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RESEARCH PAPER · Angewandte Chemie International Edition · 2012

Multiferroics by Rational Design: Implementing Ferroelectricity in Molecule‐Based Magnets

Emilio Pardo, Cyrille Train, Hongbo Liu, Lise‐Marie Chamoreau, Brahim Dkhil, K. Boubekeur, Francesc Lloret, Keitaro Nakatani, Hiroko Tokoro, Shin‐ichi Ohkoshi, Michel Verdaguer

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Multiferroics by Rational Design: Implementing Ferroelectricity in Molecule‐Based MagnetsOriginalTopological Versatility of Oxalate-Based Bimetallic One-Dimensional (1D) Compounds Associated with Ammonium Cations37The Role of Order–Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)–Iron(III) Formate Framework141A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties86First one-dimensional homochiral stairway-like Cu(ii) chains: crystal structures, circular dichroism (CD) spectra, ferroelectricity and antiferromagnetic properties19Fundamentals, Principles, and Concepts of Molecular Magnetism and Spintronics10Self-assembly of a chiral three-dimensional manganese(ii)–copper(ii) coordination polymer with a double helical architecture19The odd association of a C3h trisamidinium cation and tosylate anion with a series of linear oxalate-bridged trinuclear heterometallic complexes15Hybrid Improper Ferroelectricity in a Multiferroic and Magnetoelectric Metal‐Organic Framework338Insertion of FeII complexes with Schiff base ligands derived from imidazole or pyridine into 3D bimetallic oxalate-based ferromagnets14Stimuli Responsive Hybrid Magnets: Tuning the Photoinduced Spin-Crossover in Fe(III) Complexes Inserted into Layered Magnets61Ferroelectric Switchable Behavior through Fast Reversible De/adsorption of Water Spirals in a Chiral 3D Metal–Organic Framework133Super-Ionic Conductive Magnet Based on a Cyano-Bridged Mn–Nb Bimetal Assembly24Three isomeric copper(II) coordination polymers based on a bis-triazole-bis-amide ligand: Assembly, structures, and luminescent properties7New Multi-Ferrocenyl- and Multi-Ferricenyl- Materials via Coordination-Driven Self-Assembly and via Charge-Driven Electro-Crystallization12Synthesis and Crystal Structures of Various Phases of the Microporous Three-Dimensional Coordination Polymer [Zr(OH)2(C2O4)]n16Tuning the Ferroelectric Polarization in a Multiferroic Metal–Organic Framework294Extremely Long Cu···O Contact as a Possible Pathway for Magnetic Interactions in Na2Cu(CO3)217Insertion of a Single‐Molecule Magnet inside a Ferromagnetic Lattice Based on a 3D Bimetallic Oxalate Network: Towards Molecular Analogues of Permanent Magnets47[NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering187Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity39Oxamato-based coordination polymers: recent advances in multifunctional magnetic materials115New Metal Phthalocyanines/Metal Simple Hydroxide Multilayers: Experimental Evidence of Dipolar Field-Driven Magnetic Behavior21Chirality Transfer in Magnetic Coordination Complexes Monitored by Vibrational and Electronic Circular Dichroism16Solid-state cis–trans isomerism in bis(oxamato)palladate( ii ) complexes: synthesis, structural studies and catalytic activity16Ferrocenylethynyl - a versatile platform for new molecules to novel materials1[(C 2 H 5 ) 4 N][U 2 O 4 (HCOO) 5 ], an Ammonium Uranyl Formate Framework Showing Para- to Ferro-Electric Transition: Synthesis, Structures, and Properties17Unprecedented Sensitization of Visible and Near‐Infrared Lanthanide Luminescence by Using a Tetrathiafulvalene‐Based Chromophore26Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework195Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared via a Mild, Two-Step Hydrothermal Method27A 3D Oxalate-Based Network as a Precursor for the CoMn 2 O 4 Spinel: Synthesis and Structural and Magnetic Studies68Cesium Cyano-Bridged CoII–MV (M = Mo and W) Layered Frameworks Exhibiting High Thermal Durability and Metamagnetism20Applications of chiroptical spectroscopy to coordination compounds85A Copper–Formate Framework Showing a Simple to Helical Antiferroelectric Transition with Prominent Dielectric Anomalies and Anisotropic Thermal Expansion, and Antiferromagnetism41Hierarchical cobalt-formate framework series with (412⋅63)(49⋅66)n (n = 1–3) topologies exhibiting slow dielectric relaxation and weak ferromagnetism39One-Dimensional and Two-Dimensional Anilate-Based Magnets with Inserted Spin-Crossover Complexes59Study on a 2D layer coordination framework showing order-to-disorder phase transition by ionothermal synthesis4Towards multifunctional magnetic systems through molecular-programmed self assembly of Re(IV) metalloligands66Metal–Organic Frameworks: Functional Magnetic Materials with Formate4A High‐Temperature Molecular Ferroelectric Zn/Dy Complex Exhibiting Single‐Ion‐Magnet Behavior and Lanthanide Luminescence263A High‐Temperature Molecular Ferroelectric Zn/Dy Complex Exhibiting Single‐Ion‐Magnet Behavior and Lanthanide Luminescence55A heterometallic strategy to achieve a large magnetocaloric effect in polymeric 3d complexes41A trimetallic strategy towards ZnII4DyIII2CrIII2 and ZnII4DyIII2CoIII2 single-ion magnets29Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [Fe III (acac 2 -trien)] + and [Fe III (sal 2 -trien)] + molecules149Multiple structural transformations coupled with switchable magnetic and dielectric responses in an amphidynamic crystal of 4′-tert-butylbenzylpyridinium bis(maleonitriledithiolate)nickelate14Towards a better understanding of honeycomb alternating magnetic networks30A 36‐Fold Multiple Unit Cell and Switchable Anisotropic Dielectric Responses in an Ammonium Magnesium Formate Framework97A 36‐Fold Multiple Unit Cell and Switchable Anisotropic Dielectric Responses in an Ammonium Magnesium Formate Framework22Palladium(II)–Copper(II) Assembling with Bis(2-pyridylcarbonyl)amidate and Bis(oxamate) Type Ligands24Room-Temperature Polar Order in [NH4][Cd(HCOO)3] - A Hybrid Inorganic–Organic Compound with a Unique Perovskite Architecture88FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster70FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster10Postsynthetic Improvement of the Physical Properties in a Metal–Organic Framework through a Single Crystal to Single Crystal Transmetallation108Postsynthetic Improvement of the Physical Properties in a Metal–Organic Framework through a Single Crystal to Single Crystal Transmetallation19Spontaneous Magnetization in Homometallic μ6-Oxalate Coordination Polymers8Development of a Photoresponsive Organic–Inorganic Hybrid Magnet: Layered Cobalt Hydroxides Intercalated with Spiropyran Anions10Implementation of Chirality into High-Spin Ferromagnetic CoII9WV6 and NiII9WV6 Cyanido-Bridged Clusters30Enforcing Multifunctionality: A Pressure-Induced Spin-Crossover Photomagnet197Two novel organic–inorganic hybrid compounds with straight and zigzag chain alignments of Cu(II) centers: Synthesis, crystal structure, spectroscopy, thermal analysis and magnetism17An A‐Site Mixed‐Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)114An A‐Site Mixed‐Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)22Accommodative Behavior of Non-porous Molecular crystal at Solid-Gas and Solid-Liquid Interface6Cation Exchange in Dynamic 3D Porous Magnets: Improvement of the Physical Properties21Insertion of a [FeII(pyimH)3]2+ [pyimH = 2‐(1H‐Imidazol‐2‐yl)pyridine] Spin‐Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Oxalate Network14Solid‐State Molecular Nanomagnet Inclusion into a Magnetic Metal–Organic Framework: Interplay of the Magnetic Properties67Construction of multifunctional materials based on Tb 3+ and croconic acid, directed by K + cations: synthesis, structures, fluorescence, magnetic and ferroelectric behaviors10High thermal durability of a layered Cs 4 Co II [W V (CN) 8 ]Cl 3 framework: crystallographic and 133 Cs NMR spectroscopic studies3Magnetoelectric coupling and spin-induced electrical polarization in metal–organic magnetic chains22Observation of Resonant Quantum Magnetoelectric Effect in a Multiferroic Metal–Organic Framework131Tuning of Charge Transfer Assisted Phase Transition and Slow Magnetic Relaxation Functionalities in {Fe9–xCox[W(CN)8]6} (x = 0–9) Molecular Solid Solution88Structural Conversion and Magnetic Studies of Low-Dimensional LnIII/MoV/IV(CN)8 (Ln = Gd–Lu) Systems: From Helical Chain to Trinuclear Cluster23White Light Emissive DyIII Single‐Molecule Magnets Sensitized by Diamagnetic [CoIII(CN)6]3− Linkers96Synthesis, crystal structure, thermal analysis and dielectric properties of (C 8 H 12 N) 3 SnCl 6 .Cl compound24Molecular Dynamics of Flexible Polar Cations in a Variable Confined Space: Toward Exceptional Two‐Step Nonlinear Optical Switches2254-Bromopyridine-Induced Chirality in Magnetic MII-[NbIV(CN)8]4– (M = Zn, Mn, Ni) Coordination Networks19Solvent-Dependent Self-Assembly of an Oxalato-Based Three-Dimensional Magnet Exhibiting a Novel Architecture16Electrochemical Li-Ion Intercalation in Octacyanotungstate-Bridged Coordination Polymer with Evidence of Three Magnetic Regimes23Graphene and Fullenene Clusters0Complete Transmetalation in a Metal–Organic Framework by Metal Ion Metathesis in a Single Crystal for Selective Sensing of Phosphate Ions in Aqueous Media165Complete Transmetalation in a Metal–Organic Framework by Metal Ion Metathesis in a Single Crystal for Selective Sensing of Phosphate Ions in Aqueous Media29Amidinium‐Containing 2D [MnCr] Dimetallic Oxalate‐Based Networks – The Influence on Structure and Magnetism Explored by Combining Experience and Theory5Selective Guest Inclusion in Oxalate-Based Iron(III) Magnetic Coordination Polymers10Molecular Multiferroics0Non‐Centrosymmetric Molecular Magnets2SHG-active Ln III –[Mo I (CN) 5 (NO)] 3− (Ln = Gd, Eu) magnetic coordination chains: a new route towards non-centrosymmetric molecule-based magnets15Dehydration of Octacyanido-Bridged NiII-WIV Framework toward Negative Thermal Expansion and Magneto-Colorimetric Switching31[2 + 2] Photochemical modulation of the Dy( iii ) single-molecule magnet: opposite influence on the energy barrier and relaxation time64A novel oxalate-based three-dimensional coordination polymer showing magnetic ordering and high proton conductivity21Effect of the apical ligand on the geometry and magnetic properties of copper( ii )/mesoxalate trinuclear units7Magneto-Optical Functionalities in Cyano-Bridged Bimetal Assemblies and Metal-Oxide Nanomaterials2Photomagnetic properties of an Fe( ii ) spin-crossover complex of 6-(3,5-diamino-2,4,6-triazinyl)-2,2′-bipyridine and its insertion into 2D and 3D bimetallic oxalate-based networks10Synthesis, structures and magnetic properties of chiral 3d–3d′–4f heterotrimetallic complexes based on [(Tp*)Fe(CN) 3 ] −11Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆348Rational Synthesis of Chiral Metal–Organic Frameworks from Preformed Rodlike Secondary Building Units30Postsynthetic Approach for the Rational Design of Chiral Ferroelectric Metal–Organic Frameworks107Microscopic Insights on the Multiferroic Perovskite‐Like [CH3NH3][Co(COOH)3] Compound24Layered Simple Hydroxides Functionalized by Fluorene‐Phosphonic Acids: Synthesis, Interface Theoretical Insights, and Magnetoelectric Effect24Design of Magnetic Coordination Polymers Built from Polyoxalamide Ligands: A Thirty Year Story62Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets20Achieving white light emission and increased magnetic anisotropy by transition metal substitution in functional materials based on dinuclear Dy III (4-pyridone)[M III (CN) 6 ] 3− (M = Co, Rh) molecules51Magnetism in Heterobimetallic and Heterotrimetallic Chains Based on the Use of [WV(bipy)(CN)6]– as a Metalloligand212D and 3D mixed M II /Cu II metal–organic frameworks (M = Ca and Sr) with N , N ′-2,6-pyridinebis(oxamate) and oxalate: preparation and magneto-structural study20Chiral cyanido-bridged Mn–Nb magnets including halogen-bonds16From a square core to square opening: structural diversity and magnetic properties of the oxo-bridged [Cr III Nb V ] complexes4TbCo and Tb 0.5 Dy 0.5 Co layered cyanido-bridged frameworks for construction of colorimetric and ratiometric luminescent thermometers53Towards oxalate-bridged iron( ii ), cobalt( ii ), nickel( ii ) and zinc( ii ) complexes through oxotris(oxalato)niobate( v ): an open air non-oxidizing synthetic route13Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu2(OH)3(C12H25SO4)8Recent advances in luminescent lanthanide based Single-Molecule Magnets301Observation of Magnetodielectric Effect in a Dysprosium-Based Single-Molecule Magnet126Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networks82Métallophosphates bidimensionnels luminescents et magnétiques : relation structure-propriétés0Ferromagnetic coupling through the oxalate bridge in heterobimetallic Cr(III)–M(II) (M = Mn and Co) assemblies7Effect of Transition Metal Substitution on the Charge-Transfer Phase Transition and Ferromagnetism of Dithiooxalato-Bridged Hetero Metal Complexes, (n-C3H7)4N[FeII1−xMnIIxFeIII(dto)3]7Wide-Range UV-to-Visible Excitation of Near-Infrared Emission and Slow Magnetic Relaxation in LnIII(4,4′-Azopyridine-1,1′-dioxide)[CoIII(CN)6]3– Layered Frameworks26Solvent-induced formation of two gadolinium clusters demonstrating strong magnetocaloric effects and ferroelectric properties28A heterotrimetallic synthetic approach in versatile functionalization of nanosized {M x Cu 13–x W 7 } 3+ and {M 1 Cu 8 W 6 } (M = Co, Ni, Mn, Fe) metal–cyanide magnetic clusters10Effect of carbon-skeleton isomerism on the dielectric properties and proton conduction of organic cocrystal compounds assembled from 1,2,4,5-benzenetetracarboxylic acid and piperazine derivatives27Ladder-like [CrCu] coordination polymers containing unique bridging modes of [Cr(C 2 O 4 ) 3 ] 3− and Cr 2 O 7 2−17Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties12Optical and Magnetic Functionalities on Molecule-Based Magnetic Materials2Unique magnetic behaviour of coexistence of single ion magnet and spin crossover4Dialkyl-substituted monoamidinium-templated oxalate-based noncentrosymmetric 2D compounds3Photoluminescent Lanthanide(III) Single‐Molecule Magnets in Three‐Dimensional Polycyanidocuprate(I)‐Based Frameworks47Designing of a Magnetodielectric System in Hybrid Organic–Inorganic Framework, a Perovskite Layered Phosphonate MnO3PC6H4‐m‐Br⋅H2O11Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework146Synthesis, structures, thermal and magnetic properties of two bis(oxalato)cuprate(II) hybrid salts containing pyridinium derivative cations16Magnetic Investigation of an Atypical Three-Dimensional Bimetallic Oxalate-Based Magnet3Network-Selectivity, Magnetism, and Proton Conduction of 2-D and 3-D Metal–Organic Frameworks of the Constituents {P(CH2OH)4}+/MII (MnII, FeII, or CoII)/[CrIII(ox)3]3–191D metal-oxalates H 2 DABCO[M(C 2 O 4 ) 2 ]·3H 2 O (M( ii ): Co, Mg, Zn): phase transitions and magnetic, dielectric, and phonon properties12Multiferroic and thermal expansion properties of metal-organic frameworks36Tuning the Optical Properties of Magnetic Materials21The Mechanism of the Magnetodielectric Response in a Molecule‐Based Trinuclear Iron Cluster Material26The Mechanism of the Magnetodielectric Response in a Molecule‐Based Trinuclear Iron Cluster Material7Developing the Pressure–Temperature–Magnetic Field Phase Diagram of Multiferroic [(CH3)2NH2]Mn(HCOO)320Synthesis, Crystal Structures and Characterization of Two Nonmetal Cation Tetrafluoroborates4Giant Magnetoelectric Coupling and Magnetic-Field-Induced Permanent Switching in a Spin Crossover Mn(III) Complex37Contemporary Discoveries in the Copper Octacyanidometallate Photomagnetic Assemblies2Insertion of single-ion magnets based on mononuclear Co( ii ) complexes into ferromagnetic oxalate-based networks5Magneto-elastic coupling in multiferroic metal-organic framework [(CH3)2NH2]Co(HCOO)34Multiple rotor modes and how to trigger them: complex cation ordering in the family of relaxing hybrid formates5Second harmonic generation on chiral cyanido-bridged Fe II –Nb IV spin-crossover complexes24Tuning the dynamic magnetic behaviour and proton conductivity via water-induced reversible single-crystal to single-crystal structural transformation31Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications928Inorganic–Organic Hybrid Molecular Materials: From Multiferroic to Magnetoelectric83Magneto‐Electric Directional Anisotropy in Polar Soft Ferromagnets of Two‐Dimensional Organic–Inorganic Hybrid Perovskites56Magneto‐Electric Directional Anisotropy in Polar Soft Ferromagnets of Two‐Dimensional Organic–Inorganic Hybrid Perovskites6Multifunctional Properties of a Zn(II) Coordination Complex16Proton switching molecular magnetoelectricity17Homo- and heterometallic oxalate-based complexes obtained using [Cr(C2O4)3]3− building block – Two polymorphs of a solvate4Magnetoelectric interaction in molecular multiferroic nanocomposites2High-Field Magnetoelectric and Spin-Phonon Coupling in Multiferroic (NH4)2[FeCl5·(H2O)]6

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  1. Topological Versatility of Oxalate-Based Bimetallic One-Dimensional (1D) Compounds Associated with Ammonium Cations

    Inorganic Chemistry · 2012-10-22

    Emilio Pardo, Cyrille Train, K. Boubekeur, Geoffrey Gontard, Joan Cano, Francesc Lloret, Keitaro Nakatani, Michel Verdaguer

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  2. The Role of Order–Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)–Iron(III) Formate Framework

    Journal of the American Chemical Society · 2012-11-05

    Laura Cañadillas‐Delgado, Óscar Fabelo, José Alberto Rodríguez-Velamazán, M. H. Lemée-Cailleau, Sax A. Mason, Emilio Pardo, Francesc Lloret, Jiong‐Peng Zhao, Xian‐He Bu, Virginie Simonet, Claire V. Colin, Juan Rodríguez-Carvajal

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  3. A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties

    Inorganic Chemistry · 2012-12-05

    Bin Liu, Ran Shang, Ke-Li Hu, Zhe‐Ming Wang, Song Wei Gao

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  4. First one-dimensional homochiral stairway-like Cu(ii) chains: crystal structures, circular dichroism (CD) spectra, ferroelectricity and antiferromagnetic properties

    Dalton Transactions · 2013-01-01

    Xi-Li Li, Chun‐Lai Chen, Li-Feng Han, Cai‐Ming Liu, You Song, Xiao‐Gang Yang, Shao‐Ming Fang

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  5. Fundamentals, Principles, and Concepts of Molecular Magnetism and Spintronics

    Elsevier eBooks · 2013-01-01

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  6. Self-assembly of a chiral three-dimensional manganese(ii)–copper(ii) coordination polymer with a double helical architecture

    CrystEngComm · 2013-01-01

    Thais Grancha, C. Tourbillon, Jesús Ferrando–Soria, Miguel Julve, Francesc Lloret, Jorge Pasán, Catalina Ruíz-Pérez, Óscar Fabelo, Emilio Pardo

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  7. The odd association of a C3h trisamidinium cation and tosylate anion with a series of linear oxalate-bridged trinuclear heterometallic complexes

    Dalton Transactions · 2013-01-01

    Cătălin Maxim, Emilio Pardo, Mir Wais Hosseini, Sylvie Ferlay, Cyrille Train

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  8. Hybrid Improper Ferroelectricity in a Multiferroic and Magnetoelectric Metal‐Organic Framework

    Advanced Materials · 2013-02-06

    Alessandro Stroppa, Paolo Barone, P. Jain, Juan Manuel Perez-Mato, Silvia Picozzi

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  9. Insertion of FeII complexes with Schiff base ligands derived from imidazole or pyridine into 3D bimetallic oxalate-based ferromagnets

    Polyhedron · 2013-03-16

    A.B. Djamaa, Miguel Clemente‐León, Eugenio Coronado, M. López-Jordà

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  10. Stimuli Responsive Hybrid Magnets: Tuning the Photoinduced Spin-Crossover in Fe(III) Complexes Inserted into Layered Magnets

    Journal of the American Chemical Society · 2013-05-15

    Miguel Clemente‐León, Eugenio Coronado, M. López-Jordà, Joao Carlos Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean François Létard, Andreas Hauser, Antoine Tissot

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  11. Ferroelectric Switchable Behavior through Fast Reversible De/adsorption of Water Spirals in a Chiral 3D Metal–Organic Framework

    Journal of the American Chemical Society · 2013-07-05

    Xi‐Yan Dong, Bo Li, Bin-Bin Ma, Shijun Li, Ming-Ming Dong, Yanyan Zhu, Shuang‐Quan Zang, You Song, Hongwei Hou, Thomas C. W. Mak

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  12. Super-Ionic Conductive Magnet Based on a Cyano-Bridged Mn–Nb Bimetal Assembly

    Crystal Growth & Design · 2013-09-12

    Kenta Imoto, Kosuke Nakagawa, Hiroyuki Miyahara, Shin‐ichi Ohkoshi

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  13. Three isomeric copper(II) coordination polymers based on a bis-triazole-bis-amide ligand: Assembly, structures, and luminescent properties

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    Xiuli Wang, Wei Zhao, Ju‐Wen Zhang, Qilin Lu, Jian Luan, Guo‐Cheng Liu, Hong‐Yan Lin, Ai‐Xiang Tian

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  14. New Multi-Ferrocenyl- and Multi-Ferricenyl- Materials via Coordination-Driven Self-Assembly and via Charge-Driven Electro-Crystallization

    Inorganic Chemistry · 2013-10-09

    Hakikulla H. Shah, Rayya A. Al-Balushi, Mohammed K. Al‐Suti, Muhammad S. Khan, Christopher H. Woodall, Anna L. Sudlow, Paul R. Raithby, Gabriele I. Kociok-Köhn, Kieran C. Molloy, Frank Marken

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  15. Synthesis and Crystal Structures of Various Phases of the Microporous Three-Dimensional Coordination Polymer [Zr(OH)2(C2O4)]n

    Crystal Growth & Design · 2013-10-29

    Monia Hamdouni, Siwar Walha, A. Kabadou, Carine Duhayon, Jean‐Pascal Sutter

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  16. Tuning the Ferroelectric Polarization in a Multiferroic Metal–Organic Framework

    Journal of the American Chemical Society · 2013-11-05

    Domenico Di Sante, Alessandro Stroppa, Prashant Jain, Silvia Picozzi

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  17. Extremely Long Cu···O Contact as a Possible Pathway for Magnetic Interactions in Na2Cu(CO3)2

    Inorganic Chemistry · 2013-11-22

    Yulia Vladimirovna Nelyubina, Alexander Aleksandrovich Korlyukov, Ivan V. Fedyanin, Konstantin Alexandrovich Lyssenko

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  18. Insertion of a Single‐Molecule Magnet inside a Ferromagnetic Lattice Based on a 3D Bimetallic Oxalate Network: Towards Molecular Analogues of Permanent Magnets

    Chemistry - A European Journal · 2013-12-10

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  19. [NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn 2+ , Zn 2+ , Co 2+ and Mg 2+ ): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering

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    Sa Chen, Ran Shang, Ke-Li Hu, Zhe‐Ming Wang, Song Wei Gao

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  20. Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity

    Chemical Communications · 2014-01-01

    Cătălin Maxim, Sylvie Ferlay, Hiroko Tokoro, Shin‐ichi Ohkoshi, Cyrille Train

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  21. Oxamato-based coordination polymers: recent advances in multifunctional magnetic materials

    Chemical Communications · 2014-01-01

    Thais Grancha, Jesús Ferrando–Soria, Marı́a Castellano, Miguel Julve, Jorge Pasán, Donatella Armentano, Emilio Pardo

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  22. New Metal Phthalocyanines/Metal Simple Hydroxide Multilayers: Experimental Evidence of Dipolar Field-Driven Magnetic Behavior

    Inorganic Chemistry · 2014-01-08

    Riadh Bourzami, Séraphin Eyele‐Mezui, Émilie Delahaye, Marc Drillon, Pierre Rabu, Nathalie Parizel, Sylvie Choua, Philippe Turek, Guillaume Rogez

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  23. Chirality Transfer in Magnetic Coordination Complexes Monitored by Vibrational and Electronic Circular Dichroism

    ChemPlusChem · 2014-02-24

    Tao Wu, Xiao‐Peng Zhang, Xiao‐Zeng You, Yizhi Li, Petr Bouř

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  24. Solid-state cis–trans isomerism in bis(oxamato)palladate( ii ) complexes: synthesis, structural studies and catalytic activity

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  25. Ferrocenylethynyl - a versatile platform for new molecules to novel materials

    Maǧallaẗ ǧāmiʿaẗ al-Sulṭān Qābūs li-l-ʿulūm/Sultan Qaboos University journal for science · 2014-06-01

    Hakikulla H. Shah, Rayya A. Al-Balushi, Muhammad S. Khan

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  26. [(C 2 H 5 ) 4 N][U 2 O 4 (HCOO) 5 ], an Ammonium Uranyl Formate Framework Showing Para- to Ferro-Electric Transition: Synthesis, Structures, and Properties

    Inorganic Chemistry · 2014-07-29

    Qianqian Zhu, Ran Shang, Sa Chen, Chunli Liu, Zhe‐Ming Wang, Song Wei Gao

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  27. Unprecedented Sensitization of Visible and Near‐Infrared Lanthanide Luminescence by Using a Tetrathiafulvalene‐Based Chromophore

    Chemistry - An Asian Journal · 2014-08-01

    Min Feng, Fabrice Pointillart, Boris Le Guennic, Bertrand Lefeuvre, Stéphane Golhen, Olivier Cador, Olivier Maury, Lahcène Ouahab

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  28. Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework

    Scientific Reports · 2014-08-14

    Ying Tian, Alessandro Stroppa, Yisheng Chai, Liqin Yan, Shouguo Wang, Paolo Barone, Silvia Picozzi, Young Sun

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  29. Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared via a Mild, Two-Step Hydrothermal Method

    Crystal Growth & Design · 2014-08-19

    Dileka Abeysinghe, Mark D. Smith, Jeongho Yeon, Gregory W. Morrison, Hans‐Conrad zur Loye

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  30. A 3D Oxalate-Based Network as a Precursor for the CoMn 2 O 4 Spinel: Synthesis and Structural and Magnetic Studies

    Inorganic Chemistry · 2014-08-25

    Jelena Habjanič, Marijana Jurić, Jasminka Popović, Krešimir Molčanov, Damir Pajić

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  31. Cesium Cyano-Bridged CoII–MV (M = Mo and W) Layered Frameworks Exhibiting High Thermal Durability and Metamagnetism

    Crystal Growth & Design · 2014-09-23

    Koji Nakabayashi, Szymon Chorąży, Daisuke A. Takahashi, Takaaki Kinoshita, Barbara Sieklucka, Shin‐ichi Ohkoshi

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  32. Applications of chiroptical spectroscopy to coordination compounds

    Coordination Chemistry Reviews · 2014-09-28

    Tao Wu, Xiao‐Zeng You, Petr Bouř

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  33. A Copper–Formate Framework Showing a Simple to Helical Antiferroelectric Transition with Prominent Dielectric Anomalies and Anisotropic Thermal Expansion, and Antiferromagnetism

    Chemistry - A European Journal · 2014-10-09

    Ran Shang, Sa Chen, Zhe‐Ming Wang, Song Wei Gao

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  34. Hierarchical cobalt-formate framework series with (412⋅63)(49⋅66)n (n = 1–3) topologies exhibiting slow dielectric relaxation and weak ferromagnetism

    APL Materials · 2014-10-24

    Ran Shang, Sa Chen, Ke-Li Hu, Ze-Chun Jiang, Bing‐Wu Wang, Mohamedally Kurmoo, Zhe‐Ming Wang, Song Wei Gao

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  35. One-Dimensional and Two-Dimensional Anilate-Based Magnets with Inserted Spin-Crossover Complexes

    Inorganic Chemistry · 2014-10-28

    Alexandre Abhervé, Miguel Clemente‐León, Eugenio Coronado, Carlos J. Gómez‐García, Martin Verneret

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  36. Study on a 2D layer coordination framework showing order-to-disorder phase transition by ionothermal synthesis

    Polymer Journal · 2014-11-12

    Wenqian Chen, Satoshi Horike, Munehiro Inukai, Susumu Kitagawa

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  37. Towards multifunctional magnetic systems through molecular-programmed self assembly of Re(IV) metalloligands

    Coordination Chemistry Reviews · 2014-11-29

    José Martínez‐Lillo, Juan Faus, Francesc Lloret, Miguel Julve

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  38. Metal–Organic Frameworks: Functional Magnetic Materials with Formate

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2014-12-11

    Ran Shang, Sa Chen, Zhe‐Ming Wang, Song Wei Gao

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  39. A High‐Temperature Molecular Ferroelectric Zn/Dy Complex Exhibiting Single‐Ion‐Magnet Behavior and Lanthanide Luminescence

    Angewandte Chemie International Edition · 2014-12-30

    Jérôme Long, Jerome Alexandre Rouquette, Jean‐Marc Thibaud, Rute A. S. Ferreira, Luís D. Carlos, B. Donnadieu, Veacheslav Vieru, Liviu F. Chibotaru, L. Kończewicz, Julien Paul Haines, Yannick Guari≠, Joulia Larionova≠

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  40. A High‐Temperature Molecular Ferroelectric Zn/Dy Complex Exhibiting Single‐Ion‐Magnet Behavior and Lanthanide Luminescence

    Angewandte Chemie · 2014-12-30

    Jérôme Long, Jerome Alexandre Rouquette, Jean‐Marc Thibaud, Rute A. S. Ferreira, Luís D. Carlos, B. Donnadieu, Veacheslav Vieru, Liviu F. Chibotaru, L. Kończewicz, Julien Paul Haines, Yannick Guari≠, Joulia Larionova≠

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  41. A heterometallic strategy to achieve a large magnetocaloric effect in polymeric 3d complexes

    Chemical Communications · 2015-01-01

    Jiong‐Peng Zhao, Song‐De Han, Xue Jiang, Sui‐Jun Liu, Ran Zhao, Ze Chang, Xian‐He Bu

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  42. A trimetallic strategy towards ZnII4DyIII2CrIII2 and ZnII4DyIII2CoIII2 single-ion magnets

    Dalton Transactions · 2015-01-01

    Kong-Qiu Hu, Xiang Jiang, Shu‐Qi Wu, Cai‐Ming Liu, Ai-Li Cui, Hui‐Zhong Kou

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  43. Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [Fe III (acac 2 -trien)] + and [Fe III (sal 2 -trien)] + molecules

    Chemical Science · 2015-01-01

    Alexandre Abhervé, Samuel Mañas‐Valero, Miguel Clemente‐León, Eugenio Coronado

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  44. Multiple structural transformations coupled with switchable magnetic and dielectric responses in an amphidynamic crystal of 4′-tert-butylbenzylpyridinium bis(maleonitriledithiolate)nickelate

    Journal of Materials Chemistry C · 2015-01-01

    Weihua Ning, Lu Zhai, Jian-Lan Liu, Xiao‐Ming Ren, Katsuya Ichihashi, Sadafumi Nishihara, Katsuya Inoue

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  45. Towards a better understanding of honeycomb alternating magnetic networks

    Dalton Transactions · 2015-01-01

    Nadia Marino, Donatella Armentano, Giovanni De Munno, Francesc Lloret, Joan Cano, Miguel Julve

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  46. A 36‐Fold Multiple Unit Cell and Switchable Anisotropic Dielectric Responses in an Ammonium Magnesium Formate Framework

    Angewandte Chemie International Edition · 2015-01-13

    Ran Shang, Zhe‐Ming Wang, Song Wei Gao

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  47. A 36‐Fold Multiple Unit Cell and Switchable Anisotropic Dielectric Responses in an Ammonium Magnesium Formate Framework

    Angewandte Chemie · 2015-01-13

    Ran Shang, Zhe‐Ming Wang, Song Wei Gao

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  48. Palladium(II)–Copper(II) Assembling with Bis(2-pyridylcarbonyl)amidate and Bis(oxamate) Type Ligands

    Crystal Growth & Design · 2015-02-03

    Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. Da Costa, Ana Paula Soares Fontes, Wallace Castro Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira

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  49. Room-Temperature Polar Order in [NH4][Cd(HCOO)3] - A Hybrid Inorganic–Organic Compound with a Unique Perovskite Architecture

    Inorganic Chemistry · 2015-02-09

    L. C. Gómez-Aguirre, Breogán Pato‐Doldán, Alessandro Stroppa, Susana Yáñez‐Vilar, Lkhamsuren Bayarjargal, B. Winkler, Socorro Castro‐García, Jorge Mira, Manuel Sánchez‐Andújar, M. A. Señarı́s-Rodrı́guez

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  50. FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster

    Angewandte Chemie International Edition · 2015-03-03

    Szymon Chorąży, Robert Podgajny, Koji Nakabayashi, Jan J. Stanek, Michał Rams, Barbara Sieklucka, Shin‐ichi Ohkoshi

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