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RESEARCH PAPER · Inorganic Chemistry · 2015

Positional Flexibility: Syntheses and Characterization of Six Uranium Chalcogenides Related to the 2H Hexagonal Perovskite Family

Adel Mesbah, Jai Prakash, Jessica C. Beard, Eric A. Pozzi, М.С. Тарасенко, Sébastien Lebègue∥, Christos D. Malliakas, Richard P. Van Duyne, James A. Ibers

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Positional Flexibility: Syntheses and Characterization of Six Uranium Chalcogenides Related to the 2H Hexagonal Perovskite FamilyOriginalChemInform Abstract: Positional Flexibility: Syntheses and Characterization of Six Uranium Chalcogenides Related to the 2H Hexagonal Perovskite Family.0Syntheses, crystal structures, and electronic properties of Ba 8 Si 2 US 14 and Ba 8 SiFeUS 147Overview of the crystal chemistry of the actinide chalcogenides: incorporation of the alkaline-earth elements19Two new ternary chalcogenides Ba2ZnQ3(Q= Se, Te) with chains of ZnQ4tetrahedra: syntheses, crystal structure, and optical and electronic properties14Synthesis, Crystal Structure, Theoretical, and Resistivity Study of BaUSe311Tetrametallic Thorium Compounds with Th 4 E 4 (E = S, Se) Cubane Cores7K(Th0.75Sr0.25)2Se6: Structural Change Resulting from the Disorder of Differently Charged Cations1Syntheses, modulated crystal structures of Ba6−2xU2+xAg4Se12 (x = 0 and 0.5), and crystal structure and spectroscopy of Sr4Th2.78Cu4S122Syntheses and crystal structures of the Ba7UM2S12.5O0.5 (M = Ti, Si/Fe) compounds1AnSen (An = Th, U, Np, Pu, Am, or Cm) Coordination Polyhedra in Crystal Structures4AnSn Coordination Polyhedra (An = Th, U, Np, Pu, Am, Cm, or Cf) in Crystal Structures3Facile Oxide to Chalcogenide Conversion for Actinides Using the Boron-Chalcogen Mixture Method38Five coordinated Mn in Ba 4 Mn 2 Si 2 Te 9 : synthesis, crystal structure, physical properties, and electronic structure10Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method23Structures and Magnetic Properties of K2Pd4U6S17, K2Pt4U6S17, Rb2Pt4U6S17, and Cs2Pt4U6S17 Synthesized Using the Boron–Chalcogen Mixture Method10Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family21Synthesis of uranium mixed anion compounds synthesized using the Boron-Chalcogen Mixture method: Ba6Co6U0·91S13·5O0.5 and Ba5·47K0·53Zn6US13·5O0.55Ba8Zr2Se11(Se2): The first polychalcogenide of the ternary Ba–Zr–Q (Q = S/Se/Te) system11Synthesis, Characterization, and Magnetic Properties of Uranium-Containing 2H-Perovskite-Related Sulfides: Ba3MUS6 (M = Mn, Fe, Co, Ni) and Ba3Co0.858(5)Mg0.142(5)US65Rare Bird: U+5 in Uranium Chalcogenides6Structural evolution and bonding features of electron deficient copper chalcogenides3Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities2

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  1. ChemInform Abstract: Positional Flexibility: Syntheses and Characterization of Six Uranium Chalcogenides Related to the 2H Hexagonal Perovskite Family.

    ChemInform · 2015-05-15

    Adel Mesbah, Jai Prakash, Jessica C. Beard, Eric A. Pozzi, М.С. Тарасенко, Sébastien Lebègue∥, Christos D. Malliakas, Richard P. Van Duyne, James A. Ibers

    Read original paper ↗ ·

  2. Syntheses, crystal structures, and electronic properties of Ba 8 Si 2 US 14 and Ba 8 SiFeUS 14

    Solid State Sciences · 2015-07-26

    Adel Mesbah, Jai Prakash, Sébastien Lebègue∥, Wojciech Stojko, James A. Ibers

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  3. Overview of the crystal chemistry of the actinide chalcogenides: incorporation of the alkaline-earth elements

    Dalton Transactions · 2016-01-01

    Adel Mesbah, Jai Prakash, James A. Ibers

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  4. Two new ternary chalcogenides Ba2ZnQ3(Q= Se, Te) with chains of ZnQ4tetrahedra: syntheses, crystal structure, and optical and electronic properties

    Zeitschrift für Naturforschung B · 2016-03-25

    Jai Prakash, Adel Mesbah, Jessica C. Beard, Dario Rocca, Sébastien Lebègue∥, Christos D. Malliakas, James A. Ibers

    Read original paper ↗ ·

  5. Synthesis, Crystal Structure, Theoretical, and Resistivity Study of BaUSe3

    Inorganic Chemistry · 2016-07-11

    Jai Prakash, М.С. Тарасенко, Adel Mesbah, Sébastien Lebègue∥, Christos D. Malliakas, James A. Ibers

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  6. Tetrametallic Thorium Compounds with Th 4 E 4 (E = S, Se) Cubane Cores

    Inorganic Chemistry · 2017-08-23

    Matthew A. Stuber, Anna Y. Kornienko, Thomas J. Emge, John G. Brennan

    Read original paper ↗ ·

  7. K(Th0.75Sr0.25)2Se6: Structural Change Resulting from the Disorder of Differently Charged Cations

    Inorganic Chemistry · 2018-06-11

    Adel Mesbah, Jai Prakash, Jessica C. Beard, Christos D. Malliakas, James A. Ibers

    Read original paper ↗ ·

  8. Syntheses, modulated crystal structures of Ba6−2xU2+xAg4Se12 (x = 0 and 0.5), and crystal structure and spectroscopy of Sr4Th2.78Cu4S12

    Journal of Solid State Chemistry · 2018-08-20

    Adel Mesbah, Jai Prakash, Jessica C. Beard, Christos D. Malliakas, Sébastien Lebègue∥, James A. Ibers

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  9. Syntheses and crystal structures of the Ba7UM2S12.5O0.5 (M = Ti, Si/Fe) compounds

    Materials Letters · 2019-05-22

    Adel Mesbah, Jai Prakash, Jessica C. Beard, Christos D. Malliakas, James A. Ibers

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  10. AnSen (An = Th, U, Np, Pu, Am, or Cm) Coordination Polyhedra in Crystal Structures

    Radiochemistry · 2020-04-01

    В. Н. Сережкин, M. Albakajaji, Д. В. Пушкин, Л. Б. Сережкина

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  11. AnSn Coordination Polyhedra (An = Th, U, Np, Pu, Am, Cm, or Cf) in Crystal Structures

    Radiochemistry · 2020-06-01

    В. Н. Сережкин, M. Albakajaji, Л. Б. Сережкина

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  12. Facile Oxide to Chalcogenide Conversion for Actinides Using the Boron-Chalcogen Mixture Method

    Journal of the American Chemical Society · 2020-07-27

    Logan S. Breton, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  13. Five coordinated Mn in Ba 4 Mn 2 Si 2 Te 9 : synthesis, crystal structure, physical properties, and electronic structure

    Dalton Transactions · 2022-01-01

    Sweta Yadav, Subhendu Jana, Gopabandhu Panigrahi, Sairam K. Malladi, Manish K. Niranjan, Jai Prakash

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  14. Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

    Chemical Communications · 2022-01-01

    Logan S. Breton, Gregory W. Morrison, Matthew R. Lacroix, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  15. Structures and Magnetic Properties of K2Pd4U6S17, K2Pt4U6S17, Rb2Pt4U6S17, and Cs2Pt4U6S17 Synthesized Using the Boron–Chalcogen Mixture Method

    Inorganic Chemistry · 2022-06-29

    Logan S. Breton, Ryan Baumbach, Hunter B. Tisdale, Hans‐Conrad zur Loye

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  16. Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family

    Journal of the American Chemical Society · 2022-07-21

    Anna A. Berseneva, Vladislav V. Klepov, Koushik Pal, Kelly Seeley, Daniel Koury, Joseph C. Schaeperkoetter, Joshua Wright, Scott T. Misture, Mercouri G. Kanatzidis, Chris M. Wolverton, Artem V. Gelis, Hans‐Conrad zur Loye

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  17. Synthesis of uranium mixed anion compounds synthesized using the Boron-Chalcogen Mixture method: Ba6Co6U0·91S13·5O0.5 and Ba5·47K0·53Zn6US13·5O0.5

    Solid State Sciences · 2023-05-06

    Logan S. Breton, Mark D. Smith, Hans‐Conrad zur Loye

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  18. Ba8Zr2Se11(Se2): The first polychalcogenide of the ternary Ba–Zr–Q (Q = S/Se/Te) system

    Journal of Solid State Chemistry · 2023-09-27

    Komal Srivastava, Omair Shahid, Akshay Kumar Ray, Melepurath Deepa, Manish K. Niranjan, Jai Prakash

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  19. Synthesis, Characterization, and Magnetic Properties of Uranium-Containing 2H-Perovskite-Related Sulfides: Ba3MUS6 (M = Mn, Fe, Co, Ni) and Ba3Co0.858(5)Mg0.142(5)US6

    Inorganic Chemistry · 2023-10-09

    Logan S. Breton, Gregory W. Morrison, Hans‐Conrad zur Loye

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  20. Rare Bird: U+5 in Uranium Chalcogenides

    Chemistry of Materials · 2024-08-12

    Anna A. Berseneva, Vladislav V. Klepov, Habiba Binte Kashem, Alevtina A. Maksimova, Gregory W. Morrison, Joshua Wright, Joseph C. Schaeperkoetter, Scott T. Misture, Hans‐Conrad zur Loye

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  21. Structural evolution and bonding features of electron deficient copper chalcogenides

    CrystEngComm · 2025-01-01

    Sergei A. Novikov, James Casey, Hope A. Long, Vladislav V. Klepov

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  22. Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities

    Journal of Physics and Chemistry of Solids · 2025-04-19

    Sweta Yadav, Sambit S.S. Rout, Omair Shahid, Gohil Singh Thakur, Manish K. Niranjan, Jai Prakash

    Read original paper ↗ ·
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