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RESEARCH PAPER · Journal of Materials Chemistry A · 2015

VO 2 F: a new transition metal oxyfluoride with high specific capacity for Li ion batteries

Juan Carlos Pérez‐Flores, Raquel Villamor, David Ávila‐Brande, José Manuel Gallardo-Amores, Emilio Morán, A. Kuhn, Flaviano García‐Alvarado

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VO 2 F: a new transition metal oxyfluoride with high specific capacity for Li ion batteriesOriginalLithiation-driven structural transition of VO 2 F into disordered rock-salt Li x VO 2 F26Vanadium Oxyfluoride/Few-Layer Graphene Composite as a High-Performance Cathode Material for Lithium Batteries26Triggering the In Situ Electrochemical Formation of High Capacity Cathode Material from MnO24Transition Metal Oxyfluorides for Next‐Generation Rechargeable Batteries59Structure Evolution and Thermal Stability of High-Energy- Density Li-Ion Battery Cathode Li2VO2F31Bismuth oxyfluoride @ CMK-3 nanocomposite as cathode for lithium ion batteries25Promising half-metallicity in ductile NbF 3 : a first-principles prediction11Structural Changes in a High-Energy Density VO2F Cathode upon Heating and Li Cycling17Reactivity of VOF3 with N-Heterocyclic Carbene and Imidazolium Fluoride: Analysis of Ligand–VOF3 Bonding with Evidence of a Minute π Back-Donation of Fluoride16Electrochemical properties of chromium oxyfluoride CrO 2−x F x with 0 ≤ x ≤ 0.33Sodium insertion in high pressure β-V2O5: A new high capacity cathode material for sodium ion batteries33Two closely related polymorphs of ammonium trifluorooxovanadate2Degradation Mechanisms in Li2VO2F Li-Rich Disordered Rock-Salt Cathodes44Suppressing Dissolution of Vanadium from Cation-Disordered Li2–xVO2F via a Concentrated Electrolyte Approach36Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides1Understanding the role of crystallographic shear on the electrochemical behavior of niobium oxyfluorides20Perovskite-related ReO3-type structures120Redox Chemistry and Reversible Structural Changes in Rhombohedral VO2F Cathode during Li Intercalation7Theoretical Description, Synthesis, and Structural Characterization of β-Na0.33V2O5and Its Fluorinated Derivative β-Na0.33V2O4.67F0.33: Influence of Oxygen Substitution by Fluorine on the Electrochemical Properties8Fluorinated Materials as Positive Electrodes for Li- and Na-Ion Batteries96From high‐pressure β‐V2O5 to κ‐NaxV2O5 (x = 0.4 − 0.55): A structural, chemical, and kinetic insight into a sodiated phase with a large interlayer space2Battery materials1High pressure chemistry1New perspectives on the multianion approach to adapt electrode materials for lithium and post-lithium batteries9Structural modeling of oxygen-fluorine ordering in transition metal inorganic oxyfluorides0K 3 Mo 2 O 5.6 F 3.4 and K 3 V 2 O 3.3 F 5.7 – exploring transition metal cation valence and anion distribution in oxyfluorides0Evaluating 3D printed mesh geometries in ceramic LiB electrodes3Tunable anionic ratio synthesis of tantalum oxyfluoride nanoparticles as high-rate performance anode materials for lithium-ion battery2Correlated Anion Disorder in Heteroanionic Cubic TiOF 28Different magnitudes of second-order Jahn-Teller effect in isostructural NaMO2F2 (M = Nb, Ta) oxyfluorides4Exploration of Oxyfluoride Frameworks as Na-ion Cathodes3New mixed 3d metal-based oxyfluorinated materials as anodic catalysts for water splitting : from elaboration to mechanistic study0Li3FeF6/Fe2O3, LiF anchored oxidized multi-wall carbon nanotubes as high power cathode in lithium ion batteries3Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy25Superior catalytic effect of VO2F on dehydrogenation of magnesium hydride9Slab-Gliding–Induced Structural Evolution in β-V 2 O 5 Enables Reversible High Na-Ion Storage: A Combined Operando Synchrotron Diffraction and Operando XAS Study2

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  1. Lithiation-driven structural transition of VO 2 F into disordered rock-salt Li x VO 2 F

    RSC Advances · 2016-01-01

    Ruiyong Chen, Emad Maawad, Michael Knapp, Shuhua Ren, Přemysl Beran, Raiker Witter, Rolf Hempelmann

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  2. Vanadium Oxyfluoride/Few-Layer Graphene Composite as a High-Performance Cathode Material for Lithium Batteries

    Inorganic Chemistry · 2016-03-28

    Musa Ali Cambaz, Bhaghavathi Parambath Vinayan, Oliver Clemens, Munnangi Anji Reddy, Venkata Sai Kiran Chakravadhanula, Christian Kübel, Maximilian Fichtner

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  3. Triggering the In Situ Electrochemical Formation of High Capacity Cathode Material from MnO

    Advanced Energy Materials · 2016-12-20

    Leiting Zhang, Guohua Chen, Erik J. Berg, Jean‐Marie Tarascon

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  4. Transition Metal Oxyfluorides for Next‐Generation Rechargeable Batteries

    ChemNanoMat · 2016-12-31

    Da Deng

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  5. Structure Evolution and Thermal Stability of High-Energy- Density Li-Ion Battery Cathode Li2VO2F

    Journal of The Electrochemical Society · 2017-01-01

    Xiaoya Wang, Yiqing Huang, Dongsheng Ji, Fredrick O. Omenya, Khim Karki, Shawn Sallis, Louis F. J. Piper, Kamila Magdalena Wiaderek, Karena W. Chapman, Natasha A. Chernova, M. Stanley Whittingham

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  6. Bismuth oxyfluoride @ CMK-3 nanocomposite as cathode for lithium ion batteries

    Journal of Power Sources · 2017-11-16

    Dan Ni, Wang Sun, Liqiang Xie, Qinghua Fan, Zhenhua Wang, Kening Sun

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  7. Promising half-metallicity in ductile NbF 3 : a first-principles prediction

    Physical Chemistry Chemical Physics · 2018-01-01

    Bo Yang, Junru Wang, Xiaobiao Liu, Mingwen Zhao

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  8. Structural Changes in a High-Energy Density VO2F Cathode upon Heating and Li Cycling

    ACS Applied Energy Materials · 2018-08-28

    Xiaoya Wang, Yuh‐Chieh Lin, Hui Zhou, Fredrick O. Omenya, Iek‐Heng Chu, Khim Karki, Shawn Sallis, Jatinkumar Rana, Louis F. J. Piper, Natasha A. Chernova, Shyue Ping Ong, M. Stanley Whittingham

    Read original paper ↗ ·

  9. Reactivity of VOF3 with N-Heterocyclic Carbene and Imidazolium Fluoride: Analysis of Ligand–VOF3 Bonding with Evidence of a Minute π Back-Donation of Fluoride

    Inorganic Chemistry · 2018-10-24

    Žiga Zupanek, Melita Tramšek, Anton Kokalj, Gašper Tavčar

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  10. Electrochemical properties of chromium oxyfluoride CrO 2−x F x with 0 ≤ x ≤ 0.3

    Inorganic Chemistry Frontiers · 2019-01-01

    Kazuhiko Mukai, Takeshi Uyama, Ikuya Yamada

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  11. Sodium insertion in high pressure β-V2O5: A new high capacity cathode material for sodium ion batteries

    Journal of Power Sources · 2019-03-16

    Rafael Córdoba, A. Kuhn, Juan Carlos Pérez‐Flores, Emilio Morán, José Manuel Gallardo-Amores, Flaviano García‐Alvarado

    Read original paper ↗ ·

  12. Two closely related polymorphs of ammonium trifluorooxovanadate

    Journal of Solid State Chemistry · 2019-05-10

    Allison Wustrow, Justin C. Hancock, Michael A. Holland, Nenian Charles, James M. Rondinelli, Kenneth Reinhard Poeppelmeier

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  13. Degradation Mechanisms in Li2VO2F Li-Rich Disordered Rock-Salt Cathodes

    Chemistry of Materials · 2019-06-03

    Ida Källquist, Andrew J. Naylor, Christian Baur, Johann Chable, Jolla Kullgren, Maximilian Fichtner, Kristina Edström, Daniel Brandell, Maria Hahlin

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  14. Suppressing Dissolution of Vanadium from Cation-Disordered Li2–xVO2F via a Concentrated Electrolyte Approach

    Chemistry of Materials · 2019-09-11

    Musa Ali Cambaz, Bhaghavathi Parambath Vinayan, Syed Atif Pervez, Rune E. Johnsen, Holger Geßwein, Alexander Alexandrovich Guda, Yury V. Rusalev, M. K. Kinyanjui, Ute A. Kaiser, Maximilian Fichtner

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  15. Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides

    CrystEngComm · 2020-01-01

    Belal Ahmed, Hongil Jo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  16. Understanding the role of crystallographic shear on the electrochemical behavior of niobium oxyfluorides

    Journal of Materials Chemistry A · 2020-01-01

    Nicholas H. Bashian, Molleigh B. Preefer, JoAnna Milam-Guerrero, Joshua J. Zak, Charlotte Sendi, Suha A. Ahsan, Rebecca C. Vincent, Ralf Haiges, Kimberly A. See, Ram Seshadri, Brent C. Melot

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  17. Perovskite-related ReO3-type structures

    Nature Reviews Materials · 2020-01-22

    Hayden A. Evans, Yue Wu, Ram Seshadri, Anthony Kevin Cheetham

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  18. Redox Chemistry and Reversible Structural Changes in Rhombohedral VO2F Cathode during Li Intercalation

    Inorganic Chemistry · 2020-06-26

    A. Kuhn, Michael Rhys Plews, Juan Carlos Pérez‐Flores, François Fauth, Markus Hoelzel, Jordi Cabana, Flaviano García‐Alvarado

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  19. Theoretical Description, Synthesis, and Structural Characterization of β-Na0.33V2O5and Its Fluorinated Derivative β-Na0.33V2O4.67F0.33: Influence of Oxygen Substitution by Fluorine on the Electrochemical Properties

    Inorganic Chemistry · 2020-10-26

    Rafael Córdoba, Jakub Goclon, A. Kuhn, Flaviano García‐Alvarado

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  20. Fluorinated Materials as Positive Electrodes for Li- and Na-Ion Batteries

    Chemical Reviews · 2022-08-15

    Kévin Lemoine, Annie Hémon‐Ribaud, M. Leblanc, Jérôme Lhoste, Jean‐Marie Tarascon, V. Maisonneuve

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  21. From high‐pressure β‐V2O5 to κ‐NaxV2O5 (x = 0.4 − 0.55): A structural, chemical, and kinetic insight into a sodiated phase with a large interlayer space

    Applied Research · 2022-08-25

    Rafael Córdoba, Jakub Goclon, Angelina Sarapulova, Qiang Fu, Julia Maibach, Sonia Dsoke, François Fauth, A. Kuhn, Flaviano García‐Alvarado

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  22. Battery materials

    Elsevier eBooks · 2022-10-21

    Zachery W. B. Iton, Seong Shik Kim, Eshaan S. Patheria, Michelle D. Qian, Skyler D. Ware, Kimberly A. See

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  23. High pressure chemistry

    Elsevier eBooks · 2022-10-31

    Ulrich T. Schwarz, Kristina Spektor, Ulrich Häußermann

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  24. New perspectives on the multianion approach to adapt electrode materials for lithium and post-lithium batteries

    Physical Chemistry Chemical Physics · 2023-01-01

    Carlos Pérez-Vicente, Ricardo Alcántara

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  25. Structural modeling of oxygen-fluorine ordering in transition metal inorganic oxyfluorides

    Unknown journal · 2023-12-08

    Ouail Zakary

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  26. K 3 Mo 2 O 5.6 F 3.4 and K 3 V 2 O 3.3 F 5.7 – exploring transition metal cation valence and anion distribution in oxyfluorides

    Dalton Transactions · 2024-01-01

    Fabian Zimmerhofer, Eric Wolf, Baris Öcal, Selina Olthof, Maximilian Kai Reimann, Rainer Pöttgen, Hubert Huppertz

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  27. Evaluating 3D printed mesh geometries in ceramic LiB electrodes

    Journal of Physics Energy · 2024-01-31

    Juan Ramón Marín‐Rueda, José Fernando Valera‐Jiménez, José Miguel Ramos-Fajardo, Isabel María Peláez-Tirado, Sabrina Tair, Miguel Castro‐García, Jesús Canales‐Vázquez, Juan Carlos Pérez‐Flores

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  28. Tunable anionic ratio synthesis of tantalum oxyfluoride nanoparticles as high-rate performance anode materials for lithium-ion battery

    Chemical Engineering Science · 2024-05-01

    Ge Han, Xin Geng, Qingyang Du, Weimeng Si, Yunhui Zeng, Guangwu Wen, Xiaoxiao Lü

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  29. Correlated Anion Disorder in Heteroanionic Cubic TiOF 2

    Journal of the American Chemical Society · 2024-07-26

    Christophe Legein, Benjamin J. Morgan, Alexander G. Squires, Monique Body, Wei Li, Mario Burbano, Mathieu Salanne, Thibault Charpentier, Olaf J. Borkiewicz, Damien Dambournet

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  30. Different magnitudes of second-order Jahn-Teller effect in isostructural NaMO2F2 (M = Nb, Ta) oxyfluorides

    Journal of Alloys and Compounds · 2024-11-07

    Ouail Zakary, Monique Body, Vincent Sarou‐Kanian, B. Arnaud, Gwenaël Corbel, Christophe Legein

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  31. Exploration of Oxyfluoride Frameworks as Na-ion Cathodes

    Chemistry of Materials · 2024-12-12

    Debolina Deb, Gopalakrishnan Sai Gautam

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  32. New mixed 3d metal-based oxyfluorinated materials as anodic catalysts for water splitting : from elaboration to mechanistic study

    Unknown journal · 2024-12-18

    Alexandre Terry

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  33. Li3FeF6/Fe2O3, LiF anchored oxidized multi-wall carbon nanotubes as high power cathode in lithium ion batteries

    Journal of Power Sources · 2024-12-31

    Anna Basa, Daria Tatko, Katarzyna Lapinska, Agnieszka Zofia Wilczewska, Jakub Goclon, Krzysztof Winkler, A. Kuhn, Flaviano García‐Alvarado

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  34. Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy

    Chemical Reviews · 2025-03-31

    Helies Hyrondelle, Alexandre Terry, Jérôme Lhoste, Sophie Tencé, Kévin Lemoine, Jacob Olchowka, Damien Dambournet, Cédric Tassel, Jacinthe Gamon, Alain Demourgues

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  35. Superior catalytic effect of VO2F on dehydrogenation of magnesium hydride

    International Journal of Hydrogen Energy · 2025-04-17

    Xiaoxia Chen, Cong Peng, Qingan Zhang

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  36. Slab-Gliding–Induced Structural Evolution in β-V 2 O 5 Enables Reversible High Na-Ion Storage: A Combined Operando Synchrotron Diffraction and Operando XAS Study

    Chemistry of Materials · 2025-10-31

    Rafael Córdoba, Jakub Goclon, Angelina Sarapulova, Julia Maibach, Sonia Dsoke, Ester García-González, François Fauth, A. Kuhn, Flaviano García‐Alvarado

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