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RESEARCH PAPER · Inorganic Chemistry · 2009

Three-Dimensional Frameworks of Cubic (NH4)5Ga4SbS10, (NH4)4Ga4SbS9(OH)·H2O, and (NH4)3Ga4SbS9(OH2)·2H2O

Joshua L. Mertz, Nan Ding, Mercouri G. Kanatzidis

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Three-Dimensional Frameworks of Cubic (NH4)5Ga4SbS10, (NH4)4Ga4SbS9(OH)·H2O, and (NH4)3Ga4SbS9(OH2)·2H2OOriginalNew compounds and structures in the solid state1Arrays of Chiral Nanotubes and a Layered Coordination Polymer Containing Gallium–Sulfide Supertetrahedral Clusters51ChemInform Abstract: Three‐Dimensional Frameworks of Cubic (NH4)5Ga4SbS10, (NH4)4Ga4SbS9 (OH)·H2O, and (NH4)3Ga4SbS9 (OH2)·2H2O.0A Series of Novel Organically Templated Germanium Antimony Sulfides42Copper-Rich Framework Sulfides: A4Cu8Ge3S12 (A = K, Rb) with Cubic Perovskite Structure55Largest Molecular Clusters in the Supertetrahedral Tn Series104A novel 3-D thioindate-thioantimonate based on the linkages of large heterometallic {In2Sb2S9} clusters and 1-D [In2Sb2S84−]n chains23Solvothermal synthesis and characterization of two 2-D layered germanium thioantimonates with transition-metal complexes33Na5(Ga4S)(GaS4)3·6H2O: A three-dimensional thiogallate containing a novel octahedral building block8[BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure87Solvothermal synthesis of a bimetallic thiometallate containing germanium in two oxidation states20Layered indium chalcogenidoantimonates [Me 2 NH 2 ] 2 In 2 Sb 2 S 7-x Se x (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties51Controlling the Assembly of Chalcogenide Anions in Ionic Liquids: From Binary Ge/Se through Ternary Ge/Sn/Se to Binary Sn/Se Frameworks64Copper‐Rich Framework Selenoarsenates Based on Icosahedral Cu8Se13 Clusters14[NH 3 CH 3 ] 4 [In 4 SbS 9 SH]: a novel methylamine-directed indium thioantimonate with Rb + ion-exchange property59Chalcogenides and Nonoxides2A new Sb-based polysulfide: Ba3Sb2S7 containing (S2)2− ligand4Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680[TM(en)3][SnSb4S9] (TM = Ni, Co): 3D Chiral Framework of Mixed Main-Group Metals and [Mn(dien)2]2Sb4S9: 1D Chains with Mixed-Valent Sb Centers54New strategies to prepare crystalline chalcogenides165Two manganese–amine complexes incorporating thioantimonates and exhibiting diversiform roles of amine ligands20Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes69Ag1.75InSb5.75Se11: A new noncentrosymmetric compound with congruent-melting behavior5Syntheses and characterization of one-dimensional alkali metal antimony(III) thiostannates(IV), A2Sb2Sn3S10 (A=K, Rb, Cs)21New Members of the Family of In–Sb–S Compounds: Different Roles of Organic Amines20Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu8Sn6S24]z− Clusters34Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements94Syntheses and structural characterization of non-centrosymmetric Na2M2M'S6 (M, M′=Ga, In, Si, Ge, Sn, Zn, Cd) sulfides36Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III)68Synthesis of a Ternary Thiostannate with 3D Channel Decorated by Hydronium for High Proton Conductivity17[CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property19Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates48[(Ba19Cl4)(Ga6Si12O42S8)]: a Two-Dimensional Wide-Band-Gap Layered Oxysulfide with Mixed-Anion Chemical Bonding and Photocurrent Response20Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence18Group 11–15 Metal Chalcogenides0Group 11–15 Metal Chalcogenides0Group 11–15 Metal Chalcogenides0Two silver chalcogenidoantimonates synthesized in piperazine and their high performances for visible-light driven Cr(VI) reduction20Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5Stable 3D neutral gallium thioantimonate frameworks decorated with transition metal complexes for a tunable photocatalytic hydrogen evolution9Two new metal-chalcogenide-cluster-based frameworks with single metal ions of Zn 2+ (/Sb 3+ ) serving as inter-cluster linkers4

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41 direct citing papers saved.

  1. New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2010-01-01

    Edmund J. Cussen

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  2. Arrays of Chiral Nanotubes and a Layered Coordination Polymer Containing Gallium–Sulfide Supertetrahedral Clusters

    Chemistry - A European Journal · 2010-03-15

    Paz Vaqueiro, M.L. Romero, Brenda C. Rowan, Bryce Sydney Richards

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  3. ChemInform Abstract: Three‐Dimensional Frameworks of Cubic (NH4)5Ga4SbS10, (NH4)4Ga4SbS9 (OH)·H2O, and (NH4)3Ga4SbS9 (OH2)·2H2O.

    ChemInform · 2010-04-22

    Joshua L. Mertz, Nan Ding, Mercouri G. Kanatzidis

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  4. A Series of Novel Organically Templated Germanium Antimony Sulfides

    Chemistry - An Asian Journal · 2010-06-10

    Mei‐Ling Feng, Wei‐Wei Xiong, Dong Ye, Jian‐Rong Li, Xiao‐Ying Huang

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  5. Copper-Rich Framework Sulfides: A4Cu8Ge3S12 (A = K, Rb) with Cubic Perovskite Structure

    Inorganic Chemistry · 2010-06-21

    Ren‐Chun Zhang, Hua–Gang Yao, Shou‐Hua Ji, Meichen Liu, Min Ji, Yong‐Lin An

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  6. Largest Molecular Clusters in the Supertetrahedral Tn Series

    Journal of the American Chemical Society · 2010-07-21

    Tao Wu, Le Wang, Xianhui Bu, Victoria Chau, Pingyun Feng

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  7. A novel 3-D thioindate-thioantimonate based on the linkages of large heterometallic {In2Sb2S9} clusters and 1-D [In2Sb2S84−]n chains

    CrystEngComm · 2011-01-01

    Jian Zhou, Litao An

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  8. Solvothermal synthesis and characterization of two 2-D layered germanium thioantimonates with transition-metal complexes

    Dalton Transactions · 2011-01-01

    Jian Zhou, Litao An, Xing Liu, Lijun Huang, Xijiao Huang

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  9. Na5(Ga4S)(GaS4)3·6H2O: A three-dimensional thiogallate containing a novel octahedral building block

    Solid State Sciences · 2011-01-20

    Jack Rumble, Paz Vaqueiro

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  10. [BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure

    Inorganic Chemistry · 2011-08-02

    Yu‐Mei Lin, Stefanie Dehnen

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  11. Solvothermal synthesis of a bimetallic thiometallate containing germanium in two oxidation states

    Journal of Solid State Chemistry · 2011-10-05

    Anthony V. Powell, Rosalyn Mackay

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  12. Layered indium chalcogenidoantimonates [Me 2 NH 2 ] 2 In 2 Sb 2 S 7-x Se x (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties

    CrystEngComm · 2011-11-09

    Kai‐Yao Wang, Mei‐Ling Feng, De‐Nian Kong, Shijing Liang, Ling Wu, Xiao‐Ying Huang

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  13. Controlling the Assembly of Chalcogenide Anions in Ionic Liquids: From Binary Ge/Se through Ternary Ge/Sn/Se to Binary Sn/Se Frameworks

    Chemistry - A European Journal · 2012-09-07

    Yu‐Mei Lin, Werner Massa, Stefanie Dehnen

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  14. Copper‐Rich Framework Selenoarsenates Based on Icosahedral Cu8Se13 Clusters

    Zeitschrift für anorganische und allgemeine Chemie · 2012-09-07

    Ren‐Chun Zhang, Chi Zhang, Dao‐Jun Zhang, Junjie Wang, Zhi‐Fei Zhang, Min Ji, Yong‐Lin An

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  15. [NH 3 CH 3 ] 4 [In 4 SbS 9 SH]: a novel methylamine-directed indium thioantimonate with Rb + ion-exchange property

    Journal of Materials Chemistry A · 2012-11-14

    Kai‐Yao Wang, Mei‐Ling Feng, Jian‐Rong Li, Xiao‐Ying Huang

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  16. Chalcogenides and Nonoxides

    Elsevier eBooks · 2013-01-01

    Jacilynn A. Brant, Carl D. Brunetta, Jennifer A. Aitken

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  17. A new Sb-based polysulfide: Ba3Sb2S7 containing (S2)2− ligand

    Journal of Molecular Structure · 2013-06-17

    Lei Geng, Zhong‐Zhen Luo, Wen‐Dan Cheng

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  18. Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials

    Chemistry of Materials · 2013-08-09

    In Jae Chung, Mercouri G. Kanatzidis

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  19. [TM(en)3][SnSb4S9] (TM = Ni, Co): 3D Chiral Framework of Mixed Main-Group Metals and [Mn(dien)2]2Sb4S9: 1D Chains with Mixed-Valent Sb Centers

    Crystal Growth & Design · 2013-11-21

    Cheng‐Yang Yue, Xiao‐Wu Lei, Yun‐Xiang Ma, Ning Sheng, Ya-Dong Yang, Guodong Liu, Xiurong Zhai

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  20. New strategies to prepare crystalline chalcogenides

    Inorganic Chemistry Frontiers · 2014-01-01

    Wei‐Wei Xiong, Guodong Zhang, Qichun Zhang

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  21. Two manganese–amine complexes incorporating thioantimonates and exhibiting diversiform roles of amine ligands

    CrystEngComm · 2014-01-01

    Cheng‐Yang Yue, Xiao‐Wu Lei, Hui-Ping Zang, Xiurong Zhai, Lijuan Feng, Zhi-Fei Zhao, Jian-Qiang Zhao, Xinyue Liu

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  22. Syntheses, Crystal Structures, and Photocatalytic Properties of a Series of Mercury Thioantimonates Directed by Transition Metal Complexes

    Crystal Growth & Design · 2014-03-14

    Cheng‐Yang Yue, Xiao‐Wu Lei, Rui-Qiu Liu, Hui-Ping Zhang, Xiurong Zhai, Wenpeng Li, Meng Ran Zhou, Zhi-Fei Zhao, Yun‐Xiang Ma, Y. H. Yang

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  23. Ag1.75InSb5.75Se11: A new noncentrosymmetric compound with congruent-melting behavior

    Journal of Solid State Chemistry · 2014-06-23

    Wenyu Hao, Yemao Han, Rongjin Huang, Kai Feng, Wenlong Yin, Jiyong Yao, Yicheng Wu

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  24. Syntheses and characterization of one-dimensional alkali metal antimony(III) thiostannates(IV), A2Sb2Sn3S10 (A=K, Rb, Cs)

    Journal of Solid State Chemistry · 2014-10-24

    Jinu P. Yohannan, Kanamaluru Vidyasagar

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  25. New Members of the Family of In–Sb–S Compounds: Different Roles of Organic Amines

    Crystal Growth & Design · 2014-11-17

    Kai‐Yao Wang, Bo Zhang, Xing‐Hui Qi, Nan‐Nan Shen, Cheng‐Feng Du, Zhao‐Feng Wu, Mei‐Ling Feng, Xiao‐Ying Huang

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  26. Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu8Sn6S24]z− Clusters

    Inorganic Chemistry · 2015-05-08

    Xian Zhang, Qiuran Wang, Zhimin Ma, Jianqiao He, Zhe Wang, Chong Zheng, Jianhua Lin, Fuqiang Huang

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  27. Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements

    Coordination Chemistry Reviews · 2016-02-19

    Jian Zhou

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  28. Syntheses and structural characterization of non-centrosymmetric Na2M2M'S6 (M, M′=Ga, In, Si, Ge, Sn, Zn, Cd) sulfides

    Journal of Solid State Chemistry · 2016-03-14

    Jinu P. Yohannan, Kanamaluru Vidyasagar

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  29. Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III)

    Coordination Chemistry Reviews · 2016-05-13

    Kai-Yao Wang, Mei‐Ling Feng, Xiao‐Ying Huang, Jing Li

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  30. Synthesis of a Ternary Thiostannate with 3D Channel Decorated by Hydronium for High Proton Conductivity

    Inorganic Chemistry · 2016-12-15

    Dan Zhang, Guangshe Li, Yu Peng, Liping Li

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  31. [CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property

    Chemistry - An Asian Journal · 2018-01-18

    Bo Zhang, Wei‐An Li, Yi‐Yu Liao, Chen Zhang, Mei‐Ling Feng, Xiao‐Ying Huang

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  32. Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates

    Crystal Growth & Design · 2018-04-09

    Dandan Yang, Ying Jie Song, Bo Zhang, Nan‐Nan Shen, Guilan Xu, Wei‐Wei Xiong, Xiao‐Ying Huang

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  33. [(Ba19Cl4)(Ga6Si12O42S8)]: a Two-Dimensional Wide-Band-Gap Layered Oxysulfide with Mixed-Anion Chemical Bonding and Photocurrent Response

    Inorganic Chemistry · 2019-05-10

    Yong‐Fang Shi, Xiaofang Li, Yu‐Xiao Zhang, Hua Lin, Zuju Ma, Li‐Ming Wu, Xin‐Tao Wu, Qi‐Long Zhu

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  34. Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence

    Dalton Transactions · 2021-01-01

    Gang Yang, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  35. Group 11–15 Metal Chalcogenides

    Unknown journal · 2021-04-19

    Jian‐Rong Li, Mei‐Ling Feng, Bing Hu, Xiao‐Ying Huang

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  36. Group 11–15 Metal Chalcogenides

    Unknown journal · 2021-04-19

    Jian‐Rong Li, Mei‐Ling Feng, Bing Hu, Xiao‐Ying Huang

    Read original paper ↗ ·

  37. Group 11–15 Metal Chalcogenides

    Unknown journal · 2021-04-19

    Jian‐Rong Li, Mei‐Ling Feng, Bing Hu, Xiao‐Ying Huang

    Read original paper ↗ ·

  38. Two silver chalcogenidoantimonates synthesized in piperazine and their high performances for visible-light driven Cr(VI) reduction

    Journal of Solid State Chemistry · 2021-05-15

    Huan Wang, Ji-Ming Yu, Ning Wang, Lu-Lu Xiao, Ji-Peng Yu, Qi Xu, Bing Zheng, Fang-Fang Cheng, Wei‐Wei Xiong

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  39. Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses

    Crystal Growth & Design · 2021-07-22

    Chao Wu, Lin Lin, Tianhui Wu, Wenyan Dan, Zhipeng Huang, Chi Zhang

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  40. Stable 3D neutral gallium thioantimonate frameworks decorated with transition metal complexes for a tunable photocatalytic hydrogen evolution

    Dalton Transactions · 2021-12-07

    Juan Li, Chengdong Liu, Xiang Wang, Yayun Ding, Zhou Wu, Peipei Sun, Jiaqi Tang, Jiaxu Zhang, Dong‐Sheng Li, Ning Chen, Tao Wu

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  41. Two new metal-chalcogenide-cluster-based frameworks with single metal ions of Zn 2+ (/Sb 3+ ) serving as inter-cluster linkers

    Dalton Transactions · 2022-01-01

    Chengdong Liu, Yayun Ding, Xiang Wang, Rui Zhou

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