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RESEARCH PAPER · Crystal Growth & Design · 2014

A Synthetic Route toward Layered Materials: Introducing Stereochemically Active Lone-Pairs into Transition Metal Oxohalides

Iwan Zimmermann, Mats Johnsson

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A Synthetic Route toward Layered Materials: Introducing Stereochemically Active Lone-Pairs into Transition Metal OxohalidesOriginalBaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds18Investigation of reactivity and structure formation in a K–Te–U oxo-system under high-temperature/high-pressure conditions7Sb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures9Copper polytellurite-chlorides with A2+ cations (ACd, Pb) obtained by CVT reactions5Ni3Sb4O6F6 and Its Electrochemical Behavior toward Lithium─A Combination of Conversion and Alloying Reactions7Chemical vapor transport and solid-state exchange synthesis of new copper selenite bromides6Investigation of the Structural and Electrochemical Properties of Mn 2 Sb 3 O 6 Cl upon Reaction with Li Ions4Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties12Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl26Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides7Copper–lead selenite bromides: a new large family of compounds partly having Cu2+ substructures derivable from kagome nets10Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90Influence of the alkali cation size on the Cu2+ coordination environments in (AX)[Cu(HSeO3)2] (A=Na, K, NH4, Rb, Cs; X=Cl, Br) layered copper hydrogen selenite halides15Flux Growth of Tungsten Oxychloride Li 23 CuW 10 O 40 Cl 50Li 2 (Se 2 O 5 )(H 2 O) 1.5 ·CuCl 2 , a salt-inclusion diselenite structurally based on tetranuclear Li 4 complexes9Synthesis and Structure of New Rare Earth Cadmium Tellurite Halides9Layered calcium hydrogen selenite chlorides Ca(HSeO3)Cl and Ca(HSeO3)Cl(H2O), the first halides obtained in СaCl2–H2SeO3–H2O system4Symmetry Analysis of the Complex Polytypism of Layered Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition Metals6A new family of rare earth – strontium tellurite chlorides, SrLn4(TeO3)4Cl6 (Ln = Ce, Nd, Sm): Synthesis, crystal structures, possible polytypism, and crystal-chemical relationships5Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)32[Cd7(SeO3)8]{Cu2Br2}, a host-guest structure derived from β-CdSeO30Structural and Spectroscopic Studies of (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5]—New Members of the Transition Metal (Hydro)Selenite-Halide Family0Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br4Alkali-metal (ammonium) cadmium hydroselenite halides: an interplay of two stoichiometries2

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  1. BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions

    Journal of Materials Chemistry C · 2015-01-01

    Lei Geng, Qiang Li, Chang‐Yu Meng, Kai Dai, Hong‐Yan Lu, Chensheng Lin, Wen‐Dan Cheng

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  2. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

    Zeitschrift für Kristallographie - Crystalline Materials · 2015-08-07

    Vadim M. Kovrugin, Sergey V. Krivovichev, Olivier Mentré, Marie Colmont

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  3. Investigation of reactivity and structure formation in a K–Te–U oxo-system under high-temperature/high-pressure conditions

    Dalton Transactions · 2016-01-01

    Bin Xiao, Philip Kegler, Dirk Bosbach, Evgeny V. Alekseev

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  4. Sb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures

    Dalton Transactions · 2016-01-01

    Lei Geng, Qiang Li, Hong‐Yan Lu, Kai Dai, P. Shiv Halasyamani

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  5. Copper polytellurite-chlorides with A2+ cations (ACd, Pb) obtained by CVT reactions

    Inorganic Chemistry Communications · 2016-07-12

    Diana O. Zinyakhina, Oleg I. Siidra, Dmitri O. Charkin, Еvgeny V. Nazarchuk, Р. С. Бубнова

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  6. Ni3Sb4O6F6 and Its Electrochemical Behavior toward Lithium─A Combination of Conversion and Alloying Reactions

    Chemistry of Materials · 2016-08-29

    Viktor Renman, Shichao Hu, Rickard Eriksson, Julia Maibach, Mats Johnsson, Cesar Pay Gómez, Kristina Edström

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  7. Chemical vapor transport and solid-state exchange synthesis of new copper selenite bromides

    Solid State Sciences · 2016-12-29

    Dmitri O. Charkin, Roman A. Kayukov, Karim A. Zagidullin, Oleg I. Siidra

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  8. Investigation of the Structural and Electrochemical Properties of Mn 2 Sb 3 O 6 Cl upon Reaction with Li Ions

    The Journal of Physical Chemistry C · 2017-03-02

    Viktor Renman, Mario Valvo, Cheuk‐Wai Tai, Iwan Zimmermann, Mats Johnsson, Cesar Pay Gómez, Kristina Edström

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  9. Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties

    Dalton Transactions · 2018-01-01

    Tiffany M. Smith Pellizzeri, Michael A. McGuire, Colin D. McMillen, Yimei Wen, George D. Chumanov, Joseph W. Kolis

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  10. Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl2

    Journal of Solid State Chemistry · 2018-05-26

    Qiang Li, Lei Geng, Hong‐Yan Lu, Kai Dai, Wen‐Dan Cheng

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  11. Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides

    Zeitschrift für Kristallographie - Crystalline Materials · 2018-10-16

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Dmitry O. Charkin, Almaz Aliev, Sergey V. Krivovichev, Olivier Mentré

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  12. Copper–lead selenite bromides: a new large family of compounds partly having Cu2+ substructures derivable from kagome nets

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2018-11-30

    Oleg I. Siidra, M.S. Kozin, Wulf Depmeier, Roman A. Kayukov, Vadim M. Kovrugin

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  13. Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+

    Chemical Communications · 2019-01-01

    Kang Min Ok

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  14. Influence of the alkali cation size on the Cu2+ coordination environments in (AX)[Cu(HSeO3)2] (A=Na, K, NH4, Rb, Cs; X=Cl, Br) layered copper hydrogen selenite halides

    Zeitschrift für Kristallographie - Crystalline Materials · 2019-11-22

    Dmitri O. Charkin, Mishel R. Markovski, Oleg I. Siidra, Diana O. Nekrasova, Vasili Yu Grishaev

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  15. Flux Growth of Tungsten Oxychloride Li 23 CuW 10 O 40 Cl 5

    Journal of Inorganic Materials · 2020-01-01

    Shu‐Fang Li, Shuang ZHAO, Man‐Rong Li

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  16. Li 2 (Se 2 O 5 )(H 2 O) 1.5 ·CuCl 2 , a salt-inclusion diselenite structurally based on tetranuclear Li 4 complexes

    Dalton Transactions · 2020-01-01

    Mishel R. Markovski, Oleg I. Siidra, Dmitri O. Charkin, Victoria A. Ginga, Alexander A. Tsirlin, Vasili Yu Grishaev

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  17. Synthesis and Structure of New Rare Earth Cadmium Tellurite Halides

    Russian Journal of Inorganic Chemistry · 2020-04-01

    Dmitri O. Charkin, Vasili Yu Grishaev, Sergey N. Volkov, В. А. Долгих

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  18. Layered calcium hydrogen selenite chlorides Ca(HSeO3)Cl and Ca(HSeO3)Cl(H2O), the first halides obtained in СaCl2–H2SeO3–H2O system

    Zeitschrift für Kristallographie - Crystalline Materials · 2020-07-24

    Mishel R. Markovski, Oleg I. Siidra, Dmitri O. Charkin, Vasili Yu Grishaev

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  19. Symmetry Analysis of the Complex Polytypism of Layered Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition Metals

    Symmetry · 2022-10-07

    Dmitri O. Charkin, В. А. Долгих, Timofey A. Omelchenko, Yulia A. Vaitieva, Sergey N. Volkov, Dina V. Deyneko, Sergey M. Aksenov

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  20. A new family of rare earth – strontium tellurite chlorides, SrLn4(TeO3)4Cl6 (Ln = Ce, Nd, Sm): Synthesis, crystal structures, possible polytypism, and crystal-chemical relationships

    Journal of Solid State Chemistry · 2022-12-23

    Dmitri O. Charkin, Sergey N. Volkov, Vasili Yu Grishaev, В. А. Долгих, Alexey N. Kuznetsov∥, Dina V. Deyneko, Konstantin Alexandrovich Lyssenko, Sergey M. Aksenov

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  21. Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)

    Journal of Structural Chemistry · 2023-10-01

    Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, D. А. Banaru, Sergey N. Volkov, Д. В. Дейнеко, Alexey N. Kuznetsov∥, Рамиза Кераровна Расцветаева, Н. В. Чуканов, B. B. Shkurskii, N. A. Yamnova

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  22. [Cd7(SeO3)8]{Cu2Br2}, a host-guest structure derived from β-CdSeO3

    Zeitschrift für Kristallographie - Crystalline Materials · 2024-06-25

    Oleg I. Siidra, Vasili Yu Grishaev

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  23. Structural and Spectroscopic Studies of (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5]—New Members of the Transition Metal (Hydro)Selenite-Halide Family

    Inorganic Materials · 2025-02-01

    D. O. Charkin, А.М. Горянский, Vasili Yu Grishaev, Kompanchenko A.A., A. N. Gosteva, Sergey M. Aksenov

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  24. Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br

    Structural Chemistry · 2025-03-13

    Dmitri O. Charkin, Vasili Yu Grishaev, Oleg I. Siidra, A. M. Banaru, Sergey M. Aksenov

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  25. Alkali-metal (ammonium) cadmium hydroselenite halides: an interplay of two stoichiometries

    Structural Chemistry · 2025-07-03

    Dmitri O. Charkin, Vasili Yu Grishaev, Vadim E. Kireev, A. M. Banaru, Sergey M. Aksenov

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