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REVIEW · Chemical Society Reviews · 2017

Chirality in adsorption on solid surfaces

Francisco Zaera

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Chirality in adsorption on solid surfacesOriginalInfrared absorption spectroscopy characterization of liquid–solid interfaces: The case of chiral modification of catalysts12Tuning of chiral construction, structural diversity, scale transformation and chiroptical applications66Chirality of 20‐membered unclosed cryptand: Macroring distortion via lariat arm modification4Role of Gold Adatoms in the Adsorption of Sulfide Species on the Gold(001)-hex Surface14First-Principles Calculations of Sarin Adsorption on Anatase Surfaces21The most stable adsorption geometries of two chiral modifiers on Pt(111)9Structural Insights into the Mechanism of Chiral Recognition and Chirality Transfer in Host–Guest Assemblies at the Liquid–Solid Interface23Chiral Autocatalysis and Mirror Symmetry Breaking38Synthesis of Chiral Dendrimer-Encapsulated Nanoparticle (DEN) Catalysts10Coadsorption of Formic Acid and Hydrazine on Cu(110) Single-Crystal Surfaces22Chiral Polymeric Nanocapsules and Their Use for Conformational Deracemization of Liquid Crystals4Biasing Enantiomorph Formation via Geometric Confinement: Nanocorrals for Chiral Induction at the Liquid–Solid Interface31Enantiopure Supramolecular Motifs of Self-Assembled Diamine-Based Chiral Molecules on Cu(100)2Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation181Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation45Cell adhesion and proliferation in chiral pores triggered by polyoxometalates22Enantiomeric helical TiO 2 nanofibers modulate different peptide assemblies and subsequent cellular behaviors3Expression of chirality amplification in self-assembled achiral/chiral polyfluorene blends7Reaction mechanisms at the homogeneous–heterogeneous frontier: insights from first-principles studies on ligand-decorated metal nanoparticles44Two-dimensional supramolecular crystal engineering: chirality manipulation26Determination of Specific Electrocatalytic Sites in the Oxidation of Small Molecules on Crystalline Metal Surfaces19Spin-Dependent Ionization of Chiral Molecular Films87Chirality Transfer in Gold Nanoparticles by l -Cysteine Amino Acid: A First-Principles Study44Enantioselective hydrogenation of α‐ketoesters catalyzed by cinchona alkaloid stabilized Rh nanoparticles in ionic liquid3On-Surface Synthesis of Chiral π-Conjugate Porphyrin Tapes by Substrate-Regulated Dehydrogenative Coupling21Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces39Homochiral MOF–Polymer Mixed Matrix Membranes for Efficient Separation of Chiral Molecules57Homochiral MOF–Polymer Mixed Matrix Membranes for Efficient Separation of Chiral Molecules238Chiral Surface and Geometry of Metal Nanocrystals149Large Enantiospecificity of Step–kink Metal Surfaces: Contributions from the Backbone and Side Chain of α-Amino Acids7Helix-sense-selective surface grafting polymerization for preparing optically active hybrid microspheres3Stereospecific interactions between chiral inorganic nanomaterials and biological systems274Theoretical investigation of amino-acid adsorption on hydroxylated quartz surfaces: dispersion can determine enantioselectivity14Relative Abundances of Surface Diastereomeric Complexes Formed by Two Chiral Modifiers That Differ by a Methyl Group1Supramolecular Chiral 2D Materials and Emerging Functions135Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite19Adsorption of Chiral Modifiers from Solution onto Supported Platinum Catalysts: The Effect of the Solvent, Other Coadsorbates, and the Support10Face-selective adsorption of a prochiral compound on the chiral pore-surface of a metal–macrocycle framework (MMF) directed towards stereoselective reactions9Recent advances, challenges and perspectives in enantioselective release58Distinguishing Enantiomers by Tip‐Enhanced Raman Scattering: Chemically Modified Silver Tip with an Asymmetric Atomic Arrangement21Distinguishing Enantiomers by Tip‐Enhanced Raman Scattering: Chemically Modified Silver Tip with an Asymmetric Atomic Arrangement1Structural investigation of caffeine monolayers on Au(111)4Near‐Enantiopure Trimerization of 9‐Ethynylphenanthrene on a Chiral Metal Surface15Near‐Enantiopure Trimerization of 9‐Ethynylphenanthrene on a Chiral Metal Surface2Thermally Induced Chiral Aggregation of Dihydrobenzopyrenone on Au(111)11Recognition at chiral interfaces: From molecules to cells49On-Surface Growth of Single-Layered Homochiral 2D Covalent Organic Frameworks by Steric Hindrance Strategy48A Chiral‐Label‐Free SERS Strategy for the Synchronous Chiral Discrimination and Identification of Small Aromatic Molecules83A Chiral‐Label‐Free SERS Strategy for the Synchronous Chiral Discrimination and Identification of Small Aromatic Molecules122D Chiral Stripe Nanopatterns Self‐Assembled from Rod‐Coil Block Copolymers on Microstripes9Chirality Effects in Biomolecular Systems: Calculation of the Relative Free Energies by Molecular Dynamics Simulations2Self-assembly and spectroscopic fingerprints of photoactive pyrenyl tectons on hBN/Cu(111)4Synthesis and Two‐Dimensional Chiral Surface Self‐Assembly of a π‐Conjugated System with Three‐Fold Symmetry: Benzotri(7‐Azaindole)17Synthesis and Two‐Dimensional Chiral Surface Self‐Assembly of a π‐Conjugated System with Three‐Fold Symmetry: Benzotri(7‐Azaindole)1Redox-Driven In Situ Helix Reversal of Graphene-Based Hydrogels29Chirality from scratch: enantioselective adsorption in geometrically controlled lateral nanoconfinement7Transition from Homochiral Clusters to Racemate Monolayers during 2D Crystallization of Trioxa[11]helicene on Ag(100)16Chirality in porous self-assembled monolayer networks at liquid/solid interfaces: induction, reversion, recognition and transfer19Chiral detection by induced surface-enhanced Raman optical activity31Evaluation of Chiral Separation by Pirkle-Type Chiral Selector Based Mixed Matrix Membranes0The effect of molecular isomerism on the induced circular dichroism of cadmium sulfide quantum dots17Coexistence of Chiral and Achiral Adsorptions of Metal-Free Phthalocyanine Molecules on Cd(0001)5Enantiospecific Molecular Fingerprinting Using Potential-Modulated Surface-Enhanced Raman Scattering to Achieve Label-Free Chiral Differentiation78Symmetry-Driven Formation of Chiral Boroxine-Based Organometallic Oligomers on Ag(001)4Nonconventional driving force for selective oxidative C–C coupling reaction due to concurrent and curious formation of Ag03Catalysis0Engineering Functional Nanomaterials Through the Amino Group2Chiral 3D‐printed Bioelectrodes40Nanoengineered chiral Pt-Ir alloys for high-performance enantioselective electrosynthesis89Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces12Toward Efficient Synthesis of Porous All-Carbon-Based Nanocomposites for Enantiospecific Separation7Chiral Nanochannels of Ordered Mesoporous Silica Constructed by a Pillar[5]arene-Based Host–Guest System44Chirality of molecular nanostructures on surfaces via molecular assembly and reaction: manifestation and control54Electric field analysis, polarization, excitation wavelength dependence, and novel applications of tip‐enhanced Raman scattering12Toward the Specificity of Bare Nanomaterial Surfaces for Protein Corona Formation20In-situ and operando spectroscopies for the characterization of catalysts and of mechanisms of catalytic reactions82Molecular approaches to heterogeneous catalysis58Chiral nanoporous networks featuring various chiral vertices from an achiral molecule on Ag(100)8Chiral self-assembly of terminal alkyne and selenium clusters organic-inorganic hybrid6Microreaction and membrane technologies for continuous single-enantiomer production: A review17Cysteine Adsorption on Twisted-Bilayer Graphene10Chiral functionalization of solid surfaces with amino acid derivatives: diazonium grafting regulated by enantioselective processes4Chiral tandem modifiers: highly efficient cinchonidine-derivative modifiers at low concentrations for the enantioselective hydrogenation of ( E )-2,3-diphenylpropenoic acid over Pd/C1On-surface homocoupling reactivity of a chiral bifunctional bromoindanone molecule on Cu(111)5Possible chemical and physical scenarios towards biological homochirality186Production of Organizational Chiral Structures by Design9Seeding Chiral Ensembles of Prolinated Porphyrin Derivatives on Glass Surface: Simple and Rapid Access to Chiral Porphyrin Films9Evaluation of chiral separation by Pirkle-type chiral selector based mixed matrix membranes19Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?425Chiral Metal Electrodes for Enantioselective Analysis, Synthesis, and Separation1Vectorial Electron Spin Filtering by an All-Chiral Metal–Molecule Heterostructure16Autonomous Chiral Microswimmers with Self‐mixing Capabilities for Highly Efficient Enantioselective Synthesis2Autonomous Chiral Microswimmers with Self‐mixing Capabilities for Highly Efficient Enantioselective Synthesis13Adsorption and Reactivity of Chiral Modifiers in Heterogeneous Catalysis: 1-(1-Naphthyl)ethylamine on Pt Surfaces4Amplification of Chirality in Photopatterned 3D Nanostructures of Chiral/Achiral Mixtures0Chiral Mesostructured Inorganic Materials with Optical Chiral Response110Water Dimer-Driven DNA Base Superstructure with Mismatched Hydrogen Bonding11Aggregation structure of chiral cubic liquid crystals revealed by X-ray diffraction utilizing a new algorithm14Homochiral hierarchical molecular assemblies through dynamic combination of conformational states of a single chiral building block at the liquid/solid interface3Chirality: An inescapable concept for the pharmaceutical, bio‐pharmaceutical, food, and cosmetic industries49Synthesis of Enantiomers of Chiral Ester Derivatives Containing an Amide Group and Their Chiral Recognition by 1 H NMR Spectroscopy3Boron as a Hypothetical Participant in the Prebiological Enantiomeric Enrichment6Bimetallic Sites for Catalysis: From Binuclear Metal Sites to Bimetallic Nanoclusters and Nanoparticles689Self-assembly and tiling of a prochiral hydrogen-bonded network: bi-isonicotinic acid on coinage metal surfaces1Surface-induced demixing of self-assembled isomeric mixtures of citral5Substrate-directed chiral selectivity of molecular self-assembled and covalent structures10Adsorption and Dissociation of R-Methyl p-Tolyl Sulfoxide on Au(111)1Water Evaporation-Driven Arginine Enantiomer Recognition on a Self-Powered Flexible Chip with High Specificity16Tuning Chirality of Self-Assembled PTCDA Molecules on a Au(111) Surface by Na Coordination22Spin- and angle-resolved photoemission spectroscopy study of heptahelicene layers on Cu(111) surfaces5Chirality control of a single carbene molecule by tip-induced van der Waals interactions16Approaches to mitigation of hydrogen sulfide during anaerobic digestion process – A review64Self-Assembly of N-Rich Triimidazoles on Ag(111): Mixing the Pleasures and Pains of Epitaxy and Strain4From Short‐ to Long‐Range Chiral Recognition on Surfaces: Chiral Assembly and Synthesis10Chiral Au–Pd Alloy Nanorods with Tunable Optical Chirality and Catalytically Active Surfaces27Chiral induction in substrate-supported self-assembled molecular networks under nanoconfinement conditions5Enantiopure molecules form apparently racemic monolayers of chiral cyclic pentamers1Triphasic circularly polarized luminescence switch quantum simulation of a topologically chiral catenane18Chiral measure of chiral polyhedrons3Unraveling the Chirality Transfer from Circularly Polarized Light to Single Plasmonic Nanoparticles50Unraveling the Chirality Transfer from Circularly Polarized Light to Single Plasmonic Nanoparticles9Asymmetric Molecular Adsorption and Regioselective Bond Cleavage on Chiral PdGa Crystals6On‐Surface Fabrication toward Polar 2D Macromolecular Crystals2Cu 2+ -Dominated Chirality Transfer from Chiral Molecules to Concave Chiral Au Nanoparticles81Chiroptical and morphological investigation of achiral PF6BT blended with chiral polymers: Chirality induction and visualization of topological structures3Selective Formation of Homochiral Dimers by Intermolecular Charge Transfer on a hBN Nanomesh9Elucidating the Lability and Diversity of Self-Assembled Structures of N-Heterocyclic Carbenes at the Liquid/Metal Interface4Enantioselective Crystallization of Naturally Chiral Ag2CO3 Crystals Insights into the Influence of Chiral Additives3Recent progress on surface chemistry I: Assembly and reaction67Self‐Assembled Chiral Film Based on Melanin Polymers4Adsorption of Prochiral Solvent Molecules by Surface‐Confined Chiral Supramolecular Assemblies: How Solvent Impacts on‐Surface Chirality2Chiral Solvent-Induced Homochiral Hierarchical Molecular Assemblies at the Liquid/Solid Interface1Chiral sensing of glucose by surface-enhanced Raman spectroscopy6Synthetic Strategies for Adding Enantioselectivity to Metal-Based Solid Catalysts Using Cinchonidine As the Chiral Agent2High-Silica, Enantiomerically Enriched STW-Type Molecular Sieves2Mechanisms for translating chiral enantiomers separation research into macroscopic visualization16Principles of adsorption and ion exchange0The configuration identification of alanine molecules adsorbed on the Si(100) surface by using XPS shake-up satellites and NEXAFS1Inherent enantioselective adsorption and photocatalytic removal of l -phenylalanine on cerium phosphate films0Unraveling the conglomeratic nature of methanol clusters adsorbed on graphene surfaces. Insights from molecular dynamics simulations1Determination of Enantiomeric Excess in Confined Aprotic Solvent0Using Achiral Monomers to Synthesize Organometallic Chiral Copolymers on an Achiral Surface4Molecular Coverage Modulates Chiral Surface-Enhanced Raman Scattering on Chiral Plasmonic Nanoparticles19Theoretical Calculations in Separation Science for Analytical Chemistry: Applications and Insights3On the Hunt for Chiral Single-Atom Catalysts18Harnessing the potential of porous MOF/COF@wood composites for pollution reduction and green energy18Soliton wall and Au adatom-induced trans-to-cis isomerization promoting the formation of multiple pairs of chiral isomers of methylcyano-functionalized molecules0Tuning the geometry, composition, and optical chirality of chiral Au nanorods for asymmetric nanocatalysis6Chiroptical Amplification Beyond Enantiopurity in Chiral Films4Mirror Life: Bridging Chirality, Ethics, and the Foundations of Life Creation5

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  1. Infrared absorption spectroscopy characterization of liquid–solid interfaces: The case of chiral modification of catalysts

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  2. Tuning of chiral construction, structural diversity, scale transformation and chiroptical applications

    Materials Horizons · 2017

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  3. Chirality of 20‐membered unclosed cryptand: Macroring distortion via lariat arm modification

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    Janusz Jurczak, Adam A. Sobczuk, Kajetan Dąbrowa, Marcin Lindner, Patryk Niedbała, Paweł Stępniak

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  4. Role of Gold Adatoms in the Adsorption of Sulfide Species on the Gold(001)-hex Surface

    The Journal of Physical Chemistry C · 2017

    Flavia Lobo Maza, Pilar Carro, Carolina Vericat, Klaus Kern, Roberto Carlos Salvarezza, Doris E. Grumelli

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  5. First-Principles Calculations of Sarin Adsorption on Anatase Surfaces

    The Journal of Physical Chemistry C · 2018

    Nam Q. Le, Chinedu E. Ekuma, Brett I. Dunlap, Daniel Gunlycke

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  6. The most stable adsorption geometries of two chiral modifiers on Pt(111)

    Surface Science · 2018

    Yang C. Zeng, Federico Masini, Anton M. H. Rasmussen, Michael N. Groves, Vincent Albert, John Boukouvalas, Peter H. McBreen

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  7. Structural Insights into the Mechanism of Chiral Recognition and Chirality Transfer in Host–Guest Assemblies at the Liquid–Solid Interface

    The Journal of Physical Chemistry C · 2018

    Yuan Fang, Kazukuni Tahara, Oleksandr Ivasenko, Yoshito Tobe, Steven De Feyter

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  8. Chiral Autocatalysis and Mirror Symmetry Breaking

    Catalysis Letters · 2018

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  9. Synthesis of Chiral Dendrimer-Encapsulated Nanoparticle (DEN) Catalysts

    Topics in Catalysis · 2018

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  10. Coadsorption of Formic Acid and Hydrazine on Cu(110) Single-Crystal Surfaces

    The Journal of Physical Chemistry C · 2018

    Yunxi Yao, J. Guerrero-Sánchez, Noboru Takeuchi, Francisco Zaera

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  11. Chiral Polymeric Nanocapsules and Their Use for Conformational Deracemization of Liquid Crystals

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  12. Biasing Enantiomorph Formation via Geometric Confinement: Nanocorrals for Chiral Induction at the Liquid–Solid Interface

    Journal of the American Chemical Society · 2018

    Johannes Seibel, Lander Verstraete, Brandon E. Hirsch, Ana M. Bragança, Steven De Feyter

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  13. Enantiopure Supramolecular Motifs of Self-Assembled Diamine-Based Chiral Molecules on Cu(100)

    The Journal of Physical Chemistry C · 2018

    Rogger Palacios-Rivera, Esther Barrena, Jordi Faraudo, Pierluigi Gargiani, Miguel Ángel Niño, Dimitri Arvanitis, Iwona Agnieszka Kowalik, Juan José de Miguel, Carmen Ocal

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  14. Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation

    Angewandte Chemie International Edition · 2018

    Jun Yong Chan, Huacheng Zhang, Yada Nolvachai, Yaoxin Hu, Haijin Zhu, Maria Forsyth, Qinfen Gu, David E. Hoke, Xiwang Zhang, Philip J. Marriot, Huanting Wang

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  15. Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation

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  16. Cell adhesion and proliferation in chiral pores triggered by polyoxometalates

    Chemical Communications · 2019

    Yingyi Ma, Lei Shi, Mengcheng Zhou, Bao Li, Zhijun Chen, Lixin Wu

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  17. Enantiomeric helical TiO 2 nanofibers modulate different peptide assemblies and subsequent cellular behaviors

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  18. Expression of chirality amplification in self-assembled achiral/chiral polyfluorene blends

    Journal of Materials Chemistry C · 2019

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  19. Reaction mechanisms at the homogeneous–heterogeneous frontier: insights from first-principles studies on ligand-decorated metal nanoparticles

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  20. Two-dimensional supramolecular crystal engineering: chirality manipulation

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  21. Determination of Specific Electrocatalytic Sites in the Oxidation of Small Molecules on Crystalline Metal Surfaces

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  22. Spin-Dependent Ionization of Chiral Molecular Films

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    John M. Abendroth, Kevin M. Cheung, Dominik M. Stemer, Mohammed Salah El Hadri, Chuanzhen Zhao, Eric E. Fullerton, Paul S. Weiss

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  23. Chirality Transfer in Gold Nanoparticles by l -Cysteine Amino Acid: A First-Principles Study

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  24. Enantioselective hydrogenation of α‐ketoesters catalyzed by cinchona alkaloid stabilized Rh nanoparticles in ionic liquid

    Chirality · 2019

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  25. On-Surface Synthesis of Chiral π-Conjugate Porphyrin Tapes by Substrate-Regulated Dehydrogenative Coupling

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    Feifei Xiang, Yan Lü, Zhongping Wang, Huanxin Ju, Gianluca Di Filippo, Chao Li, Xiaoqing Liu, Xinli Leng, Junfa Zhu, Li Wang, M. Alexander Schneider

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  26. Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces

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  27. Homochiral MOF–Polymer Mixed Matrix Membranes for Efficient Separation of Chiral Molecules

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  28. Homochiral MOF–Polymer Mixed Matrix Membranes for Efficient Separation of Chiral Molecules

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  29. Chiral Surface and Geometry of Metal Nanocrystals

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  30. Large Enantiospecificity of Step–kink Metal Surfaces: Contributions from the Backbone and Side Chain of α-Amino Acids

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  31. Helix-sense-selective surface grafting polymerization for preparing optically active hybrid microspheres

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  32. Stereospecific interactions between chiral inorganic nanomaterials and biological systems

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  33. Theoretical investigation of amino-acid adsorption on hydroxylated quartz surfaces: dispersion can determine enantioselectivity

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  34. Relative Abundances of Surface Diastereomeric Complexes Formed by Two Chiral Modifiers That Differ by a Methyl Group

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  35. Supramolecular Chiral 2D Materials and Emerging Functions

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  36. Chiral Monolayers with Achiral Tetrapod Molecules on Highly Oriented Pyrolytic Graphite

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  37. Adsorption of Chiral Modifiers from Solution onto Supported Platinum Catalysts: The Effect of the Solvent, Other Coadsorbates, and the Support

    The Journal of Physical Chemistry C · 2020

    Yufei Ni, Zihao Wang, Ilkeun Lee, Francisco Zaera

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  38. Face-selective adsorption of a prochiral compound on the chiral pore-surface of a metal–macrocycle framework (MMF) directed towards stereoselective reactions

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  39. Recent advances, challenges and perspectives in enantioselective release

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  40. Distinguishing Enantiomers by Tip‐Enhanced Raman Scattering: Chemically Modified Silver Tip with an Asymmetric Atomic Arrangement

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  41. Distinguishing Enantiomers by Tip‐Enhanced Raman Scattering: Chemically Modified Silver Tip with an Asymmetric Atomic Arrangement

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  42. Structural investigation of caffeine monolayers on Au(111)

    Physical review. B./Physical review. B · 2020

    Malte G. H. Schulte, Andreas Jeindl, Ismail Baltaci, Peter Roese, Marie Schmitz, U. Berges, Oliver T. Hofmann, C. Westphal

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  43. Near‐Enantiopure Trimerization of 9‐Ethynylphenanthrene on a Chiral Metal Surface

    Angewandte Chemie International Edition · 2020

    Samuel Stolz, Aliaksandr V. Yakutovich, Jan Prinz, Thomas Dienel, Carlo Antonio Pignedoli, Harald Brune, Oliver Gröning, Roland Widmer

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  44. Near‐Enantiopure Trimerization of 9‐Ethynylphenanthrene on a Chiral Metal Surface

    Angewandte Chemie · 2020

    Samuel Stolz, Aliaksandr V. Yakutovich, Jan Prinz, Thomas Dienel, Carlo Antonio Pignedoli, Harald Brune, Oliver Gröning, Roland Widmer

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  45. Thermally Induced Chiral Aggregation of Dihydrobenzopyrenone on Au(111)

    ACS Applied Materials & Interfaces · 2020

    Dingguan Wang, Ming Yang, Arramel Arramel, Jishan Wu, Andrew T. S. Wee

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  46. Recognition at chiral interfaces: From molecules to cells

    Colloids and Surfaces B Biointerfaces · 2020

    Yingyi Ma, Lei Shi, Hongyan Yue, Xin Gao

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  47. On-Surface Growth of Single-Layered Homochiral 2D Covalent Organic Frameworks by Steric Hindrance Strategy

    Journal of the American Chemical Society · 2020

    Lu Cheng, Yiping Mo, Ye Hong, Ting Chen, Zhiyong Yang, Li‐Jun Wan, Dong Wang

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  48. A Chiral‐Label‐Free SERS Strategy for the Synchronous Chiral Discrimination and Identification of Small Aromatic Molecules

    Angewandte Chemie International Edition · 2020

    Yue Wang, Xueqi Zhao, Zhi Yu, Zhang‐Run Xu, Bing Zhao, Yukihiro Ozaki

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  49. A Chiral‐Label‐Free SERS Strategy for the Synchronous Chiral Discrimination and Identification of Small Aromatic Molecules

    Angewandte Chemie · 2020

    Yue Wang, Xueqi Zhao, Zhi Yu, Zhang‐Run Xu, Bing Zhao, Yukihiro Ozaki

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  50. 2D Chiral Stripe Nanopatterns Self‐Assembled from Rod‐Coil Block Copolymers on Microstripes

    Macromolecular Rapid Communications · 2020

    Zhengmin Tang, Zhanwen Xu, Chunhua Cai, Jiaping Lin, Yuan Xiang Yao, Chunming Yang, Xiaohui Tian

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