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RESEARCH PAPER · Inorganic Chemistry · 2004

Metamagnetism in Cobalt Phosphates with Pillared Layer Structures: [Co3(pyz)(HPO4)2F2] and [Co3(4,4‘-bpy)(HPO4)2F2]·xH2O

Wei-Kuo Chang, Ray‐Kuang Chiang, Yau-Chen Jiang, Sue‐Lein Wang, Shang‐Fan Lee, Kwang‐Hwa Lii

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Metamagnetism in Cobalt Phosphates with Pillared Layer Structures: [Co3(pyz)(HPO4)2F2] and [Co3(4,4‘-bpy)(HPO4)2F2]·xH2OOriginalA Novel Layered Structure of a New Cadmium Chlorophosphate with an Imidazolium Template4Hydrothermal synthesis and crystal structure of a hybrid material based on [Cu4(bpy)4(H2O)2(PO4)2]2+ and an α-Keggin polyoxoanion22A two-dimensional cationic lattice built from [Zn6(HPO4)2(PO4)2]2+ clusters57Two Novel Transition‐Metal Phosphite Compounds with 4‐, 6‐ and 12‐Membered Rings: Hydrothermal Syntheses, Crystal Structures and Magnetic Properties of Na2[M(HPO3)2] (M = Fe, Co)38Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt( II )‐Coordination‐Polymer Sheets285Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt( II )‐Coordination‐Polymer Sheets16New Series of Layered Vanadyl Phosphates with Varied Polyamine Templates17Pillared-Layer Microporous Metal−Organic Frameworks Constructed by Robust Hydrogen Bonds. Synthesis, Characterization, and Magnetic and Adsorption Properties of 2,2‘-Biimidazole and Carboxylate Complexes143Synthesis, structural characterization, and solid-state NMR spectroscopy of [Ga(phen)(H1.5PO4)2]·H2O and [Ga(phen)(HPO4)(H2PO4)]·1.5H2O (phen=1, 10-phenanthroline), two organic–inorganic hybrid compounds with 1-D chain structures5Synthesis and properties of pyrazine-pillared Ag3Mo2O4F7 and AgReO4 layered phases13Syntheses, Structures, and Magnetic Properties of Inorganic−Organic Hybrid Cobalt(II) Phosphites Containing Bifunctional Ligands137Magnetic structures of [Co3(pyz)(HPO4)2F2], a fluorinated cobalt phosphate with a pillared layer structutre0[C4N2H12]2[In3(HPO4)5(H2PO4)F2]: The first 2-D fluorinated indium phosphate with double-sheet layers and 8-ring channels8Syntheses, Structures, Ionic Conductivities, and Magnetic Properties of Three New Transition-Metal Borophosphates Na5(H3O){MII3[B3O3(OH)]3(PO4)6}·2H2O (MII = Mn, Co, Ni)252D Hydrogen-Bonded Square-Grid Coordination Networks with a Substitution-Active Metal Site36Synthesis and structural characterization of two polymorphs of Fe(2,2′-bpy)(HPO4)(H2PO4)6Hydrothermal Synthesis of a Three-Dimensional Organic−Inorganic Hybrid Network Formed by Poly(oxomolybdophosphate) Anions and Nickel Coordination Cations69The use of hydrothermal methods in the synthesis of novel open-framework materials41Novel fluorinated indium phosphate with a double-layers structure: Assembled from racemic chiral building units11Building up 3-D framework structure from interlinking layered cobalt phosphates and organic pillars10A two-step field-induced magnetic transition in spin-canted systems observed only for the Co II coordination polymer722H3O·[Co8(HPO3)9(CH3OH)3]·2H2O: An Open-Framework Cobalt Phosphite Containing Extra-Large 18-Ring Channels56Isomorphous CoII and MnII materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours95Antiferromagnetic interactions in melamine-bridged trinuclear cobalt complex29Syntheses, structures and magnetic properties of two new one-dimensional cobalt (II) phosphites with organic amines acting as ligands15Luminescent Lanthanide Oxalatophosphites with a 3D Framework Structure: [Ln(H2O)(C2O4)0.5(HPO3)]·H2O (Ln = Pr, Nd, and Sm−Lu)43A Two-Dimensional Iron(II) Carboxylate Linear Chain Polymer that Exhibits a Metamagnetic Spin-Canted Antiferromagnetic to Single-Chain Magnetic Transition125Offene Gerüststrukturen von Übergangsmetallen24Open‐Framework Structures of Transition‐Metal Compounds380Controlling the In situ Decomposition of Chain-Type Polyamines To Direct the Crystal Growth of Cobalt−zinc Phosphates11Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications370Complex Long‐Range Magnetic Ordering Behaviors in Anisotropic Cobalt(II)–Azide Multilayer Systems98Adsorption–desorption and photocatalytic properties of inorganic–organic hybrid cadmium thiosulfate compounds83Spin canting and/or metamagnetic behaviours of four isostructural grid-type coordination networks27Syntheses, crystal structures, thermal stabilities, luminescence and magnetism of two 3D pillared metal phosphonates19Hydrothermal synthesis, crystal structure and physical properties of a new gadolinium phosphite hydrate11An End‐On Azide‐Bridged Antiferromagnetic Single‐Chain Magnet Involving Spin Canting and Field‐Induced Two‐Step Magnetic Transitions104Synthesis, characterization and magnetic properties of a novel fluorinated iron phosphite Fe2(HPO3)F2 with infinite –Fe–F–Fe–O–Fe– linkage and –Fe–F–Fe– layer7Network Topology of a Hybrid Organic Zinc Phosphate with Bimodal Porosity and Hydrogen Adsorption82Network Topology of a Hybrid Organic Zinc Phosphate with Bimodal Porosity and Hydrogen Adsorption23Magneto−Structural Correlation in a Metamagnetic Cobalt(II)-Based Pillared Trilayer Motif Constructed by Mixed Pyridyl-Type Carboxylate Ligands54Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium36Microwave-Assisted Stepwise Synthesis and Typically Metamagnetic Behavior of a Unique Two-Dimensional Net-Based Material Based on Linear Cu(II)-Azido Chains Mediated by Discrete Cu(II) Segments51A series of transition metal–azido extended complexes with various anionic and neutral co-ligands: synthesis, structure and their distinct magnetic behavior42Synthesis, structure, transformation studies and catalytic properties of open-framework cadmium thiosulfate compounds32Layered Zinc Phosphates with Photoluminescence and Photochromism: Chemistry in Deep Eutectic Solvents175Layered Zinc Phosphates with Photoluminescence and Photochromism: Chemistry in Deep Eutectic Solvents29Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties38Ligand-Directed Assembly of Asymmetric 1,3,5-Triazine Ligands Containing Pyridyl and Hydroxyl Groups15Two-step relaxation in the 3D spin-canted manganese phosphate with high P–O–Mn connectivity12One‐Dimensional End‐To‐End Azide‐Bridged MnIII Complexes Incorporating Alkali Metal Ions: Slow Magnetic Relaxations and Metamagnetism56A series of 3d–4f heterometallic frameworks comprising 2D lanthanide-organic layers and diverse Cu-complex pillars7Synthesis, Structure, Photochemical [2 + 2] Cycloaddition, Transformation, and Photocatalytic Studies in a Family of Inorganic–Organic Hybrid Cadmium Thiosulfate Compounds59The multifunctional roles of the ionic liquid [Bmim][BF4] in the creation of cadmium metal–organic frameworks37Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C–F Activation Reactions82Synthesis of Cobalt-Zinc Phosphates Templated by Polyamines1Cobalt(II)/manganese(II)-based molecular metamagnets3Copper uranyl phosphate and arsenate incorporating an organic ligand with a pillared layer structure: [Cu(4,4′-bpy)(UO2)0.5(HPO4)(H2PO4)]·H2O and [Cu(4,4′-bpy)(UO2)0.5(HAsO4)(H2AsO4)]·1.5H2O15An inorganic–organic hybrid zinc phosphite framework with unusual topology9A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)]210Spin canting and metamagnetism in 3D pillared-layer homospin cobalt(ii) molecular magnetic materials constructed via a mixed ligands approach37Ionothermal Synthesis, Crystal Structure, and Magnetic Study of Co2PO4OH Isostructural with Caminite19Ionothermal synthesis of open-framework metal phosphates with a Kagomé lattice network exhibiting canted anti-ferromagnetism24Utilization of a ligand containing 2,2′-bipyridyl and tetrazolate groups to construct a 2D Co( ii ) coordination polymer: spin canting and metamagnetism20Solvent-free synthesis of new metal phosphites with double-layered, pillared-layered, and framework structures6Synthesis and characterization of a novel inorganic–organic hybrid open-framework zinc phosphate with 16-ring channels10Charge-Complementary-Ligands Directed Assembly of a Lithium Dimer into a Three-Dimensional Porous Framework11Azide-bridged Cu( ii ), Mn( ii ) and Co( ii ) coordination polymers constructed with a bifunctional ligand of 6-(1H-tetrazol-5-yl)-2,2′-bipyridine20Composition dependence of magnetic relaxation for CoIIxNiII1−x chain-based compounds with mixed double azide–tetrazolate bridges14The construction, structures, and functions of pillared layer metal–organic frameworks104Synthesis and structures of two cobalt compounds of 2-amino-2-methyl-1-propanol1Five Multidimensional Co(II)-Complexes (Zero-Dimensional to Three-Dimensional) Derived from an Asymmetric 5-(Pyridin-3-yl)-1H-pyrazole-3-carboxylic Acid: Syntheses, Structures, and Magnetic Properties49The use of a semi-flexible bipyrimidyl ligand for the construction of azide-based coordination polymers: structural diversities and magnetic properties24Two New Three-Dimensional Pillared-Layer Co(II) and Cu(II) Frameworks Involving a [M2(EO-N3)2] Motif from a Semi-Flexible N-Donor Ligand, 5,5′-Bipyrimidin: Syntheses, Structures and Magnetic Properties6Indium Phosphite‐Based Porous Solids Exhibiting Organic Sensing and a Facile Route to Superhydrophobicity9An unusual homospin Co II ferrimagnetic single-chain magnet with large hysteresis4A Three-Dimensional Coordination Framework with a Ferromagnetic Coupled Ni(II)-CrO4 Layer: Synthesis, Structure, and Magnetic Studies3Novel Co5 Cluster Based Triazole Bridged Cobalt‐Fluorophosphate: Synthesis, Structure, Magnetic and Heterogeneous Catalytic Epoxidation Studies2Spin Canting and Weak Ferromagnetism in a New 2D Coordination Polymer with the Co(II) Chain Bridged by a Single End-to-End Azide1Synthesis, structures and properties of tetrazolate-bridged di-, tri-, and tetranuclear cobalt complexes: a review0

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  1. A Novel Layered Structure of a New Cadmium Chlorophosphate with an Imidazolium Template

    Chemistry Letters · 2004-09-04

    Wei Liu, Hao-Hong Chen, Xinxin Yang, Man‐Rong Li, Ming-Hui Ge, Jing‐Tai Zhao

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  2. Hydrothermal synthesis and crystal structure of a hybrid material based on [Cu4(bpy)4(H2O)2(PO4)2]2+ and an α-Keggin polyoxoanion

    Journal of Molecular Structure · 2004-12-15

    Ying Jie Lu, Enbo Wang, Yaqin Guo, Xinxin Xu, Lin Xu

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  3. A two-dimensional cationic lattice built from [Zn6(HPO4)2(PO4)2]2+ clusters

    Chemical Communications · 2005-01-01

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  4. Two Novel Transition‐Metal Phosphite Compounds with 4‐, 6‐ and 12‐Membered Rings: Hydrothermal Syntheses, Crystal Structures and Magnetic Properties of Na2[M(HPO3)2] (M = Fe, Co)

    European Journal of Inorganic Chemistry · 2005-03-01

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  5. Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt( II )‐Coordination‐Polymer Sheets

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  6. Spin Canting and Metamagnetism in a 3D Homometallic Molecular Material Constructed by Interpenetration of Two Kinds of Cobalt( II )‐Coordination‐Polymer Sheets

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  7. New Series of Layered Vanadyl Phosphates with Varied Polyamine Templates

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  8. Pillared-Layer Microporous Metal−Organic Frameworks Constructed by Robust Hydrogen Bonds. Synthesis, Characterization, and Magnetic and Adsorption Properties of 2,2‘-Biimidazole and Carboxylate Complexes

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  9. Synthesis, structural characterization, and solid-state NMR spectroscopy of [Ga(phen)(H1.5PO4)2]·H2O and [Ga(phen)(HPO4)(H2PO4)]·1.5H2O (phen=1, 10-phenanthroline), two organic–inorganic hybrid compounds with 1-D chain structures

    Journal of Solid State Chemistry · 2005-11-16

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  10. Synthesis and properties of pyrazine-pillared Ag3Mo2O4F7 and AgReO4 layered phases

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  11. Syntheses, Structures, and Magnetic Properties of Inorganic−Organic Hybrid Cobalt(II) Phosphites Containing Bifunctional Ligands

    Inorganic Chemistry · 2005-12-22

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  12. Magnetic structures of [Co3(pyz)(HPO4)2F2], a fluorinated cobalt phosphate with a pillared layer structutre

    Physica B Condensed Matter · 2006-03-04

    Chun‐Chuen Yang, Shang‐Fan Lee, Y. D. Yao, W.-H. Li, Kwang‐Hwa Lii, Jeffrey W. Lynn

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  13. [C4N2H12]2[In3(HPO4)5(H2PO4)F2]: The first 2-D fluorinated indium phosphate with double-sheet layers and 8-ring channels

    Inorganic Chemistry Communications · 2006-03-15

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  14. Syntheses, Structures, Ionic Conductivities, and Magnetic Properties of Three New Transition-Metal Borophosphates Na5(H3O){MII3[B3O3(OH)]3(PO4)6}·2H2O (MII = Mn, Co, Ni)

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  15. 2D Hydrogen-Bonded Square-Grid Coordination Networks with a Substitution-Active Metal Site

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  16. Synthesis and structural characterization of two polymorphs of Fe(2,2′-bpy)(HPO4)(H2PO4)

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  17. Hydrothermal Synthesis of a Three-Dimensional Organic−Inorganic Hybrid Network Formed by Poly(oxomolybdophosphate) Anions and Nickel Coordination Cations

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  18. The use of hydrothermal methods in the synthesis of novel open-framework materials

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  19. Novel fluorinated indium phosphate with a double-layers structure: Assembled from racemic chiral building units

    Microporous and Mesoporous Materials · 2007-01-26

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  20. Building up 3-D framework structure from interlinking layered cobalt phosphates and organic pillars

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  21. A two-step field-induced magnetic transition in spin-canted systems observed only for the Co II coordination polymer

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  22. 2H3O·[Co8(HPO3)9(CH3OH)3]·2H2O: An Open-Framework Cobalt Phosphite Containing Extra-Large 18-Ring Channels

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  23. Isomorphous CoII and MnII materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours

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  24. Antiferromagnetic interactions in melamine-bridged trinuclear cobalt complex

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  25. Syntheses, structures and magnetic properties of two new one-dimensional cobalt (II) phosphites with organic amines acting as ligands

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  26. Luminescent Lanthanide Oxalatophosphites with a 3D Framework Structure: [Ln(H2O)(C2O4)0.5(HPO3)]·H2O (Ln = Pr, Nd, and Sm−Lu)

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  27. A Two-Dimensional Iron(II) Carboxylate Linear Chain Polymer that Exhibits a Metamagnetic Spin-Canted Antiferromagnetic to Single-Chain Magnetic Transition

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  29. Open‐Framework Structures of Transition‐Metal Compounds

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  30. Controlling the In situ Decomposition of Chain-Type Polyamines To Direct the Crystal Growth of Cobalt−zinc Phosphates

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  31. Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications

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  32. Complex Long‐Range Magnetic Ordering Behaviors in Anisotropic Cobalt(II)–Azide Multilayer Systems

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  33. Adsorption–desorption and photocatalytic properties of inorganic–organic hybrid cadmium thiosulfate compounds

    Physical Chemistry Chemical Physics · 2009-01-01

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  34. Spin canting and/or metamagnetic behaviours of four isostructural grid-type coordination networks

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  35. Syntheses, crystal structures, thermal stabilities, luminescence and magnetism of two 3D pillared metal phosphonates

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  36. Hydrothermal synthesis, crystal structure and physical properties of a new gadolinium phosphite hydrate

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  37. An End‐On Azide‐Bridged Antiferromagnetic Single‐Chain Magnet Involving Spin Canting and Field‐Induced Two‐Step Magnetic Transitions

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  38. Synthesis, characterization and magnetic properties of a novel fluorinated iron phosphite Fe2(HPO3)F2 with infinite –Fe–F–Fe–O–Fe– linkage and –Fe–F–Fe– layer

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  39. Network Topology of a Hybrid Organic Zinc Phosphate with Bimodal Porosity and Hydrogen Adsorption

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  40. Network Topology of a Hybrid Organic Zinc Phosphate with Bimodal Porosity and Hydrogen Adsorption

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  41. Magneto−Structural Correlation in a Metamagnetic Cobalt(II)-Based Pillared Trilayer Motif Constructed by Mixed Pyridyl-Type Carboxylate Ligands

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  42. Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium

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  43. Microwave-Assisted Stepwise Synthesis and Typically Metamagnetic Behavior of a Unique Two-Dimensional Net-Based Material Based on Linear Cu(II)-Azido Chains Mediated by Discrete Cu(II) Segments

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  44. A series of transition metal–azido extended complexes with various anionic and neutral co-ligands: synthesis, structure and their distinct magnetic behavior

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  45. Synthesis, structure, transformation studies and catalytic properties of open-framework cadmium thiosulfate compounds

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  46. Layered Zinc Phosphates with Photoluminescence and Photochromism: Chemistry in Deep Eutectic Solvents

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  47. Layered Zinc Phosphates with Photoluminescence and Photochromism: Chemistry in Deep Eutectic Solvents

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  48. Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties

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  49. Ligand-Directed Assembly of Asymmetric 1,3,5-Triazine Ligands Containing Pyridyl and Hydroxyl Groups

    Crystal Growth & Design · 2010-10-18

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  50. Two-step relaxation in the 3D spin-canted manganese phosphate with high P–O–Mn connectivity

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