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RESEARCH PAPER · Dalton Transactions · 2004

The triruthenium complex [{(acac) 2 Ru II } 3 (L)] containing a conjugated diquinoxaline[2,3-a:2′,3′-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation

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The triruthenium complex [{(acac) 2 Ru II } 3 (L)] containing a conjugated diquinoxaline[2,3-a:2′,3′-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigationOriginalSynthesis, structure, redox, NLO and DNA interaction aspects of [{(L′ – ‴) 2 Ru II } 3 (μ 3 -L)] 3+ and [(L′) 2 Ru II (NC 5 H 4 S − )] + [L 3− = 1,3,5-triazine-2,4,6-trithiolato, L′ – ‴ = arylazopyridine]46Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation6015 Noble metals13,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H + ) − as ligands for {(acac) 2 Ru n+ } or {(bpy) 2 Ru m+ }: investigation of mixed valency in [{(acac) 2 Ru} 2 (μ-L − H + )] 0 and [{(bpy) 2 Ru} 2 (μ-L − H + )] 4+ by spectroelectrochemistry and EPR44Syntheses, crystal structure and electrochemical properties of dinuclear ruthenium complexes containing saturated and unsaturated spacers18Tetrazine derived mononuclear RuII(acac)2(L) (1), [RuII(bpy)2(L)](ClO4)2 (2) and [RuII(bpy)(L)2](ClO4)2 (3) (L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac=acetylacetonate, bpy=2,2′-bipyridine): syntheses, structures, spectra and redox properties18Unusual Monodentate Binding Mode of 2,2‘-Dipyridylamine (L) in Isomeric trans-(acac)2RuII(L)2, trans-[(acac)2RuIII(L)2]ClO4, and cis-(acac)2RuII(L)2 (acac = Acetylacetonate). Synthesis, Structures, and Spectroscopic, Electrochemical, and Magnetic Aspects302,5‐Dioxido‐1,4‐benzoquinonediimine (H2L2−), A Hydrogen‐Bonding Noninnocent Bridging Ligand Related to Aminated Topaquinone: Different Oxidation State Distributions in Complexes [{(bpy)2Ru}2(μ‐H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(μ‐H2L)]m (m=2−,−,0,+,2+)87Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties46Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium331Mixed valency in ruthenium complexes—Coordinative aspects1662,2‘-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes [(dpk)(Cl)Ru(μ-tppz)Ru(Cl)(dpk)]n+where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine29An Experimental and Density Functional Theory Approach Towards the Establishment of Preferential Metal‐ or Ligand‐Based Electron‐Transfer Processes in Large Quinonoid‐Bridged Diruthenium Complexes [{(aap)2Ru}2(μ‐BL2–)]n+ (aap = 2‐Arylazopyridine)33Tuning intermetallic electronic coupling in polyruthenium systems via molecular architecture2Electronic communication in “chain-like” trimetallic ruthenium complexes with two C 7 carbon-rich conjugated bridges28Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A 2 Ru(µ-L)RuA 2 ] n , A = 2,4-pentanedionato or 2-phenylazopyridine, L 2− = 2,5-bis(2-oxidophenyl)pyrazine34Unconventional Mixed‐Valent Complexes of Ruthenium and Osmium345Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums115Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex {(μ-tppz)[Ru(bik)Cl]2}3+(tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2‘-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and νCOLine Broadening32Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands22Dinuclear RuIIPHEHAT and -TPAC Complexes: Effects of the Second RuII Center on Their Spectroelectrochemical Properties36Photophysical and Structural Properties of Cyanoruthenate Complexes of Hexaazatriphenylene70Binuclear ruthenium(III) Schiff base complexes bearing N4O4 donors and their catalytic oxidation of alcohols41Mixed-Valent Metals Bridged by a Radical Ligand: Fact or Fiction Based on Structure-Oxidation State Correlations117Mixed-Valence Intermediates as Ideal Targets for Spectroelectrochemistry (SEC)10The synthesis and electrochemistry of 2,5-dimethylazaferrocenes with heteroaryl bridges40Valence‐State Analysis through Spectroelectrochemistry in a Series of Quinonoid‐Bridged Diruthenium Complexes [(acac)2Ru(μ‐L)Ru(acac)2]n (n=+2, +1, 0, −1, −2)85Valence structures of the diastereomeric complexes meso- and rac-[Ru2(acac)4(μ-Q)]n (n = 2−, 1−, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane26Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4− Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species32Tricarbonylrhenium(i) complexes of highly symmetric hexaazatrinaphthylene ligands (HATN): structural, electrochemical and spectroscopic properties26“Chain-Like” Trimetallic Ruthenium Complexes with C7Carbon-Rich Bridges: Experimental and Theoretical Investigations of Electronic Communication Tuning in Five Distinct Oxidation States79Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties181Valence and spin situations in isomeric [(bpy)Ru(Q′)2]n (Q′ = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine). An experimental and DFT analysis38Binuclear Ruthenium(II) Carbonyl Schiff Base Complexes Containing N2O2 Donors and their Catalytic and Biological Activities6Complete Family of Mono-, Bi-, and Trinuclear Re I (CO) 3 Cl Complexes of the Bridging Polypyridyl Ligand 2,3,8,9,14,15-Hexamethyl-5,6,11,12,17,18-hexaazatrinapthalene: Syn/Anti Isomer Separation, Characterization, and Photophysics57Manifestations of Noninnocent Ligand Behavior498Influence of ancillary ligands on the electronic structure and anion sensing features of ligand bridged diruthenium complexes25Electronic structures and selective fluoride sensing features of Os(bpy) 2 (HL 2− ) and [{Os(bpy) 2 } 2 (μ-HL 2− )] 2+ (H 3 L: 5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic acid)25Sensitivity of the Valence Structure in Diruthenium Complexes As a Function of Terminal and Bridging Ligands38Trinuclear Complexes and Coordination Polymers of Redox-Active Guanidino-Functionalized Aromatic (GFA) Compounds with a Triphenylene Core25Dinuclear iridium and rhodium complexes with bridging arylimidazolide-N 3 ,C 2 ligands: synthetic, structural, reactivity, electrochemical and spectroscopic studies16Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand18Synthesis and Optical Properties of Unsymmetrically Substituted Triarylamine Hexaazatrinaphthalenes19Long-Lived Polypyridyl Based Mononuclear Ruthenium Complexes: Synthesis, Structure, and Azo Dye Decomposition21Mixed Donor–Acceptor‐Derived N,N′‐Diarylpyrazine‐2,5‐dicarboxamido‐Bridged Diruthenium Systems: Structures, Magnetic Properties, and Electronic Forms in Multiredox States11Redox Behavior of a Dinuclear Ruthenium(II) Complex Bearing an Uncommon Bridging Ligand: Insights from High-Pressure Electrochemistry14Mixed valency in ligand-bridged diruthenium frameworks: divergences and perspectives29Synthesis, Crystal Structures, and Magnetic and Electrochemical Properties of Highly Phenyl Substituted Trinuclear 5,6,11,12,17,18-Hexaazatrinaphthylene (HATNPh6)-Bridged Titanium Complexes10On the non-innocence and reactive versus non-reactive nature of α-diketones in a set of diruthenium frameworks92,5-Pyrazine dicarboxylic acid ligand bridged symmetrical dinuclear ruthenium(II) complexes: Synthesis, structure and spectroelectrochemical properties1

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  1. Synthesis, structure, redox, NLO and DNA interaction aspects of [{(L′ – ‴) 2 Ru II } 3 (μ 3 -L)] 3+ and [(L′) 2 Ru II (NC 5 H 4 S − )] + [L 3− = 1,3,5-triazine-2,4,6-trithiolato, L′ – ‴ = arylazopyridine]

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  2. Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation

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    Srikanta Patra, Biprajit Sarkar, Sandeep Kaur‐Ghumaan, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri

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  3. 15 Noble metals

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  4. 3,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H + ) − as ligands for {(acac) 2 Ru n+ } or {(bpy) 2 Ru m+ }: investigation of mixed valency in [{(acac) 2 Ru} 2 (μ-L − H + )] 0 and [{(bpy) 2 Ru} 2 (μ-L − H + )] 4+ by spectroelectrochemistry and EPR

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  5. Syntheses, crystal structure and electrochemical properties of dinuclear ruthenium complexes containing saturated and unsaturated spacers

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  6. Tetrazine derived mononuclear RuII(acac)2(L) (1), [RuII(bpy)2(L)](ClO4)2 (2) and [RuII(bpy)(L)2](ClO4)2 (3) (L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac=acetylacetonate, bpy=2,2′-bipyridine): syntheses, structures, spectra and redox properties

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  7. Unusual Monodentate Binding Mode of 2,2‘-Dipyridylamine (L) in Isomeric trans-(acac)2RuII(L)2, trans-[(acac)2RuIII(L)2]ClO4, and cis-(acac)2RuII(L)2 (acac = Acetylacetonate). Synthesis, Structures, and Spectroscopic, Electrochemical, and Magnetic Aspects

    Inorganic Chemistry · 2005-02-08

    Sanjib Kar, Nripen Chanda, Shaikh Md. Mobin, F.A. Urbanos, M. Niemeyer, Vedavati G. Puranik, Reyes Jiménez‐Aparicio, Goutam Kumar Lahiri

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  8. 2,5‐Dioxido‐1,4‐benzoquinonediimine (H2L2−), A Hydrogen‐Bonding Noninnocent Bridging Ligand Related to Aminated Topaquinone: Different Oxidation State Distributions in Complexes [{(bpy)2Ru}2(μ‐H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(μ‐H2L)]m (m=2−,−,0,+,2+)

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    Sanjib Kar, Biprajit Sarkar, Sandeep Kaur‐Ghumaan, Deepa Janardanan, Joris van Slageren, Jan Fiedler, Vedavati G. Puranik, Raghavan B. Sunoj, Wolfgang Kaim, Goutam Kumar Lahiri

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  9. Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties

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    Juan Manuel Herrera, Michael D. Ward, Harry Adams, Simon J. A. Pope, Stephen Faulkner

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  10. Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium

    Chemical Reviews · 2006-05-24

    Deanna M. D’Alessandro, F. Richard Keene

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  11. Mixed valency in ruthenium complexes—Coordinative aspects

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  12. 2,2‘-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes [(dpk)(Cl)Ru(μ-tppz)Ru(Cl)(dpk)]n+where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine

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  13. An Experimental and Density Functional Theory Approach Towards the Establishment of Preferential Metal‐ or Ligand‐Based Electron‐Transfer Processes in Large Quinonoid‐Bridged Diruthenium Complexes [{(aap)2Ru}2(μ‐BL2–)]n+ (aap = 2‐Arylazopyridine)

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  14. Tuning intermetallic electronic coupling in polyruthenium systems via molecular architecture

    Journal of Chemical Sciences · 2006-11-01

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  15. Electronic communication in “chain-like” trimetallic ruthenium complexes with two C 7 carbon-rich conjugated bridges

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  16. Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A 2 Ru(µ-L)RuA 2 ] n , A = 2,4-pentanedionato or 2-phenylazopyridine, L 2− = 2,5-bis(2-oxidophenyl)pyrazine

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  17. Unconventional Mixed‐Valent Complexes of Ruthenium and Osmium

    Angewandte Chemie International Edition · 2007-02-26

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  18. Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums

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  19. Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex {(μ-tppz)[Ru(bik)Cl]2}3+(tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2‘-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and νCOLine Broadening

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  20. Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands

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  21. Dinuclear RuIIPHEHAT and -TPAC Complexes: Effects of the Second RuII Center on Their Spectroelectrochemical Properties

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  22. Photophysical and Structural Properties of Cyanoruthenate Complexes of Hexaazatriphenylene

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  23. Binuclear ruthenium(III) Schiff base complexes bearing N4O4 donors and their catalytic oxidation of alcohols

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  24. Mixed-Valent Metals Bridged by a Radical Ligand: Fact or Fiction Based on Structure-Oxidation State Correlations

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    Biprajit Sarkar, Srikanta Patra, Jan Fiedler, Raghavan B. Sunoj, Deepa Janardanan, Goutam Kumar Lahiri, Wolfgang Kaim

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  25. Mixed-Valence Intermediates as Ideal Targets for Spectroelectrochemistry (SEC)

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  26. The synthesis and electrochemistry of 2,5-dimethylazaferrocenes with heteroaryl bridges

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  27. Valence‐State Analysis through Spectroelectrochemistry in a Series of Quinonoid‐Bridged Diruthenium Complexes [(acac)2Ru(μ‐L)Ru(acac)2]n (n=+2, +1, 0, −1, −2)

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  28. Valence structures of the diastereomeric complexes meso- and rac-[Ru2(acac)4(μ-Q)]n (n = 2−, 1−, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane

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  29. Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4− Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species

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  30. Tricarbonylrhenium(i) complexes of highly symmetric hexaazatrinaphthylene ligands (HATN): structural, electrochemical and spectroscopic properties

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  31. “Chain-Like” Trimetallic Ruthenium Complexes with C7Carbon-Rich Bridges: Experimental and Theoretical Investigations of Electronic Communication Tuning in Five Distinct Oxidation States

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  32. Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties

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  33. Valence and spin situations in isomeric [(bpy)Ru(Q′)2]n (Q′ = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine). An experimental and DFT analysis

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  34. Binuclear Ruthenium(II) Carbonyl Schiff Base Complexes Containing N2O2 Donors and their Catalytic and Biological Activities

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  35. Complete Family of Mono-, Bi-, and Trinuclear Re I (CO) 3 Cl Complexes of the Bridging Polypyridyl Ligand 2,3,8,9,14,15-Hexamethyl-5,6,11,12,17,18-hexaazatrinapthalene: Syn/Anti Isomer Separation, Characterization, and Photophysics

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  36. Manifestations of Noninnocent Ligand Behavior

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  37. Influence of ancillary ligands on the electronic structure and anion sensing features of ligand bridged diruthenium complexes

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  38. Electronic structures and selective fluoride sensing features of Os(bpy) 2 (HL 2− ) and [{Os(bpy) 2 } 2 (μ-HL 2− )] 2+ (H 3 L: 5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic acid)

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  39. Sensitivity of the Valence Structure in Diruthenium Complexes As a Function of Terminal and Bridging Ligands

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  40. Trinuclear Complexes and Coordination Polymers of Redox-Active Guanidino-Functionalized Aromatic (GFA) Compounds with a Triphenylene Core

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  41. Dinuclear iridium and rhodium complexes with bridging arylimidazolide-N 3 ,C 2 ligands: synthetic, structural, reactivity, electrochemical and spectroscopic studies

    Dalton Transactions · 2015-01-01

    Fan He, Laurent Ruhlmann, Jean‐Paul Gisselbrecht, Sylvie Choua, Maylis Orio, Marcel Wesolek, Andreas A. Danopoulos, Pierre Braunstein

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  42. Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand

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    Mohd. Asif Ansari, Abhishek Mandal, Katharina Beyer, Alexa Paretzki, Brigitte E. Schwederski, Wolfgang Kaim, Goutam Kumar Lahiri

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  43. Synthesis and Optical Properties of Unsymmetrically Substituted Triarylamine Hexaazatrinaphthalenes

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    Christopher B. Larsen, Jonathan E. Barnsley, Holly van der Salm, Michael G. Fraser, Nigel T. Lucas, Keith Christopher Gordon

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  44. Long-Lived Polypyridyl Based Mononuclear Ruthenium Complexes: Synthesis, Structure, and Azo Dye Decomposition

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    Koushik Singha, Paltan Laha, Falguni Chandra, Niranjan Dehury, Apurba Lal Koner, Srikanta Patra

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  45. Mixed Donor–Acceptor‐Derived N,N′‐Diarylpyrazine‐2,5‐dicarboxamido‐Bridged Diruthenium Systems: Structures, Magnetic Properties, and Electronic Forms in Multiredox States

    European Journal of Inorganic Chemistry · 2017-10-25

    Farheen Fatima Khan, Abhishek Mandal, Johannes E. M. N. Klein, José Luis Priego, Reyes Jiménez‐Aparicio, Biprajit Sarkar, Goutam Kumar Lahiri

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  46. Redox Behavior of a Dinuclear Ruthenium(II) Complex Bearing an Uncommon Bridging Ligand: Insights from High-Pressure Electrochemistry

    Inorganic Chemistry · 2017-11-20

    Maximilian Dürr, Johannes E. M. N. Klein, Axel Kahnt, Sabine Becker, Ralph Puchta, Biprajit Sarkar, Ivana Ivanović‐Burmazović

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  47. Mixed valency in ligand-bridged diruthenium frameworks: divergences and perspectives

    RSC Advances · 2018-01-01

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