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RESEARCH PAPER · Advanced Functional Materials · 2017

New Apatite‐Type Oxide Ion Conductor, Bi2La8[(GeO4)6]O3: Structure, Properties, and Direct Imaging of Low‐Level Interstitial Oxygen Atoms Using Aberration‐Corrected Scanning Transmission Electron Microscopy

Matthew L. Tate, Douglas A. Blom, Maxim Avdeev, Helen E. A. Brand, Garry James McIntyre, Thomas Vogt, Ivana Radosavljević Evans

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New Apatite‐Type Oxide Ion Conductor, Bi2La8[(GeO4)6]O3: Structure, Properties, and Direct Imaging of Low‐Level Interstitial Oxygen Atoms Using Aberration‐Corrected Scanning Transmission Electron MicroscopyOriginalLocation and orientation of lone pairs in apatite-type materials: a computational study8Synthesis and characterisation of new Bi( iii )-containing apatite-type oxide ion conductors: the influence of lone pairs13Rational Design of a Commensurate (3 + 3)-D Modulated Structure within the Fast-Ion Conducting Stabilized δ-Bi2O3 Series6Emerging Postsynthetic Improvements of BiVO4 Photoanodes for Solar Water Splitting124Dynamics in Bi( iii )-containing apatite-type oxide ion conductors: a combined computational and experimental study20Insight into the structure and functional application of Mg-doped Na0.5Bi0.5TiO3 electrolyte for solid oxide fuel cells30Bi-apatite: Synthesis, crystal structure and low-temperature heat capacity6Pyrochlore Pr2Zr2-xMxO7+δ (M = Al, Ga, In) solid-state electrolytes: Defect-mediated oxygen hopping pathways and enhanced NO2 sensing properties29High Oxide Ion Conduction in Molten Na2W2O726Cooperative mechanisms of oxygen vacancy stabilization and migration in the isolated tetrahedral anion Scheelite structure153Single-phase white-emitting phosphors based on apatite-type gadolinium silicate, Gd 9.33 (SiO 4 ) 6 O 2 doped with Dy 3+ , Eu 3+ and Tb 3+29Interstitial Oxide Ion Migration Mechanism in Aluminate Melilite La1+xCa1–xAl3O7+0.5x Ceramics Synthesized by Glass Crystallization35Chemical Bonding Effect on the Incorporation and Conduction of Interstitial Oxide Ions in Gallate Melilites9Brownmillerite-Type Sr2ScGaO5 Oxide Ion Conductor: Local Structure, Phase Transition, and Dynamics30Average and Local Structure of Apatite-Type Germanates and Implications for Oxide Ion Conductivity12Structure and thermal expansion behavior of Ca 4 La 6−x Nd x (SiO 4 ) 4 (PO 4 ) 2 O 2 apatite for nuclear waste immobilization10Evolution of Structure in the Incommensurate Modulated LaNb1–xWxO4+x/2 (x = 0.04–0.16) Oxide Ion Conductors14A2B2O7 (A= La, Pr, Nd, Sm, Gd and B Ti, Zr, Sn) ceramics for mild-temperature NO2 sensing and reduction48Oxide Ion and Proton Conductivity in Highly Oxygen-Deficient Cubic Perovskite SrSc0.3Zn0.2Ga0.5O2.430Rare earth elements based oxide ion conductors52Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.517Hydroxyapatites as Versatile Inorganic Hosts of Unusual Pentavalent Manganese Cations9Polyol-mediated synthesis of Bi-deficient Mg2+-doped sodium bismuth titanate and study of oxide ion migration behavior with functional properties24Effect of synthesis route on the structural and electrical properties of sodium bismuth titanate: A comparative study of solid-state and polyol mediated synthesis4Lone-pair stabilized channels and blocked transport in apatite-related structures0Effect of Long- and Short-Range Disorder on the Oxygen Ionic Conductivity of Tm2(Ti2–xTmx)O7–x/2 “Stuffed” Pyrochlores24Average and local ordering of Yb2(Ti2-Yb )O7-/2 ‘stuffed’ pyrochlores: The development of a robust structural model14Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures18Synthesis and Ion-Transport Properties of EuKGe2O6-, Ca3Fe2Ge3O12-, and BaCu2Ge2O7-Type Oxide-Ion Conductors3Diagnostic and Theranostic Applications of Inorganic Materials0New apatite‐type oxide ion conductors Ce9.33+xSi6O26+δ: Structures, phase stabilities, electrical properties, and conducting mechanisms3Oxide Ion and Proton Conductivity in a Family of Highly Oxygen-Deficient Perovskite Derivatives43Structure, electrical properties, and conduction mechanism of new germanate mixed Zn-doped In 2 Ge 2 O 7 conductors2Oxide Ion Conductivity, Proton Conductivity, and Phase Transitions in Perovskite-Derived Ba3–xSrxYGa2O7.5 0 ≤ x ≤ 3 Materials12Effective regulation of electronic structures and luminescence properties of LiGd9(SiO4)6–(GeO4) O2:Dy3+ phosphors by tetrahedral substitution13Borates as a new direction in the design of oxide ion conductors21Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms94Mixed oxide ion–proton conductivity and the ionic migration mechanism in isolated tetrahedral LaVO 4 by acceptor doping7Unlocking zeolite-like structures as a new family of interstitial oxide ion conductors: insights into carrier trapping, collective local distortion, and correlated disorder6Cooperative mechanisms of oxide ion conduction in tellurites with secondary bond interactions and Grotthuss-like processes8Interstitial Oxygen Induced K+ Ions’ Order-to-Disorder Transition and High Oxide Ion Conduction in K2ZnV2O73Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity0Enhanced Oxygen Ion Conductivity and Ionic Conduction Mechanistic Visualization in Tetragonal Zircon-Type Pr1–xSrxVO4–0.5x1A‐Site Doping Enables Stabilization and Migration of Oxygen Vacancies in Langasite Frameworks1Local Rigid-Unit Design Modulates Interstitial Oxygen Coordination Geometry for Developing Langasite-Type Oxide-Ion Solid Electrolytes2High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide0High-Sensitivity and High-Precision Near-Infrared Luminescence Thermometry Using Mn5+-Activated Sr5(VO4)3Cl and Ba5(VO4)3Cl-Based Phosphors1Ba7Zn5Ga6O21: Terminal Oxygens Enable High Oxide-Ion and Proton Conductivity in a Condensed Three-Dimensional Tetrahedral Framework0Phonon‐Driven Tetrahedral Tilts Enable Ultralow Bulk Thermal Expansion and Interstitial Oxide‐Ion Migration in Phenacite Solid Electrolytes0Minimal Transport Units Govern Oxygen‐Defect Stabilization and Transport for Lightweight Solid Electrolytes0Ionic-Layer Engineering Enables Propeller-Type Interstitialcy Oxygen Migration in Close-Packed Perovskite Solid Electrolytes0

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  1. Location and orientation of lone pairs in apatite-type materials: a computational study

    Dalton Transactions · 2017-01-01

    Joseph R. Peet, Andrea Piovano, Mark Robert Johnson, Ivana Radosavljević Evans

    Read original paper ↗ ·

  2. Synthesis and characterisation of new Bi( iii )-containing apatite-type oxide ion conductors: the influence of lone pairs

    Dalton Transactions · 2017-01-01

    Matthew L. Tate, Chloe A. Fuller, Maxim Avdeev, Helen E. A. Brand, Garry James McIntyre, Ivana Radosavljević Evans

    Read original paper ↗ ·

  3. Rational Design of a Commensurate (3 + 3)-D Modulated Structure within the Fast-Ion Conducting Stabilized δ-Bi2O3 Series

    Chemistry of Materials · 2017-10-04

    Julia Wind, Julia Polt, Zhaoming Zhang, Douglas A. Blom, Thomas Vogt, Ray Leslie Withers, Chris D. Ling

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  4. Emerging Postsynthetic Improvements of BiVO4 Photoanodes for Solar Water Splitting

    ACS Energy Letters · 2017-11-22

    Benjamin W. Lamm, Bartek J. Trześniewski, Henning Döscher, Wilson A. Smith, Morgan Stefik

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  5. Dynamics in Bi( iii )-containing apatite-type oxide ion conductors: a combined computational and experimental study

    Journal of Materials Chemistry A · 2018-01-01

    Joseph R. Peet, Matthew S. Chambers, Andrea Piovano, Mark Robert Johnson, Ivana Radosavljević Evans

    Read original paper ↗ ·

  6. Insight into the structure and functional application of Mg-doped Na0.5Bi0.5TiO3 electrolyte for solid oxide fuel cells

    Journal of Alloys and Compounds · 2018-04-06

    Yao Lu, Carlos Alberto López, Jie Wang, J. A. Alonso, Chunwen Sun

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  7. Bi-apatite: Synthesis, crystal structure and low-temperature heat capacity

    The Journal of Chemical Thermodynamics · 2018-04-26

    E.N. Bulanov, K.S. Korshak, Maxim I. Lelet, Alexander Vladimirovich Knyazev, Tom Baikie

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  8. Pyrochlore Pr2Zr2-xMxO7+δ (M = Al, Ga, In) solid-state electrolytes: Defect-mediated oxygen hopping pathways and enhanced NO2 sensing properties

    Sensors and Actuators B Chemical · 2018-04-30

    Fulan Zhong, Lanqian Shi, Jiwu Zhao, Guohui Cai, Yong Zheng, Yihong Xiao, Ying Zheng, Lilong Jiang

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  9. High Oxide Ion Conduction in Molten Na2W2O7

    Advanced Electronic Materials · 2018-09-05

    Jungu Xu, Yanchang Li, Jiehua Wang, Hongliang Bao, Jian‐Qiang Wang, Changli Zhu, Lingting Ye, Kui Xie, Xiaojun Kuang

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  10. Cooperative mechanisms of oxygen vacancy stabilization and migration in the isolated tetrahedral anion Scheelite structure

    Nature Communications · 2018-10-22

    Xiaoyan Yang, Alberto José Fernández-Carrión, Jiehua Wang, Florence Porcher, Franck Fayon, Mathieu M. B. Allix, Xiaojun Kuang

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  11. Single-phase white-emitting phosphors based on apatite-type gadolinium silicate, Gd 9.33 (SiO 4 ) 6 O 2 doped with Dy 3+ , Eu 3+ and Tb 3+

    Journal of Materials Chemistry C · 2019-01-01

    Melissa M. Rodríguez-García, J. A. Gareth Williams, Ivana Radosavljević Evans

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  12. Interstitial Oxide Ion Migration Mechanism in Aluminate Melilite La1+xCa1–xAl3O7+0.5x Ceramics Synthesized by Glass Crystallization

    ACS Applied Energy Materials · 2019-04-03

    Jungu Xu, Jiehua Wang, Aydar I. Rakhmatullin, Sandra Ory, Alberto José Fernández-Carrión, Huaibo Yi, Xiaojun Kuang, Mathieu M. B. Allix

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  13. Chemical Bonding Effect on the Incorporation and Conduction of Interstitial Oxide Ions in Gallate Melilites

    Advanced Theory and Simulations · 2019-06-24

    Jungu Xu, Yanchang Li, Lijia Zhou, Xin Tang, Xiaojun Kuang

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  14. Brownmillerite-Type Sr2ScGaO5 Oxide Ion Conductor: Local Structure, Phase Transition, and Dynamics

    Chemistry of Materials · 2019-08-06

    Chloe A. Fuller, Quentin Berrod, Bernhard Frick, Mark Robert Johnson, Stewart J. Clark, John S. O. Evans, Ivana Radosavljević Evans

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  15. Average and Local Structure of Apatite-Type Germanates and Implications for Oxide Ion Conductivity

    Inorganic Chemistry · 2019-10-16

    Matthew S. Chambers, Philip A. Chater, Ivana Radosavljević Evans, John S. O. Evans

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  16. Structure and thermal expansion behavior of Ca 4 La 6−x Nd x (SiO 4 ) 4 (PO 4 ) 2 O 2 apatite for nuclear waste immobilization

    Dalton Transactions · 2020-01-01

    Shan Yan, Dongyan Yang, Shuangqiang Chen, Juan Wen, Wenhao He, Shiyin Ji, Yue Xia, Yinlong Wang, Liangfu Zhou, Yuhong Li

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  17. Evolution of Structure in the Incommensurate Modulated LaNb1–xWxO4+x/2 (x = 0.04–0.16) Oxide Ion Conductors

    Chemistry of Materials · 2020-02-20

    Cheng Li, Stevin S. Pramana, Ryan D. Bayliss, Clare P. Grey, Frédéric Blanc, Stephen J. Skinner

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  18. A2B2O7 (A= La, Pr, Nd, Sm, Gd and B Ti, Zr, Sn) ceramics for mild-temperature NO2 sensing and reduction

    Journal of Alloys and Compounds · 2020-03-20

    Pei Duan, Cheng Han, Yong Zheng, Guohui Cai, Fulan Zhong, Yihong Xiao

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  19. Oxide Ion and Proton Conductivity in Highly Oxygen-Deficient Cubic Perovskite SrSc0.3Zn0.2Ga0.5O2.4

    Chemistry of Materials · 2020-04-27

    Chloe A. Fuller, Quentin Berrod, Bernhard Frick, Mark Robert Johnson, Maxim Avdeev, John S. O. Evans, Ivana Radosavljević Evans

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  20. Rare earth elements based oxide ion conductors

    Inorganic Chemistry Frontiers · 2020-08-19

    Xiaohui Li, Xiaojun Kuang, Junliang Sun

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  21. Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.5

    Inorganic Chemistry · 2020-09-24

    Josie E. Auckett, Matthias Josef Gutmann, Ivana Radosavljević Evans

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  22. Hydroxyapatites as Versatile Inorganic Hosts of Unusual Pentavalent Manganese Cations

    Chemistry of Materials · 2020-12-04

    Áurea Varela, Isabel Gómez‐Recio, Laura Serrador, María Hernando, Emilio Matesanz, Almudena Torres‐Pardo, María Teresa Fernández-Díaz, José Luis Martínez, Francisco Gonell, Gwenaëlle Rousse, Clément Sánchez, Christel Laberty‐Robert, David Portehault, José María González-Calbet, M. Parras

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  23. Polyol-mediated synthesis of Bi-deficient Mg2+-doped sodium bismuth titanate and study of oxide ion migration behavior with functional properties

    Journal of Alloys and Compounds · 2020-12-24

    Pragati Singh, Raghvendra Pandey, Prabhakar Singh

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  24. Effect of synthesis route on the structural and electrical properties of sodium bismuth titanate: A comparative study of solid-state and polyol mediated synthesis

    Materials Today Proceedings · 2021-01-01

    Pragati Singh, Pragati Singh, Raghvendra Pandey, Pramod K. Singh, Pramod K. Singh, Prabhakar Singh, Prabhakar Singh

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  25. Lone-pair stabilized channels and blocked transport in apatite-related structures

    Dalton Transactions · 2021-01-01

    Ce Tao, Rukang K. Li

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  26. Effect of Long- and Short-Range Disorder on the Oxygen Ionic Conductivity of Tm2(Ti2–xTmx)O7–x/2 “Stuffed” Pyrochlores

    Inorganic Chemistry · 2021-03-10

    Bryce G. Mullens, Zhaoming Zhang, Maxim Avdeev, Helen E. A. Brand, Bruce C. C. Cowie, Matilde Saura Muzquiz, Brendan J. Kennedy

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  27. Average and local ordering of Yb2(Ti2-Yb )O7-/2 ‘stuffed’ pyrochlores: The development of a robust structural model

    Journal of Solid State Chemistry · 2021-07-13

    Bryce G. Mullens, Zhaoming Zhang, Maxim Avdeev, Helen E. A. Brand, Bruce C. C. Cowie, Anita M. D’Angelo, Matilde Saura Muzquiz, Brendan J. Kennedy

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  28. Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures

    Laser & Photonics Review · 2021-08-16

    Elena Dobretsova, Xiaojing Xia, Anupum Pant, Matthew B. Lim, Michael C. De Siena, Kirill N. Boldyrev, A. D. Molchanova, Nadezhda N. Novikova, С. А. Климин, Marina N. Popova, Yueyang Chen, Arka Majumdar, Daniel R. Gamelin, Peter J. Pauzauskie

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  29. Synthesis and Ion-Transport Properties of EuKGe2O6-, Ca3Fe2Ge3O12-, and BaCu2Ge2O7-Type Oxide-Ion Conductors

    Inorganic Chemistry · 2021-10-26

    Shin Tajima, Nobuko Ohba, Akitoshi Suzumura, Seiji Kajita

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  30. Diagnostic and Theranostic Applications of Inorganic Materials

    Royal Society of Chemistry eBooks · 2021-12-08

    Junzi Wu, Yanyan Zhang, Li‐Min Zhu

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  31. New apatite‐type oxide ion conductors Ce9.33+xSi6O26+δ: Structures, phase stabilities, electrical properties, and conducting mechanisms

    Energy Science & Engineering · 2021-12-28

    Tianjie Wei, Jungu Xu, Wenfeng Zhu

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  32. Oxide Ion and Proton Conductivity in a Family of Highly Oxygen-Deficient Perovskite Derivatives

    Journal of the American Chemical Society · 2021-12-30

    Chloe A. Fuller, Douglas A. Blom, Thomas Vogt, Ivana Radosavljević Evans, John S. O. Evans

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  33. Structure, electrical properties, and conduction mechanism of new germanate mixed Zn-doped In 2 Ge 2 O 7 conductors

    Inorganic Chemistry Frontiers · 2022-01-01

    Xiaoling Zeng, Xiaohui Li, Jungu Xu, Xiaoge Wang, Sihao Deng, Lunhua He, Junliang Sun, Xiaojun Kuang, Xianran Xing

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  34. Oxide Ion Conductivity, Proton Conductivity, and Phase Transitions in Perovskite-Derived Ba3–xSrxYGa2O7.5 0 ≤ x ≤ 3 Materials

    Chemistry of Materials · 2022-03-28

    Chloe A. Fuller, James I. Murrell, Douglas A. Blom, Thomas Vogt, Weiguo Zhang, P. Shiv Halasyamani, Ivana Radosavljević Evans, John S. O. Evans

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  35. Effective regulation of electronic structures and luminescence properties of LiGd9(SiO4)6–(GeO4) O2:Dy3+ phosphors by tetrahedral substitution

    Journal of Rare Earths · 2022-05-23

    Yuanyuan Zhang, Lefu Mei, Haikun Liu, Sergey M. Aksenov, Dina V. Deyneko, Deliang Chen

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  36. Borates as a new direction in the design of oxide ion conductors

    Science China Materials · 2022-05-24

    Xiaohui Li, Yang Li, Zhenyu Zhu, Xiaoge Wang, Pohua Chen, Senchuan Huang, Xianyi Wei, Guohong Cai, Pascal Manuel, Sihai Yang⧫, Jianhua Lin, Xiaojun Kuang, Junliang Sun

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  37. Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms

    Chemical Reviews · 2023-07-24

    Xiaoyan Yang, Alberto José Fernández-Carrión, Xiaojun Kuang

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  38. Mixed oxide ion–proton conductivity and the ionic migration mechanism in isolated tetrahedral LaVO 4 by acceptor doping

    Inorganic Chemistry Frontiers · 2024-01-01

    Xinyue Geng, G Hang, Alberto José Fernández-Carrión, Xing Ming, Sihao Deng, Lunhua He, Xiaojun Kuang, Xiaoyan Yang

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  39. Unlocking zeolite-like structures as a new family of interstitial oxide ion conductors: insights into carrier trapping, collective local distortion, and correlated disorder

    Chemical Science · 2025-01-01

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  40. Cooperative mechanisms of oxide ion conduction in tellurites with secondary bond interactions and Grotthuss-like processes

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  41. Interstitial Oxygen Induced K+ Ions’ Order-to-Disorder Transition and High Oxide Ion Conduction in K2ZnV2O7

    Inorganic Chemistry · 2025-02-06

    Wenzhuo Chen, Jian Yang, Jiazheng Hao, Feiran Shen, Lunhua He, Xia Deng, Jiasheng Lv, Jing Fang, Laijun Liu, Jungu Xu

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  42. Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity

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  43. Enhanced Oxygen Ion Conductivity and Ionic Conduction Mechanistic Visualization in Tetragonal Zircon-Type Pr1–xSrxVO4–0.5x

    Inorganic Chemistry · 2025-08-19

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  44. A‐Site Doping Enables Stabilization and Migration of Oxygen Vacancies in Langasite Frameworks

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  45. Local Rigid-Unit Design Modulates Interstitial Oxygen Coordination Geometry for Developing Langasite-Type Oxide-Ion Solid Electrolytes

    Chemistry of Materials · 2026-02-09

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  46. High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide

    Advanced Functional Materials · 2026-02-24

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  47. High-Sensitivity and High-Precision Near-Infrared Luminescence Thermometry Using Mn5+-Activated Sr5(VO4)3Cl and Ba5(VO4)3Cl-Based Phosphors

    Chemistry of Materials · 2026-07-08

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  48. Ba7Zn5Ga6O21: Terminal Oxygens Enable High Oxide-Ion and Proton Conductivity in a Condensed Three-Dimensional Tetrahedral Framework

    Inorganic Chemistry · 2026-07-16

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  49. Phonon‐Driven Tetrahedral Tilts Enable Ultralow Bulk Thermal Expansion and Interstitial Oxide‐Ion Migration in Phenacite Solid Electrolytes

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  50. Minimal Transport Units Govern Oxygen‐Defect Stabilization and Transport for Lightweight Solid Electrolytes

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    Xiaohui Li, Yongkang Zheng, Li Yang, Xiaoge Wang, Yuan Gou, Guanqun Cai, Jie Liu, Cheng Li, Kun Lin, Qiang Li, Mingxue Tang, Junliang Sun, Xianran Xing, Xiaojun Kuang

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