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RESEARCH PAPER · Inorganic Chemistry · 2016

Changing Ce3+ Content and Codoping Mn2+ Induced Tunable Emission and Energy Transfer in Ca2.5Sr0.5Al2O6:Ce3+,Mn2+

Mengqiao Li, Jilin Zhang, Jin Han, Zhongxian Qiu, Wenli Zhou, Liping Yu, Zhiqiang Li, Shixun Lian

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Changing Ce3+ Content and Codoping Mn2+ Induced Tunable Emission and Energy Transfer in Ca2.5Sr0.5Al2O6:Ce3+,Mn2+OriginalLuminescence properties and energy transfer of YGa 1.5 Al 1.5 (BO 3 ) 4 :Tb 3+ ,Eu 3+ as a multi-colour emitting phosphor for WLEDs84Near-UV-to-red light conversion through energy transfer in Ca 2 Sr(PO 4 ) 2 :Ce 3+ ,Mn 2+ for plant growth66Luminescence, Energy Transfer and Tunable Color of Ce3+- and Tb3+-Activated Na3Gd(BO3)2 Phosphors9A full-color emitting phosphor Ca9Ce(PO4)7:Mn2+, Tb3+: Efficient energy transfer, stable thermal stability and high quantum efficiency101Ce 3+ -sensitized red Mn 2+ luminescence in calcium aluminoborate phosphor material7Insight into temperature-dependent photoluminescence of LaOBr: Ce3+, Tb3+ phosphor as a ratiometric and colorimetric luminescent thermometer66Luminescence properties of single-phase color-tunable CeZn1−x(B5O10):xMn2+ phosphor2Composition Screening in Blue-Emitting Li4Sr1+xCa0.97–x(SiO4)2:Ce3+ Phosphors for High Quantum Efficiency and Thermally Stable Photoluminescence133Toward Bi3+ Red Luminescence with No Visible Reabsorption through Manageable Energy Interaction and Crystal Defect Modulation in Single Bi3+-Doped ZnWO4 Crystal193Color-Tunable Luminescence Properties of Bi3+ in Ca5(BO3)3F via Changing Site Occupation and Energy Transfer196Photoluminescence of Eu2+, Ce3+ and Tb3+ in a new potassium barium phosphate K2Ba3(P2O7)2 host lattice23Broadband-excited and efficient blue/green/red-emitting Ba2Y5B5O17: Ce3+, Tb3+, Eu3+ phosphors using Tb3+-bridged Ce3+-Eu3+ energy transfer66Luminescence properties of single-phase color-tunable TbZn (B5O10):xMn2+ phosphor4Manipulating the alkali metal charge compensation and tungsten oxide to continuously enhance the red fluorescence in (Li,Na,K)Ca(Mo,W)O 4 :Eu 3+ solid solution compounds9Electronic structure and photoluminescence properties of single component white emitting Sr 3 LuNa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor for WLEDs53Multifunctional luminescent magnetic cryocooler in a Gd 5 Mn 2 pyramidal complex40Color-tunable emission by cation substitution in Ba3−ySryY4O9:Bi3+ and sites occupation preference11Redefinition of Crystal Structure and Bi3+ Yellow Luminescence with Strong Near-Ultraviolet Excitation in La3BWO9:Bi3+ Phosphor for White Light-Emitting Diodes180Tungsten doped manganese dioxide for efficient removal of gaseous formaldehyde at ambient temperatures44Improving Quantum Efficiency and Thermal Stability in Blue-Emitting Ba 2– x Sr x SiO 4 :Ce 3+ Phosphor via Solid Solution244Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15: Ce3+, Tb3+ phosphors20Near UV based LED fabricated with K2Ba3Si8O20:Eu2+ and energy transfer between Ce3+ and Eu2+9Ce3+/Mn2+-activated Ca7(PO4)2(SiO4)2: efficient luminescent materials for multifunctional applications13A ratiometric optical thermometer with high sensitivity and superior signal discriminability based on Na3Sc2P3O12: Eu2+, Mn2+ thermochromic phosphor330Highly Efficient and Thermally Stable Blue-Green (Ba0.8Eu0.2O)(Al2O3)4.575×(1+x) Phosphor through Structural Modification55Ce3+-activated CaSr2Al2O6 green-emitting phosphors: Potential application as color converter for warm WLEDs42Luminescence of Ca3ZrSi2O9: Ce3+ blue phosphor with good thermal stability44A rate equation model for the energy transfer mechanism of a novel multi-color-emissive phosphor, Ca 1.624 Sr 0.376 Si 5 O 3 N 6 :Eu 2+12Crystal structure and photoluminescence tuning of novel single-phase Ca 8 ZnLu(PO 4 ) 7 :Eu 2+ ,Mn 2+ phosphors for near-UV converted white light-emitting diodes61Dopant preferential site occupation and high efficiency white emission in K 2 BaCa(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphors for high quality white LED applications87Full visible light emission in Eu 2+ ,Mn 2+ -doped Ca 9 LiY 0.667 (PO 4 ) 7 phosphors based on multiple crystal lattice substitution and energy transfer for warm white LEDs with high colour-rendering111Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes71Highly efficient and thermal stable La2Si2O7:Ce3+,Tb3+,Eu3+ phosphors: Emission color tuning through terbium bridge36Broadband orange phosphor by energy transfer between Ce3+ and Mn2+ in Ca3Al2Ge3O12 garnet host41Blue emitting phosphor Sr0.8Ca0.2Al2+ySi2-yO8:Ce3+: Substitution of Al-Si, structural modification, luminescence property and application21Achieving high energy transfer efficiency in Sr6Ca4(PO4)6F2:Ce3+, Mn2+ by regulating the occupation of activator12Efficient energy transfer, multi-colour emitting and temperature sensing behavior of single-phase Tb3+, Eu3+ co-doped strontium fluoride phosphors37Partial cation substitution of tunable blue‐cyan‐emitting Ba 2 B 2 O 5 :Ce 3+ for near‐UV white LEDs8High-efficient and thermal-stable Ca19Zn2(PO4)14: Eu2+, Mn2+ blue-red dual-emitting phosphor for plant cultivation LEDs57Synthesis and investigation of orange-emitting Eu2+ doped Ba4Li2B10O20 phosphor4Tunable emission of Sr3Sc(PO4)3: Tb3+, Eu3+ phosphors with efficient energy transfer and high thermal stability27Ionic occupation sites, luminescent spectra, energy transfer behaviors in Y3MgAl3SiO12: Ce3+, Mn2+ phosphors for warm white LED50Tunable lanthanide/transition metal ion‐doped novel phosphors for possible application in w‐LEDs: a review77From blue to cyan emission: Ce 3+ and Tb 3+ co-doped silicon phosphate phosphors with high thermal stability11Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation40Silica nanoparticles assisted preparation of reddish-yellow emitting Eu2+ activated remote-type CaSrSiO4 phosphor for warm white LED applications20High-efficient, spherical and thermal-stable carbon dots@silica fluorescent composite as rare earth-free phosphors for white LED39Tunable photoluminescence and energy transfer of Sr9LiMg(PO4)7: Ce3+/Tb3+/Mn2+ phosphors6Unraveling the Eu2+ → Mn2+ Energy Transfer Mechanism in w-LED Phosphors72Photoluminescence and Color-Tunable Properties of Na4Ca4Mg21(PO4)18:Eu2+,Tb3+/Mn2+ Phosphors for Applications in White LEDs29The photoluminescence, thermal properties and tunable color of bright green-emitting Ba3Sc(BO3)3:Ce3+/Tb3+ phosphors via efficient energy transfer41Achievement of narrow-band blue-emitting phosphors KScSr 1−y Ca y Si 2 O 7 :Bi 3+ by the migration of luminescence centers23Enhanced luminescence properties of Ca 1+x Sr 2−x Al 2 O 6 :Eu 3+ (0 ≤ x ≤ 1) red phosphors based on composition modulation6Research on the quantum confinement effect and enhanced luminescence of red-emitting P 5+ -doped CaAl 12 O 19 :Mn 4+ ,Mg 2+ phosphors17Compared catalytic properties of OMS-2-based nanocomposites for the degradation of organic pollutants31Synthesis and luminescent properties of new green Li2Mg1-xSiO4:xMn2+ phosphors16Tunable blue-red dual emission via energy transfer in Na4CaSi3O9: Ce3+, Mn2+ phosphors for plant growth LED29Enhancing the blue luminescence behaviour of the Na+ co-doped novel LiLaSiO4: ξTm3+ phosphor7Site occupancy and photoluminescence properties of cyan-emitting K2Ca2Si2O7:Bi3+ phosphor for white light emitting diodes44Charge compensating effect of alkali metal ions R+ (R = Li, Na, K) on the luminescence enhancement of CaAl11.9P0.1O19.1:Mn4+ red-emitting phosphor16Tunable photoluminescence and temperature sensing properties of Ce3+, Eu2+ co-doped Ca2-Sr MgSi2O7 phosphors11Luminescence and energy transfer of single-phase white-emitting phosphor Ba 2 Mg(PO 4 ) 2 :Ce 3+ , Eu 2+ for white LEDs9Photoluminescence of β-Ba2ScAlO5: Eu3+ red emitting phosphors effectively activated by UV light13Luminescence investigation of Eu2+/Ce3+/Mn2+ doped Y2Mg2Al2Si2O12 phosphors10Excellent enhancement of thermal stability and quantum efficiency for Na2BaCa(PO4)2:Eu2+ phosphor based on Sr doping into Ca30Temperature-induced phase transition and tunable luminescence properties of Ce3+-Mn2+-Zr4+ tri-doped LaPO4 phosphor12Photoluminescence of Bi3+ in LiCaY5(BO3)6 and color-tunable emission through energy transfer to Eu3+/Tb3+11Defect and energy transfer induced abnormal thermally stable and highly efficient narrow-band green emission19Synthesis and luminescent property of Ce3+-doped NaSrY(BO3)2 efficient blue-emitting phosphor as luminescent thermometer18Color-tunable blue-emitting Na2MgSiO4:Ce3+ phosphors for white light-emitting diodes33High performance of broad excitation and narrow emission green phosphor NaAl 11 O 17 :Eu 2+ , Mn 2+ for backlight displays20Structure and Luminescence Studies of a Ce3+-Activated Ba5La3MgAl3O15 Green-Emitting Phosphor31Single-phase white light emission Ca9NaLu0.667(PO4)7: Eu2+, Mn2+ phosphor for the application of WLED37Strategies for fourfold enhancement of narrowband green AC-driven electroluminescence from zinc gallate co-doped with Ce3+ and Mn2+ ions by field-enhanced energy transfer5Fluorescence properties and thermal stability of Sr2Gd1-xNbO6: xEu3+ with dual-wavelength excitation response5An ab initio modelling for pristine and defect-induced emissions from NaCe(WO4)2: a potential material for solid-state lighting application8Anomalous thermal quenching behavior of novel orange-red SrLa1-xNaTeO6:xSm3+ phosphors for optical temperature sensing8Luminescence center modulation for the synthesis of a narrow-band green phosphor: mechanism and backlighting display application4Tunable emission and thermal sensitivity via energy transfer from Bi 3+ to Eu 3+ in BaY 2 Al 2 Ga 2 GeO 122Charge compensation effect of alkali metal ions on luminescence enhancement and negative thermal quenching of Sr1-xLaNaTeO6:xEu3+ red phosphors18Ba3Lu(BO3)3:Ce3+,Tb3+/Mn2+: Dual-Functional Material for WLEDs and Optical Pressure Sensing35High sensitivity dual-mode ratiometric optical thermometry based on Ce3+/Mn2+ co-doped LiYF4 single crystal9Killing Three Birds with One Stone: Energy Transfer Inducing Efficient, Zero Thermal Quenching, and Emission‐Color Tunable Phosphors21Ultrasonication synthesis of a Mn2+-doped zero-dimensional metal halide: Structure, luminescence property and display application0Improving the luminescence properties of the near-infrared phosphor Ca 0.8 Sr 0.2 O:Eu 2+ via energy transfer and its application in the concentration detection of ethanol solutions3Preparation and enhanced photoluminescence features of white-emitting single-phased Ba3Sc(PO4)3: Dy3+ phosphors for light-emitting diodes though the use of flux1Recent developments in near-infrared phosphors for broad-band light-emitting diodes light sources9Hydrochromism and cross-scale fluorescence lifetime contrast in lead-free double perovskites for programmable spatiotemporal optical encryption0Realization of blue-red dual-emission via energy transfer in Ca9ZnK(PO4)7: Eu2 +, Mn2+ phosphors for plant cultivation and warm white illumination0Novel BaCa13Mg2(SiO4)8: Ce3+, Mn2+ Phosphor for Plant Lighting with Robust Thermal Stability and High Energy Transfer Efficiency0

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  1. Luminescence properties and energy transfer of YGa 1.5 Al 1.5 (BO 3 ) 4 :Tb 3+ ,Eu 3+ as a multi-colour emitting phosphor for WLEDs

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  2. Near-UV-to-red light conversion through energy transfer in Ca 2 Sr(PO 4 ) 2 :Ce 3+ ,Mn 2+ for plant growth

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  3. Luminescence, Energy Transfer and Tunable Color of Ce3+- and Tb3+-Activated Na3Gd(BO3)2 Phosphors

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  4. A full-color emitting phosphor Ca9Ce(PO4)7:Mn2+, Tb3+: Efficient energy transfer, stable thermal stability and high quantum efficiency

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  5. Ce 3+ -sensitized red Mn 2+ luminescence in calcium aluminoborate phosphor material

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  6. Insight into temperature-dependent photoluminescence of LaOBr: Ce3+, Tb3+ phosphor as a ratiometric and colorimetric luminescent thermometer

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  7. Luminescence properties of single-phase color-tunable CeZn1−x(B5O10):xMn2+ phosphor

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  8. Composition Screening in Blue-Emitting Li4Sr1+xCa0.97–x(SiO4)2:Ce3+ Phosphors for High Quantum Efficiency and Thermally Stable Photoluminescence

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  9. Toward Bi3+ Red Luminescence with No Visible Reabsorption through Manageable Energy Interaction and Crystal Defect Modulation in Single Bi3+-Doped ZnWO4 Crystal

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  10. Color-Tunable Luminescence Properties of Bi3+ in Ca5(BO3)3F via Changing Site Occupation and Energy Transfer

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  11. Photoluminescence of Eu2+, Ce3+ and Tb3+ in a new potassium barium phosphate K2Ba3(P2O7)2 host lattice

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  12. Broadband-excited and efficient blue/green/red-emitting Ba2Y5B5O17: Ce3+, Tb3+, Eu3+ phosphors using Tb3+-bridged Ce3+-Eu3+ energy transfer

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  13. Luminescence properties of single-phase color-tunable TbZn (B5O10):xMn2+ phosphor

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  14. Manipulating the alkali metal charge compensation and tungsten oxide to continuously enhance the red fluorescence in (Li,Na,K)Ca(Mo,W)O 4 :Eu 3+ solid solution compounds

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  15. Electronic structure and photoluminescence properties of single component white emitting Sr 3 LuNa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor for WLEDs

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  16. Multifunctional luminescent magnetic cryocooler in a Gd 5 Mn 2 pyramidal complex

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  17. Color-tunable emission by cation substitution in Ba3−ySryY4O9:Bi3+ and sites occupation preference

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  18. Redefinition of Crystal Structure and Bi3+ Yellow Luminescence with Strong Near-Ultraviolet Excitation in La3BWO9:Bi3+ Phosphor for White Light-Emitting Diodes

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  19. Tungsten doped manganese dioxide for efficient removal of gaseous formaldehyde at ambient temperatures

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  20. Improving Quantum Efficiency and Thermal Stability in Blue-Emitting Ba 2– x Sr x SiO 4 :Ce 3+ Phosphor via Solid Solution

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  21. Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15: Ce3+, Tb3+ phosphors

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  22. Near UV based LED fabricated with K2Ba3Si8O20:Eu2+ and energy transfer between Ce3+ and Eu2+

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  23. Ce3+/Mn2+-activated Ca7(PO4)2(SiO4)2: efficient luminescent materials for multifunctional applications

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  25. Highly Efficient and Thermally Stable Blue-Green (Ba0.8Eu0.2O)(Al2O3)4.575×(1+x) Phosphor through Structural Modification

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  26. Ce3+-activated CaSr2Al2O6 green-emitting phosphors: Potential application as color converter for warm WLEDs

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  27. Luminescence of Ca3ZrSi2O9: Ce3+ blue phosphor with good thermal stability

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  30. Dopant preferential site occupation and high efficiency white emission in K 2 BaCa(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphors for high quality white LED applications

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  31. Full visible light emission in Eu 2+ ,Mn 2+ -doped Ca 9 LiY 0.667 (PO 4 ) 7 phosphors based on multiple crystal lattice substitution and energy transfer for warm white LEDs with high colour-rendering

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  32. Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes

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  33. Highly efficient and thermal stable La2Si2O7:Ce3+,Tb3+,Eu3+ phosphors: Emission color tuning through terbium bridge

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  34. Broadband orange phosphor by energy transfer between Ce3+ and Mn2+ in Ca3Al2Ge3O12 garnet host

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  35. Blue emitting phosphor Sr0.8Ca0.2Al2+ySi2-yO8:Ce3+: Substitution of Al-Si, structural modification, luminescence property and application

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  36. Achieving high energy transfer efficiency in Sr6Ca4(PO4)6F2:Ce3+, Mn2+ by regulating the occupation of activator

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  37. Efficient energy transfer, multi-colour emitting and temperature sensing behavior of single-phase Tb3+, Eu3+ co-doped strontium fluoride phosphors

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  39. High-efficient and thermal-stable Ca19Zn2(PO4)14: Eu2+, Mn2+ blue-red dual-emitting phosphor for plant cultivation LEDs

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  41. Tunable emission of Sr3Sc(PO4)3: Tb3+, Eu3+ phosphors with efficient energy transfer and high thermal stability

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  42. Ionic occupation sites, luminescent spectra, energy transfer behaviors in Y3MgAl3SiO12: Ce3+, Mn2+ phosphors for warm white LED

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  43. Tunable lanthanide/transition metal ion‐doped novel phosphors for possible application in w‐LEDs: a review

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  44. From blue to cyan emission: Ce 3+ and Tb 3+ co-doped silicon phosphate phosphors with high thermal stability

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  45. Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation

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    Xujian Zhang, Jilin Zhang, Xiangli Wu, Liping Yu, Yongfu Liu, Xuhui Xu, Shixun Lian

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  46. Silica nanoparticles assisted preparation of reddish-yellow emitting Eu2+ activated remote-type CaSrSiO4 phosphor for warm white LED applications

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  47. High-efficient, spherical and thermal-stable carbon dots@silica fluorescent composite as rare earth-free phosphors for white LED

    Ceramics International · 2020-02-29

    Xinguo Zhang, Zishan Sun, Zhenpng Zhu, Jiabao Luo, Zhan‐Chao Wu, Zhengliang Wang

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  48. Tunable photoluminescence and energy transfer of Sr9LiMg(PO4)7: Ce3+/Tb3+/Mn2+ phosphors

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2020-03-31

    Jiabao Luo, Zishan Sun, Zhenpeng Zhu, Xinguo Zhang, Zhan‐Chao Wu, Fuwang Mo

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  49. Unraveling the Eu2+ → Mn2+ Energy Transfer Mechanism in w-LED Phosphors

    The Journal of Physical Chemistry C · 2020-06-03

    Atul D. Sontakke, Arnoldus J. van Bunningen, Freddy T. Rabouw, Sam Meijers, Andries Meijerink

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  50. Photoluminescence and Color-Tunable Properties of Na4Ca4Mg21(PO4)18:Eu2+,Tb3+/Mn2+ Phosphors for Applications in White LEDs

    Inorganic Chemistry · 2020-09-25

    Dan Zhang, Xiangting Zhang, Zhengce An, Rujia Dong, Zhan Shi, Yanhua Song, Haifeng Zou

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