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RESEARCH PAPER · Dalton Transactions · 2004

Synthesis, structure, redox, NLO and DNA interaction aspects of [{(L′ – ‴) 2 Ru II } 3 (μ 3 -L)] 3+ and [(L′) 2 Ru II (NC 5 H 4 S − )] + [L 3− = 1,3,5-triazine-2,4,6-trithiolato, L′ – ‴ = arylazopyridine]

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Synthesis, structure, redox, NLO and DNA interaction aspects of [{(L′ – ‴) 2 Ru II } 3 (μ 3 -L)] 3+ and [(L′) 2 Ru II (NC 5 H 4 S − )] + [L 3− = 1,3,5-triazine-2,4,6-trithiolato, L′ – ‴ = arylazopyridine]OriginalIsovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation6015 Noble metals13,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H + ) − as ligands for {(acac) 2 Ru n+ } or {(bpy) 2 Ru m+ }: investigation of mixed valency in [{(acac) 2 Ru} 2 (μ-L − H + )] 0 and [{(bpy) 2 Ru} 2 (μ-L − H + )] 4+ by spectroelectrochemistry and EPR44Effect of 2-(2-Pyridyl)azole-Based Ancillary Ligands (L1-4) on the Electrophilicity of the Nitrosyl Function in [RuII(trpy)(L1-4)(NO)]3+ [trpy = 2,2‘:6‘,2‘ ‘-Terpyridine]. Synthesis, Structures, and Spectroscopic, Electrochemical, and Kinetic Aspects64Halogenation of Ru(COD)(8-quinolinolate)2 and Ru(COD)(5-formyl-8-quinolinolate)282,5‐Dioxido‐1,4‐benzoquinonediimine (H2L2−), A Hydrogen‐Bonding Noninnocent Bridging Ligand Related to Aminated Topaquinone: Different Oxidation State Distributions in Complexes [{(bpy)2Ru}2(μ‐H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(μ‐H2L)]m (m=2−,−,0,+,2+)87Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (NN) Cleavage21A strategy of Pd(II) assisted C–H activation in 2-alkylamino azobenzene ligands: Syntheses, characterisation and structure of a new family of orthopalladated complexes34Controlling Metal–Ligand–Metal Oxidation State Combinations by Ancillary Ligand (L) Variation in the Redox Systems [L2Ru(μ‐boptz)RuL2]n, boptz=3,6‐bis(2‐oxidophenyl)‐1,2,4,5‐tetrazine, and L=acetylacetonate, 2,2′‐bipyridine, or 2‐phenylazopyridine60Ruthenium Complexes as Versatile Chromophores with Large, Switchable Hyperpolarizabilities10Tuning interaction in dinuclear ruthenium complexes: HOMO versus LUMO mediated superexchange through azole and azine bridges97Synthesis, characterization and screening of biological activity of Zn(II), Fe(II) and Mn(II) complexes with trithiocyanuric acid20Unconventional Mixed‐Valent Complexes of Ruthenium and Osmium345Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums115Synthesis, characterization and reactivity of a trinuclear copper(II) thiocyanurate complex: A spin-frustrated molecular propeller10Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands22Novel Rh(III) pentamethylcyclopentadienyl and Ru(II) cyclopentadienyl complexes containing 1,3,5-triazine-2,4,6-trithiol in trinucleating mode9Synthesis, Characterization, and Norbornene Polymerization Behavior of the Half-Sandwich Complexes [Cp*3M3(μ3-L)Cl3] and [Cp*M(2-SPyH)Cl2] (M = Ir, M = Rh, [L]3−= 1,3,5-Triazine-2,4,6-trithiolato, 2-SPy = 2-Pyridinethione)34Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates33Sensitive Valence Structures of [(pap)2Ru(Q)]n(n= +2, +1, 0, −1, −2) with Two Different Redox Noninnocent Ligands, Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine and pap = 2-Phenylazopyridine48Ferromagnetic Properties of a Trinuclear Nickel(II) Complex with a Trithiocyanurate Bridge21Conformational isomerism and hydrogen-bonded motifs of anion assisted supramolecular self-assemblies using CuII/CoII salts and pyridine-4-acetamide21Ruthenium nitrosyl complexes with 1,4,7-trithiacyclononane and 2,2′-bipyridine (bpy) or 2-phenylazopyridine (pap) coligands. Electronic structure and reactivity aspects32Synthesis, Characterization, and Crystal Structure of Bis(2,2′-Dipyridyl) (Nitropyridylsulfide) Ruthenium(II) (Hexafluorophosphate)2Electronic structures and reactivity aspects of ruthenium–nitrosyls18Terpyridine platinum(ii) complexes containing triazine di- or tri-thiolate bridges: structures, luminescence, electrochemistry, and aggregation28Influence of ancillary ligands on the electronic structure and anion sensing features of ligand bridged diruthenium complexes25Electroacupuncture Attenuates Reference Memory Impairment Associated with Astrocytic NDRG2 Suppression in APP/PS1 Transgenic Mice41Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes10Trithiocyanurate Complexes of Iron, Manganese and Nickel and Their Anticholinesterase Activity14Introducing a New Azoaromatic Pincer Ligand. Isolation and Characterization of Redox Events in Its Ferrous Complexes56Synthesis and spectral studies on metal complexes of s-triazine based ligand and non linear optical properties26Biological Activity and Molecular Structures of Bis(benzimidazole) and Trithiocyanurate Complexes46Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes471,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled β-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes24Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand18Molecular ReI Cages: Structural and Luminescent Properties16Anionic Dinuclear Oxidovanadium(IV) Complexes with Azo Functionalized Tridentate Ligands and μ-Ethoxido Bridge Leading to an Unsymmetric Twisted Arrangement: Synthesis, X-ray Structure, Magnetic Properties, and Cytotoxicity42Toward a dodecanuclear molecular Re( i ) box: structural and spectroscopic properties4Review. Inverse coordination. Organic nitrogen heterocycles as coordination centers. A survey of molecular topologies and systematization. Part 2. Six-membered rings29Toward Heteronuclear Molecular Re(I)-Cu(II) Boxes: Structural, Luminescent, and Magnetic Properties2Diruthenium and triruthenium compounds of the potential redox active non-chelated η 1 -N,η 1 -N-benzothiadiazole bridge8On the Question of S–S Bond Cleavage of 2,2′-Dithiodipyridine on Selective Ru and Os Platforms. MLCT or Hydride or Solvent Mediated Event9Synthesis, Structure and Magnetic Behavior of a Novel Series of Trinuclear Windwheel Complexes4Azopyridinium Ionic Photoswitches: Tuning Half‐Lives of Z Isomers from Seconds to Days in Water8Toward heteronuclear Re( i )-C 3 N 3 S 3 (C 3 N 3 S 3 = trithiocyanurate trianion) cages: structural, luminescence, and magnetic properties0

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  1. Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation

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  2. 15 Noble metals

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  3. 3,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H + ) − as ligands for {(acac) 2 Ru n+ } or {(bpy) 2 Ru m+ }: investigation of mixed valency in [{(acac) 2 Ru} 2 (μ-L − H + )] 0 and [{(bpy) 2 Ru} 2 (μ-L − H + )] 4+ by spectroelectrochemistry and EPR

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  4. Effect of 2-(2-Pyridyl)azole-Based Ancillary Ligands (L1-4) on the Electrophilicity of the Nitrosyl Function in [RuII(trpy)(L1-4)(NO)]3+ [trpy = 2,2‘:6‘,2‘ ‘-Terpyridine]. Synthesis, Structures, and Spectroscopic, Electrochemical, and Kinetic Aspects

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  5. Halogenation of Ru(COD)(8-quinolinolate)2 and Ru(COD)(5-formyl-8-quinolinolate)2

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  6. 2,5‐Dioxido‐1,4‐benzoquinonediimine (H2L2−), A Hydrogen‐Bonding Noninnocent Bridging Ligand Related to Aminated Topaquinone: Different Oxidation State Distributions in Complexes [{(bpy)2Ru}2(μ‐H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(μ‐H2L)]m (m=2−,−,0,+,2+)

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  7. Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (NN) Cleavage

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    Jahar Lal Pratihar, Nilkamal Maiti, Surajit Chattopadhyay

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  9. Controlling Metal–Ligand–Metal Oxidation State Combinations by Ancillary Ligand (L) Variation in the Redox Systems [L2Ru(μ‐boptz)RuL2]n, boptz=3,6‐bis(2‐oxidophenyl)‐1,2,4,5‐tetrazine, and L=acetylacetonate, 2,2′‐bipyridine, or 2‐phenylazopyridine

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  10. Ruthenium Complexes as Versatile Chromophores with Large, Switchable Hyperpolarizabilities

    Challenges and advances in computational chemistry and physics · 2006-01-01

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  11. Tuning interaction in dinuclear ruthenium complexes: HOMO versus LUMO mediated superexchange through azole and azine bridges

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    Wesley R. Browne, Ronald Hage B, Johannes G. Vos

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  12. Synthesis, characterization and screening of biological activity of Zn(II), Fe(II) and Mn(II) complexes with trithiocyanuric acid

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  13. Unconventional Mixed‐Valent Complexes of Ruthenium and Osmium

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  14. Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums

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  15. Synthesis, characterization and reactivity of a trinuclear copper(II) thiocyanurate complex: A spin-frustrated molecular propeller

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  16. Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands

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  17. Novel Rh(III) pentamethylcyclopentadienyl and Ru(II) cyclopentadienyl complexes containing 1,3,5-triazine-2,4,6-trithiol in trinucleating mode

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    Manoj Trivedi, Daya Shankar Pandey, Ru-Qiang Zou, Qiang Xü

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  18. Synthesis, Characterization, and Norbornene Polymerization Behavior of the Half-Sandwich Complexes [Cp*3M3(μ3-L)Cl3] and [Cp*M(2-SPyH)Cl2] (M = Ir, M = Rh, [L]3−= 1,3,5-Triazine-2,4,6-trithiolato, 2-SPy = 2-Pyridinethione)

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  19. Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates

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  20. Sensitive Valence Structures of [(pap)2Ru(Q)]n(n= +2, +1, 0, −1, −2) with Two Different Redox Noninnocent Ligands, Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine and pap = 2-Phenylazopyridine

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  24. Synthesis, Characterization, and Crystal Structure of Bis(2,2′-Dipyridyl) (Nitropyridylsulfide) Ruthenium(II) (Hexafluorophosphate)

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  26. Terpyridine platinum(ii) complexes containing triazine di- or tri-thiolate bridges: structures, luminescence, electrochemistry, and aggregation

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  27. Influence of ancillary ligands on the electronic structure and anion sensing features of ligand bridged diruthenium complexes

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  28. Electroacupuncture Attenuates Reference Memory Impairment Associated with Astrocytic NDRG2 Suppression in APP/PS1 Transgenic Mice

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  31. Introducing a New Azoaromatic Pincer Ligand. Isolation and Characterization of Redox Events in Its Ferrous Complexes

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  35. 1,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled β-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes

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  36. Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand

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  44. Synthesis, Structure and Magnetic Behavior of a Novel Series of Trinuclear Windwheel Complexes

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