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RESEARCH PAPER · Journal of the American Chemical Society · 2014

Room-Temperature Polar Ferromagnet ScFeO 3 Transformed from a High-Pressure Orthorhombic Perovskite Phase

Takahiro Kawamoto, Koji Fujita, Ikuya Yamada, Tomohiko Matoba, Sung Joo Kim, Peng Dong Gao, Xiaoqing Q. Pan, Scott D. Findlay, Cédric Tassel, Hiroshi Kageyama, Andrew J. Studer, James Hester, Tetsuo Irifune, Hirofumi Akamatsu, Katsuhisa Tanaka

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Room-Temperature Polar Ferromagnet ScFeO 3 Transformed from a High-Pressure Orthorhombic Perovskite PhaseOriginalSynthesis, structures and magnetic properties of the dimorphic Mn 2 CrSbO 6 oxide48ChemInform Abstract: Room‐Temperature Polar Ferromagnet ScFeO3 Transformed from a High‐Pressure Orthorhombic Perovskite Phase.1Exploring pure and RE co-doped (Eu3+, Tb3+ and Dy3+) gadolinium scandate: Luminescence behaviour and dynamics of energy transfer69A new LiNbO3-type polar oxide with closed-shell cations: ZnPbO320Synthesis, Direct Formation under High Pressure, Structure, and Electronic Properties of LiNbO3-type Oxide PbZnO335First-principles study of magnetoelectric effects and ferroelectricity in complex oxides1Comparative studies on the room-temperature ferrielectric and ferrimagnetic Ni3TeO6-type A2FeMoO6 compounds (A = Sc, Lu)14LiNbO3-Type Oxide (Tl1–xScx)ScO3: High-Pressure Synthesis, Crystal Structure, and Electronic Properties6Hexagonal phase stabilization and magnetic orders of multiferroic L u 1 − x S c x Fe O 370Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO1057Ferroelectricity in corundum derivatives60High-Pressure Single-Crystal Structures of 3D Lead-Halide Hybrid Perovskites and Pressure Effects on their Electronic and Optical Properties448Crystal Isomers of ScFeO333LiNbO3-Type InFeO3: Room-Temperature Polar Magnet without Second-Order Jahn–Teller Active Ions51Magnetoelectric coupling in the type-I multiferroic ScFeO323ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure28First-principles study on the dielectric and transport properties of the LiNbO3-type CdPbO30Room Temperature Magnetically Ordered Polar Corundum GaFeO 3 Displaying Magnetoelectric Coupling46Synthesis, Structural, Electrical and Thermal Properties of ScFeO3 Ceramic14Electronic structure and phase transition in polar ScFeO3 from first principles calculations17Polar Magnets in Double Corundum Oxides60High‐Pressure Perovskite: Synthesis, Structure, and Phase Relation5Electronic and magnetic properties of multiferroic ScFeO 3 available from diffraction experiments9Perovskite-Type InCoO3 with Low-Spin Co3+: Effect of In–O Covalency on Structural Stabilization in Comparison with Rare-Earth Series17Epitaxial thin film growth of garnet-, GdFeO3-, and YMnO3-type LuFeO3 using pulsed laser deposition6Magnetic field controlled electronic state and electric field controlled magnetic state in α-Fe1.6Ga0.4O3 oxide2Structural, Magnetic, and XPS Studies of the Double-Perovskite Mn2VSbO66Synthesis, Crystal Structure, and Optical Properties of Layered Perovskite Scandium Oxychlorides: Sr2ScO3Cl, Sr3Sc2O5Cl2, and Ba3Sc2O5Cl212Cooperative Couplings between Octahedral Rotations and Ferroelectricity in Perovskites and Related Materials63Ba3Fe1.56Ir1.44O9: A Polar Semiconducting Triple Perovskite with Near Room Temperature Magnetic Ordering11Asymmetric covalence bonding between In 5s and O 2p states in ferroelectric InFeO39Modélisation des propriétés magnétiques et multiferroïques d'oxydes de cuivre0High-Pressure Synthesis, Crystal Structure, Chemical Bonding, and Ferroelectricity of LiNbO3-Type LiSbO329Comparative study of magnetic and electronic properties of room‐temperature polar magnets ScFeO3 and InFeO33Predicted polymorph manipulation in an exotic double perovskite oxide13Reversible Structural Transformation between Polar Polymorphs of Li2GeTeO617High-Pressure Synthesis of Non-Stoichiometric LixWO3 (0.5 ≤ x ≤ 1.0) with LiNbO3 Structure13Polar–Nonpolar Phase Transition Accompanied by Negative Thermal Expansion in Perovskite-Type Bi1–xPbxNiO329First-principles screening of ABO3 oxides with two magnetic sublattices3Theoretical study of stability and optical absorption properties of ferroelectric materials ZnXO3 (X=Ge, Sn and Pb)2Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure9Switchable third ScFeO 3 polar ferromagnet with YMnO 3 -type structure19Above-Room-Temperature LiNbO3-Type Polar Magnet Stabilized by Chemical and Physical Pressure10Universal A-Cation Splitting in LiNbO3-Type Structure Driven by Intrapositional Multivalent Coupling11Pressure Effects on Optoelectronic Properties of CsPbBr3 Nanocrystals32Perovskite-Type CuNbO3 Exhibiting Unusual Noncollinear Ferrielectric to Collinear Ferroelectric Dipole Order Transition14Perspective on the pressure-driven evolution of the lattice and electronic structure in perovskite and double perovskite13Structural and magnetic properties of multiferroic hexagonal Lu0.5(Sc1-In )0.5FeO3 ceramics13Discovery of Rhombohedral NaIrO3 Polymorph by In Situ High-Pressure Synthesis of High-Oxidation-State Materials Using Laser Heating in Diamond Anvil Cells2Scandium immobilization by goethite: Surface adsorption versus structural incorporation39Data-driven computational prediction and experimental realization of exotic perovskite-related polar magnets25Pressure-Induced High-κ Dielectric Properties and Multiple Phase Transitions between Novel Nonperovskite and Perovskite Phases in LiSbO3: A First-Principles Study5Complex magnetism in Ni 3 TeO 6 -type Co 3 TeO 6 and high-pressure polymorphs of Mn 3−x Co x TeO 6 solid solutions12Study of the Photoluminescence Characteristics of 4,4′-((1E,1′E)-Quinoxaline-2,3-diylbis(ethene-2,1-diyl))bis(N,N-dimethylaniline)4First-principles investigation of the elastic, photocatalytic and ferroelectric properties of LiNbO3-type LiSbO3 under high pressure3Magnetic structure and multiferroicity of Sc-substituted hexagonal Yb Fe O 323Alkali-Rich Antiperovskite M3FCh (M = Li, Na; Ch = S, Se, Te): The Role of Anions in Phase Stability and Ionic Transport40High pressure structural evolution of cubic solid solution YbInO34Critical Role of Sc Substitution in Modulating Ferroelectricity in Multiferroic LuFeO319Electronic and optical properties of multifunctional R3c AFeO3 (A = Sc or In) compounds: Insights into their potential for photovoltaic applications8Stromataxic Stabilization of a Metastable Layered ScFeO3 Polymorph11Chemical design of a new displacive-type ferroelectric20Designing new polar materials1Exploration en couches minces de nouveaux oxydes multi-ferroïques à base de titanates de nickel NiTiO30Convert Widespread Paraelectric Perovskite to Ferroelectrics13Fe3–xInSnxO6 (x = 0, 0.25, or 0.5): A Family of Corundum Derivatives with Sn-Induced Polarization and Above Room Temperature Antiferromagnetic Ordering5Topochemical Synthesis of LiCoF3 with a High-Temperature LiNbO3-Type Structure1Suppression of Pressure-Induced Phase Transitions in a Monoclinically Distorted LiNbO3-Type CuNbO3 by Preference for a CuO3 Triangular Coordination Environment2Solution combustion synthesis of iron-deficient Sc2-xFexO3 (x = 0.17-0.47) nanocrystals with bixbyite structure: The effect of spatial constraints10Controllable synthesis of ScFeO3 ceramics with microstructural evolution for thin and broadband high-performance microwave absorption24Synergistic effect of tuning nanocomposite morphology, composition and layer arrangement for boosting microwave dissipation performance9Two-step combustion synthesis of single-phase mesoporous ScFeO3 with bixbyite structure and magnetically soft behavior5High pressure studies of transition metal oxides5High pressure chemistry1ScFeO3 (Synthesized Under Pressure)0Structural, magnetic and electrical properties of Y1-xScxFeO3 (x= 0, 0.5 & 1) nanoparticles synthesized by the sol-gel method5Growth, microstructure and magnetic properties of bixbyite structure ScFeO3: A comparative study between bulk and thin film0Atomic Substitution to Tune ScO6 Distortion in Ba2MSc2(BO3)4 (M = Na, K, Ba) to Acquire a Large Birefringence15Influence of Synthetic Conditions on the Crystal Structure, Optical and Magnetic Properties of o-EuFeO3 Nanoparticles15Exploring complex magnetic behavior induced by Mn in LaNiO3 perovskite9Temperature-driven magnetic and structural transitions in multiferroic Lu(1-)Sc FeO38Structural, Optical, and Magnetic Properties of o ‐TbFeO 3 Nanomaterials Synthesized by the co‐Precipitation Method5Development and investigation of transition metal oxides having controllable ferroic properties0Near room temperature hexagonal multiferroic (Yb0.25Lu0.25In0.25Sc0.25)FeO3 high-entropy ceramics12Exploring ferroelectric and photovoltaic attributes of Pna21-LaWN3: A first-principles approach9Exploring the ferroelectric photocatalytic potential of R3c-structured InVO3: A computational study2Zipper‐Like Dynamic Switching of Coordination Bonds Gives a Polar Bimetallic Halide Toward Self‐Driven X‐Ray Detection14Zipper‐Like Dynamic Switching of Coordination Bonds Gives a Polar Bimetallic Halide Toward Self‐Driven X‐Ray Detection3A computational and Raman spectroscopic study of successive phase transitions in Co 3 TeO 6 under high pressure and high temperature1Role of lattice structure and breaking of antiferromagnetic spin order in enhancement of ferromagnetic, electronic, and magneto-electric properties in Fe2-xScxO3 system0Unraveling metastable perovskite oxides insights from structural engineering to synthesis paradigms17Epitaxial Stress-Stabilized Rhombohedral Ferroelectric and Dual-Phase Structure Induced Large Photovoltaic Effect in YFeO3 Films0Heuristic Engineering of Magnetic Mn4Ta2O9 Phases from High-Pressure and High-Temperature Synthesis1Flexible perovskite Sr-doped cobaltite thin film for enhanced visible light detection0Flexible perovskite Sr-doped cobaltite thin film for enhanced visible light detection0Role of lattice structure and breaking of antiferromagnetic spin order in enhancement of ferromagnetic, electronic, and magneto-electric properties in Fe2-xScxO3 system2Stabilization of high-pressure metastable states by chemical approaches0Rational synthesis of a new Haldane chain compound by predicted pressure-induced phase modification0First-principles calculations of the effect of doping on the ZnGeO 3 of LiNbO 3 -type ferroelectrics0Flexible perovskite Sr-doped cobaltite thin film for enhanced visible light detection0Chemical bond engineering and modifying electronic and magneto-electronic properties in Ga-doped α-Fe2O3 system0Coexistence of Altermagnetism and Ferroelectricity in Rhombohedral GaFeO3: A Promising Multiferroic Platform for Spintronics0Antisite-disorder-tailored anisotropic negative thermal expansion and synergistic multifunction in Mn2CuReO60

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  1. Synthesis, structures and magnetic properties of the dimorphic Mn 2 CrSbO 6 oxide

    Dalton Transactions · 2015-01-01

    Antonio J. Dos santos‐García, Elena Solana‐Madruga, C. Ritter, David Ávila‐Brande, Óscar Fabelo, R. Sáez-Puche

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  2. ChemInform Abstract: Room‐Temperature Polar Ferromagnet ScFeO3 Transformed from a High‐Pressure Orthorhombic Perovskite Phase.

    ChemInform · 2015-02-24

    Koji Fujita, et al. et al.

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  3. Exploring pure and RE co-doped (Eu3+, Tb3+ and Dy3+) gadolinium scandate: Luminescence behaviour and dynamics of energy transfer

    Chemical Engineering Journal · 2015-07-17

    Santosh K. Gupta, V. Grover, Rakesh Shukla, Srinivasu Kancharlapalli, V. Natarajan, A. K. Tyagi

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  4. A new LiNbO3-type polar oxide with closed-shell cations: ZnPbO3

    Journal of Applied Physics · 2015-09-04

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  5. Synthesis, Direct Formation under High Pressure, Structure, and Electronic Properties of LiNbO3-type Oxide PbZnO3

    Inorganic Chemistry · 2015-11-17

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  6. First-principles study of magnetoelectric effects and ferroelectricity in complex oxides

    PhDT · 2016-01-01

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  7. Comparative studies on the room-temperature ferrielectric and ferrimagnetic Ni3TeO6-type A2FeMoO6 compounds (A = Sc, Lu)

    Scientific Reports · 2016-02-01

    Guang Song, Weiyi Zhang

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  8. LiNbO3-Type Oxide (Tl1–xScx)ScO3: High-Pressure Synthesis, Crystal Structure, and Electronic Properties

    Inorganic Chemistry · 2016-02-03

    Alexei А. Belik, Wei Yi, Yu Kumagai, Yoshio Katsuya, Masahiko Tanaka, Fumiyasu Oba

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  9. Hexagonal phase stabilization and magnetic orders of multiferroic L u 1 − x S c x Fe O 3

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  10. Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO10

    Chemistry of Materials · 2016-03-23

    Hyung Gu Kim, T. Thao Tran, Woongjin Choi, Tae‐Soo You, P. Shiv Halasyamani, Kang Min Ok

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  11. Ferroelectricity in corundum derivatives

    Physical review. B./Physical review. B · 2016-04-04

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  12. High-Pressure Single-Crystal Structures of 3D Lead-Halide Hybrid Perovskites and Pressure Effects on their Electronic and Optical Properties

    ACS Central Science · 2016-04-06

    Adam Jaffe, Yu Pin Lin, Christine M. Beavers, Johannes Voss, Wendy L. Mao, Hemamala I. Karunadasa

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  13. Crystal Isomers of ScFeO3

    Crystal Growth & Design · 2016-07-29

    Yosuke Hamasaki, Takao Shimizu, Shintaro Yasui, Tomoyasu Taniyama, Osami Sakata, Mitsuru Itoh

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  14. LiNbO3-Type InFeO3: Room-Temperature Polar Magnet without Second-Order Jahn–Teller Active Ions

    Chemistry of Materials · 2016-08-25

    Koji Fujita, Takahiro Kawamoto, Ikuya Yamada, Olivier Hernandez, Naoaki Hayashi, Hirofumi Akamatsu, William Lafargue‐Dit‐Hauret, Xavier Rocquefelte, Masafumi Fukuzumi, Pascal Manuel, Andrew J. Studer, Christopher S. Knee, Katsuhisa Tanaka

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  15. Magnetoelectric coupling in the type-I multiferroic ScFeO3

    Physical review. B./Physical review. B · 2016-11-09

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  16. ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure

    Journal of the American Chemical Society · 2016-11-18

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  17. First-principles study on the dielectric and transport properties of the LiNbO3-type CdPbO3

    International Journal of Modern Physics B · 2016-12-13

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  18. Room Temperature Magnetically Ordered Polar Corundum GaFeO 3 Displaying Magnetoelectric Coupling

    Journal of the American Chemical Society · 2016-12-24

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  19. Synthesis, Structural, Electrical and Thermal Properties of ScFeO3 Ceramic

    American Journal of Modern Physics · 2017-01-01

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  20. Electronic structure and phase transition in polar ScFeO3 from first principles calculations

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  21. Polar Magnets in Double Corundum Oxides

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  22. High‐Pressure Perovskite: Synthesis, Structure, and Phase Relation

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  23. Electronic and magnetic properties of multiferroic ScFeO 3 available from diffraction experiments

    Journal of Physics Condensed Matter · 2017-08-14

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  24. Perovskite-Type InCoO3 with Low-Spin Co3+: Effect of In–O Covalency on Structural Stabilization in Comparison with Rare-Earth Series

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  25. Epitaxial thin film growth of garnet-, GdFeO3-, and YMnO3-type LuFeO3 using pulsed laser deposition

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  26. Magnetic field controlled electronic state and electric field controlled magnetic state in α-Fe1.6Ga0.4O3 oxide

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  27. Structural, Magnetic, and XPS Studies of the Double-Perovskite Mn2VSbO6

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  28. Synthesis, Crystal Structure, and Optical Properties of Layered Perovskite Scandium Oxychlorides: Sr2ScO3Cl, Sr3Sc2O5Cl2, and Ba3Sc2O5Cl2

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  29. Cooperative Couplings between Octahedral Rotations and Ferroelectricity in Perovskites and Related Materials

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  30. Ba3Fe1.56Ir1.44O9: A Polar Semiconducting Triple Perovskite with Near Room Temperature Magnetic Ordering

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  31. Asymmetric covalence bonding between In 5s and O 2p states in ferroelectric InFeO3

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  32. Modélisation des propriétés magnétiques et multiferroïques d'oxydes de cuivre

    Unknown journal · 2018-09-28

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  33. High-Pressure Synthesis, Crystal Structure, Chemical Bonding, and Ferroelectricity of LiNbO3-Type LiSbO3

    Inorganic Chemistry · 2018-12-03

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  34. Comparative study of magnetic and electronic properties of room‐temperature polar magnets ScFeO3 and InFeO3

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  35. Predicted polymorph manipulation in an exotic double perovskite oxide

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  36. Reversible Structural Transformation between Polar Polymorphs of Li2GeTeO6

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  37. High-Pressure Synthesis of Non-Stoichiometric LixWO3 (0.5 ≤ x ≤ 1.0) with LiNbO3 Structure

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  38. Polar–Nonpolar Phase Transition Accompanied by Negative Thermal Expansion in Perovskite-Type Bi1–xPbxNiO3

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  39. First-principles screening of ABO3 oxides with two magnetic sublattices

    Physical Review Materials · 2019-06-10

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  40. Theoretical study of stability and optical absorption properties of ferroelectric materials ZnXO3 (X=Ge, Sn and Pb)

    Physica B Condensed Matter · 2019-10-07

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  41. Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure

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  42. Switchable third ScFeO 3 polar ferromagnet with YMnO 3 -type structure

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  43. Above-Room-Temperature LiNbO3-Type Polar Magnet Stabilized by Chemical and Physical Pressure

    Chemistry of Materials · 2020-01-29

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  44. Universal A-Cation Splitting in LiNbO3-Type Structure Driven by Intrapositional Multivalent Coupling

    Journal of the American Chemical Society · 2020-03-27

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  45. Pressure Effects on Optoelectronic Properties of CsPbBr3 Nanocrystals

    The Journal of Physical Chemistry C · 2020-05-11

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  46. Perovskite-Type CuNbO3 Exhibiting Unusual Noncollinear Ferrielectric to Collinear Ferroelectric Dipole Order Transition

    Chemistry of Materials · 2020-05-14

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  47. Perspective on the pressure-driven evolution of the lattice and electronic structure in perovskite and double perovskite

    Applied Physics Letters · 2020-08-24

    Nana Li, Qian Zhang, Yonggang Wang, Wenge Yang

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  48. Structural and magnetic properties of multiferroic hexagonal Lu0.5(Sc1-In )0.5FeO3 ceramics

    Journal of Alloys and Compounds · 2020-09-12

    Kai Yang, Yuan Yuan, Changcai Chen, Guang Hua Yu, Xiaohua Luo, Shengcan Ma, Sajjad Ur Rehman, Zhenchen Zhong

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  49. Discovery of Rhombohedral NaIrO3 Polymorph by In Situ High-Pressure Synthesis of High-Oxidation-State Materials Using Laser Heating in Diamond Anvil Cells

    Inorganic Chemistry · 2020-10-14

    Camilla Hjort Kronbo, Martin Ottesen, Mads F. Hansen, Emma Ehrenreich-Petersen, Yue Meng, Martin Bremholm

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  50. Scandium immobilization by goethite: Surface adsorption versus structural incorporation

    Geochimica et Cosmochimica Acta · 2020-11-27

    Haibo Qin, Shitong Yang, Masato Tanaka, Kenzo Sanematsu, Carlo A. Arcilla, Yoshio Takahashi

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