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RESEARCH PAPER · Journal of Materials Chemistry C · 2017

Thermally stable K x Cs 1−x AlSi 2 O 6 :Eu 2+ phosphors and their photoluminescence tuning

Manli Zhang, Zhiguo Xia, Qiulin Liu

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Thermally stable K x Cs 1−x AlSi 2 O 6 :Eu 2+ phosphors and their photoluminescence tuningOriginalA thermal-sensitizing and thermochromic phosphor30CaF 2 :Eu films shine novel blue, white or red luminescence though adjustment of the valence state of Eu ions using the electro-deposition method17Improvement of thermal stability and photoluminescence in Sr 0.8 Ca 0.2 Al 2 Si 2 O 8 :Eu 2+ by the substitution of Si–Na # Al–Sr and Ca # Sr for structural modifications16Achieving long-term zero-thermal-quenching with the assistance of carriers from deep traps112Luminescent properties of Eu-doped magnetic Na 3 FeF 63Synthesis, electronic structures, and photoluminescence properties of an efficient and thermally stable red-emitting phosphor Ca 3 ZrSi 2 O 9 :Eu 3+ ,Bi 3+ for deep UV-LEDs20Zero-thermal-quenching and photoluminescence tuning with the assistance of carriers from defect cluster traps52Thermally stable photoluminescence and long persistent luminescence of Ca 3 Ga 4 O 9 :Tb 3+ /Zn 2+41Identifying the Emission Centers and Probing the Mechanism for Highly Efficient and Thermally Stable Luminescence in the La3Si6N11:Ce3+ Phosphor48A zero-thermal-quenching and color-tunable phosphor LuVO4: Bi3+, Eu3+ for NUV LEDs79Design and Development of a Bluish-Green Luminescent Material (K2HfSi3O9:Eu2+) with Robust Thermal Stability for White Light-Emitting Diodes106A ratiometric optical thermometer with high sensitivity and superior signal discriminability based on Na3Sc2P3O12: Eu2+, Mn2+ thermochromic phosphor330Understanding the blue-emitting orthoborate phosphor NaBaBO 3 :Ce 3+ through experiment and computation49Luminescence quenching properties of Sr2Ga2GeO7: Pr3+ with and without traps participation18Insights into anti-thermal quenching of photoluminescence from SrCaGa4O8 based on defect state and application in temperature sensing24Dopant preferential site occupation and high efficiency white emission in K 2 BaCa(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphors for high quality white LED applications87Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes71Structural design of new Ce 3+ /Eu 2+ -doped or co-doped phosphors with excellent thermal stabilities for WLEDs133Recent advances in solid-state LED phosphors with thermally stable luminescence325Abnormal thermal quenching and blue-shift of Zn3(BO3)(PO4):Inducing host defect by doping Mn2+ and Tb3+29One‐Step Synthesis of Silica‐Coated Carbon Dots with Controllable Solid‐State Fluorescence for White Light‐Emitting Diodes126Red photo-stimulated luminescence from deep traps of BaZrGe3O9: Pr3+ for optical imaging application20Activating persistent luminescence and thermal stability of K2Ba7Si16O40: Eu2+ via traps modulation9Crystal structure insight aided design of SrGa2Si2O8:Mn2+ with multi-band and thermally stable emission for high-power LED applications43Synthesis and investigation of orange-emitting Eu2+ doped Ba4Li2B10O20 phosphor4Site occupancy and tunable photoluminescence properties of Eu2+-Activated Ba3Sc(BO3)3 phosphors for white light emitting diodes33Broad Green Emission in the Leucite-Like Cs2ZnSi5O12:Eu2+ Phosphor15Photoluminescence Control and Superior Thermal Stability Enhancement in Eu2+-activated pollucite phosphors2Role of H3BO3 and Sr2+/K+ in the luminescent property of NaBaB9O15:Eu2+5Tunable dual‐mode emission with excellent thermal stability in Ca 4 ZrGe 3 O 12 :Eu phosphors prepared in air for NUV‐LEDs14Combining experiment and computation to elucidate the optical properties of Ce 3+ in Ba 5 Si 8 O 2113Hierarchical Cs–Pollucite Nanozeolite Modified with Novel Organosilane as an Excellent Solid Base Catalyst for Claisen–Schmidt Condensation of Benzaldehyde and Acetophenone9Energy transfer from Mn4+ to Mn5+ and near infrared emission with wide excitation band in Ca14Zn6Ga10O35:Mn phosphors67Energy transfer, superior thermal stability and multi-color emitting properties of langbeinite-type solid-solution phosphor K2Dy1.5–Eu Ta0.5(PO4)37Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lighting67Energy transfer and highly thermal stability in single-phase SrY2O4:Bi3+,Sm3+ phosphors for UV-LEDs28Thermally Robust and Color-Tunable Blue-Green-Emitting BaMgSi 4 O 10 :Eu 2+ ,Mn 2+ Phosphor for Warm-White LEDs44Effects of Eu2+ substitution on structural and optical properties with blue light emission in pollucite CsAlSi2O6 phosphor10Highly efficient blue-emitting phosphor of Sr[B 8 O 11 (OH) 4 ]:Eu 2+ prepared by a self-reduction method19Thermal stability of nitride phosphors for light-emitting diodes66Conversion of thermal energy to light energy and energy transfer in KGdF4: Eu3+,Tb3+ phosphors10Near-ultraviolet excited broadband orange-yellow emitting Sr8MgIn(PO4)7:Eu2+ phosphors for WLEDs with high color rendering index10Designing a Thermally Robust Green-Emitting Phosphor Rb2HfSi2O7: Eu2+ by an Atomic Chain Vibration Model and Its White Light-Emitting Diode Application16Thermal-stable blue-red dual-emitting Na2Mg2Si6O15: Eu2+, Mn2+ phosphor for plant growth lighting31Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Compensation effect of electron traps for enhanced fluorescence intensity ratio thermometry performance22Energy transfer properties of a single-phase Na 3 Gd(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphor with excellent thermal stability for w-LEDs28How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Near-UV excited green-emission enhancement by efficient energy transfer in Na1.8Mg0.9Si1.1O4:Ce3+,Tb3+ phosphor for solid-state lighting applications13Novel green-emitting phosphor Na2CaGe6O14: Tb3+ with high thermal stability by assistant of carriers from traps0A tunable blue–cyan dual emission phosphor in Ca 4− x Lu 2 x Hf 1− x Ge 3 O 12 :Bi 3+ via forming segregation structure for WLEDs13Strategies for Enhancement Luminance of Sub‐Micrometer Phosphor: A Sub‐Micrometer Narrow‐Band Red Phosphor with Ultrahigh Thermal Stability50Defect-induced zero thermal quenching of a bright red-emitting nonlinear optical material10On The Validity of the Defect- Induced Negative Thermal Quenching of Eu2+-Doped Phosphors7Non-rare-earth-doped submicron-grade narrow-band red phosphors for W-LED as well as FED and enhanced Bi 3+ -doped blue light absorption32Trap-regulated highly efficient mechanoluminescence and persistent mechanoluminescence of Ca 2 MgSi 2 O 7 :Eu 2+41A nitriding garnet structure cyan emitting phosphor Ca2(Y, Ce)Hf2(Al, Si)3(O, N)12 with high efficiency and excellent thermal stability10Thermally-stable novel NaBaBi2(PO4)3: Sm3+/Dy3+ white phosphors with tunable photoluminescence50Narrow-Band Deep-Blue Emission and Superior Thermal Stability of Fluoroaluminate Phosphor Based on Tungsten Bronze-Type Mineral Structure5On the luminescence properties of Eu2+ with multiple-site occupancy in silicate K2MgSi3O83High-Quantum-Efficiency Blue Phosphors with Superior Thermal Stability Derived from Eu3+-Doped Faujasite Y Zeolite11Regulating luminescence thermal quenching based on the synergistic effect of energy transfer and energy gap modulation3Structure tailoring and defect engineering of a highly thermally stable red emitting phosphor22Multiple optical thermometry and dynamic anti-counterfeiting based on multicolor luminescence of SrY2O4:Bi3+,Er3+ phosphor45Novel orange red phosphor BaLaGaO4: Sm3+ with high quantum efficiency and good thermal stability for indoor illumination and anti-counterfeiting inks applications59A novel highly thermal-stable Ca2GaNbO6: Sm3+ phosphor with excellent color purity for high CRI wLEDs and security ink51Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Killing Three Birds with One Stone: Energy Transfer Inducing Efficient, Zero Thermal Quenching, and Emission‐Color Tunable Phosphors21Energy transfer and tunable photoluminescence of novel white-emitting Sr8MgY(PO4)7: Ce3+/Eu2+/Sm3+ phosphors7A Novel Anti-Thermal Quenching Ca9znk(Vo4)7:Sm3+ Phosphor for Highly Sensitive Dual-Modal Optical Thermometer1A novel negative-thermal quenching Ca 9 ZnK(VO 4 ) 7 :Sm 3+ phosphor for a sensitive optical thermometer2Remarkable Thermal Stability of Ca9mgk(Vo4)7:Sm3+ Phosphor for Sensitive Optical Thermometry and Plant-Growth Lighting0Remarkable Thermal Stability of Ca9mgk(Vo4)7:Sm3+ Phosphor For Sensitive Optical Thermometry and Plant-Growth Lighting0Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9Ca9-zMzCsLu0.667(PO4)7:Eu2+ (M = Mg2+, Sr2+): β-Ca3(PO4)2-based LED phosphors with improved thermal stability and standard white light3A novel single-phase Ca3Gd2Si3O12:Dy3+, Sm3+ phosphor exhibiting high thermal stability for solid-state lighting applications19Europium(II) Activated Blue–Cyan Aluminosilicate Phosphors with Zero Thermal Quenching3Multi-mode dynamic anti-counterfeiting and self-calibrated temperature sensing applications based on Bi/Mn -activated CaSb2O6 phosphor5Facilitated self-reduction of manganese through alkali metal ions co-doping and photoluminescence properties in CaSb2O6 host lattice3Remarkable thermal stability of Ca9MgK(VO4)7:Sm3+ phosphor for sensitive optical thermometry and plant-growth lighting4A novel Eu-doped broadband orange-red phosphor SrLaGaO4 with high thermal stability for WLEDs and anti-counterfeiting inks3Novel thermally-stable Sr2AlTaO6: Sm3+ phosphors: synthesis, optical properties and applications in WLEDs and anti-counterfeiting1Antithermal Quenching in Sm 3+ Doped Double Perovskite Phosphors2Spectroscopic investigation of Sr1−xCaxLiAl3N4:Eu2+ phosphor involving structural characterization, luminescence mechanism and potential LED applications0

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  2. CaF 2 :Eu films shine novel blue, white or red luminescence though adjustment of the valence state of Eu ions using the electro-deposition method

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  3. Improvement of thermal stability and photoluminescence in Sr 0.8 Ca 0.2 Al 2 Si 2 O 8 :Eu 2+ by the substitution of Si–Na # Al–Sr and Ca # Sr for structural modifications

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  4. Achieving long-term zero-thermal-quenching with the assistance of carriers from deep traps

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  5. Luminescent properties of Eu-doped magnetic Na 3 FeF 6

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  6. Synthesis, electronic structures, and photoluminescence properties of an efficient and thermally stable red-emitting phosphor Ca 3 ZrSi 2 O 9 :Eu 3+ ,Bi 3+ for deep UV-LEDs

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  7. Zero-thermal-quenching and photoluminescence tuning with the assistance of carriers from defect cluster traps

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  8. Thermally stable photoluminescence and long persistent luminescence of Ca 3 Ga 4 O 9 :Tb 3+ /Zn 2+

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  9. Identifying the Emission Centers and Probing the Mechanism for Highly Efficient and Thermally Stable Luminescence in the La3Si6N11:Ce3+ Phosphor

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  11. Design and Development of a Bluish-Green Luminescent Material (K2HfSi3O9:Eu2+) with Robust Thermal Stability for White Light-Emitting Diodes

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  12. A ratiometric optical thermometer with high sensitivity and superior signal discriminability based on Na3Sc2P3O12: Eu2+, Mn2+ thermochromic phosphor

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  13. Understanding the blue-emitting orthoborate phosphor NaBaBO 3 :Ce 3+ through experiment and computation

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  14. Luminescence quenching properties of Sr2Ga2GeO7: Pr3+ with and without traps participation

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  15. Insights into anti-thermal quenching of photoluminescence from SrCaGa4O8 based on defect state and application in temperature sensing

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  16. Dopant preferential site occupation and high efficiency white emission in K 2 BaCa(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphors for high quality white LED applications

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  17. Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes

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  18. Structural design of new Ce 3+ /Eu 2+ -doped or co-doped phosphors with excellent thermal stabilities for WLEDs

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  19. Recent advances in solid-state LED phosphors with thermally stable luminescence

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  20. Abnormal thermal quenching and blue-shift of Zn3(BO3)(PO4):Inducing host defect by doping Mn2+ and Tb3+

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  23. Activating persistent luminescence and thermal stability of K2Ba7Si16O40: Eu2+ via traps modulation

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  27. Broad Green Emission in the Leucite-Like Cs2ZnSi5O12:Eu2+ Phosphor

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  28. Photoluminescence Control and Superior Thermal Stability Enhancement in Eu2+-activated pollucite phosphors

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  29. Role of H3BO3 and Sr2+/K+ in the luminescent property of NaBaB9O15:Eu2+

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  30. Tunable dual‐mode emission with excellent thermal stability in Ca 4 ZrGe 3 O 12 :Eu phosphors prepared in air for NUV‐LEDs

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  31. Combining experiment and computation to elucidate the optical properties of Ce 3+ in Ba 5 Si 8 O 21

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  34. Energy transfer, superior thermal stability and multi-color emitting properties of langbeinite-type solid-solution phosphor K2Dy1.5–Eu Ta0.5(PO4)3

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  35. Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lighting

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  36. Energy transfer and highly thermal stability in single-phase SrY2O4:Bi3+,Sm3+ phosphors for UV-LEDs

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  37. Thermally Robust and Color-Tunable Blue-Green-Emitting BaMgSi 4 O 10 :Eu 2+ ,Mn 2+ Phosphor for Warm-White LEDs

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  38. Effects of Eu2+ substitution on structural and optical properties with blue light emission in pollucite CsAlSi2O6 phosphor

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  39. Highly efficient blue-emitting phosphor of Sr[B 8 O 11 (OH) 4 ]:Eu 2+ prepared by a self-reduction method

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  40. Thermal stability of nitride phosphors for light-emitting diodes

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  41. Conversion of thermal energy to light energy and energy transfer in KGdF4: Eu3+,Tb3+ phosphors

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  42. Near-ultraviolet excited broadband orange-yellow emitting Sr8MgIn(PO4)7:Eu2+ phosphors for WLEDs with high color rendering index

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  45. Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction

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  46. Compensation effect of electron traps for enhanced fluorescence intensity ratio thermometry performance

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  47. Energy transfer properties of a single-phase Na 3 Gd(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphor with excellent thermal stability for w-LEDs

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  48. How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications

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  49. Near-UV excited green-emission enhancement by efficient energy transfer in Na1.8Mg0.9Si1.1O4:Ce3+,Tb3+ phosphor for solid-state lighting applications

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  50. Novel green-emitting phosphor Na2CaGe6O14: Tb3+ with high thermal stability by assistant of carriers from traps

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