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RESEARCH PAPER · Coordination Chemistry Reviews · 2015

Ionic metal-organic frameworks (iMOFs): Design principles and applications

Avishek Karmakar, Aamod V. Desai, Sujit K. Ghosh

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Ionic metal-organic frameworks (iMOFs): Design principles and applicationsOriginalNeutral N-donor ligand based flexible metal–organic frameworks86An anionic zeolite-like metal–organic framework (AZMOF) with a Moravia network for organic dye absorption through cation-exchange41Anionic metal–organic frameworks lead the way to eco-friendly high-energy-density materials91Anionic porous polymers with tunable structures and catalytic properties31Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives368Structural variation of transition metal coordination polymers based on bent carboxylate and flexible spacer ligand: polymorphism, gas adsorption and SC-SC transmetallation35Tuning the properties of the metal–organic framework UiO-67-bpy via post-synthetic N-quaternization of pyridine sites75A Water‐Stable Cationic Metal–Organic Framework as a Dual Adsorbent of Oxoanion Pollutants351A Water‐Stable Cationic Metal–Organic Framework as a Dual Adsorbent of Oxoanion Pollutants73Novel 3d/4f Metal Organic Networks Containing CoII Chiral Chains28Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−6ChemInform Abstract: Ionic Metal‐Organic Frameworks (IMOFs): Design Principles and Applications0A Bifunctional Metal–Organic Framework: Striking CO 2 ‐Selective Sorption Features along with Guest‐Induced Tuning of Luminescence16Emerging adsorptive removal of azo dye by metal–organic frameworks271Interconvertible structural transformations between two Zn(II) interpenetrating coordination polymers4Zn(II) and Cd(II) complexes assembled from versatile 1,2,3,5-benzenetetracarboxylic acid and chelating N-donor auxiliary coligands16N-donor co-ligands driven two new Co(II)- coordination polymers with bi- and trinuclear units: Crystal structures, and magnetic properties8A New Approach to Non-Coordinating Anions: Lewis Acid Enhancement of Porphyrin Metal Centers in a Zwitterionic Metal–Organic Framework101Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores213Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores54Positional isomeric effect on CuII and CdII complexes based on perfluorinated dicarboxylate ligands and bipyridyl co-tectons8Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water206M(II)-dipyridylamide-based coordination frameworks (M=Mn, Co, Ni): Structural transformation3A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2 Gas over CO Gas in the Solid State52A PCP Pincer Ligand for Coordination Polymers with Versatile Chemical Reactivity: Selective Activation of CO2 Gas over CO Gas in the Solid State7Construction of Noninterpenetrating and Interpenetrating (4-Fold and 8-Fold) 3-D Cd(II) Networks with Tris(1,2,4-triazol-4-yl)phenyl)amine Modulated by Aromatic Dicarboxylate Coligands43Nanocage containing metal-organic framework constructed from a newly designed low symmetry tetra-pyrazole ligand6Structural Investigation of a Flexible MOF [Cu(BF4)2(1,3-bis(4-pyridyl)propane)2] Showing Selective Gate Adsorption with Dynamic Pore-Opening/Pore-Closing Processes32Mixed matrix membranes based on UiO-66 MOFs in the polymer of intrinsic microporosity PIM-1199Removal of Pertechnetate‐Related Oxyanions from Solution Using Functionalized Hierarchical Porous Frameworks137Supramolecular Assemblies, Luminescence and Anion Exchange of Helical Pb(II) Complexes Based on Enantiomeric N-(2-pyridylmethyl) Alanine Ligands1Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions509A Rigid Nested Metal–Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions192A Rigid Nested Metal–Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions23Exploring 4-(3-carboxyphenyl)picolinic acid as a semirigid building block for the hydrothermal self-assembly of diverse metal–organic and supramolecular networks16Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand21Aqueous phase sensing of cyanide ions using a hydrolytically stable metal–organic framework63An anionic metal–organic framework with ternary building units for rapid and selective adsorption of dyes95An anionic Na( i )–organic framework platform: separation of organic dyes and post-modification for highly sensitive detection of picric acid132An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors1210Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism87Luminescent lanthanide metal–organic frameworks for chemical sensing and toxic anion detection68Metal–organic frameworks: functional luminescent and photonic materials for sensing applications3050Synthesis, structure, characterization, and multifunctional properties of a family of rare earth organic frameworks24Trends and challenges for microporous polymers479Two (5,5)-connected isomeric frameworks as highly selective and sensitive photoluminescent probes of nitroaromatics19Anionic Lanthanide MOFs as a Platform for Iron-Selective Sensing, Systematic Color Tuning, and Efficient Nanoparticle Catalysis167Highly selective and sensitive detection of 4-nitrophenol and Fe3+ ion based on a luminescent layered terbium (III) coordination polymer81Syntheses, Structural Evolutions, and Properties of Cd(II) Coordination Polymers Induced by Bis(pyridyl) Ligand with Chelated or Protonated Spacer and Diverse Counteranions14Hydrolytically Stable Luminescent Cationic Metal Organic Framework for Highly Sensitive and Selective Sensing of Chromate Anions in Natural Water Systems256Local Deprotonation Enables Cation Exchange, Porosity Modulation, and Tunable Adsorption Selectivity in a Metal–Organic Framework28Significant Proton Conductivity Enhancement through Rapid Water-Induced Structural Transformation from a Cationic Framework to a Water-Rich Neutral Chain31Influence of N-donor ancillary ligands on the structures of three cadmium(II) complexes with L-shaped carboxylate ligand13Water‐Mediated Structural Transformations of CuII 5‐Halonicotinates Coordination Networks with Distinct Mechanisms11In-situ Selenization of Co-based Metal-Organic Frameworks as a Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction104Mixed sulfoisophthalate and 1,2,4-triazole directed d 10 metal coordination polymers: Synthesis, property and structural diversity10Self-assembly of coordination polymers of Pr(III), Nd(III), Tb(III), Dy(III) and Ho(III) with 5-hydroxyisophthalic acid and adipic acid: Syntheses, structures, porosity, luminescence and magnetic properties23Guest-Responsive Metal–Organic Frameworks as Scaffolds for Separation and Sensing Applications279Metal‐Organic Frameworks (MOFs) as Functional Supramolecular Architectures for Anion Recognition and Sensing49Metal–Organic Frameworks assembled from tetraphosphonic ligands and lanthanides105A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants409Solvent-controlled synthesis of various Anderson-type polyoxometalate-based metal–organic complexes with excellent capacity for the chromatographic separation of dyes37An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO 2 fixation into cyclic carbonate179Metal–organic frameworks and porous organic polymers for sustainable fixation of carbon dioxide into cyclic carbonates444Suspending ionic single-atom catalysts in porphyrinic frameworks for highly efficient aerobic oxidation at room temperature28A charge-separated diamondoid metal–organic framework12A new metal–organic framework constructed from cationic nodes and cationic linkers for highly efficient anion exchange43A new series of Co, Ni, Zn, and Cd metal–organic architectures driven by an unsymmetrical biphenyl-tricarboxylic acid: hydrothermal assembly, structural features and properties25Chemically stable ionic viologen-organic network: an efficient scavenger of toxic oxo-anions from water132New synthetic strategies to prepare metal–organic frameworks306Photonic functional metal–organic frameworks661Polymorphism of a porous hydrogen bond-assisted ionic organic framework7Selective molecular-gating adsorption in a novel copper-based metal–organic framework36Spatial confinement of a cationic MOF: a SC–SC approach for high capacity Cr( vi )-oxyanion capture in aqueous solution176Syntheses, crystal structures, and properties of two dinuclear iron(III) complexes constructed with 1,2,3,5-benzenetetracarboxylic acid and chelating N-donor auxiliary coligands2Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion16A Comparative Investigation of Proton Conductivities for Two Metal−Organic Frameworks under Water and Aqua-Ammonia Vapors76A Zwitterionic Ligand‐Based Cationic Metal‐Organic Framework for Rapidly Selective Dye Capture and Highly Efficient Cr2O72− Removal76Metal–organic frameworks with catalytic centers: From synthesis to catalytic application486Distinct supramolecular assemblies of nickel(II) complexes constructed from N-(4-pyridylmethyl)-l-amino acid derivatives: Synergistic effects of substituent groups and counter anions8Two Cd(II) coordination polymers based on tris(p-carboxylphenyl)phosphine oxide accompanied by in situ ligand formation4Two water-stable 3D supramolecules supported by hydrogen bonds for proton conduction38Base-Resistant Ionic Metal-Organic Framework as a Porous Ion-Exchange Sorbent60Structural Design and Properties of Coordination Polymers4Dye confined in metal-organic framework for two-photon fluorescent temperature sensing26Potential of metal–organic frameworks for adsorptive separation of industrially and environmentally relevant liquid mixtures130Li-Crown ether complex inclusion in MOF materials for enhanced H2 volumetric storage capacity at room temperature56Metal–organic framework assembled from erbium and a tetrapodal polyphosphonic acid organic linker4A Porous Framework as a Variable Chemosensor: From the Response of a Specific Carcinogenic Alkyl‐Aromatic to Selective Detection of Explosive Nitroaromatics26Construction of mixed-valence Cu(I)/Cu(II) 3-D framework and its photocatalytic activities9Two metal–organic frameworks based on carboxyphenyl–terpyridine ligands: Synthesis, structure and highly luminescent sensing of nitrobenzene27Goal‐Directed Design of Metal–Organic Frameworks for HgII and PbII Adsorption from Aqueous Solutions47A Zn based anionic metal-organic framework for trace Hg2+ ion detection25A 3D supramolecular assembly of Co(II) MOF constructed with 2,5-pyridinedicarboxylate strut and its catalytic activity towards synthesis of tetrahydrobiphenylene-1,3-dicarbonitriles16Beyond pristine metal-organic frameworks: Preparation and application of nanostructured, nanosized, and analogous MOFs173The role of the counter-ion in metal-organic frameworks’ chemistry and applications204Enhancing Proton Conductivity of a 3D Metal–Organic Framework by Attaching Guest NH3 Molecules67Synthesis and structural elucidation of neutral N-donor linker based bi-porous isostructural cationic metal-organic frameworks4A Zn(II)-based pillar-layered metal–organic framework: Synthesis, structure, and CO2 selective adsorption20A Highly Proton-Conductive 3D Ionic Cadmium–Organic Framework for Ammonia and Amines Impedance Sensing107Cu(I)-Based Metal–Organic Frameworks as Efficient and Recyclable Heterogeneous Catalysts for Aqueous-Medium C–H Oxidation20A mesoporous cationic metal–organic framework with a high density of positive charge for enhanced removal of dichromate from water33A survey on application of MOFs in chemistry2Amide-functionalized ionic indium–organic frameworks for efficient separation of organic dyes based on diverse adsorption interactions43Construction of three-dimensional anionic molecular frameworks based on hydrogen-bonded metal dithiolene complexes and the crystal solvent effect12Design and Applications of Charge-Separated Metal-Organic Frameworks0Dynamic self-assembly of ions with variable size and charge in solution7Metal-organic frameworks for recognition and sequestration of toxic anionic pollutants9Multifunctional anionic indium–organic frameworks for organic dye separation, white-light emission and dual-emitting Fe 3+ sensing37Phosphonium zwitterions for lighter and chemically-robust MOFs: highly reversible H 2 S capture and solvent-triggered release31Ultra-highly selective trapping of perrhenate/pertechnetate by a flexible cationic coordination framework61Tuning the Ionicity of Stable Metal–Organic Frameworks through Ionic Linker Installation101Efficient Fe‐Co‐N‐C Electrocatalyst Towards Oxygen Reduction Derived from a Cationic CoII‐based Metal–Organic Framework Modified by Anion‐Exchange with Potassium Ferricyanide30Theoretical studies of the adamantane-like [Ag24(trz)18]n nanocages with n = 0, +2, +4 and +61Successful Decontamination of 99 TcO 4 − in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets48Successful Decontamination of 99TcO4− in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets267Synthesis of DtBuCH18C6-coated magnetic metal–organic framework Fe3O4@UiO-66-NH2 for strontium adsorption38Introduction to Metal‐Organic Frameworks1Nanosized Functional MOFs Loading Ag/AgBr with Throughout‐Visible‐Light Absorption for High‐Efficiency Photocatalysis7Water adsorption/desorption over metal-organic frameworks with ammonium group for possible application in adsorption heat transformation69N-donor linker based metal-organic frameworks (MOFs): Advancement and prospects as functional materials146Design strategies and applications of charged metal organic frameworks104Design of a Multifunctional Indium–Organic Framework: Fluorescent Sensing of Nitro Compounds, Physical Adsorption, and Photocatalytic Degradation of Organic Dyes83Integrating cationic metal-organic frameworks with ultrafiltration membrane for selective removal of perchlorate from Water48Smart cationic coordination polymer: A single-crystal-to-single-crystal approach for simultaneous detection and removal of perchlorate in aqueous media19Two entangled photoluminescent MOFs of naphthalenedisulfonate and bis(benzimidazole) ligands for selective sensing of Fe3+36Polymerization of Counteranions in the Cationic Nanopores of a Cross-linked Lyotropic Liquid Crystal Network to Modify Ion Transport Properties14An Ion‐Exchangeable MOF with Reversible Dehydration and Dynamic Structural Behavior (NH4)2[Zn2(O3PCH2CH2COO)2]⋅5 H2O (BIRM‐1)1Anion‐directed Silver(I) Coordination Assemblies Based on 1‐(2‐Pyridyl)‐2‐(4‐pyridyl)‐1,2,4‐triazolewith Diverse Supramolecular Networks and Dichromate Removal Capabilities1Photophysical Tuning of Viologen-Based Metal–Organic Framework Hybrids via Anion Exchange and Chemical Sensing on Persulfate (S2O82–)15A Dye@MOF composite as luminescent sensory material for selective and sensitive recognition of Fe(III) ions in water46Specific recognition of toxic allyl alcohol by pore-functionalized metal–organic frameworks9Probing the Role of Anions in Influencing the Structure, Stability, and Properties in Neutral N-Donor Linker Based Metal–Organic Frameworks32Proton conductive carboxylate-based metal–organic frameworks302Dual-Functionalized Fluorescent Cationic Organic Network: Highly Efficient Detection and Removal of Dichromate from Water50A Thiophene-2-carboxamide-Functionalized Zr(IV) Organic Framework as a Prolific and Recyclable Heterogeneous Catalyst for Regioselective Ring Opening of Epoxides26Lanthanide coordination polymers of viologen carboxylic acid: Crystal structures and luminescence response tuning9Various Anderson-type polyoxometalate-based metal–organic complexes induced by diverse solvents: assembly, structures and selective adsorption for organic dyes44Selective and sensitive recognition of Fe3+ ion by a Lewis basic functionalized chemically stable metal-organic framework (MOF)33A series of anionic MOFs with cluster-based, pillared-layer and rod-spacer motifs: near-sunlight white-light emission and selective dye capture13Surface modified colloidal silica nanoparticles: Novel aspect for complete identification of explosive materials14A tubular luminescent framework: precise decoding of nitroaniline isomers and quantitative detection of traces of benzaldehyde in benzyl alcohol19Architectural and catalytic aspects of designer materials built using metalloligands of pyridine-2,6-dicarboxamide based ligands20Luminescent metal–organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants180Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials21Selective CO 2 or CH 4 adsorption of two anionic bcu-MOFs with two different counterions: experimental and simulation studies9Utilization of counter anions for charge transportation in the electrical device fabrication of Zn( ii ) metal–organic frameworks11A Comparison of Two Isoreticular Metal–Organic Frameworks with Cationic and Neutral Skeletons: Stability, Mechanism, and Catalytic Activity91A Comparison of Two Isoreticular Metal–Organic Frameworks with Cationic and Neutral Skeletons: Stability, Mechanism, and Catalytic Activity10Organic Counteranion Co-assembly Strategy for the Formation of γ-Cyclodextrin-Containing Hybrid Frameworks45

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  1. Neutral N-donor ligand based flexible metal–organic frameworks

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  2. An anionic zeolite-like metal–organic framework (AZMOF) with a Moravia network for organic dye absorption through cation-exchange

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  5. Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives

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  6. Structural variation of transition metal coordination polymers based on bent carboxylate and flexible spacer ligand: polymorphism, gas adsorption and SC-SC transmetallation

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  7. Tuning the properties of the metal–organic framework UiO-67-bpy via post-synthetic N-quaternization of pyridine sites

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  8. A Water‐Stable Cationic Metal–Organic Framework as a Dual Adsorbent of Oxoanion Pollutants

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  9. A Water‐Stable Cationic Metal–Organic Framework as a Dual Adsorbent of Oxoanion Pollutants

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  10. Novel 3d/4f Metal Organic Networks Containing CoII Chiral Chains

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  11. Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−

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  12. ChemInform Abstract: Ionic Metal‐Organic Frameworks (IMOFs): Design Principles and Applications

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  13. A Bifunctional Metal–Organic Framework: Striking CO 2 ‐Selective Sorption Features along with Guest‐Induced Tuning of Luminescence

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  30. Removal of Pertechnetate‐Related Oxyanions from Solution Using Functionalized Hierarchical Porous Frameworks

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  31. Supramolecular Assemblies, Luminescence and Anion Exchange of Helical Pb(II) Complexes Based on Enantiomeric N-(2-pyridylmethyl) Alanine Ligands

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  32. Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions

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  33. A Rigid Nested Metal–Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions

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  34. A Rigid Nested Metal–Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions

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  35. Exploring 4-(3-carboxyphenyl)picolinic acid as a semirigid building block for the hydrothermal self-assembly of diverse metal–organic and supramolecular networks

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  36. Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

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  37. Aqueous phase sensing of cyanide ions using a hydrolytically stable metal–organic framework

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    Avishek Karmakar, Biplab Joarder, Abhik Mallick, Partha Samanta, Aamod V. Desai, Sudipta Basu, Sujit K. Ghosh

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  38. An anionic metal–organic framework with ternary building units for rapid and selective adsorption of dyes

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  39. An anionic Na( i )–organic framework platform: separation of organic dyes and post-modification for highly sensitive detection of picric acid

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    Di‐Ming Chen, Jia‐Yue Tian, Zhuo‐Wei Wang, Chun‐Sen Liu, Min Chen, Miao Du

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  40. An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors

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  41. Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

    CrystEngComm · 2017-01-01

    Jin‐Zhong Gu, Xiao-Xiao Liang, Yan-Hui Cui, Jiang Wu, Zi‐Fa Shi, Alexander M. Kirillov

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  42. Luminescent lanthanide metal–organic frameworks for chemical sensing and toxic anion detection

    Dalton Transactions · 2017-01-01

    Ruizhi Wu, Xing Yang, Liangwei Zhang, Panpan Zhou

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  43. Metal–organic frameworks: functional luminescent and photonic materials for sensing applications

    Chemical Society Reviews · 2017-01-01

    William P. Lustig, Soumya Mukherjee, Nathan D. Rudd, Aamod V. Desai, Jing Li, Sujit K. Ghosh

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  44. Synthesis, structure, characterization, and multifunctional properties of a family of rare earth organic frameworks

    CrystEngComm · 2017-01-01

    Haoran Li, Tian‐Lu Sheng, Zhen‐Zhen Xue, Xiao‐Quan Zhu, Shengmin Hu, Yuehong Wen, Ruibiao Fu, Chao Zhuo, Xintao Wu

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  45. Trends and challenges for microporous polymers

    Chemical Society Reviews · 2017-01-01

    Nicolas Chaoui, Matthias Trunk, Robert Dawson, Johannes Schmidt, Arne Thomas

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  46. Two (5,5)-connected isomeric frameworks as highly selective and sensitive photoluminescent probes of nitroaromatics

    CrystEngComm · 2017-01-01

    Yue Dai, Huajun Zhou, Xuedan Song, Jianjun Zhang, Ce Hao, Ling Di, Yuanxia Wang, Jun Ni, Hui‐Long Wang

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  47. Anionic Lanthanide MOFs as a Platform for Iron-Selective Sensing, Systematic Color Tuning, and Efficient Nanoparticle Catalysis

    Inorganic Chemistry · 2017-01-10

    Ya‐Pan Wu, Guo‐Wang Xu, Wen‐Wen Dong, Jun Wei Zhao, Dong‐Sheng Li, Jian Zhang, Xianhui Bu

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  48. Highly selective and sensitive detection of 4-nitrophenol and Fe3+ ion based on a luminescent layered terbium (III) coordination polymer

    Sensors and Actuators B Chemical · 2017-01-27

    Raji Feyisa Bogale, Yanzhen Chen, Junwei Ye, Yaoyao Yang, Abdul Rauf, Liying Duan, Peng Tian, Guiling Ning

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  49. Syntheses, Structural Evolutions, and Properties of Cd(II) Coordination Polymers Induced by Bis(pyridyl) Ligand with Chelated or Protonated Spacer and Diverse Counteranions

    Crystal Growth & Design · 2017-04-13

    Fa-Yuan Ge, Xin Ma, Dandan Guo, Li−Na Zhu, Zhao‐Peng Deng, Li-Hua Huo, Shan Gao

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  50. Hydrolytically Stable Luminescent Cationic Metal Organic Framework for Highly Sensitive and Selective Sensing of Chromate Anions in Natural Water Systems

    ACS Applied Materials & Interfaces · 2017-04-25

    Wei Liu, Yanlong Wang, Zhuanling Bai, Yuxiang Li, Yaxing Wang, Lanhua Chen, Lin Xu, Juan Diwu, Zhifang Chai, Shuao Wang

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