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RESEARCH PAPER · Advanced Materials · 2019

Chiral Surface and Geometry of Metal Nanocrystals

Sang Won Im, Hyo‐Yong Ahn, Ryeong Myeong Kim, Nam Heon Cho, Hyeohn Kim, Yae‐Chan Lim, Hye‐Eun Lee, Ki Tae Nam

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Chiral Surface and Geometry of Metal NanocrystalsOriginalChiral AuCuAu Heterogeneous Nanorods with Tailored Optical Activity49Photoinduced Chirality Switching of Metal-Inorganic Plasmonic Nanostructures72γ‐Glutamylcysteine‐ and Cysteinylglycine‐Directed Growth of Chiral Gold Nanoparticles and their Crystallographic Analysis102γ‐Glutamylcysteine‐ and Cysteinylglycine‐Directed Growth of Chiral Gold Nanoparticles and their Crystallographic Analysis12Inorganic Nanostructures with Strong Chiroptical Activity64Single Nanoparticle Chiroptics in a Liquid: Optical Activity in Hyper-Rayleigh Scattering from Au Helicoids57Electromagnetic chirality: from fundamentals to nontraditional chiroptical phenomena573Chirality Detection by Raman Spectroscopy: The Case of Enantioselective Interactions between Amino Acids and Polymer-Modified Chiral Silica42Electrocatalytic and photocatalytic applications of atomically precise gold-based nanoclusters34One-Fold Anisotropy of Silver Chiral Nanoparticles Studied by Second-Harmonic Generation6Tyrosyltyrosylcysteine-Directed Synthesis of Chiral Cobalt Oxide Nanoparticles and Peptide Conformation Analysis39Chirality transfer of cysteine to the plasmonic resonance region through silver coating of gold nanobipyramids21Imprinting chirality in inorganic nanomaterials for optoelectronic and bio-applications: strategies, challenges, and opportunities33Surface overgrowth on gold nanoparticles modulating high-energy facets for efficient electrochemical CO 2 reduction10Chirality communications between inorganic and organic compounds82Recent Advances in Inorganic Chiral Nanomaterials108Tuning the Chiral Morphology of Gold Nanoparticles with Oligomeric Gold–Glutathione Complexes67Plasmon-mediated photochemical transformation of inorganic nanocrystals19Mesoporous molecularly imprinted materials: From preparation to biorecognition and analysis40Engineering of inorganic nanostructures with hierarchy of chiral geometries at multiple scales19Stereochemistry and Twisted Crystals17Multidimensional nanoscopic chiroptics212Selenocystine and Photo‐Irradiation Directed Growth of Helically Grooved Gold Nanoarrows50Rhombic dodecahedral gold nanoparticles: chiral sensing probes for naked-eye recognition of histidine enantiomers17Chiral plasmonic nanostructures: recent advances in their synthesis and applications144Chiral functionalization of solid surfaces with amino acid derivatives: diazonium grafting regulated by enantioselective processes4Chiral nanomaterials for biosensing, bioimaging, and disease therapies56Homochirality0Seed-directed synthesis of chiroptically active Au nanocrystals of varied symmetries22Selectively Regulating the Chiral Morphology of Amino Acid-Assisted Chiral Gold Nanoparticles with Circularly Polarized Light50Liquid Crystal Templated Chiral Plasmonic Films with Dynamic Tunability and Moldability55Enantiomer-dependent immunological response to chiral nanoparticles641Random Lasing with a High Degree of Circular Dichroism by Chiral Plasmonic Gold Nanoparticles34Second Harmonic Optical Circular Dichroism of Plasmonic Chiral Helicoid-III Nanoparticles493‐Dimensional Scanning of Entire Unit Cells in Single Nanoparticles.1Chiral carbon dots: synthesis, optical properties, and emerging applications286Synthesis of Chiral Au Nanocrystals with Precise Homochiral Facets for Enantioselective Surface Chemistry112Core–Gap–Shell Nanoparticles@Polyaniline with Tunable Plasmonic Chiroptical Activities by pH and Electric Potential Dual Modulation19Chiral plasmonic nanomaterials for assembly0Determine the complete configuration of single carbon nanotubes by one photograph of transmission electron microscopy0Vectorial Electron Spin Filtering by an All-Chiral Metal–Molecule Heterostructure16Enantioseparation and determination of oxypeucedanin and its application to a stereoselective analysis in Angelica Dahuricae Radix and pharmacokinetic study of rats3Chiral Perovskite Nanoplatelets Exhibiting Circularly Polarized Luminescence through Ligand Optimization41Assembly of planar chiral superlattices from achiral building blocks64Generation and manipulation of chiroptical activities in coinage-metal clusters43Plasmonic and Photonic Enhancement of Chiral Near‐Fields42Chirality in the Solid State: Chiral Crystal Structures in Chiral and Achiral Space Groups125Morphological Evolution Trajectory of Multifaceted Palladium Nanoparticles7A Review on the Various Mechanisms of Green Synthesis of Metal Nanoparticles for Biomedical Applications7Chiral Mesostructured Inorganic Materials with Optical Chiral Response110Tunable Reversal of Circular Dichroism in the Seed-Mediated Growth of Bichiral Plasmonic Nanoparticles93Morphological and Optical Transitions during Micelle-Seeded Chiral Growth on Gold Nanorods54Hydrophobic Gold Nanoparticles with Intrinsic Chirality for the Efficient Fabrication of Chiral Plasmonic Nanocomposites16Enhancing terahertz circular dichroism spectrum of amino acid chiral enantiomers by all-dielectric metasurface41Near-infrared photothermal therapy of chiral Au helicoids with broadband optical absorption7Chiral Au Nanorods: Synthesis, Chirality Origin, and Applications87Synthesis of Ligand-Induced Chiral Tellurium Nanocrystals9Enantioselective sensing by collective circular dichroism244Homochirality1Intrinsic Optical Properties and Emerging Applications of Gold Nanostructures86Bioinspired chiral inorganic nanomaterials230Immunologically effective poly(D-lactic acid) nanoparticle enhances anticancer immune response39Enantiospecific Affinities of Chiral Cu Films for Both d -Ribose and l -Amino Acids18Synthesis and Plasmonic Chiroptical Properties of Double‐Helical Gold Nanorod Enantiomers35Recent Advances of Seed‐Mediated Growth of Metal Nanoparticles: from Growth to Applications163Tuning Geometric Chirality in Metallic and Hybrid Nanostructures by Controlled Nanoscale Crystal Symmetry Breaking41Determine the Complete Configuration of Single‐Walled Carbon Nanotubes by One Photograph of Transmission Electron Microscopy1132‐Symmetric Chiral Gold Nanoplates with Near‐Infrared Circular Dichroism30Site‐Selective Chiral Growth of Anisotropic Au Triangular Nanoplates for Tuning the Optical Chirality50Helical polymers for dissymmetric circularly polarized light imaging225Shape Evolution of Two-Dimensional Au Hexagonal Nanoplates into Pseudo Three-Dimensional Oblate Spheroids12Strain and crystallographic identification of the helically concaved gap surfaces of chiral nanoparticles19Halide-assisted differential growth of chiral nanoparticles with threefold rotational symmetry108Engineering the Intrinsic Chirality of Plasmonic Au@Pd Metamaterials for Highly Sensitive Chiroplasmonic Hydrogen Sensing55Chiral Inorganic Nanomaterials for Photo(electro)catalytic Conversion71Geometric Control and Optical Properties of Intrinsically Chiral Plasmonic Nanomaterials52Surface Topographical Engineering of Chiral Au Nanocrystals with Chiral Hot Spots for Plasmon-Enhanced Chiral Discrimination42Amino Acid‐Modulated Chirality Evolution and Highly Enantioselective Chiral Nanogap‐Enhanced Raman Scattering24Chiral Metasurfaces: A Review of the Fundamentals and Research Advances61Élaboration de nanoflèches chirales : modulation des propriétés chiroplasmoniques0Shapeshifting Nanoplatelets : Inducing Chirality in Ultrathin Systems0Adsorption of Glucose Molecules on Stainless Steel Enables Ni‐Rich Passivation Film3Chiral Plasmonic Hybrid Nanostructures: A Gateway to Advanced Chiroptical Materials69Characterization of Chiral Near Field Within Nanogaps Using Surface‐Enhanced Raman Scattering4Multicomponent chiral plasmonic hybrid nanomaterials: recent advances in synthesis and applications21Chiral nanomaterial-based approaches for diagnosis and treatment of protein-aggregated neurodiseases: current status and future opportunities16Factors influencing the chiral imprinting in perovskite nanoparticles2From individuals to families: design and application of self-similar chiral nanomaterials7Turmeric extract-mediated biogenic synthesis of Ag@SeO 2 magnetic nanoparticles: characterization, optimization, antibacterial and antioxidant activities44Chiral Cu x Co y S‐Cu z S Nanoflowers with Bioinspired Enantioselective Catalytic Performances12Expanding the Horizons of Machine Learning in Nanomaterials to Chiral Nanostructures74Chiral plasmonic sensing: From the perspective of light–matter interaction25Tuning the Geometry and Optical Chirality of Pentatwinned Au Nanoparticles with 5-Fold Rotational Symmetry45Biomimetic Chiral Nanomaterials with Selective Catalysis Activity40Structural and Electronic Chirality in Inorganic Crystals: from Construction to Application20Crystallography, Design, and Synthesis of Two‐Dimensional Metastable‐Phase Oxides0Chiral Materials for Optics and Electronics: Ready to Rise?12Single Crystal and Pentatwinned Gold Nanorods Result in Chiral Nanocrystals with Reverse Handedness5Single Crystal and Pentatwinned Gold Nanorods Result in Chiral Nanocrystals with Reverse Handedness40Investigating chiral morphogenesis of gold using generative cellular automata44Spin angular momentum–encoded single-photon emitters in a chiral nanoparticle–coupled WSe 2 monolayer33Highly Chiral Light Emission Using Plasmonic Helicoid Nanoparticles22Chirality Determination of Nanocrystals by Electron Crystallography8GSH Oligomer-Directed Chiral Au-Helicoid Nanoparticles for Discriminating Penicillamine Enantiomers2Multifunctional spatial-potential resolved electrochemiluminescence biosensor for dual-channel simultaneous detection of hepatitis A virus and hepatitis C virus DNA19Immunomodulatory metal-based biomaterials for cancer immunotherapy38Enhanced Performance of La2NiO4+δ Oxygen-Transporting Membranes Using Crystal Facet Engineering via Microemulsion-Based Synthesis6Chiral plasmonic-dielectric coupling enables strong near-infrared chiroptical responses from helicoidal core-shell nanoparticles39Helicoid Grating-Coupled Surface Plasmon Resonance Sensor22Plasmonic nanocrystals with intrinsic chirality: Biomolecule-directed synthesis and applications6Strong Chiral Response of Chiral Plasmonic Nanoparticles to Photonic Orbital Angular Momentum15Mechanisms for translating chiral enantiomers separation research into macroscopic visualization16Terahertz time-domain ellipsometry based on spintronic phenomena0A repertoire of gold-based nanostructures with integrated optical and catalytic tunabilities7Light-to-matter chirality transfer in plasmonics9Discovery of D-Ring-Contracted Artemisinin as a Potent Hydrophobic Tag for Targeted Protein Degradation18Emergence of Chirality in an Optically Active Two-Dimensional Crystal with a Spiral Surface Pattern6Plasmonic Chirality Meets Reactivity: Challenges and Opportunities5Recent Advances in Chiral Gold Nanomaterials: From Synthesis to Applications10Precise Synthesis of High-Strength Chiral Au Nanomaterials: From Chiral Au Nanoclusters to Chiral Au Nanoparticles3Templated Synthesis of Mono- and Bimetallic Nanogap Dimer Arrays13Optically tunable catalytic cancer therapy using enzyme-like chiral plasmonic nanoparticles30Crystal Facet Effect in Chiral PdPt3 Hollow Nanocages as Nanozymes for Use in Enantiomer Recognition8Nanofabrication for Nanophotonics132Etching‐Based Chiroplasmonic Sensing with Helicoid Au Nanocrystals for Anti‐Interference Biochemical Detection1Reticular Synthesis of a Highly Stable Homochiral Cr 3+ -Based Metal–Organic Framework for Enantioselective Separation6Multidentate Chirality Inducers in the Synthesis of Intrinsically Chiral Gold Nanoparticles: Effects of Multiplicity and Spatial Distribution of Cysteine2Chiral Symmetry Breaking in Gold Stellated Nanoicosahedrons25Tunable Plasmonic Circular Dichroism of Hierarchical Chiral Assemblies5Biotemplate-Guided Self-Assembly of Gold Nanoparticles with Plasmonic Circular Dichroism0Chiral memory-guided construction of fluorinated covalent organic frameworks for efficient photocatalytic hydrogen peroxide synthesis in seawater4Pro-Angiogenic Bioactive Molecules in Vascular Morphogenesis: Integrating Endothelial Cell Dynamics6The Carrier Dynamics of Chiral Gold Nanoparticles2In Situ Observation of Active Surface Etching in Gold Nanoplates: Evidence for Intermediate Ligand Effects5Chiral Inorganic Nanomaterials: Exploring New Horizons in Catalysis Through Symmetry Breaking9Solvent and Achiral Crystalline Phase-Induced Chiral Resolution of CsCuCl 31Harnessing chirality in nanomaterials: advancing photocatalysis for hydrogen production and beyond4Surfactant-Layer Engineering Enables Growth Pathway Switching and Reversal of Chiroptical Activity in Helicoid Gold Nanocrystals7Chiral Au@Ag Core–Shell Nanoparticles for Enantioselective SERS Detection of Bio-Relevant Chiral Molecules3High-throughput chiral copper foils by curved-surface confinement recrystallization1Specifying the Origin of Chiral Sensitivity through Conformal Nanogap Engineering in a Single Helicoid Gold Nanoparticle1Metasurface analogues of molecular diastereomers from hierarchical multiscale chiral interactions with biomolecules1Synthesis of Chiral Ag Nanostructures: Wet‐Chemical Methods and Physicalfielddriven Methods1Spin-Polarization Tailored Oxygen Evolution of Chiral Gold Nanocrystals Probed by Single-Particle Electrochemistry3Chiral Graphene Quantum Dots and Carbon Dots: From Chirality Induction to Spin‐Selective Effects and Advanced Applications3General Synthesis of Chiral Mesostructured Carbonates Using Chiral Vicinal Polyhydroxy Molecules0Morphing active networks0Advances and Prospects of Chiral Plasmonic Nanomaterials in Emerging Applications0Enantioselective SERS Sensing of Amino Acids by Self-Assembled Chiral Au Nanorods0

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  1. Chiral AuCuAu Heterogeneous Nanorods with Tailored Optical Activity

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  2. Photoinduced Chirality Switching of Metal-Inorganic Plasmonic Nanostructures

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  3. γ‐Glutamylcysteine‐ and Cysteinylglycine‐Directed Growth of Chiral Gold Nanoparticles and their Crystallographic Analysis

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  4. γ‐Glutamylcysteine‐ and Cysteinylglycine‐Directed Growth of Chiral Gold Nanoparticles and their Crystallographic Analysis

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  5. Inorganic Nanostructures with Strong Chiroptical Activity

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  6. Single Nanoparticle Chiroptics in a Liquid: Optical Activity in Hyper-Rayleigh Scattering from Au Helicoids

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  7. Electromagnetic chirality: from fundamentals to nontraditional chiroptical phenomena

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  8. Chirality Detection by Raman Spectroscopy: The Case of Enantioselective Interactions between Amino Acids and Polymer-Modified Chiral Silica

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  10. One-Fold Anisotropy of Silver Chiral Nanoparticles Studied by Second-Harmonic Generation

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  11. Tyrosyltyrosylcysteine-Directed Synthesis of Chiral Cobalt Oxide Nanoparticles and Peptide Conformation Analysis

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  12. Chirality transfer of cysteine to the plasmonic resonance region through silver coating of gold nanobipyramids

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  15. Chirality communications between inorganic and organic compounds

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  16. Recent Advances in Inorganic Chiral Nanomaterials

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  17. Tuning the Chiral Morphology of Gold Nanoparticles with Oligomeric Gold–Glutathione Complexes

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  20. Engineering of inorganic nanostructures with hierarchy of chiral geometries at multiple scales

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  21. Stereochemistry and Twisted Crystals

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  28. Homochirality

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  37. Synthesis of Chiral Au Nanocrystals with Precise Homochiral Facets for Enantioselective Surface Chemistry

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  39. Chiral plasmonic nanomaterials for assembly

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  40. Determine the complete configuration of single carbon nanotubes by one photograph of transmission electron microscopy

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  44. Assembly of planar chiral superlattices from achiral building blocks

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  45. Generation and manipulation of chiroptical activities in coinage-metal clusters

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  46. Plasmonic and Photonic Enhancement of Chiral Near‐Fields

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  47. Chirality in the Solid State: Chiral Crystal Structures in Chiral and Achiral Space Groups

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  48. Morphological Evolution Trajectory of Multifaceted Palladium Nanoparticles

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  49. A Review on the Various Mechanisms of Green Synthesis of Metal Nanoparticles for Biomedical Applications

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  50. Chiral Mesostructured Inorganic Materials with Optical Chiral Response

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