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RESEARCH PAPER · Topics in Current Chemistry · 2016

Inorganic Phosphor Materials for Lighting

Yuan-Chih Lin, Maths Karlsson, Marco Bettinelli

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Inorganic Phosphor Materials for LightingOriginalPhotoluminescence and charge compensation effects in Lu3MgyAl5−−Si O12:Ce3+ phosphors for white LEDs8White‐Light‐Emitting Carbon Dots Prepared by the Electrochemical Exfoliation of Graphite102Synthesis of cubic yttrium aluminum garnet (YAG) powders by co-precipitation and two-step calcinations5Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects1025Recent progress on synthesis and structural aspects of rare-earth phosphates108Crystal Structure and Nontypical Deep-Red Luminescence of Ca3Mg[Li2Si2N6]:Eu2+50Sr 3 GdLi(PO 4 ) 3 F:Eu 2+ , Mn 2+ : A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs10Zn 2 SiO 4 :Eu 3+ micro-structures: Controlled morphologies and luminescence properties16Color-Tunable Heterodinuclear Pt(II)/B(III) and Pt(II)/Ir(III) Arrays with N^O-julolidine Ligands4Extended broadband luminescence of dodecahedral multisite Ce3+ ions in garnets {Y3}[MgA](BAlSi)O12 (A = Sc, Ga, Al; B = Ga, Al)26Microstructure and optical properties of TiO2nanocrystallites–CaTiO3:Pr3+ hybrid thick films2Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)60Defect states and temperature stability of Eu2+ center in Eu-doped yttrium aluminum garnet13Mechanism for bifurcation of broadband luminescence spectra from Ce 3+ ions at dodecahedral sites in garnets {CaY 2 }[M 2 ](Al 2 Si)O 12 (M = Al, Ga, Sc)26Understanding the Interactions between Vibrational Modes and Excited State Relaxation in Y3–xCexAl5O12: Design Principles for Phosphors Based on 5d–4f Transitions72On the crystal structure and luminescence characteristics of a novel deep red emitting SrLaScO4:Mn4+90Impact of C5+ ion beam on Dy activated Sr2B5O9Cl TL phosphor4Composition dependent spectral shift of Mn4+ luminescence in silicate garnet hosts CaY2M2Al2SiO12 (M = Al, Ga, Sc)43On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors40Role of Ag multimers as broadband sensitizers in Tb3+/Yb3+ co-doped glass-ceramics5Thermal quenching of Mn4+ luminescence in Sn4+-containing garnet hosts10Ag-Sensitized Yb3+ Emission in Glass-Ceramics13Ag nanoaggregates as efficient broadband sensitizers for Tb3+ ions in silica-zirconia ion-exchanged sol-gel glasses and glass-ceramics16Optimization red emission of SrMoO4: Eu3+ via hydro-thermal co-precipitation synthesis using orthogonal experiment18Control of Narrow-Band Emission in Phosphor Materials for Application in Light-Emitting Diodes160Comparison of the Changes in Luminescence Properties Between Cool White and Warm White LEDs at Varying Temperatures13Persistent luminescence instead of phosphorescence: History, mechanism, and perspective680Photoluminescence Properties of Layered Perovskite-Type Strontium Scandium Oxyfluoride Activated With Mn4+21Highly Efficient and Thermally Stable Blue-Green (Ba0.8Eu0.2O)(Al2O3)4.575×(1+x) Phosphor through Structural Modification55Concentration dependence of energy transfer Ce3+→Er3+ in YAG host6Structural and photoluminescence properties of UV-excited Er3+ doped Ba2CaWO6 yellowish-green phosphors38Blue-Light-Emitting Photostable Hybrid Films for High-Efficiency Large-Area Light Converter and Photonic Applications16(INVITED) Review of luminescent properties of Ce3+-doped garnet phosphors: New insight into the effect of crystal and electronic structure125Highly efficient platinum-based emitters for warm white light emitting diodes17RE 2 [B 2 (SO 4 ) 6 ] ( RE = Y, La–Nd, Sm, Eu, Tb–Lu): a silicate-analogous host structure with weak coordination behaviour45Enhanced optical properties of YAG:Ce yellow phosphor by modification with gold nanoparticles22Aggregation induced emission small molecules for blue light-emitting electrochemical cells29Broadband orange phosphor by energy transfer between Ce3+ and Mn2+ in Ca3Al2Ge3O12 garnet host41Preparation, structural and spectroscopical properties of silver terbium diphosphate AgTbP2O73Synthesis, spectroscopic properties and applications of divalent lanthanides apart from Eu2+108Single-Component Color-Tunable Gd(pic)3: Eu3+ Phosphor Based on a Metal–Organic Framework for Near-UV White-Light-Emitting Diodes20Investigation of sintering temperature and Ce3+ concentration in YAG:Ce phosphor powder prepared by microwave combustion for white-light-emitting diode luminance applications28Blue and green emission bands in the enantiopure (S)-(-)-1-[(1-phenyl)-N-(biphen-2-yl)methylidene]ethylamine: Morphological, structural and optical properties6Fast and simultaneous doping of Sr0.9−−−Ca0.1In2O4:(xEu3+, yTm3+, zTb3+) superstructure by ultrasonic spray pyrolysis10Unraveling the Mechanisms of Thermal Quenching of Luminescence in Ce3+-Doped Garnet Phosphors238Spectral Properties and Thermal Quenching of Mn4+ Luminescence in Silicate Garnet Hosts CaY2MgMAlSi2O12 (M = Al, Ga, Sc)1Cation vacancy repair towards a new yellow Ca7Sr3Na(PO4)7:Eu2+ phosphor15Phosphors-Based Photocatalysts for Wastewater Treatment3Non-stoichiometric Ce-doped LiAl5O8 phosphors: Synthesis, structural and optical properties18Influence of cerium content and heat treatment on Ce:YAG@glass wool nanostructures6Nanophosphors-Based White Light Sources32YAGG:Ce transparent ceramics with high luminous efficiency for solid-state lighting application87Weak thermal quenching of the luminescence in Y2.94-xLuxAl4GaO12: 0.06Ce3+ green phosphor for white light-emitting diodes9Doping of ZnO inorganic-organic nanohybrids with metal elements22Exploring Main Group Metal Borosulfates: Similarities and Differences of Two New Borosulfates M[B2O(SO4)3] (M = Sr, Pb)21Time- and temperature-resolved luminescence spectroscopy of LiAl4O6F:Mn red phosphors3Implementation of phosphor sedimentation to reduce thermal instability issue affecting white LED luminescence4Development and application of simultaneous 2D flow velocity and gas temperature measurements using thermographic phosphors under engine-relevant conditions0Ab Initio Calculations of the Electronic Structure of Red-Emitting Mn 4+ -Doped Fluorides9High quality, highly transparent Cu incorporated WO3 thin films suitable for blue LED application18Eu(O2C‐C≡C‐CO2): An EuII Containing Anhydrous Coordination Polymer with High Stability and Negative Thermal Expansion7Super stable (Ba,Sr)LuAl 2 Si 2 O 2 N 5 :Ce 3+ ,Eu 2+ phosphors30Unraveling the impact of different thermal quenching routes on the luminescence efficiency of the Y 3 Al 5 O 12 :Ce 3+ phosphor for white light emitting diodes76Dy3+ Activated Nearly White Emitting NaCdPO4 as Potential Phosphors for Solid State Light Applications10Luminescence and up-conversion properties in La2Ti2O7:Eu3+,Er3+ oxides under UV and NIR radiations towards a two-color sensor28Long-living and highly efficient bio-hybrid light-emitting diodes with zero-thermal-quenching biophosphors37Effect of microwave time on the structural and luminescence properties of YAG:Ce prepared by microwave solution combustion (MSC) synthesis10Novel color tunable garnet phosphor of Tb3+ and Eu3+ co-doped Ca2YZr2Al3O12 with high thermal stability via energy transfer73Strategies for Designing Antithermal‐Quenching Red Phosphors216A novel green-emitting Ni2+-doped Ca-Li hydroxyapatite nanopowders: structural, optical, and photoluminescence properties13Underestimated Color Centers: Defects as Useful Reducing Agents in Lanthanide‐Activated Luminescent Materials30Unterschätzte Farbzentren: Defekte als nützliche Reduktionsmittel in Lanthanid‐dotierten lumineszenten Materialien1Ag-Sensitized NIR-Emitting Yb3+-Doped Glass-Ceramics14UV emitting Gd incorporated LiBaB9O15 phosphors: An ESR and photoluminescence investigation2Promising green Sr5B3O9F: Ce3+/ Tb3+/Na+ phosphors for NUV-executable LED applications29Synthesis condition effects on the emission enhancement of YBO3 powder11The effect of the polymeric matrix on the emission properties of YAG-based phosphors17Fabrication, structural and spectroscopic studies of wide bandgap semiconducting nanoparticles of ZnO for application as white light emitting diodes0Epitaxial strain engineering of luminescent properties in ZnGa2O4:Mn thin films2Improving thermal stability of novel single-component white-light emitting phosphor Ca8MgLu(PO4)7:Tm3+, Dy3+ by back-energy-transfer43Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles12Investigation on structural and optical properties of CuO doped CdS-Zn3(PO4)2 nanocomposite for optoelectronic devices9Highly Robust Oxynitride Phosphor against Thermal Oxidization and Hydrolysis36Luminescence enhancement and site-dependent energy transfer of Ba5(B2O5)2F2: Ce3+/Tb3+/Na+ phosphors3Luminescence Properties of Spinels Doped with Manganese Ions15Lanthanide Luminescence in Visible-Light-Promoted Photochemical Reactions18Glass-ceramic phosphors for solid state lighting: A review117Greenish-yellow emitting Ca9MgLi(PO4)7:Dy3+ phosphors – Photoluminescence and thermal stability30Luminescence properties of high thermal stability Sr2ScTaO6:Ln3+ (Ln3+ = Sm3+/Dy3+) phosphors with novel double perovskite structures12Study of Photoluminescence,Thermoluminescence, and Afterglow properties of Dy3+ doped Ba2ZnSi2O7 phosphor47Nanocristaux de grenat pour l'éclairage blanc par LED et pour la nanothermométrie0YAG:Ce3+ Phosphor: From Micron-Sized Workhorse for General Lighting to a Bright Future on the Nanoscale182Thermally stable laser-driven phosphor converted white light source using multilayer structured diffuser system7Rapid synthesis of Ce3+:YAG via CO2 laser irradiation combustion method: Influence of Ce doping and thickness of phosphor ceramic on the performance of a white LED device18Development of dumbbell-shaped La2Si2O7:Eu3+ nanocrystalline phosphors for solid-state lighting applications15The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs14Novel Nitride Phosphors0Luminescence Quenching via Deep Defect States: A Recombination Pathway via Oxygen Vacancies in Ce-Doped YAG91Discovery of a new phosphor via aliovalent cation substitution: DFT predictions, phase transition and luminescence properties for lighting and anti-counterfeiting applications22High partial thermal conductivity of luminescence sites: a crucial factor for reducing the heat-induced lowering of the luminescence efficiency8Large area coverage and controlled photoluminescence from vertically aligned ZnO nanorods on Cu substrates0Improving the thermal stability and luminescent efficiency of (Ba,Sr)3SiO5:Eu2+ phosphors by structure, bandgap engineering and soft chemistry synthesis method98Luminescent behavior of Tb3+ transitions in green Ba6Ca3Al2Si6O24:Ce3+/ Tb3+/Na+ phosphors4New lanthanide‐free self‐activated full‐color emission phosphor in Y3+ doped Sr3Bi(VO4)3 system for white light emitting diode applications5SYNTHESIS AND CRYSTAL STRUCTURE OF LiTb6O5(BO3)32Emission mechanism in single and co-doped Tb:Eu:CaZnOS15NIR light guided enhanced photoluminescence and temperature sensing in Ho3+/Yb3+/Bi3+ co-doped ZnGa2O4 phosphor88Solid solution of novel LixByGdEu (WO4)2 (B=Na, K) red phosphors: Influence of Na/K substitution on microstructures, Judd-Ofelt and luminescence properties for WLED applications21Quantitative assessing of crystal field, nephelauxetic, and Stokes shift effects on the blue luminescence of Eu2+ ions incorporated in ZnS films7Preparation and characterization of Gd3(ScAl)2Al3O12:Ce3+ garnet phosphors towards high-color-rendering white-light illumination15Monitoring the health of laser-driven phosphor-converted white light source using spectral interference technique3Rare earth (RE) doped phosphors and their emerging applications: A review632The deep red Ca2YZr2Al3O12:Mn4+ phosphor and enhanced emission by Bi3+ doping27Enhanced photoluminescence and energy transfer behavior in Ba3Lu4O9:Bi3+,Eu3+ for flexible lighting applications11Ga-modified YAG:Pr3+ dual-mode tunable luminescence thermometers66Composite Color Converters Based on Tb3Al5O12:Ce Single‐Crystalline Films and Y3Al5O12:Ce Crystal Substrates10Solid‐State Lighting5Structure–Property Relationships in Photoluminescent Bismuth Halide Organic Hybrid Materials20(NH4)2AgX3 (X = Br, I): 1D Silver Halides with Broadband White Light Emission and Improved Stability26New efficient lighting device. Part 1. hybrid materials based on inorganic aerogel and metal-organic phosphor5Synthesis and photoluminescence properties of novel LaGa0.5Sb1.5O6: Eu3+, Dy3+, Tb3+ and BiGeSbO6: Eu3+, Dy3+, Tb3+ phosphors12AlN–Ce-doped yttrium aluminum garnet composite ceramic phosphor for high-power laser lighting38Red emitting Eu 3+ induced SrWO 4 materials: synthesis, structural, morphological and photoluminescence analysis19New efficient OSL detectors based on the crystals of Ce3+ doped Gd3Al5−xGaxO12 mixed garnet10Optical and EPR Spectroscopy of Manganese Ions in Fluorozirconate Glasses4Effects of Halogen Substitution on the Optoelectronic Properties of Two-Dimensional All-Inorganic Double Perovskite Cs4AgBiX8 ( X=Cl,Br,I ) with Ruddlesden-Popper Structure18Spectroscopic investigation on luminescence, ab initio and electrical properties of Li2Cu(WO4)21A novel Mn 4+ -activated fluoride red phosphor Cs 30 (Nb 2 O 2 F 9 ) 9 (OH) 3 ·H 2 O:Mn 4+ with good waterproof stability for WLEDs34Barium molybdate white emitting phosphor synthesized at room temperature by co-precipitation16Enhancement of emission and luminescent thermal stability of K 2 SiF 6 : Mn 4+ by synergy of co-doping with Na + and coating with GQDs3Introduction to phosphors and luminescence6Physics of inorganic upconverting nanophosphors and their relevance in applications3Revealing Eu 3+ -doped yttrium pyrogermanate as a soft UV excitable phosphor: retaining the pros of the commercial phosphor and compensating for the cons13Stabilized photoemission from organic molecules in zero-dimensional hybrid Zn and Cd halides25Surface-enhanced luminescence of Cr 3+ -doped ZnAl 2 O 4 and MgAl 2 O 4 using Ag@SiO 2 and Au@SiO 2 core–shell nanoparticles1Synthesis and optical properties of Gd 4 Al 2 O 9 :Eu 3+ , a red emitting phosphor with a strong negative thermal quenching effect8Synthesis of Phosphorus-Based Phosphors2Designing Artificial Fluorescent Proteins: Squaraine‐LmrR Biophosphors for High Performance Deep‐Red Biohybrid Light‐Emitting Diodes13Remote phosphor-based extended white light source pumped by single blue LED for efficient lighting0Long Persistent Luminescent HDPE Composites with Strontium Aluminate and Their Phosphorescence, Thermal, Mechanical, and Rheological Characteristics10Investigations on the effect of NH 4 Cl flux on the structural and optical properties of CdSiO 3 :Eu 3+ nanophosphor1Structural and temperature-tuned band gap energy characteristics of PbMoO4 single crystals12New fluorescent organic-inorganic nanohybrid materials for optoelectronic applications0Homogeneous distribution of phosphor particles inside resin using a vertical vibration method for efficient laser-based white light illumination5Green luminescent Sr3Gd(PO4)3: Tb3+ phosphors for lighting applications20Highly Efficient and Thermally Stable Ba0.75Al11O17.25: Eu2+, Mn2+ Phosphor with Dual Narrowband Blue and Green Emissions: A Promising Candidate for Wide Gamut Displays8Single-Phase Silicate Phosphors (Ba1.3Ca0.7−xSiO4:xDy3+) Doped with Dysprosium for White Solid-State Lighting6Luminescence of Fluorozirconate Glasses Containing Cerium and Manganese Ions1Structural and optical properties of a new Milarite type Na3Mg4LiSi12O30:Eu3+ phosphor7Hierarchical self-assembly of an excitation-wavelength-dependent emissive fluorophore and cucurbiturils for secondary encryption70

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  1. Photoluminescence and charge compensation effects in Lu3MgyAl5−−Si O12:Ce3+ phosphors for white LEDs

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  2. White‐Light‐Emitting Carbon Dots Prepared by the Electrochemical Exfoliation of Graphite

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  3. Synthesis of cubic yttrium aluminum garnet (YAG) powders by co-precipitation and two-step calcinations

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  4. Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects

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  5. Recent progress on synthesis and structural aspects of rare-earth phosphates

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  6. Crystal Structure and Nontypical Deep-Red Luminescence of Ca3Mg[Li2Si2N6]:Eu2+

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  7. Sr 3 GdLi(PO 4 ) 3 F:Eu 2+ , Mn 2+ : A tunable blue-white color emitting phosphor via energy transfer for near-UV white LEDs

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  9. Color-Tunable Heterodinuclear Pt(II)/B(III) and Pt(II)/Ir(III) Arrays with N^O-julolidine Ligands

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  10. Extended broadband luminescence of dodecahedral multisite Ce3+ ions in garnets {Y3}[MgA](BAlSi)O12 (A = Sc, Ga, Al; B = Ga, Al)

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  11. Microstructure and optical properties of TiO2nanocrystallites–CaTiO3:Pr3+ hybrid thick films

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  12. Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

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  13. Defect states and temperature stability of Eu2+ center in Eu-doped yttrium aluminum garnet

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  14. Mechanism for bifurcation of broadband luminescence spectra from Ce 3+ ions at dodecahedral sites in garnets {CaY 2 }[M 2 ](Al 2 Si)O 12 (M = Al, Ga, Sc)

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  15. Understanding the Interactions between Vibrational Modes and Excited State Relaxation in Y3–xCexAl5O12: Design Principles for Phosphors Based on 5d–4f Transitions

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  16. On the crystal structure and luminescence characteristics of a novel deep red emitting SrLaScO4:Mn4+

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  17. Impact of C5+ ion beam on Dy activated Sr2B5O9Cl TL phosphor

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  18. Composition dependent spectral shift of Mn4+ luminescence in silicate garnet hosts CaY2M2Al2SiO12 (M = Al, Ga, Sc)

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  19. On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors

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  20. Role of Ag multimers as broadband sensitizers in Tb3+/Yb3+ co-doped glass-ceramics

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  21. Thermal quenching of Mn4+ luminescence in Sn4+-containing garnet hosts

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  23. Ag nanoaggregates as efficient broadband sensitizers for Tb3+ ions in silica-zirconia ion-exchanged sol-gel glasses and glass-ceramics

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  24. Optimization red emission of SrMoO4: Eu3+ via hydro-thermal co-precipitation synthesis using orthogonal experiment

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  27. Persistent luminescence instead of phosphorescence: History, mechanism, and perspective

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  28. Photoluminescence Properties of Layered Perovskite-Type Strontium Scandium Oxyfluoride Activated With Mn4+

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  29. Highly Efficient and Thermally Stable Blue-Green (Ba0.8Eu0.2O)(Al2O3)4.575×(1+x) Phosphor through Structural Modification

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  30. Concentration dependence of energy transfer Ce3+→Er3+ in YAG host

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  31. Structural and photoluminescence properties of UV-excited Er3+ doped Ba2CaWO6 yellowish-green phosphors

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  32. Blue-Light-Emitting Photostable Hybrid Films for High-Efficiency Large-Area Light Converter and Photonic Applications

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  33. (INVITED) Review of luminescent properties of Ce3+-doped garnet phosphors: New insight into the effect of crystal and electronic structure

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  34. Highly efficient platinum-based emitters for warm white light emitting diodes

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  35. RE 2 [B 2 (SO 4 ) 6 ] ( RE = Y, La–Nd, Sm, Eu, Tb–Lu): a silicate-analogous host structure with weak coordination behaviour

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  36. Enhanced optical properties of YAG:Ce yellow phosphor by modification with gold nanoparticles

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  37. Aggregation induced emission small molecules for blue light-emitting electrochemical cells

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  38. Broadband orange phosphor by energy transfer between Ce3+ and Mn2+ in Ca3Al2Ge3O12 garnet host

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  39. Preparation, structural and spectroscopical properties of silver terbium diphosphate AgTbP2O7

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  40. Synthesis, spectroscopic properties and applications of divalent lanthanides apart from Eu2+

    Journal of Luminescence · 2019-02-15

    Markus Suta, Claudia Wickleder

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  41. Single-Component Color-Tunable Gd(pic)3: Eu3+ Phosphor Based on a Metal–Organic Framework for Near-UV White-Light-Emitting Diodes

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  42. Investigation of sintering temperature and Ce3+ concentration in YAG:Ce phosphor powder prepared by microwave combustion for white-light-emitting diode luminance applications

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  43. Blue and green emission bands in the enantiopure (S)-(-)-1-[(1-phenyl)-N-(biphen-2-yl)methylidene]ethylamine: Morphological, structural and optical properties

    Optik · 2019-03-27

    J. Ramírez-Márquez, O. Portillo Moreno, R. Palomino‐Merino, E. Rubio, M.A. Mora-Ramírez, Guadalupe Hernández-Téllez, G.E. Moreno, René Gutiérrez‐Pérez

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  44. Fast and simultaneous doping of Sr0.9−−−Ca0.1In2O4:(xEu3+, yTm3+, zTb3+) superstructure by ultrasonic spray pyrolysis

    Ultrasonics Sonochemistry · 2019-03-28

    A.A.G. Santiago, Laura X. Lovisa, P.N. Medeiros, M.S. Li, Neftalı́ Lenin Villarreal Carreño, E. Longo, C. A. Paskocimas, Mauricio R. D. Bomio, F.V. Motta

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  45. Unraveling the Mechanisms of Thermal Quenching of Luminescence in Ce3+-Doped Garnet Phosphors

    Chemistry of Materials · 2019-04-02

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  46. Spectral Properties and Thermal Quenching of Mn4+ Luminescence in Silicate Garnet Hosts CaY2MgMAlSi2O12 (M = Al, Ga, Sc)

    Physics of the Solid State · 2019-05-01

    M. Kirm, Marek Oja, Jelena Kozlova, Hugo Mändar, S. Vielhauer, Thomas H. Jansen, Thomas Jüstel, Nicholas M. Khaidukov, Vladimir N. Makhov

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  47. Cation vacancy repair towards a new yellow Ca7Sr3Na(PO4)7:Eu2+ phosphor

    Ceramics International · 2019-05-27

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  48. Phosphors-Based Photocatalysts for Wastewater Treatment

    Environmental chemistry for a sustainable world · 2019-06-07

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  49. Non-stoichiometric Ce-doped LiAl5O8 phosphors: Synthesis, structural and optical properties

    Ceramics International · 2019-06-18

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  50. Influence of cerium content and heat treatment on Ce:YAG@glass wool nanostructures

    Journal of Nanoparticle Research · 2019-07-01

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