual‑substitution strategy for highly efficient Far‑red Mn4+‑doped double perovskite phosphors toward plant growth lighting0Ultraviolet/green light dual-excited far-red SrLa1-yGdyAl1-xGaxO4:Mn4+ phosphors for high-efficiency plant cultivation0Anti-thermal quenching of YNbO4:Eu3+/Er3+ for multi-functional applications0Luminescence properties and ns2-related mechanism of Sb3+-activated Sr2YTaO6 red phosphors0

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