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RESEARCH PAPER · Inorganic Chemistry · 2017

Structural Design of Two Fluorine–Beryllium Borates BaMBe2(BO3)2F2 (M = Mg, Ca) Containing Flexible Two-Dimensional [Be3B3O6F3]∞ Single Layers without Structural Instability Problems

Shu Hai Guo, Xingxing Jiang, Mingjun Xia, Lijuan Liu, Zhi Gang Fang, Qian Huang, Ruofei Wu, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen

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Structural Design of Two Fluorine–Beryllium Borates BaMBe2(BO3)2F2 (M = Mg, Ca) Containing Flexible Two-Dimensional [Be3B3O6F3]∞ Single Layers without Structural Instability ProblemsOriginalK2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31Na 3 B 7 O 11 F 2 : a new sodium-rich fluorooxoborate with a unique [B 14 O 24 F 4 ] ring and a short ultraviolet absorption edge27BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure11BaZnBe 2 (BO 3 ) 2 F 2 : a novel zinc-beryllium borate with SBBO-type structure overcoming the polymorphism problem13Role of rare earth sites and vacancies in the anomalous compression of modulated scheelite tungstates RE2 ( WO4)36Na 3 AEZn 2 B 3 O 9 (AE = Mg, Ca): two new short-wave ultraviolet beryllium-free Sr 2 Be 2 B 2 O 7 -type zincoborates designed by chemical cosubstitution9Realization of Enlarged Birefringence from BaCdBe2(BO3)2F2 to NaMgBe2(BO3)2F via the Cation Size Effect as a Potential Deep-Ultraviolet Birefringent Material18Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers7(C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement5A deep-ultraviolet nonlinear-optical material with a wide bandgap and large static dielectric polarizability coefficient: Na 6 Si 3 F 181The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Review on birefringence in borates based on birefringence-active functional groups and arrangements57SrMBe 2 (BO 3 ) 2 F 2 (M = Zn, Mg): two SBBO-like compounds obtained by cation regulation1Towards equilateral triangular lattice frustrated quantum magnets through crystal symmetry–protected molecular-brick chemical strategy4

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  1. K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups

    Journal of Alloys and Compounds · 2017-11-16

    Qian Wang, Chensheng Lin, Guohong Zou, Mengjiao Liu, Daojiang Gao, Jian Bi, Ling Huang

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  2. Na 3 B 7 O 11 F 2 : a new sodium-rich fluorooxoborate with a unique [B 14 O 24 F 4 ] ring and a short ultraviolet absorption edge

    Dalton Transactions · 2018-10-18

    Changcheng Tang, Xingxing Jiang, Wenlong Yin, Lijuan Liu, Mingjun Xia, Qian Huang, Gaomin Song, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen

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  3. BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure

    Dalton Transactions · 2021-01-01

    Haotian Qiu, Ming Xia, Wenbing Cai, Zhihua Yang, Yanli Liu, Miriding Mutailipu, Shilie Pan

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  4. BaZnBe 2 (BO 3 ) 2 F 2 : a novel zinc-beryllium borate with SBBO-type structure overcoming the polymorphism problem

    Dalton Transactions · 2021-01-01

    Ruixin Guo, Xiaomeng Liu, Ce Tao, Changcheng Tang, Mingjun Xia, Lijuan Liu, Zheshuai Lin, Xiaoyang Wang

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  5. Role of rare earth sites and vacancies in the anomalous compression of modulated scheelite tungstates RE2 ( WO4)3

    Physical Review Materials · 2021-12-03

    N. Sabalisck, Gerardo Gil de Cos, Cristina González-Silgo, Candelaria Guzmán-Afonso, Víctor Lavín, Javier López-Solano, Isabel Martín-Mateos, L. Mestres, Andrés Mujica, David Santamarı́a-Pérez, Manuel Eulalio Torres, Xavier Vendrell

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  6. Na 3 AEZn 2 B 3 O 9 (AE = Mg, Ca): two new short-wave ultraviolet beryllium-free Sr 2 Be 2 B 2 O 7 -type zincoborates designed by chemical cosubstitution

    Inorganic Chemistry Frontiers · 2022-01-01

    Zhi Gang Fang, Chun‐Li Hu, Wen‐Tong Chen, Jiang‐Gao Mao

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  7. Realization of Enlarged Birefringence from BaCdBe2(BO3)2F2 to NaMgBe2(BO3)2F via the Cation Size Effect as a Potential Deep-Ultraviolet Birefringent Material

    Inorganic Chemistry · 2022-05-02

    Ruixin Guo, Xingxing Jiang, Shu Hai Guo, Mingjun Xia, Lijuan Liu, Zheshuai Lin, Xiaoyang Wang

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  8. Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers

    Inorganic Chemistry · 2023-02-20

    Ruixin Guo, Shu Hai Guo, Mingjun Xia, Lijuan Liu, Minjuan Li, Sangen Zhao, Xiaoyang Wang

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  9. (C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement

    Journal of Materials Chemistry C · 2024-01-01

    Zhi Gang Fang, Yu-Ming Pan, Pei Han, Bing‐Ping Yang, Meihong Duan

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  10. A deep-ultraviolet nonlinear-optical material with a wide bandgap and large static dielectric polarizability coefficient: Na 6 Si 3 F 18

    Materials Advances · 2024-01-01

    Changcheng Tang, Xingxing Jiang, Xiuyu Wu, Yuechen Gong, Chao Yang, Ruixin Guo, Panpan Wang, Yongming Huang, Dayu Zhou, H Chen, Zheshuai Lin

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  11. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

    Journal of Physics and Chemistry of Solids · 2024-02-22

    Sergey M. Aksenov, Nikita V. Chukanov, Viktor P. Tarasov, Daria A. Banaru, Stephanie A. Mackley, A. M. Banaru, Sergey V. Krivovichev, Peter Carman Burns

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  12. Review on birefringence in borates based on birefringence-active functional groups and arrangements

    Science China Chemistry · 2024-06-14

    Qianzhen Zhang, Ran An, Zhihua Yang, Xifa Long, Shilie Pan, Yun Mo Yang

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  13. SrMBe 2 (BO 3 ) 2 F 2 (M = Zn, Mg): two SBBO-like compounds obtained by cation regulation

    Dalton Transactions · 2025-12-16

    Tong Wu, Lei Kang, Fan Liu, Ruixin Guo, Shu Guo, Tianhong Huang, Shuangyue Shang, Lijuan Liu, Xiaoyang Wang

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  14. Towards equilateral triangular lattice frustrated quantum magnets through crystal symmetry–protected molecular-brick chemical strategy

    Chinese Chemical Letters · 2026-03-15

    Ruixin Guo, Jieming Sheng, Bowen Li, Kaizhen Guo, Wenjiao Yao, Nan Zhao, Jianqiao Wang, Zhibin Qiu, Bo Wen, Shuang Jia, Xiaoyang Wang, Ping Wu, Feng Yang, Liusuo Wu, Qiushi Yao, Shu Guo

    Read original paper ↗ ·
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