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RESEARCH PAPER · Journal of Materials Chemistry C · 2016

Transparent conductive CuCrO 2 thin films deposited by pulsed injection metal organic chemical vapor deposition: up-scalable process technology for an improved transparency/conductivity trade-off

Jonathan Crêpellière, Petru Lunca‐Popa, Naoufal Bahlawane, Renaud Leturcq, Florian Werner, Susanne Siebentritt, D. Lenoble

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Transparent conductive CuCrO 2 thin films deposited by pulsed injection metal organic chemical vapor deposition: up-scalable process technology for an improved transparency/conductivity trade-offOriginalEnhanced p‐Type Transparent Semiconducting Characteristics for ALD‐Grown Mg‐Substituted CuCrO2 Thin Films48Facile chemical solution synthesis of p-type delafossite Ag-based transparent conducting AgCrO 2 films in an open condition43Effect of the Substrate Temperature on the Structural and Morphological Properties of MoO2 Thin Films Obtained by Pulsed Injection MOCVD19Copper‐Decorated Microsized Nanoporous Titanium Dioxide Photocatalysts for Carbon Dioxide Reduction by Water58Invisible electronics: Metastable Cu-vacancies chain defects for highly conductive p-type transparent oxide44Cu/Cu 2 O nanoparticle interface: Rational designing of a heterogeneous catalyst system for selective hydroamination32Quantifying the Performance of P-Type Transparent Conducting Oxides by Experimental Methods59Hall measurements on low-mobility thin films116Thermal solid-phase crystallization of amorphous CuCrO2:N thin films deposited by reactive radio-frequency magnetron sputtering11Hydrothermally processed CuCrO 2 nanoparticles as an inorganic hole transporting material for low-cost perovskite solar cells with superior stability106Combustion Synthesis of p-Type Transparent Conducting CuCrO2+x and Cu:CrOx Thin Films at 180 °C32Semiconducting and photoelectrochemical characterizations of CuCrO2 powder synthesized by sol-gel method9Tuning the electrical properties of the p-type transparent conducting oxide Cu1−xCr1+xO2 by controlled annealing35p-type transparent conductivity in high temperature superconducting Bi-2212 thin films13Effect of Ni doping on the structural, electrical, and optical properties of transparent CuCrO2 films grown using pulsed laser deposition28Inorganic p‐Type Semiconductors as Hole Conductor Building Blocks for Robust Perovskite Solar Cells35Bending stability of Cu0.4CrO2—A transparent p-type conducting oxide for large area flexible electronics12ZnO/CuCrO2 Core–Shell Nanowire Heterostructures for Self‐Powered UV Photodetectors with Fast Response97Oxygen Vacancy Defects Boosted High Performance p-Type Delafossite CuCrO2 Gas Sensors141Delafossite CuFeO2 thin films via aerosol assisted CVD: Synthesis and characterization21Are Small Polarons Always Detrimental to Transparent Conducting Oxides ?2Etude de couches minces à base de delafossite CuCr1-xFexO2(0 ≤ x ≤ 1) dopées au Mg déposées par pulvérisation cathodique radiofréquence en vue d'optimiser leurs propriétés thermoélectriques0Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides92Branched Copper Oxide Nanoparticles Induce Highly Selective Ethylene Production by Electrochemical Carbon Dioxide Reduction366Temperature‐dependent electrical transport behavior and structural evolution in hollandite‐type titanium‐based oxide14High-performance transparent conducting oxides through small-polaron transport13Solution‐Processed Ternary Oxides as Carrier Transport/Injection Layers in Optoelectronics52Assessment of thermodynamic data for CuCrO2 delafossite from calorimetric measurements9Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst30Tuneable interplay between atomistic defects morphology and electrical properties of transparent p-type highly conductive off-stoichiometric Cu-Cr-O delafossite thin films20Efficient Resistive Switching and Spike Rate Dependent Plasticity in a New CuCrO2 Memristor for Plausible Neuromorphic Systems22Cu2O/reduced graphene oxide/TiO2nanomaterial: An effective photocatalyst for azide‐alkyne cycloaddition with benzyl halides or epoxide derivatives under visible light irradiation28p-type transparent superconductivity in a layered oxide21Innovative development on a p-type delafossite CuCrO2 nanoparticles based triethylamine sensor48Tunable Syngas Formation from Electrochemical CO 2 Reduction on Copper Nanowire Arrays63Highly sensitive and selective electrochemical detection of dopamine based on CuCrO2-TiO2 composite decorated screen-printed modified electrode39Abnormal Deviation of Temperature–Resistivity Correlation for Nanostructured Delafossite CuCrO2 Due to Local Reconfiguration5Novel construction of carbon nanofiber/CuCrO 2 composite for selective determination of 4-nitrophenol in environmental samples and for supercapacitor application19Out of stoichiometry CuCrO 2 films as a promising p-type TCO for transparent electronics39Magnetic, dielectric and optical properties of Al-, Mg-, Co- and Zn-ion–doped CuCrO 21The roles of interstitial oxygen and phase compositions on the thermoelectric properties CuCr0.85Mg0.15O2 delafossite material19Preparation and characterization of delafossite CuCrO2 film on flexible substrate20Thermodynamic and Structural Properties of CuCrO 2 and CuCr 2 O 4 : Experimental Investigation and Phase Equilibria Modeling of the Cu–Cr–O System21Optimized Stoichiometry for CuCrO2 Thin Films as Hole Transparent Layer in PBDD4T-2F:PC70BM Organic Solar Cells10Removal of heavy metals by surface tailored copper ion enhanced ceramic-supported-polymeric composite nanofiltration membrane27An all-sputtered photovoltaic ultraviolet photodetector based on co-doped CuCrO2 and Al-doped ZnO heterojunction50Plasma-assisted solution combustion synthesis of Mg-incorporated CuCrO2 and AgCrO2 delafossite thin films4Selective phase transformation of layered double hydroxides into mixed metal oxides for catalytic CO oxidation24Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4252A Novel Ternary Metal Oxide Cascade Z-Scheme Heterojunction for Efficient Co2 Photoconversion Without a Co-Catalyst0Dual photocatalysis for CO 2 reduction along with the oxidative coupling of benzylamines promoted by Cu/Cu 2 O@g-C 3 N 4 under visible irradiation14p‐Type Near‐Infrared Transparent Delafossite Thin Films with Ultrahigh Conductivity13New record high thermoelectric ZT of delafossite-based CuCrO2 thin films obtained by simultaneously reducing electrical resistivity and thermal conductivity via heavy doping with controlled residual stress15Highly Conductive and Visibly Transparent p-Type CuCrO2 Films by Ultrasonic Spray Pyrolysis24A novel ternary metal oxide cascade Z-scheme heterojunction for efficient CO2 photoconversion without a co-catalyst28Copper activated near-full two-electron Mn4+/Mn2+ redox for mild aqueous Zn/MnO2 battery41Bifacial CdTe Solar Cells with Copper Chromium Oxide Back‐Buffer Layer13Feasibility of nanomaterial tungsten carbide as lead-free nanomaterial-based radiation shielding116n-ZnO/Out-of-Stoichiometry p-CuCrO2 Diodes for Efficient and Low-Cost Transparent Electronic Applications2Effect of Annealing Temperature on Radio Frequency Sputtered p-Type Delafossite Copper Chromium Oxide (CuCrO2) Thin Films and Investigation of Diode Characteristics Forming Transparent pn-Heterojunction12Effect of Cu2O Sputtering Power Variation on the Characteristics of Radio Frequency Sputtered p-Type Delafossite CuCrO2 Thin Films10Ultra-low-energy catalytic degradation of ozone by off-stoichiometric delafossite Cu–Cr–O for highly selective low-temperature solid-state O3 sensors61.37×102 S·cm-1 p-type conductivity LaCuOS films with a very wide optical transparency window of 400-6000 nm4Transparent p-n heterojunction thin film diodes based on p-CuCrO2 and n-In2O36Characterization of reactively sputter deposited CuCrO 2 thin films using Cu and Cr targets11Discoloration Process of Minted Copper-Nickel Alloys in Chloride Ion-Containing Environments: Experimental and Dft Research0Improved transparency and conductivity in copper chromium oxide coatings through aliovalent doping and stoichiometry control6High-performance p-type V2O3 films by spray pyrolysis for transparent conducting oxide applications18High-Responsivity Self-Powered Solar-Blind Photodetectors Based on Magnetron-Sputtered CuCrO₂/ β -Ga₂O₃ p-n Heterojunction29Ca-Cu/Al2O3 catalysts for H2S removal at near ambient temperature: Synthesis, characterization, DFT calculation, and mechanistic insights29Critical Review of Cu‐Based Hole Transport Materials for Perovskite Solar Cells: From Theoretical Insights to Experimental Validation30RETRACTED ARTICLE: Functional organic materials for energy storage and conversion: recent developments and future perspectives8On the charge transport models in high intrinsic defect doped transparent and conducting p-type Cu–Cr–O delafossite thin films7Electrochemical Properties of CuCrO2 Prepared by Chemical Route4Enhanced H2S removal efficiency using CuO/Al2O3 catalyst impregnated with Ca(NO3)2: Influence of calcination temperature and mechanistic insights2On some distinct characteristics of reactive and normal flash sintering: A case study using low-temperature synthesized p-type cuprous delafossite, CuCrO22A Comprehensive Study on the Impact of Off-Stoichiometry and Mg Doping in CuCrO 2 Thin Films for Heterojunction Device Fabrication7Advancing Ce–Cu–Al2O3 catalysts for waste-to-energy through strategic surface coordination modulation6Discoloration Process of Minted Copper–Nickel Alloys in Chloride Ion-Containing Environments: Experimental and DFT Research1Heterointercalation in Chevrel-Phase Sulfides: A Model Periodic Solid for the Investigation of Chain Electron Transfer8Electrical and Optical Characterization of CuCrO2 Thin Films Deposited Using Cu and Cr2O3 Targets2Ultrasmooth Mg‐Doped CuCrO 2 Thin Films: Optimizing Thermoelectric Performance for Energy Harvesting0Emerging trends in inorganic hole transport materials for high-efficiency PSCs7Synthesis and properties of a Cu2O decorated BiVO4 nanocomposite photocatalyst3Inorganic Charge Transport Layers for High‐Performance p‐i‐n Perovskite Solar Cells6Solution-Processed Mg-Doped Epitaxial CuCrO 2 Thin Films with Optoelectronic Tunability1Improving functional properties in Cr2O3 thin films through annealing: a route toward sustainable materials engineering1The critical role of amorphous oxygen in low-temperature catalytic oxidation of H2S: Performance and mechanisms0

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  1. Enhanced p‐Type Transparent Semiconducting Characteristics for ALD‐Grown Mg‐Substituted CuCrO2 Thin Films

    Advanced Electronic Materials · 2016-12-30

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  2. Facile chemical solution synthesis of p-type delafossite Ag-based transparent conducting AgCrO 2 films in an open condition

    Journal of Materials Chemistry C · 2017-01-01

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  3. Effect of the Substrate Temperature on the Structural and Morphological Properties of MoO2 Thin Films Obtained by Pulsed Injection MOCVD

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  4. Copper‐Decorated Microsized Nanoporous Titanium Dioxide Photocatalysts for Carbon Dioxide Reduction by Water

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    Tao Zhang, Jingxiang Low, Xiaoxi Huang, Jafar F. Al‐Sharab, Jiaguo Yu, Tewodros Asefa

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  5. Invisible electronics: Metastable Cu-vacancies chain defects for highly conductive p-type transparent oxide

    Applied Materials Today · 2017-07-27

    Petru Lunca‐Popa, Jonathan Crêpellière, Pavan Nukala, Renaud Leturcq, D. Lenoble

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  6. Cu/Cu 2 O nanoparticle interface: Rational designing of a heterogeneous catalyst system for selective hydroamination

    Molecular Catalysis · 2017-08-16

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  7. Quantifying the Performance of P-Type Transparent Conducting Oxides by Experimental Methods

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    K. Fleischer, Emma Norton, Daragh Mullarkey, David F. Caffrey, Igor V Shvets

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  8. Hall measurements on low-mobility thin films

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  9. Thermal solid-phase crystallization of amorphous CuCrO2:N thin films deposited by reactive radio-frequency magnetron sputtering

    Thin Solid Films · 2017-11-22

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  10. Hydrothermally processed CuCrO 2 nanoparticles as an inorganic hole transporting material for low-cost perovskite solar cells with superior stability

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  11. Combustion Synthesis of p-Type Transparent Conducting CuCrO2+x and Cu:CrOx Thin Films at 180 °C

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  12. Semiconducting and photoelectrochemical characterizations of CuCrO2 powder synthesized by sol-gel method

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    N. Benreguia, A. Abdi, Ousama Mahroua, Mohamed Trari

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  13. Tuning the electrical properties of the p-type transparent conducting oxide Cu1−xCr1+xO2 by controlled annealing

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  14. p-type transparent conductivity in high temperature superconducting Bi-2212 thin films

    Applied Physics Letters · 2018-06-18

    Renhuai Wei, Li Zhang, Ling Hu, Xianwu Tang, Jie Yang, Jianming Dai, Wenhai Song, Xuebin Zhu, Yuping Sun

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  15. Effect of Ni doping on the structural, electrical, and optical properties of transparent CuCrO2 films grown using pulsed laser deposition

    Ceramics International · 2018-06-30

    Se‐Yun Kim, Joon‐Hyung Lee, Jeong-Joo Kim, Young-Woo Heo

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  16. Inorganic p‐Type Semiconductors as Hole Conductor Building Blocks for Robust Perovskite Solar Cells

    Advanced Sustainable Systems · 2018-07-20

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  17. Bending stability of Cu0.4CrO2—A transparent p-type conducting oxide for large area flexible electronics

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  18. ZnO/CuCrO2 Core–Shell Nanowire Heterostructures for Self‐Powered UV Photodetectors with Fast Response

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  19. Oxygen Vacancy Defects Boosted High Performance p-Type Delafossite CuCrO2 Gas Sensors

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  20. Delafossite CuFeO2 thin films via aerosol assisted CVD: Synthesis and characterization

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  21. Are Small Polarons Always Detrimental to Transparent Conducting Oxides ?

    arXiv (Cornell University) · 2018-10-11

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  22. Etude de couches minces à base de delafossite CuCr1-xFexO2(0 ≤ x ≤ 1) dopées au Mg déposées par pulvérisation cathodique radiofréquence en vue d'optimiser leurs propriétés thermoélectriques

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  23. Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides

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  24. Branched Copper Oxide Nanoparticles Induce Highly Selective Ethylene Production by Electrochemical Carbon Dioxide Reduction

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  26. High-performance transparent conducting oxides through small-polaron transport

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  27. Solution‐Processed Ternary Oxides as Carrier Transport/Injection Layers in Optoelectronics

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  28. Assessment of thermodynamic data for CuCrO2 delafossite from calorimetric measurements

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  29. Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst

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  30. Tuneable interplay between atomistic defects morphology and electrical properties of transparent p-type highly conductive off-stoichiometric Cu-Cr-O delafossite thin films

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  31. Efficient Resistive Switching and Spike Rate Dependent Plasticity in a New CuCrO2 Memristor for Plausible Neuromorphic Systems

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  33. p-type transparent superconductivity in a layered oxide

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  34. Innovative development on a p-type delafossite CuCrO2 nanoparticles based triethylamine sensor

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  35. Tunable Syngas Formation from Electrochemical CO 2 Reduction on Copper Nanowire Arrays

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  36. Highly sensitive and selective electrochemical detection of dopamine based on CuCrO2-TiO2 composite decorated screen-printed modified electrode

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  37. Abnormal Deviation of Temperature–Resistivity Correlation for Nanostructured Delafossite CuCrO2 Due to Local Reconfiguration

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  38. Novel construction of carbon nanofiber/CuCrO 2 composite for selective determination of 4-nitrophenol in environmental samples and for supercapacitor application

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  39. Out of stoichiometry CuCrO 2 films as a promising p-type TCO for transparent electronics

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  40. Magnetic, dielectric and optical properties of Al-, Mg-, Co- and Zn-ion–doped CuCrO 2

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  41. The roles of interstitial oxygen and phase compositions on the thermoelectric properties CuCr0.85Mg0.15O2 delafossite material

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  42. Preparation and characterization of delafossite CuCrO2 film on flexible substrate

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  46. An all-sputtered photovoltaic ultraviolet photodetector based on co-doped CuCrO2 and Al-doped ZnO heterojunction

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  47. Plasma-assisted solution combustion synthesis of Mg-incorporated CuCrO2 and AgCrO2 delafossite thin films

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  48. Selective phase transformation of layered double hydroxides into mixed metal oxides for catalytic CO oxidation

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  49. Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4

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  50. A Novel Ternary Metal Oxide Cascade Z-Scheme Heterojunction for Efficient Co2 Photoconversion Without a Co-Catalyst

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