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RESEARCH PAPER · Inorganic Chemistry · 2017

Syntheses and Characterization of AM2V2O11 (A = Ba, Sr, Pb; M = Nb, Ta) Vanadates with Centrosymmetric and Noncentrosymmetric Structures

Anil Kumar Paidi, P. W. Jaschin, K. B. R. Varma, Kanamaluru Vidyasagar

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Syntheses and Characterization of AM2V2O11 (A = Ba, Sr, Pb; M = Nb, Ta) Vanadates with Centrosymmetric and Noncentrosymmetric StructuresOriginalThe crystal structure of visible light absorbing piezoelectric semiconductor SrNb 2 V 2 O 11 revisited: high-resolution X-ray diffraction, vibrational spectroscopy and computational study4Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region33A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation64K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20Structural and Electronic Effect Driven Distortions in Visible Light Absorbing Polar Materials ATa2V2O11 (A = Sr, Pb)2Syntheses and characterization of noncentrosymmetric layered phosphates, Sr3Nb2P2O13 and Sr3Ta2P2O130K4ZnV5O15Cl: A Congruent‐Melting Mid‐Infrared Nonlinear Optical Crystal Combined with Strong Second‐Harmonic Generation and High Laser‐Induced Damage Threshold14Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence12A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold6Accelerating ferroelectric materials discovery through high-throughput first-principles screening and experimental validation3Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups11Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal10Design and Synthesis of Vanadium-Based Infrared Nlo Crystal K4cdv5o15br Through Aliovalent Substitution with Strongly Polarized Active Units0Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10First-Principles High-Throughput Screening Combined with Experimental Synthesis to Find Vanadate Nonlinear Optical Material BiCa2VO64Topochemical Reaction Involving Double-to-Single Layer Conversion: Mo 3 Ta 2 O 10 N with a Kagomé Lattice3Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses3Ba(PO4)2M5+2O3 mixed metal systems (M = Nb, Ta, W) at the edge between dielectrics and 2D-metals0中红外氧化物非线性光学晶体研究进展（特邀）0Ba(PO4)2M5+2O3 mixed metal systems (M = Nb, Ta, W) at the edge between dielectrics and 2D-metals0

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  1. The crystal structure of visible light absorbing piezoelectric semiconductor SrNb 2 V 2 O 11 revisited: high-resolution X-ray diffraction, vibrational spectroscopy and computational study

    Journal of Materials Chemistry C · 2019-01-01

    Ievgen V. Odynets, Sergei A. Khainakov, Santiago García‐Granda, Roman V. Gumeniuk, Matthias Zschornak, Natalia Soloviova, Nikolay S. Slobodyanik, Patricia Horcajada, Artem A. Babaryk

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  2. Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region

    Inorganic Chemistry · 2019-09-25

    Gang Yang, Long-Hua Li, Chao Wu, Mark Graeme Humphrey, Chi Zhang

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  3. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  4. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  5. K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations

    Chemical Science · 2021-12-06

    Jin Chen, Chun‐Li Hu, Yilin Li, Yan Chen, Qianqian Chen, Jiang‐Gao Mao

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  6. Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra

    Inorganic Chemistry · 2022-01-10

    Yuanyu Yang, Yao Guo, Bingbing Zhang, Ting Wang, Yi-Gang Chen, Xiaohui Hao, Xiaoxiu Yu, Xian‐Ming Zhang

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  7. Structural and Electronic Effect Driven Distortions in Visible Light Absorbing Polar Materials ATa2V2O11 (A = Sr, Pb)

    The Journal of Physical Chemistry C · 2022-04-28

    Artem A. Babaryk, Ievgen V. Odynets, Álvaro Lobato, Alaa Adawy, José Manuel Recio, Santiago García‐Granda

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  8. Syntheses and characterization of noncentrosymmetric layered phosphates, Sr3Nb2P2O13 and Sr3Ta2P2O13

    Journal of Solid State Chemistry · 2023-09-27

    Rintu Robert, Kanamaluru Vidyasagar

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  9. K4ZnV5O15Cl: A Congruent‐Melting Mid‐Infrared Nonlinear Optical Crystal Combined with Strong Second‐Harmonic Generation and High Laser‐Induced Damage Threshold

    Advanced Optical Materials · 2023-12-12

    Wenfei Li, Lei Geng, Chang‐Yu Meng, Shihua Ma, Baozhu Zhu, You‐Zhao Lan, Qi Wu

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  10. Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Shuya Liu, Conggang Li, Jinmiao Jiao, Yuheng She, Tinghui Zhang, Dianxing Ju, Ning Ye, Zhanggui Hu, Yicheng Wu

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  11. A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold

    Journal of Alloys and Compounds · 2024-04-14

    Lei Geng, Wenfei Li, Chang‐Yu Meng, You‐Zhao Lan, Baozhu Zhu, Shihua Ma, Qi Wu

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  12. Accelerating ferroelectric materials discovery through high-throughput first-principles screening and experimental validation

    Japanese Journal of Applied Physics · 2024-07-01

    Daisuke Hirai, Tomoki Murata, Sakyo Hirose

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  13. Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups

    Inorganic Chemistry · 2024-10-11

    Yanyan Ding, Mengmeng Zhu, Junbo Wang, Bo Li, Hai-Xin Qi, Lili Liu, Yaoqing Chu

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  14. Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal

    Inorganic Chemistry · 2024-10-28

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Qian Wu, Mingjun Xia

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  15. Design and Synthesis of Vanadium-Based Infrared Nlo Crystal K4cdv5o15br Through Aliovalent Substitution with Strongly Polarized Active Units

    SSRN Electronic Journal · 2025-01-01

    Baozhu Zhu, Lei Geng, You‐Zhao Lan, Shihua Ma, Chang‐Yu Meng, Qi Wu

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  16. Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br

    Inorganic Chemistry · 2025-03-24

    Baozhu Zhu, Lei Geng, Shoubao Zhang, Shuo Han, Chang‐Yu Meng, You‐Zhao Lan, Qi Wu

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  17. First-Principles High-Throughput Screening Combined with Experimental Synthesis to Find Vanadate Nonlinear Optical Material BiCa2VO6

    Inorganic Chemistry · 2025-04-18

    Xiaomin Zhang, Limin Duan, Dongxue Sun, Xuefan Wang, Ruqing Wei, Daqing Yang, Ying Wang, Bingbing Zhang

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  18. Topochemical Reaction Involving Double-to-Single Layer Conversion: Mo 3 Ta 2 O 10 N with a Kagomé Lattice

    Journal of the American Chemical Society · 2025-07-24

    Ryoya Higuchi, K. Ishida, Cédric Tassel, Baptiste Vignolle, Daichi Kato, Kantaro Murayama, Hsin‐Hui Huang, Akihide Kuwabara, Shunsuke Kobayashi, Yusuke Nambu, Hiroyasu Matsudaira, Shunsaku Kitagawa, Kenji Ishida, Congling Yin, Hiroshi Takatsu, Hiroshi Kageyama

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  19. Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses

    Inorganic Chemistry · 2025-12-23

    Haochen Li, Jinhua Wang, Haotian Tian, Xiaodong Zhang, T. Wang, Hongrui Liu, Bing Li, Pengyun Chen, Pifu Gong, Qian Wu, Shu Hai Guo, Mingjun Xia

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  20. Ba(PO4)2M5+2O3 mixed metal systems (M = Nb, Ta, W) at the edge between dielectrics and 2D-metals

    SSRN Electronic Journal · 2026-01-01

    Olivier Mentré, Sandy Al Bacha, Ángel M. Arévalo‐López, Robert Glaum, A. Cano

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  21. 中红外氧化物非线性光学晶体研究进展（特邀）

    Chinese Journal of Lasers · 2026-01-01

    李浩辰 Li Haochen, 吴倩 Wu Qian, 王天予 Wang Tianyu, 刘弘睿 Liu Hongrui, 李兵 Li Bing, 田皓天 Tian Haotian, 夏明军 Xia Mingjun, 王晓洋 Wang XiaoYang

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  22. Ba(PO4)2M5+2O3 mixed metal systems (M = Nb, Ta, W) at the edge between dielectrics and 2D-metals

    Solid State Sciences · 2026-06-04

    Sandy Al Bacha, Ángel M. Arévalo‐López, Christine Terryn, Robert Glaum, A. Cano, Olivier Mentré

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