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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2018

Existence of Solid Electrolyte Interphase in Mg Batteries: Mg/S Chemistry as an Example

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Existence of Solid Electrolyte Interphase in Mg Batteries: Mg/S Chemistry as an ExampleOriginalPrimary Sjogren's syndrome: rarity in India.20A conductive selenized polyacrylonitrile cathode in nucleophilic Mg 2+ /Li + hybrid electrolytes for magnesium–selenium batteries40A critical review of cathodes for rechargeable Mg batteries591Direct insights into the electrochemical processes at anode/electrolyte interfaces in magnesium-sulfur batteries50A Review of Advanced Energy Materials for Magnesium–Sulfur Batteries154On the Feasibility of Practical Mg–S Batteries: Practical Limitations Associated with Metallic Magnesium Anodes64High-capacity lithium sulfur battery and beyond: a review of metal anode protection layers and perspective of solid-state electrolytes125Challenges and recent progress in the design of advanced electrode materials for rechargeable Mg batteries151CHAPTER 1. Motivation for a Magnesium Battery7Magnesium Batteries23Electrochemically-driven interphase conditioning of magnesium electrode for magnesium sulfur batteries28Tuning Anionic Chemistry To Improve Kinetics of Mg Intercalation139Halide‐Based Materials and Chemistry for Rechargeable Batteries238Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien18High-Energy-Density Rechargeable Mg Battery Enabled by a Displacement Reaction86A Metal–Organic Framework Thin Film for Selective Mg2+ Transport70A Metal–Organic Framework Thin Film for Selective Mg2+ Transport1A Pyrazine‐Based Polymer for Fast‐Charge Batteries260A Pyrazine‐Based Polymer for Fast‐Charge Batteries22Mapping mechanisms and growth regimes of magnesium electrodeposition at high current densities120Investigation of Magnesium–Sulfur Batteries using Electrochemical Impedance Spectroscopy159Quest for magnesium-sulfur batteries: Current challenges in electrolytes and cathode materials developments69Three-Dimensional Magnesiophilic Scaffolds for Reduced Passivation toward High-Rate Mg Metal Anodes in a Noncorrosive Electrolyte72Current status and future directions of multivalent metal-ion batteries1519Synthesis and characterization of heterogeneous catalyst EDTMPA-Cu-LDH and study of the mechanism of visible-light photocatalytic degradation of Rhodamine B10Insight into interfacial processes and degradation mechanism in magnesium metal batteries24Characteristics of magnesium-sulfur batteries based on a sulfurized poly(acrylonitrile) composite and a fluorinated electrolyte34Pseudocapacitive Ti-Doped Niobium Pentoxide Nanoflake Structure Design for a Fast Kinetics Anode toward a High-Performance Mg-Ion-Based Dual-Ion Battery52Material design strategies to improve the performance of rechargeable magnesium–sulfur batteries77Voltage hysteresis of magnesium anode: Taking magnesium-sulfur battery as an example20Facilitated magnesium atom adsorption and surface diffusion kinetics via artificial bismuth-based interphases27Nanostructured alkali and alkaline earth metal interfaces for high-energy batteries5Influence of Complexing Additives on the Reversible Deposition/Dissolution of Magnesium in an Ionic Liquid16Material stability assessment of R-1234ze(E) as a working fluid for supercritical organic Rankine cycle9Al2O3 Thin Films on Magnesium: Assessing the Impact of an Artificial Solid Electrolyte Interphase16Solid Electrolyte Interphase Growth on Mg Metal Anode: Case Study of Glyme‐Based Electrolytes30Polyoxometalate Modified Separator for Performance Enhancement of Magnesium–Sulfur Batteries63A Review of Magnesium Aluminum Chloride Complex Electrolytes for Mg Batteries86Progress and Perspective on Rechargeable Magnesium–Sulfur Batteries41Recent Advances in Emerging Non‐Lithium Metal–Sulfur Batteries: A Review76Formation of an Artificial Mg2+-Permeable Interphase on Mg Anodes Compatible with Ether and Carbonate Electrolytes60An artificial interphase enables the use of Mg(TFSI)2-based electrolytes in magnesium metal batteries87Mg Anode Passivation Caused by the Reaction of Dissolved Sulfur in Mg–S Batteries25Hybrid MgCl 2 /AlCl 3 /Mg(TFSI) 2 Electrolytes in DME Enabling High-Rate Rechargeable Mg Batteries79A Bismuth-Based Protective Layer for Magnesium Metal Anode in Noncorrosive Electrolytes193Surface Engineering of a Mg Electrode via a New Additive to Reduce Overpotential56Opportunities and Limitations of Ionic Liquid‐ and Organic Carbonate Solvent‐Based Electrolytes for Mg‐Ion‐Based Dual‐Ion Batteries37Controlled defective engineering of MoS2 nanosheets for rechargeable Mg batteries24Performance enhancement of rechargeable magnesium–sulfur batteries based on a sulfurized poly(acrylonitrile) composite and a lithium salt23Solvation sheath reorganization enables divalent metal batteries with fast interfacial charge transfer kinetics604Current Design Strategies for Rechargeable Magnesium-Based Batteries208Enabling Magnesium Anodes by Tuning the Electrode/Electrolyte Interfacial Structure24An Electrochemically Activated Nanofilm for Sustainable Mg Anode with Fast Charge Transfer Kinetics4Review—Carbon Electrodes in Magnesium Sulphur Batteries: Performance Comparison of Electrodes and Future Directions15Reversible Mg metal anode in conventional electrolyte enabled by durable heterogeneous SEI with low surface diffusion barrier111Development of chloride-free electrolyte for rechargeable magnesium battery0Dual Role of Mo6S8 in Polysulfide Conversion and Shuttle for Mg–S Batteries68Interaction of Mg with the ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide—An experimental and computational model study of the electrode–electrolyte interface in post-lithium batteries10Effect of doping nickel/cobalt ions on the structural and photocatalytic efficiency of magnesium manganese oxide materials for the environmental applications3Preparation of a Novel Organic Phosphonic Acid Intercalated Phosphate Tailings Based Hydrotalcite and Its Application in Enhancing Fire Safety for Epoxy Resin11An Electrochemically Polymerized Protective Layer for a Magnesium Metal Anode29Comparative Study of Conventional Electrolytes for Rechargeable Magnesium Batteries33RETRACTED: Super-hydrophilic MgO/NiCo2S4 heterostructure for high-efficient oxygen evolution reaction in neutral electrolytes39Enabling the conventional TFSI-based electrolytes for high-performance Mg/Li hybrid batteries by Mg electrode interfacial regulation13Achieving high-energy-density magnesium/sulfur battery via a passivation-free Mg-Li alloy anode50Off-Planar, Two-Dimensional Polymer Cathode for High-Rate, Durable Rechargeable Magnesium Batteries24Synthesis of Layered Double Hydroxides with Phosphate Tailings and Its Effect on Flame Retardancy of Epoxy Resin8Simultaneous optimization of solvation structure and water-resistant capability of MgCl2-based electrolyte using an additive combination of organic and inorganic lithium salts40Interface regulation of Mg anode and redox couple conversion in cathode by copper for high-performance Mg-S battery34Amorphous germanium-crystalline bismuth films as a promising anode for magnesium-ion batteries44Evolution of the Dynamic Solid Electrolyte Interphase in Mg Electrolytes for Rechargeable Mg-Ion Batteries24Organic Electrolyte Design for Rechargeable Batteries: From Lithium to Magnesium95Organic Electrolyte Design for Rechargeable Batteries: From Lithium to Magnesium3The Key Role of Magnesium Polysulfides in the Development of Mg-S Batteries27From lithium to emerging mono- and multivalent-cation-based rechargeable batteries: non-aqueous organic electrolyte and interphase perspectives137Surface film formation on Mg electrode containing magnesium polysulfides in TFSI-based electrolytes12A Low‐Cost and Recyclable Mg/SOCl2 Primary Battery Via Synergistic Solvation and Kinetics Regulation14A practical perspective on the potential of rechargeable Mg batteries138Post-functionalization of sulfur quantum dots and their aggregation-dependent antibacterial activity20The origin of anode–electrolyte interfacial passivation in rechargeable Mg-metal batteries141Unveiling the electronic properties of native solid electrolyte interphase layers on Mg metal electrodes using local electrochemistry10Insights into the Degradation Mechanism of the Magnesium Anode in Magnesium–Chalcogen Batteries: Revealing Principles for Anode Design with a 3D-Structured Magnesium Anode14Deeping insight of Mg(CF3SO3)2 and comprehensive modified electrolyte with ionic liquid enabling high-performance magnesium batteries74Structural, Morphological and Interfacial Investigation of H2V3O8 upon Mg2+ Intercalation3A Passivation-Free Solid Electrolyte Interface Regulated by Magnesium Bromide Additive for Highly Reversible Magnesium Batteries76Effect of Polysulfide Speciation on Mg Anode Passivation in Mg–S Batteries13Solid electrolyte interphase-ization of Mg2+-blocking layers for lithium ions in anode-free rechargeable lithium metal batteries17The Proof‐of‐Concept of Anode‐Free Rechargeable Mg Batteries30Advances in Cathodes for High-Performance Magnesium-Sulfur Batteries: A Critical Review17Slowing Sintering to Increase the Lifetime of Cu Nanoparticles on Metal Oxide Supports6Brief Introduction on Manufacturing and Characterization of Metallic Electrode and Corresponding Modified Materials2Chemical Reaction Networks Explain Gas Evolution Mechanisms in Mg-Ion Batteries40Reversible Mg-Metal Batteries Enabled by a Ga-Rich Protective Layer through One-Step Interface Engineering25Magnesium Anode Protection by an Organic Artificial Solid Electrolyte Interphase for Magnesium-Sulfur Batteries34A covalent organic framework protection layer for highly active and stable Mg metal anode toward magnesium–sulfur batteries10Polysulfides in Magnesium‐Sulfur Batteries38Porphyrin organic framework microsphere modified separator to enhance the cycling performance of Mg-S batteries3Diglyme-Based “Solvate Ionic Liquid” Gelled in Poly(vinylidine fluoride-co-hexafluoropropylene): A Flexible Electrolyte for High-Performance Magnesium-Ion Batteries14Unveiling the Mystery of LiF within Solid Electrolyte Interphase in Lithium Batteries88Ca2+ pre-intercalated bilayered vanadium oxide for high-performance aqueous Mg-ion batteries30Recent developments and future prospects of magnesium–sulfur batteries11Intercalation–Conversion and Displacement–Conversion Strategies in Magnesium–Sulfur Batteries4Impact of Cl- on the performance of magnesium oxysulfate (MOS) cement15References0Synchronous regulation on solvation structure and interface engineering to enable reversible magnesium metal batteries16Direct crystallization of deep eutectic solvent into solid-state electrolyte for magnesium metal batteries4Advancing Reversible Magnesium−Sulfur Batteries with a Self-Standing Gel Polymer Electrolyte20The Rise of Multivalent Metal–Sulfur Batteries: Advances, Challenges, and Opportunities46Challenges and Progress in Rechargeable Magnesium‐Ion Batteries: Materials, Interfaces, and Devices90Multifunctional Water Additive Enabling Stable Cycling of Chloride‐Free Magnesium Metal Batteries Based on Carbonate Electrolyte12Comparison of Construction Strategies of Solid Electrolyte Interface (SEI) in Li Battery and Mg Battery—A Review21Doping of magnesium ions into polyaniline enables high-performance Zn-Mg alkaline batteries13Bismuth/tin-based artificial interface for overcoming the anode passivation of rechargeable magnesium batteries2Enabling high-performance multivalent metal-ion batteries: current advances and future prospects146Contact Ion-Pair-Dominated Electrolyte Enabling Inorganic-Rich Solid–Electrolyte Interphase for Long-Cycling Magnesium Metal Anodes47Dendritic Magnesium Formation in Conventional Electrolytes: Local Adsorption of Amine Solvents at Inner Helmholtz Plane Matters8Boron sulfide chemical vapor deposition: A new method for the efficient and low-temperature growth of boron nitride nanotubes7Solid‐State Synthesis of Phase‐Pure Micron‐Sized Patrónite Vanadium Tetrasulfide toward Practical Magnesium Batteries2Achieving internal reversible plating/stripping by designing three-dimensional magnesiophilic gradient conductivity scaffolds for rechargeable Mg batteries4Tailoring Ca2+/Li+ Dual-Cation Gel Polymer Electrolytes via Cross-Linking for Reductive and Oxidative Stability in Ca-Metal Batteries3Anion-Regulated Solvation Structure and Electrode Interface toward Rechargeable Magnesium Batteries15Multifunctional Sustainable Carbon Catalyst for Glucose to Fructose Isomerization Reaction5The interfacial reactions of Mg battery anodes24Interfacial processes of Mg anodes for magnesium-sulfur batteries: An EIS study13Electrolyte Transport Parameters and Interfacial Effects in Calcium Metal Batteries: Analogies and Differences to Magnesium and Lithium Counterparts1CuCl as a Mg2+ reservoir for in situ interface layer engineering and highly stable Mg plating/stripping4Successes and failures predicting the solubility of solid electrolyte interphase (SEI) species0Biochar from renewable wood as an ion-conducting protective layer on stable magnesium metal anodes2Origin of preferential magnesium electrodeposition on separators: Synergistic effects of interface-accelerating desolvation and spatial confinement1Computationally‐Guided Development of Sulfide Solid Electrolyte Powder Coatings for Enhanced Stability and Performance of Solid‐State Batteries7Formation mechanisms of solid electrolyte interphase and its influence on lithium battery performance17Dendrite Formation and Self‐Healing Mechanism in Ionic Liquid‐Based Magnesium Batteries4Combining ultrathin lithiophobic and lithiophilic interlayers to enhance the reversibility of anode-free lithium metal batteries4Harnessing Transition Metal Chalcogenides for Efficient Performance in Magnesium–Sulfur Battery: Synergising Experimental and Theoretical Techniques3Suppressed calendar aging losses via dynamic interfaces in metal anodes0Unlocking Mg 2+ Transport in Magnesium Batteries: Aromatic Architectures and Systemic Co‐Design0Wide-temperature metal-sulfur batteries: Challenges and opportunities0Improving Mg deposition uniformity and interfacial ion diffusion kinetics in Mg(SO3CF3)2-based electrolyte by selecting suitable metal chloride0Solvation/Interface Tuning with Cl − ‐Mediated Passivation Suppression for MgCl 2 ‐Based Electrolytes1Electrochemical corrosion behavior of magnesium anodes0Insights into fluorochemical-driven combustion enhancement of Al-Mg alloy fuels by perfluoro-2-methyl-3-pentanone coating: a combined experimental and DFT study0

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  50. Solvation sheath reorganization enables divalent metal batteries with fast interfacial charge transfer kinetics

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