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RESEARCH PAPER · Applied Materials Today · 2017

Invisible electronics: Metastable Cu-vacancies chain defects for highly conductive p-type transparent oxide

Petru Lunca‐Popa, Jonathan Crêpellière, Pavan Nukala, Renaud Leturcq, D. Lenoble

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Invisible electronics: Metastable Cu-vacancies chain defects for highly conductive p-type transparent oxideOriginalMagnetization study in LaCr1−xAlxO3 (0 ≤ x ≤ 0.95)17Tuning the electrical properties of the p-type transparent conducting oxide Cu1−xCr1+xO2 by controlled annealing35Influence of thickness and microstructure on thermoelectric properties of Mg-doped CuCrO2 delafossite thin films deposited by RF-magnetron sputtering33Bending stability of Cu0.4CrO2—A transparent p-type conducting oxide for large area flexible electronics12Are Small Polarons Always Detrimental to Transparent Conducting Oxides ?2Transparent p-Cu0.66Cr1.33O2/n-ZnO heterojunction prepared in a five-step scalable process13Investigation of the structural, optical and electrical properties of Ca 2+ doped CuCoO 2 nanosheets34Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides92Insights on the Stability and Cationic Nonstoichiometry of CuFeO 2 Delafossite40High-performance transparent conducting oxides through small-polaron transport13Introduction of TiO2 in CuI for Its Improved Performance as a p-Type Transparent Conductor54Solution‐Processed Ternary Oxides as Carrier Transport/Injection Layers in Optoelectronics52Functional Oxides for Photoneuromorphic Engineering: Toward a Solar Brain52Crystallographic Characterisation of Ultra-Thin, or Amorphous Transparent Conducting Oxides—The Case for Raman Spectroscopy13Tuneable interplay between atomistic defects morphology and electrical properties of transparent p-type highly conductive off-stoichiometric Cu-Cr-O delafossite thin films20Effects of multi-scale defects on the thermoelectric properties of delafossite CuCr1-xMgxO2 materials27Surfactant-Modified Hydrothermal Synthesis of Ca-Doped CuCoO2 Nanosheets with Abundant Active Sites for Enhanced Electrocatalytic Oxygen Evolution38Indium-Free Alternative Transparent Conducting Electrodes: An Overview and Recent Developments8Out of stoichiometry CuCrO 2 films as a promising p-type TCO for transparent electronics39The roles of interstitial oxygen and phase compositions on the thermoelectric properties CuCr0.85Mg0.15O2 delafossite material19Investigation of crystallinity, electrical conductivity, and optical transmittance of Mg-doped CuCrO2 deposited on buffer layer7Thermodynamic and Structural Properties of CuCrO 2 and CuCr 2 O 4 : Experimental Investigation and Phase Equilibria Modeling of the Cu–Cr–O System21Dependence of mechanical and electrical properties on crystal orientation of CuCr0.95Mg0.05O2 ceramics1Highly transparent and conductive p-type CuI films by optimized solid-iodination at room temperature11A review on the p-type transparent Cu–Cr–O delafossite materials67New record high thermoelectric ZT of delafossite-based CuCrO2 thin films obtained by simultaneously reducing electrical resistivity and thermal conductivity via heavy doping with controlled residual stress15Accelerated Testing and Reliability of FDM-Based Structural Electronics11Highly Conductive and Visibly Transparent p-Type CuCrO2 Films by Ultrasonic Spray Pyrolysis24Heteroepitaxy of Scandium Delafossite on ZnO0A comparative study of the antibacterial properties of copper-based transparent oxides at the solid–liquid interface1Ultra-low-energy catalytic degradation of ozone by off-stoichiometric delafossite Cu–Cr–O for highly selective low-temperature solid-state O3 sensors6Fine-tuning high electrical conductivity of Mg-Doped CuCrO2 delafossite thin films through preferred-(110) orientation and film thickness control10Impact of Zn doping on the structural properties and thermoelectric performance of CuCr 0.85 Mg (0.15-x) Zn x O 2 (x ≤ 0.05) delafossite materials3High-performance p-type V2O3 films by spray pyrolysis for transparent conducting oxide applications18Electrical properties of strained off-stoichiometric Cu–Cr–O delafossite thin films5Critical Review of Cu‐Based Hole Transport Materials for Perovskite Solar Cells: From Theoretical Insights to Experimental Validation30Supercapacitor electrode based on ternary activated carbon/CuCoO2 hybrid material13On the charge transport models in high intrinsic defect doped transparent and conducting p-type Cu–Cr–O delafossite thin films7A Comprehensive Study on the Impact of Off-Stoichiometry and Mg Doping in CuCrO 2 Thin Films for Heterojunction Device Fabrication7Ultrasmooth Mg‐Doped CuCrO 2 Thin Films: Optimizing Thermoelectric Performance for Energy Harvesting0Inorganic Charge Transport Layers for High‐Performance p‐i‐n Perovskite Solar Cells6Extrinsic dopants as growth modifiers in Cu–Cr–O delafossites: a study of incorporation limits and film properties2Defect-driven optoelectronic and magnetic properties of Delafossite materials for photocatalytic, energy, and biomedical applications2Defect-mediated carrier transport in MgTi co-doped CuCrO2 thin films via donor–acceptor compensation for thermoelectric applications0

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  1. Magnetization study in LaCr1−xAlxO3 (0 ≤ x ≤ 0.95)

    Ceramics International · 2017-12-23

    Romualdo Santos Silva Junior, Jose Albino Aguiar, Petrucio Barrozo

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  2. Tuning the electrical properties of the p-type transparent conducting oxide Cu1−xCr1+xO2 by controlled annealing

    Scientific Reports · 2018-05-02

    Petru Lunca‐Popa, João Ricardo Antunes Afonso, Patrick Grysan, Jonathan Crêpellière, Renaud Leturcq, D. Lenoble

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  3. Influence of thickness and microstructure on thermoelectric properties of Mg-doped CuCrO2 delafossite thin films deposited by RF-magnetron sputtering

    Applied Surface Science · 2018-05-19

    Inthuga Sinnarasa, Yohann Thimont, Lionel Presmanes, Corine Bonningue, Antoine Barnabé, Philippe Tailhades

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  4. Bending stability of Cu0.4CrO2—A transparent p-type conducting oxide for large area flexible electronics

    AIP Advances · 2018-08-01

    Emma Norton, Leo Farrell, Ainur Zhussupbekova, Daragh Mullarkey, David F. Caffrey, Dorina T. Papanastasiou, Dorian Oser, Daniel Bellet, Igor V Shvets, K. Fleischer

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  5. Are Small Polarons Always Detrimental to Transparent Conducting Oxides ?

    arXiv (Cornell University) · 2018-10-11

    Guillaume Brunin, Gian‐Marco Rignanese, Geoffroy Hautier

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  6. Transparent p-Cu0.66Cr1.33O2/n-ZnO heterojunction prepared in a five-step scalable process

    Journal of Materials Science Materials in Electronics · 2018-11-28

    João Ricardo Antunes Afonso, Renaud Leturcq, Petru Lunca‐Popa, D. Lenoble

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  7. Investigation of the structural, optical and electrical properties of Ca 2+ doped CuCoO 2 nanosheets

    Dalton Transactions · 2019-01-01

    Zijuan Du, Dehua Xiong, Jinchen Qian, Tianyang Zhang, Jilin Bai, De Fang, Hong Li

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  8. Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides

    Coatings · 2019-02-20

    Nengduo Zhang, Jian Sun, Hao Gong

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  9. Insights on the Stability and Cationic Nonstoichiometry of CuFeO 2 Delafossite

    Inorganic Chemistry · 2019-04-22

    Juliano Schorne Pinto, Laurent Cassayre, Lionel Presmanes, Antoine Barnabé

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  10. High-performance transparent conducting oxides through small-polaron transport

    Physical Review Materials · 2019-06-13

    Guillaume Brunin, Gian‐Marco Rignanese, Geoffroy Hautier

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  11. Introduction of TiO2 in CuI for Its Improved Performance as a p-Type Transparent Conductor

    ACS Applied Materials & Interfaces · 2019-06-17

    Vidur Raj, Teng Lü, Mark Lockrey, Rong Liu, Felipe Kremer, Li Li, Yun Liu, Hark Hoe Tan, C. Jagadish

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  12. Solution‐Processed Ternary Oxides as Carrier Transport/Injection Layers in Optoelectronics

    Advanced Energy Materials · 2019-07-01

    Zhanfeng Huang, Dan Ouyang, Chun‐Jen Shih, Boping Yang, Wallace C. H. Choy

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  13. Functional Oxides for Photoneuromorphic Engineering: Toward a Solar Brain

    Advanced Materials Interfaces · 2019-07-11

    Amador Pérez‐Tomás

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  14. Crystallographic Characterisation of Ultra-Thin, or Amorphous Transparent Conducting Oxides—The Case for Raman Spectroscopy

    Materials · 2020-01-07

    David F. Caffrey, Ainur Zhussupbekova, Rajani K. Vijayaraghavan, Ardak Ainabаyev, Aitkazy Kaisha, Gulnar K. Sugurbekova, Igor V Shvets, K. Fleischer

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  15. Tuneable interplay between atomistic defects morphology and electrical properties of transparent p-type highly conductive off-stoichiometric Cu-Cr-O delafossite thin films

    Scientific Reports · 2020-01-29

    Petru Lunca‐Popa, Jacques Botsoa, Mounib Bahri, Jonathan Crêpellière, P. Desgardin, Jean‐Nicolas Audinot, Tom Wirtz, Didier Arl, Ovidiu Ersen, M.F. Barthe, D. Lenoble

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  16. Effects of multi-scale defects on the thermoelectric properties of delafossite CuCr1-xMgxO2 materials

    Journal of Alloys and Compounds · 2020-06-25

    Dung Van Hoang, Anh Tuấn Thanh Phạm, Hanh Kieu Thi Ta, Trương Hữu Nguyễn, Ngoc Kim Pham, Thi Hoa Lai, Vinh Cao Trần, Michitaka Ohtaki, Nhat Quang Minh Tran, Jong-Ho Park, Jae-Ki Lee, Su-Dong Park, Tae‐Seong Ju, Hongjun Park, Sungkyun Park, Thắng Bách Phan

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  17. Surfactant-Modified Hydrothermal Synthesis of Ca-Doped CuCoO2 Nanosheets with Abundant Active Sites for Enhanced Electrocatalytic Oxygen Evolution

    Inorganic Chemistry · 2020-07-07

    Zijuan Du, Jinchen Qian, Jilin Bai, Hong Li, Mingkui Wang, Xiujian Zhao, Dehua Xiong

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  18. Indium-Free Alternative Transparent Conducting Electrodes: An Overview and Recent Developments

    Environmental chemistry for a sustainable world · 2020-10-05

    R. Ramarajan, D. Paul Joseph, Kuppusamy Thangaraju, M. Kovendhan

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  19. Out of stoichiometry CuCrO 2 films as a promising p-type TCO for transparent electronics

    Materials Advances · 2021-01-01

    Lorenzo Bottiglieri, João Resende, Matthieu J. Weber, Odette Chaix‐Pluchery, Carmen Jiménez, Jean‐Luc Deschanvres

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  20. The roles of interstitial oxygen and phase compositions on the thermoelectric properties CuCr0.85Mg0.15O2 delafossite material

    Journal of Alloys and Compounds · 2021-02-03

    Dung Van Hoang, Tu Anh Kieu Le, Anh Tuấn Thanh Phạm, Hanh Kieu Thi Ta, Ngoc Kim Pham, Trương Hữu Nguyễn, Hoa Thi Lai, Dai Cao Truong, Ngoc Van Le, Cong Thanh Huynh, Sunglae Cho, Hongjun Park, Sehwan Song, Sunkyun Park, Takao Mori, Vinh Cao Trần, Thắng Bách Phan

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  21. Investigation of crystallinity, electrical conductivity, and optical transmittance of Mg-doped CuCrO2 deposited on buffer layer

    Materials Science in Semiconductor Processing · 2021-06-24

    Takeru Okada, Shoya Usui, Tomoyuki Kawashima, Katsuyoshi Washio

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  22. Thermodynamic and Structural Properties of CuCrO 2 and CuCr 2 O 4 : Experimental Investigation and Phase Equilibria Modeling of the Cu–Cr–O System

    The Journal of Physical Chemistry C · 2021-07-02

    Juliano Schorne Pinto, Patrice Chartrand, Antoine Barnabé, Laurent Cassayre

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  23. Dependence of mechanical and electrical properties on crystal orientation of CuCr0.95Mg0.05O2 ceramics

    Journal of Physics Conference Series · 2021-09-01

    Dung Van Hoang, Anh Tuấn Thanh Phạm, Trương Hữu Nguyễn, Dai Cao Truong, Ngoc Kim Pham, Hanh Kieu Thi Ta, Thu Bao Nguyen Le, Vinh Cao Trần, Thắng Bách Phan

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  24. Highly transparent and conductive p-type CuI films by optimized solid-iodination at room temperature

    Nanotechnology · 2021-10-06

    Shulin Luo, Jing Lei Xu, Jianhong Gong, Ruisong You, Yong Wang, Songsheng Lin, Mingjiang Dai, Hui Sun

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  25. A review on the p-type transparent Cu–Cr–O delafossite materials

    Journal of Materials Science · 2022-01-17

    Marco Moreira, João Ricardo Antunes Afonso, Jonathan Crêpellière, D. Lenoble, Petru Lunca‐Popa

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  26. New record high thermoelectric ZT of delafossite-based CuCrO2 thin films obtained by simultaneously reducing electrical resistivity and thermal conductivity via heavy doping with controlled residual stress

    Applied Surface Science · 2022-01-19

    Dung Van Hoang, Anh Tuấn Thanh Phạm, Takahiro Baba, Trương Hữu Nguyễn, Thu Bao Nguyen Le, Ung Thi Dieu Thuy, Jongill Hong, Jong‐Seong Bae, Hongjun Park, Sungkyun Park, I. Ohkubo, Takao Mori, Vinh Cao Trần, Thắng Bách Phan

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  27. Accelerated Testing and Reliability of FDM-Based Structural Electronics

    Applied Sciences · 2022-01-21

    Bartłomiej Wałpuski, Marcin Słoma

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  28. Highly Conductive and Visibly Transparent p-Type CuCrO2 Films by Ultrasonic Spray Pyrolysis

    ACS Applied Materials & Interfaces · 2022-02-25

    Jaewon Kim, Owen Kendall, Jiawen Ren, Billy James Murdoch, Chris F. McConville, Joel van Embden, Enrico Della Gaspera

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  29. Heteroepitaxy of Scandium Delafossite on ZnO

    physica status solidi (b) · 2022-04-14

    S. Grenier, Fabrice Donatini, E. Mossang, Pierre Muret

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  30. A comparative study of the antibacterial properties of copper-based transparent oxides at the solid–liquid interface

    Japanese Journal of Applied Physics · 2022-09-12

    Takeru Okada, Kotaro Ohno, Makoto Kanzaki, Katsuyoshi Washio

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  31. Ultra-low-energy catalytic degradation of ozone by off-stoichiometric delafossite Cu–Cr–O for highly selective low-temperature solid-state O3 sensors

    Materials Today Advances · 2023-04-05

    João Ricardo Antunes Afonso, Mark T. Greiner, Petru Lunca‐Popa, Jean‐Pierre Raskin, D. Lenoble

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  32. Fine-tuning high electrical conductivity of Mg-Doped CuCrO2 delafossite thin films through preferred-(110) orientation and film thickness control

    Physica B Condensed Matter · 2023-07-31

    Dung Van Hoang, Hanh Duc Thi Dinh, Trương Hữu Nguyễn, Anh Tuấn Thanh Phạm, Uyen Tu Thi Doan, Trang Thuy Thi Phan, Ke Huu Nguyen, Thắng Bách Phan, Vinh Cao Trần

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  33. Impact of Zn doping on the structural properties and thermoelectric performance of CuCr 0.85 Mg (0.15-x) Zn x O 2 (x ≤ 0.05) delafossite materials

    Advanced Composite Materials · 2024-01-02

    Dung Van Hoang, Anh Tuấn Thanh Phạm, Trương Hữu Nguyễn, Thắng Bách Phan, Vinh Cao Trần

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  34. High-performance p-type V2O3 films by spray pyrolysis for transparent conducting oxide applications

    Scientific Reports · 2024-01-22

    Ardak Ainabаyev, Brian Walls, Daragh Mullarkey, David F. Caffrey, K. Fleischer, Christopher Michael Smith, Amy McGlinchey, Daniel Casey, Sarah J. McCormack, Igor V Shvets

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  35. Electrical properties of strained off-stoichiometric Cu–Cr–O delafossite thin films

    Journal of Physics Condensed Matter · 2024-02-16

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  36. Critical Review of Cu‐Based Hole Transport Materials for Perovskite Solar Cells: From Theoretical Insights to Experimental Validation

    Advanced Materials · 2024-05-20

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  37. Supercapacitor electrode based on ternary activated carbon/CuCoO2 hybrid material

    Materials Chemistry and Physics · 2024-05-29

    Katia Ait Kaci Azzou, Achour Terbouche, Chafia Ait Ramdane-Terbouche, Thierry Bataille B, Didier Hauchard, Djillali Mezaoui

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  38. On the charge transport models in high intrinsic defect doped transparent and conducting p-type Cu–Cr–O delafossite thin films

    Journal of Physics D Applied Physics · 2024-09-26

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  39. A Comprehensive Study on the Impact of Off-Stoichiometry and Mg Doping in CuCrO 2 Thin Films for Heterojunction Device Fabrication

    ACS Applied Electronic Materials · 2025-01-02

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  40. Ultrasmooth Mg‐Doped CuCrO 2 Thin Films: Optimizing Thermoelectric Performance for Energy Harvesting

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  41. Inorganic Charge Transport Layers for High‐Performance p‐i‐n Perovskite Solar Cells

    ChemSusChem · 2025-11-16

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  42. Extrinsic dopants as growth modifiers in Cu–Cr–O delafossites: a study of incorporation limits and film properties

    Journal of Materials Science · 2025-12-23

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  43. Defect-driven optoelectronic and magnetic properties of Delafossite materials for photocatalytic, energy, and biomedical applications

    Coordination Chemistry Reviews · 2026-04-11

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  44. Defect-mediated carrier transport in MgTi co-doped CuCrO2 thin films via donor–acceptor compensation for thermoelectric applications

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