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RESEARCH PAPER · Journal of the American Chemical Society · 2021

Oxide Ion and Proton Conductivity in a Family of Highly Oxygen-Deficient Perovskite Derivatives

Chloe A. Fuller, Douglas A. Blom, Thomas Vogt, Ivana Radosavljević Evans, John S. O. Evans

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Oxide Ion and Proton Conductivity in a Family of Highly Oxygen-Deficient Perovskite DerivativesOriginalDefects and disorder in apatite-type silicate oxide ion conductors: implications for conductivity11Temperature-driven order–disorder structural transition in the oxygen sub-lattice and the complex superstructure of the high-temperature polymorph of CaSrZn 2 Ga 2 O 73Oxide Ion Conductivity, Proton Conductivity, and Phase Transitions in Perovskite-Derived Ba3–xSrxYGa2O7.5 0 ≤ x ≤ 3 Materials12Thermogravimetric Analysis on a Resonant Microcantilever36Energy transfer mediated single-phased white light emission in Bi3+-Eu3+ codoped Ba3YGa2O7.5 for WLED33Proton and Oxide Ion Conductivity in Palmierite Oxides45Sulfonated covalent organic framework packed Nafion membrane with high proton conductivity for H 2 /O 2 fuel cell applications78An Engineering Method for Resonant Microcantilever Using Double-Channel Excitation and Signal Acquisition Based on LabVIEW2Competing Magnetic Interactions and the Role of Unpaired 4 f Electrons in Oxygen-Deficient Perovskites Ba 3 R Fe 2 O 7.5 ( R = Y, Dy)6Near-zero thermal quenching of upconversion green emission implemented with the polymorphic phase transition9Proton Diffusion Mechanism in Hydrated Barium Indate Oxides15Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms94New Triclinic Perovskite-Type Oxide Ba5CaFe4O12 for Low-Temperature Operated Chemical Looping Air Separation11Perovskite-related structures of Ba2YAlO5 and the β and α phases of Ba6Y2Al4O15 containing AlO4 tetrahedra3Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides32High proton conductivity within the ‘Norby gap’ by stabilizing a perovskite with disordered intrinsic oxygen vacancies73High proton conduction by full hydration in highly oxygen deficient perovskite32Oxide ion dynamics in hexagonal perovskite mixed conductor Ba 7 Nb 4 MoO 20 : a comprehensive ab initio molecular dynamics study10Self-assembly of water-filled molecular saddles to generate diverse morphologies and high proton conductivity2Oxygen-ion and proton conductivity in the Ba3InGa2O7.5 complex oxide with incomplete oxygen sublattice2MEMS Resonant Beam with Outstanding Uniformity of Sensitivity and Temperature Distribution for Accurate Gas Sensing and On-Chip TGA1Preparation and study on H–MoS2/SLS modified SPI@SPEEK blend proton exchange membrane with balanced proton conductivity and stability13Upconversion luminescence and temperature sensing properties of Ba3GdAl2O7.5: Yb3+, Er3+ phosphor0Topotactic Reduction-Induced Stabilization of β-La2Mo2O8.68 Phase: Structure, Static Oxygen Disorder, and Electrical Properties3Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides1High proton conductivity in Nb 5+ -doped BaScO 2.59Introduction0Oxide Ion Dynamics and Structure–Property Relationships in A3OhTd2O7.5 Ionic Conductors (A = Ba, Sr; Oh = Y; Td = Ga, Zn)4Layered perovskite SrLaAlO4 as a proton-conducting material for intermediate-temperature solid oxide fuel cells: synthesis, hydration, and electrical properties6Defect-engineered photoluminescence in Ba6Y2Ga4O15: Synergistic cation and atmosphere regulation for ultraviolet-driven WLEDs18Advancing electrochemical devices: the promise of triple ionic–electronic conducting oxides5Ba3EuGa2O7.5 red-emitting phosphor combining anti-thermal quenching with high efficiency for white light-emitting diodes and latent fingerprint1Defect-assisted vertical proton channels in highly oriented bismuth strontium tantalum oxide nanosheet laminar films1Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure0Dual ionic conductivity in Ba 3 InGa 2 O 7.5 : correlating structure and electrochemical properties0Recent advances in perovskite-derived microwave absorption materials2Sulfonated Covalent Organic Framework-Carbon Nanotube Hybrid Interfaces to Boost Proton Transport in Nafion-Based Fuel Cell Membranes0Locally concentrated protons control the proton diffusivity in heavily Sc-doped perovskites0Ba7Zn5Ga6O21: Terminal Oxygens Enable High Oxide-Ion and Proton Conductivity in a Condensed Three-Dimensional Tetrahedral Framework0Dual-polymorph abnormal thermal quenching in Yb3+, Er3+ co-doped Ba3YAl2O7.5 phosphor: Defect-assisted and phase-transition-driven mechanisms0High−entropy perovskite−based S-scheme heterojunction with interfacial Cu0 as electron-transport highway for efficient CO2 conversion0Sulfonated covalent organic framework-carbon nanotube hybrid interfaces to boost proton transport in Nafion-based fuel cell membranes0Decoupling the Roles of B‐Site Cation Defects and Oxygen Vacancies in Exsolved Perovskites for Robust CO 2 Electrolysis in Solid‐State Cells0

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  1. Defects and disorder in apatite-type silicate oxide ion conductors: implications for conductivity

    Journal of Materials Chemistry A · 2022-01-01

    Chloe A. Fuller, Matthias Josef Gutmann, Chris D. Ling, Chun‐Hai Wang, Weiguo Zhang, P. Shiv Halasyamani, Ivana Radosavljević Evans, John S. O. Evans

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  2. Temperature-driven order–disorder structural transition in the oxygen sub-lattice and the complex superstructure of the high-temperature polymorph of CaSrZn 2 Ga 2 O 7

    Dalton Transactions · 2022-01-01

    Jie Qin, Pengfei Jiang, Guangxiang Lu, Rong Wang, Tao Yang

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  3. Oxide Ion Conductivity, Proton Conductivity, and Phase Transitions in Perovskite-Derived Ba3–xSrxYGa2O7.5 0 ≤ x ≤ 3 Materials

    Chemistry of Materials · 2022-03-28

    Chloe A. Fuller, James I. Murrell, Douglas A. Blom, Thomas Vogt, Weiguo Zhang, P. Shiv Halasyamani, Ivana Radosavljević Evans, John S. O. Evans

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  4. Thermogravimetric Analysis on a Resonant Microcantilever

    Analytical Chemistry · 2022-06-22

    Fanglan Yao, Pengcheng Xu, Hao Wei Jia, Xinyu Li, Xinyu Li, Haitao Yu, Xinxin Li, Xinxin Li

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  5. Energy transfer mediated single-phased white light emission in Bi3+-Eu3+ codoped Ba3YGa2O7.5 for WLED

    Journal of Alloys and Compounds · 2022-07-21

    Shuai Wei, Zhijun Li, Zeyu Lyu, Dashuai Sun, Sida Shen, Jianhui Wang, Chengyu Zhuo, Hongpeng You

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  6. Proton and Oxide Ion Conductivity in Palmierite Oxides

    Chemistry of Materials · 2022-09-06

    Sacha Fop, James Alexander Dawson, Dylan N. Tawse, Matthew G. Skellern, J.M.S. Skakle, Abbie Christina Mclaughlin

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  7. Sulfonated covalent organic framework packed Nafion membrane with high proton conductivity for H 2 /O 2 fuel cell applications

    Journal of Materials Chemistry A · 2023-01-01

    Zhichao Shao, Xiaojing Xue, Kexin Gao, Junshuai Chen, Lipeng Zhai, Tianyang Wen, Shenglin L. Xiong, Hongwei Hou, Liwei Mi

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  8. An Engineering Method for Resonant Microcantilever Using Double-Channel Excitation and Signal Acquisition Based on LabVIEW

    Micromachines · 2023-04-07

    Shanlai Wang, Zhi Cao, Xiaoyang Zhang, Haitao Yu, Lei Yao

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  9. Competing Magnetic Interactions and the Role of Unpaired 4 f Electrons in Oxygen-Deficient Perovskites Ba 3 R Fe 2 O 7.5 ( R = Y, Dy)

    Inorganic Chemistry · 2023-04-20

    Alex J. Brown, Maxim Avdeev, Alicia Maria Manjón-Sanz, Helen E. A. Brand, Chris D. Ling

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  10. Near-zero thermal quenching of upconversion green emission implemented with the polymorphic phase transition

    Journal of Luminescence · 2023-05-12

    Ruonan Wang, Xiaomin Bian, Xin Yang, Qiuyang Li, Tian Luo, Junshan Hu, Hao Fu

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  11. Proton Diffusion Mechanism in Hydrated Barium Indate Oxides

    Chemistry of Materials · 2023-07-13

    Adrien Perrichon, Michael Marek Koza, Zach Evenson, Bernhard Frick, F. Demmel, Peter Fouquet, Maths Karlsson

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  12. Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms

    Chemical Reviews · 2023-07-24

    Xiaoyan Yang, Alberto José Fernández-Carrión, Xiaojun Kuang

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  13. New Triclinic Perovskite-Type Oxide Ba5CaFe4O12 for Low-Temperature Operated Chemical Looping Air Separation

    Journal of the American Chemical Society · 2023-10-09

    Satoshi Ogawa, Sayaka Tamura, Hisanori Yamane, Toyokazu Tanabe, Miwa Saito, Teruki Motohashi

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  14. Perovskite-related structures of Ba2YAlO5 and the β and α phases of Ba6Y2Al4O15 containing AlO4 tetrahedra

    Acta Crystallographica Section C Structural Chemistry · 2023-10-17

    Rayko Simura, Yamato Suzuki, Hisanori Yamane

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  15. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Chemistry of Materials · 2023-11-14

    Yuichi Sakuda, Taito Murakami, Maxim Avdeev, Kotaro Fujii, Yuta Yasui, James Hester, Masato Hagihala, Yoichi Ikeda, Yusuke Nambu, Masatomo Yashima

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  16. High proton conductivity within the ‘Norby gap’ by stabilizing a perovskite with disordered intrinsic oxygen vacancies

    Nature Communications · 2023-11-17

    K. Saito, Masatomo Yashima

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  17. High proton conduction by full hydration in highly oxygen deficient perovskite

    Journal of Materials Chemistry A · 2024-01-01

    K. Saito, Kensei Umeda, Kotaro Fujii, Kazuhiro John Mori, Masatomo Yashima

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  18. Oxide ion dynamics in hexagonal perovskite mixed conductor Ba 7 Nb 4 MoO 20 : a comprehensive ab initio molecular dynamics study

    Materials Advances · 2024-01-01

    Bettina Schwaighofer, Markus Appel, Miguel Angel Gonzalez, Ivana Radosavljević Evans

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  19. Self-assembly of water-filled molecular saddles to generate diverse morphologies and high proton conductivity

    Nanoscale · 2024-01-01

    Nyaya Prakash Pradhan, Sweety Gupta, Swapnendu Narayan Ghosh, Amit Paul, Santanu Talukder, Aasheesh Srivastava

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  20. Oxygen-ion and proton conductivity in the Ba3InGa2O7.5 complex oxide with incomplete oxygen sublattice

    Chimica Techno Acta · 2024-01-17

    Nadezhda A. Kochetova, Veronika Cherepanova, Alyona A. Pikalova, Artem R. Gilev

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  21. MEMS Resonant Beam with Outstanding Uniformity of Sensitivity and Temperature Distribution for Accurate Gas Sensing and On-Chip TGA

    Sensors · 2024-04-13

    Lu Zheng, Hao Wei Jia, Ding Wang, Haitao Yu

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  22. Preparation and study on H–MoS2/SLS modified SPI@SPEEK blend proton exchange membrane with balanced proton conductivity and stability

    International Journal of Hydrogen Energy · 2024-05-25

    Lingwei Li, Yao Wang, Feibo Li, Jiale Zhao, Bihai Su, Xiaojing Wang, Linlin Shi, Jingbo Mu, Yanming Wang, Ping Li, Xiaoliang Zhang

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  23. Upconversion luminescence and temperature sensing properties of Ba3GdAl2O7.5: Yb3+, Er3+ phosphor

    Journal of Physics Conference Series · 2024-08-01

    Ruonan Wang, Tian Luo, Hao Fu

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  24. Topotactic Reduction-Induced Stabilization of β-La2Mo2O8.68 Phase: Structure, Static Oxygen Disorder, and Electrical Properties

    Inorganic Chemistry · 2024-11-19

    Xueting Zhang, Cécile Genevois, Cheng Li, Xiaoyan Yang, Michael J. Pitcher, Mathieu M. B. Allix, Xiaojun Kuang, Alberto José Fernández-Carrión

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  25. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Springer theses · 2025-01-01

    Yuichi Sakuda

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  26. High proton conductivity in Nb 5+ -doped BaScO 2.5

    Inorganic Chemistry Frontiers · 2025-01-01

    K. Saito, Mitsuki Baba, Kensei Umeda, Kotaro Fujii, Takashi Honda, Masatomo Yashima

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  27. Introduction

    Springer theses · 2025-01-01

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  28. Oxide Ion Dynamics and Structure–Property Relationships in A3OhTd2O7.5 Ionic Conductors (A = Ba, Sr; Oh = Y; Td = Ga, Zn)

    Chemistry of Materials · 2025-04-16

    Oliver J. Wagstaff, Maxim Avdeev, Stewart J. Clark, John S. O. Evans, Ivana Radosavljević Evans

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  29. Layered perovskite SrLaAlO4 as a proton-conducting material for intermediate-temperature solid oxide fuel cells: synthesis, hydration, and electrical properties

    Ionics · 2025-06-02

    D.S. Vasin, Наталья Владимировна Лакиза, Irina E. Animitsa

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  30. Defect-engineered photoluminescence in Ba6Y2Ga4O15: Synergistic cation and atmosphere regulation for ultraviolet-driven WLEDs

    Chemical Engineering Journal · 2025-06-05

    Wenjie Deng, Decai Huang, Jiaqing Peng, Fengli Yang, Weixiong You, Xinyu Ye

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  31. Advancing electrochemical devices: the promise of triple ionic–electronic conducting oxides

    Journal of Physics D Applied Physics · 2025-09-09

    Mudasir A. Yatoo, Stephen J. Skinner

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  32. Ba3EuGa2O7.5 red-emitting phosphor combining anti-thermal quenching with high efficiency for white light-emitting diodes and latent fingerprint

    Materials Today Chemistry · 2025-10-01

    Sen Yan, Ruitong Song, Hao Wang, Wei Jin, Junshan Hu, Hao Fu

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  33. Defect-assisted vertical proton channels in highly oriented bismuth strontium tantalum oxide nanosheet laminar films

    Nanoscale · 2026-01-01

    Xiang Sun, Mohammad Atiqur Rahman, Satsuki Tomatsu, Yuichi Sakuda, Kazuto Hatakeyama, Shintaro Ida

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  34. Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure

    Springer theses · 2026-01-01

    Yuta Yasui

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  35. Dual ionic conductivity in Ba 3 InGa 2 O 7.5 : correlating structure and electrochemical properties

    Materials Advances · 2026-01-01

    Oliver J. Wagstaff, Archie D. Collins, John S. O. Evans, Ivana Radosavljević Evans

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  36. Recent advances in perovskite-derived microwave absorption materials

    Nanoscale · 2026-01-01

    Yu-Kai Luo, Ming Wang

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  37. Sulfonated Covalent Organic Framework-Carbon Nanotube Hybrid Interfaces to Boost Proton Transport in Nafion-Based Fuel Cell Membranes

    SSRN Electronic Journal · 2026-01-01

    Chellouche Djohaina, Mohamed A. Elnaggar, Hossam E. Emam, Jun Zhang, Shengli Qi, Yong Liu

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  38. Locally concentrated protons control the proton diffusivity in heavily Sc-doped perovskites

    Acta Materialia · 2026-07-13

    Zihan Zhao, Lulu Jiang, Wang Hay Kan, J J Lu, R L Wang, Maths Karlsson, Donglin Han, Qianli Chen

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  39. Ba7Zn5Ga6O21: Terminal Oxygens Enable High Oxide-Ion and Proton Conductivity in a Condensed Three-Dimensional Tetrahedral Framework

    Inorganic Chemistry · 2026-07-16

    Zien Cheng, Guangxiang Lu, Maxim Avdeev, Ying Wang, Zhengyang Zhou, Rihong Cong, Tao Yang, Pengfei Jiang

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  40. Dual-polymorph abnormal thermal quenching in Yb3+, Er3+ co-doped Ba3YAl2O7.5 phosphor: Defect-assisted and phase-transition-driven mechanisms

    Ceramics International · 2026-07-20

    Ruonan Wang, Sen Yan, Junshan Hu, Hao Fu

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  41. High−entropy perovskite−based S-scheme heterojunction with interfacial Cu0 as electron-transport highway for efficient CO2 conversion

    Journal of Cleaner Production · 2026-08-01

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  42. Sulfonated covalent organic framework-carbon nanotube hybrid interfaces to boost proton transport in Nafion-based fuel cell membranes

    Journal of Power Sources · 2026-08-17

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  43. Decoupling the Roles of B‐Site Cation Defects and Oxygen Vacancies in Exsolved Perovskites for Robust CO 2 Electrolysis in Solid‐State Cells

    Advanced Energy Materials · 2026-08-22

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