RESEARCH PAPER · Dalton Transactions · 2004
The triruthenium complex [{(acac) 2 Ru II } 3 (L)] containing a conjugated diquinoxaline[2,3-a:2′,3′-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation
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Synthesis, structure, redox, NLO and DNA interaction aspects of [{(L′ – ‴) 2 Ru II } 3 (μ 3 -L)] 3+ and [(L′) 2 Ru II (NC 5 H 4 S − )] + [L 3− = 1,3,5-triazine-2,4,6-trithiolato, L′ – ‴ = arylazopyridine]
Dalton Transactions · 2004-01-01
Sanjib Kar, Biswajit Pradhan, Rajeev K. Sinha, Tapanendu Kundu, Prashant Kodgire, Kestur Krishnamurthy Rao, Vedavati G. Puranik, Goutam Kumar Lahiri
Read original paper ↗ ·Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation
Inorganic Chemistry · 2004-08-18
Srikanta Patra, Biprajit Sarkar, Sandeep Kaur‐Ghumaan, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·15 Noble metals
Annual Reports Section A (Inorganic Chemistry) · 2005-01-01
Nicholas C. Fletcher
Read original paper ↗ ·3,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H + ) − as ligands for {(acac) 2 Ru n+ } or {(bpy) 2 Ru m+ }: investigation of mixed valency in [{(acac) 2 Ru} 2 (μ-L − H + )] 0 and [{(bpy) 2 Ru} 2 (μ-L − H + )] 4+ by spectroelectrochemistry and EPR
Dalton Transactions · 2005-01-01
Sandeep Kaur‐Ghumaan, Biprajit Sarkar, Srikanta Patra, Kumar Parimal, Joris van Slageren, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Syntheses, crystal structure and electrochemical properties of dinuclear ruthenium complexes containing saturated and unsaturated spacers
New Journal of Chemistry · 2005-01-01
Ping Cai, Mingxue Li, Chunying Duan, Feng Lu, Dong Guo, Qingjin Meng
Read original paper ↗ ·Tetrazine derived mononuclear RuII(acac)2(L) (1), [RuII(bpy)2(L)](ClO4)2 (2) and [RuII(bpy)(L)2](ClO4)2 (3) (L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac=acetylacetonate, bpy=2,2′-bipyridine): syntheses, structures, spectra and redox properties
Polyhedron · 2005-01-01
Animesh Nayak, Srikanta Patra, Biprajit Sarkar, Sandeep Kaur‐Ghumaan, Vedavati G. Puranik, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Unusual Monodentate Binding Mode of 2,2‘-Dipyridylamine (L) in Isomeric trans-(acac)2RuII(L)2, trans-[(acac)2RuIII(L)2]ClO4, and cis-(acac)2RuII(L)2 (acac = Acetylacetonate). Synthesis, Structures, and Spectroscopic, Electrochemical, and Magnetic Aspects
Inorganic Chemistry · 2005-02-08
Sanjib Kar, Nripen Chanda, Shaikh Md. Mobin, F.A. Urbanos, M. Niemeyer, Vedavati G. Puranik, Reyes Jiménez‐Aparicio, Goutam Kumar Lahiri
Read original paper ↗ ·2,5‐Dioxido‐1,4‐benzoquinonediimine (H2L2−), A Hydrogen‐Bonding Noninnocent Bridging Ligand Related to Aminated Topaquinone: Different Oxidation State Distributions in Complexes [{(bpy)2Ru}2(μ‐H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(μ‐H2L)]m (m=2−,−,0,+,2+)
Chemistry - A European Journal · 2005-06-14
Sanjib Kar, Biprajit Sarkar, Sandeep Kaur‐Ghumaan, Deepa Janardanan, Joris van Slageren, Jan Fiedler, Vedavati G. Puranik, Raghavan B. Sunoj, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties
Chemical Communications · 2006-01-01
Juan Manuel Herrera, Michael D. Ward, Harry Adams, Simon J. A. Pope, Stephen Faulkner
Read original paper ↗ ·Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium
Chemical Reviews · 2006-05-24
Deanna M. D’Alessandro, F. Richard Keene
Read original paper ↗ ·Mixed valency in ruthenium complexes—Coordinative aspects
Coordination Chemistry Reviews · 2006-06-16
Wolfgang Kaim, Biprajit Sarkar
Read original paper ↗ ·2,2‘-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes [(dpk)(Cl)Ru(μ-tppz)Ru(Cl)(dpk)]n+where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine
Inorganic Chemistry · 2006-08-02
Sandeep Kaur‐Ghumaan, Biprajit Sarkar, Nripen Chanda, Monika Sieger, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·An Experimental and Density Functional Theory Approach Towards the Establishment of Preferential Metal‐ or Ligand‐Based Electron‐Transfer Processes in Large Quinonoid‐Bridged Diruthenium Complexes [{(aap)2Ru}2(μ‐BL2–)]n+ (aap = 2‐Arylazopyridine)
European Journal of Inorganic Chemistry · 2006-08-24
Sandeep Kaur‐Ghumaan, Sriparna Mukherjee, Sanjib Kar, Dipankar Roy, Shaikh Md. Mobin, Raghavan B. Sunoj, Goutam Kumar Lahiri
Read original paper ↗ ·Tuning intermetallic electronic coupling in polyruthenium systems via molecular architecture
Journal of Chemical Sciences · 2006-11-01
Sandeep Kaur‐Ghumaan, Goutam Kumar Lahiri
Read original paper ↗ ·Electronic communication in “chain-like” trimetallic ruthenium complexes with two C 7 carbon-rich conjugated bridges
Chemical Communications · 2007-01-01
Céline Olivier, Sylvie Choua, Philippe Turek, Daniel Touchard, Stéphane Rigaut
Read original paper ↗ ·Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A 2 Ru(µ-L)RuA 2 ] n , A = 2,4-pentanedionato or 2-phenylazopyridine, L 2− = 2,5-bis(2-oxidophenyl)pyrazine
Dalton Transactions · 2007-01-01
Somnath Maji, Biprajit Sarkar, Shaikh Md. Mobin, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Unconventional Mixed‐Valent Complexes of Ruthenium and Osmium
Angewandte Chemie International Edition · 2007-02-26
Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums
Angewandte Chemie · 2007-02-26
Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex {(μ-tppz)[Ru(bik)Cl]2}3+(tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2‘-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and νCOLine Broadening
Inorganic Chemistry · 2007-03-28
Moumita Koley, Biprajit Sarkar, Sandeep Kaur‐Ghumaan, E. Bulak, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands
Polyhedron · 2007-03-31
Sandeep Kaur‐Ghumaan, Biprajit Sarkar, Mahendra P. Patil, Jan Fiedler, Raghavan B. Sunoj, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Dinuclear RuIIPHEHAT and -TPAC Complexes: Effects of the Second RuII Center on Their Spectroelectrochemical Properties
Inorganic Chemistry · 2007-05-09
Benjamin Elias, Leslie Herman, Cécile Moucheron, Andrée Kirsch‐De Mesmaeker
Read original paper ↗ ·Photophysical and Structural Properties of Cyanoruthenate Complexes of Hexaazatriphenylene
Journal of the American Chemical Society · 2007-08-22
Juan Manuel Herrera, Simon J. A. Pope, Anthony J. H. M. Meijer, Timothy L. Easun, Harry Adams, W.Z. Alsindi, Xue-Zhong Sun, Michael W. George, Stephen Faulkner, Michael D. Ward
Read original paper ↗ ·Binuclear ruthenium(III) Schiff base complexes bearing N4O4 donors and their catalytic oxidation of alcohols
Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2008-02-15
Galmari Venkatachalam, Nandhagopal Raja, Devaraj Pandiarajan, Rengan Ramesh
Read original paper ↗ ·Mixed-Valent Metals Bridged by a Radical Ligand: Fact or Fiction Based on Structure-Oxidation State Correlations
Journal of the American Chemical Society · 2008-02-22
Biprajit Sarkar, Srikanta Patra, Jan Fiedler, Raghavan B. Sunoj, Deepa Janardanan, Goutam Kumar Lahiri, Wolfgang Kaim
Read original paper ↗ ·Mixed-Valence Intermediates as Ideal Targets for Spectroelectrochemistry (SEC)
Royal Society of Chemistry eBooks · 2008-07-15
Wolfgang Kaim, Biprajit Sarkar, Goutam Kumar Lahiri
Read original paper ↗ ·The synthesis and electrochemistry of 2,5-dimethylazaferrocenes with heteroaryl bridges
Journal of Organometallic Chemistry · 2008-09-11
Konrad Kowalski, Rainer F. Winter
Read original paper ↗ ·Valence‐State Analysis through Spectroelectrochemistry in a Series of Quinonoid‐Bridged Diruthenium Complexes [(acac)2Ru(μ‐L)Ru(acac)2]n (n=+2, +1, 0, −1, −2)
Chemistry - A European Journal · 2008-10-16
Sandeep Kaur‐Ghumaan, Biprajit Sarkar, Somnath Maji, Vedavati G. Puranik, Jan Fiedler, F.A. Urbanos, Reyes Jiménez‐Aparicio, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Valence structures of the diastereomeric complexes meso- and rac-[Ru2(acac)4(μ-Q)]n (n = 2−, 1−, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane
Dalton Transactions · 2009-01-01
Doyel Kumbhakar, Biprajit Sarkar, Amit Das, Atanu Kumar Das, Shaikh Md. Mobin, Jan Fiedler, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4− Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species
Chemistry - A European Journal · 2009-06-04
Sayak Roy, Biprajit Sarkar, Carole Duboc, Jan Fiedler, Orkan Sarper, Falk Lissner, Shaikh Md. Mobin, Goutam Kumar Lahiri, Wolfgang Kaim
Read original paper ↗ ·Tricarbonylrhenium(i) complexes of highly symmetric hexaazatrinaphthylene ligands (HATN): structural, electrochemical and spectroscopic properties
Dalton Transactions · 2010-01-01
Sayak Roy, Clifford P. Kubiak
Read original paper ↗ ·“Chain-Like” Trimetallic Ruthenium Complexes with C7Carbon-Rich Bridges: Experimental and Theoretical Investigations of Electronic Communication Tuning in Five Distinct Oxidation States
Journal of the American Chemical Society · 2010-04-01
Céline Olivier, Karine Costuas, Sylvie Choua, Vincent Maurel, Philippe Turek, Jean‐Yves Saillard, Daniel Touchard, Stéphane Rigaut
Read original paper ↗ ·Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties
Dalton Transactions · 2011-01-01
Karine Costuas, Stéphane Rigaut
Read original paper ↗ ·Valence and spin situations in isomeric [(bpy)Ru(Q′)2]n (Q′ = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine). An experimental and DFT analysis
Dalton Transactions · 2011-01-01
Dipanwita Das, Tapan Kumar Mondal, Abhishek Dutta Chowdhury, Fritz Weißer, David Schweinfurth, Biprajit Sarkar, Shaikh Md. Mobin, F.A. Urbanos, Reyes Jiménez‐Aparicio, Goutam Kumar Lahiri
Read original paper ↗ ·Binuclear Ruthenium(II) Carbonyl Schiff Base Complexes Containing N2O2 Donors and their Catalytic and Biological Activities
Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry · 2011-01-31
Nagarajan Sathya, Gunasekaran Raja, Chinnasamy Jayabalakrishnan
Read original paper ↗ ·Complete Family of Mono-, Bi-, and Trinuclear Re I (CO) 3 Cl Complexes of the Bridging Polypyridyl Ligand 2,3,8,9,14,15-Hexamethyl-5,6,11,12,17,18-hexaazatrinapthalene: Syn/Anti Isomer Separation, Characterization, and Photophysics
Inorganic Chemistry · 2011-06-03
Michael G. Fraser, Charlotte A. Clark, Raphael Horvath, Samuel J. Lind, Allan G. Blackman, Xue‐Zhong Sun, Michael W. George, Keith Christopher Gordon
Read original paper ↗ ·Manifestations of Noninnocent Ligand Behavior
Inorganic Chemistry · 2011-07-11
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Read original paper ↗ ·Influence of ancillary ligands on the electronic structure and anion sensing features of ligand bridged diruthenium complexes
Dalton Transactions · 2013-01-01
Ankita Das, Tanaya Kundu, Shaikh Md. Mobin, José Luis Priego, Reyes Jiménez‐Aparicio, Goutam Kumar Lahiri
Read original paper ↗ ·Electronic structures and selective fluoride sensing features of Os(bpy) 2 (HL 2− ) and [{Os(bpy) 2 } 2 (μ-HL 2− )] 2+ (H 3 L: 5-(1H-benzo[d]imidazol-2-yl)-1H-imidazole-4-carboxylic acid)
Dalton Transactions · 2014-01-01
Ankita Das, Hemlata Agarwala, Tanaya Kundu, Prabir Ghosh, Sudipta Mondal, Shaikh Md. Mobin, Goutam Kumar Lahiri
Read original paper ↗ ·Sensitivity of the Valence Structure in Diruthenium Complexes As a Function of Terminal and Bridging Ligands
Inorganic Chemistry · 2014-06-04
Abhishek Mandal, Hemlata Agarwala, Ritwika Ray, Sebastian Plebst, Shaikh Md. Mobin, José Luis Priego, Reyes Jiménez‐Aparicio, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Trinuclear Complexes and Coordination Polymers of Redox-Active Guanidino-Functionalized Aromatic (GFA) Compounds with a Triphenylene Core
Inorganic Chemistry · 2014-09-04
A. Lebkucher, Christoph Wagner, Olaf Hübner, Elisabeth Kaifer, Hans‐Jörg Himmel
Read original paper ↗ ·Dinuclear iridium and rhodium complexes with bridging arylimidazolide-N 3 ,C 2 ligands: synthetic, structural, reactivity, electrochemical and spectroscopic studies
Dalton Transactions · 2015-01-01
Fan He, Laurent Ruhlmann, Jean‐Paul Gisselbrecht, Sylvie Choua, Maylis Orio, Marcel Wesolek, Andreas A. Danopoulos, Pierre Braunstein
Read original paper ↗ ·Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand
Dalton Transactions · 2017-01-01
Mohd. Asif Ansari, Abhishek Mandal, Katharina Beyer, Alexa Paretzki, Brigitte E. Schwederski, Wolfgang Kaim, Goutam Kumar Lahiri
Read original paper ↗ ·Synthesis and Optical Properties of Unsymmetrically Substituted Triarylamine Hexaazatrinaphthalenes
European Journal of Organic Chemistry · 2017-02-24
Christopher B. Larsen, Jonathan E. Barnsley, Holly van der Salm, Michael G. Fraser, Nigel T. Lucas, Keith Christopher Gordon
Read original paper ↗ ·Long-Lived Polypyridyl Based Mononuclear Ruthenium Complexes: Synthesis, Structure, and Azo Dye Decomposition
Inorganic Chemistry · 2017-05-16
Koushik Singha, Paltan Laha, Falguni Chandra, Niranjan Dehury, Apurba Lal Koner, Srikanta Patra
Read original paper ↗ ·Mixed Donor–Acceptor‐Derived N,N′‐Diarylpyrazine‐2,5‐dicarboxamido‐Bridged Diruthenium Systems: Structures, Magnetic Properties, and Electronic Forms in Multiredox States
European Journal of Inorganic Chemistry · 2017-10-25
Farheen Fatima Khan, Abhishek Mandal, Johannes E. M. N. Klein, José Luis Priego, Reyes Jiménez‐Aparicio, Biprajit Sarkar, Goutam Kumar Lahiri
Read original paper ↗ ·Redox Behavior of a Dinuclear Ruthenium(II) Complex Bearing an Uncommon Bridging Ligand: Insights from High-Pressure Electrochemistry
Inorganic Chemistry · 2017-11-20
Maximilian Dürr, Johannes E. M. N. Klein, Axel Kahnt, Sabine Becker, Ralph Puchta, Biprajit Sarkar, Ivana Ivanović‐Burmazović
Read original paper ↗ ·Mixed valency in ligand-bridged diruthenium frameworks: divergences and perspectives
RSC Advances · 2018-01-01
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Read original paper ↗ ·Synthesis, Crystal Structures, and Magnetic and Electrochemical Properties of Highly Phenyl Substituted Trinuclear 5,6,11,12,17,18-Hexaazatrinaphthylene (HATNPh6)-Bridged Titanium Complexes
Inorganic Chemistry · 2018-08-10
Pia Sander, Aleksandra Markovic, Marc Schmidtmann, Oliver Janka, Günther Wittstock, Rüdiger Beckhaus
Read original paper ↗ ·On the non-innocence and reactive versus non-reactive nature of α-diketones in a set of diruthenium frameworks
Dalton Transactions · 2020-12-10
Farheen Fatima Khan, Saikat Mondal, Shubhadeep Chandra, Nicolás I. Neuman, Biprajit Sarkar, Goutam Kumar Lahiri
Read original paper ↗ ·2,5-Pyrazine dicarboxylic acid ligand bridged symmetrical dinuclear ruthenium(II) complexes: Synthesis, structure and spectroelectrochemical properties
Inorganic Chemistry Communications · 2025-04-15
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Read original paper ↗ ·