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RESEARCH PAPER · Chemistry of Materials · 2004

Transport and Defect Mechanisms in Cuprous Delafossites. 2. CuScO2and CuYO2

Brian J. Ingram, Bryan J. Harder, Nikolas W. Hrabe, Thomas O. Mason, Kenneth Reinhard Poeppelmeier

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Transport and Defect Mechanisms in Cuprous Delafossites. 2. CuScO2and CuYO2OriginalPoint defects and transport mechanisms in transparent conducting oxides of intermediate conductivity34Transport and Defect Mechanism in Cuprous Delafossites. Part 2. CuScO2 and CuYO2.0First-principles study of Sn and Ca doping in CuInO224Crystal chemistry and electrical properties of the delafossite structure384First-Principles Study of Bipolar Dopability in the CuInO2 Transparent Semiconductor16Preparation of delafossite CuFeO2 thin films by rf-sputtering on conventional glass substrate80Syntheses, crystal and electronic structure, and some optical and transport properties of LnCuOTe (Ln=La, Ce, Nd)68p -type transparent conductor: Zn-doped CuAlS258Effects of Postannealing on Orientation and Crystallinity of P-Type Transparent Conducting CuScO2 Thin Films10Electrical and optical properties of excess oxygen intercalated CuScO2(0001) epitaxial films prepared by oxygen radical annealing11Optical and electrical properties study on p-type conducting CuAlS2+x with wide band gap25A promising p-type transparent conducting material: Layered oxysulfide [Cu2S2][Sr3Sc2O5]55ZnO and Its Applications65The Optical and Electrical Properties of Zn-Doped CuAlO[sub 2] Thin Films Deposited by RF Magnetron Sputtering18Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesis94p-Type electrical conduction and wide optical band gap in Mg-doped CuAlS219P-Type Transparent Conductivity of Cu1-xAlS2 (x = 0 ~ 0.08)7Silver Delafossite Oxides97First-principle study of extrinsic defects in CuScO2 and CuYO214Syntheses, Crystal Structures, and Physical Properties of La5Cu6O4S7 and La5Cu6.33O4S718Band structure and thermopower of doped YCuO221Structure and optoelectronic properties of spray deposited Mg doped p-CuCrO2 semiconductor oxide thin films75First-principles study of p-type transparent conductive oxides CuXO2 (X=Y, Sc, and Al)37First-principle study of native defects in CuScO 2 and CuYO 213Optical and electrical properties of CuScO2 epitaxial films prepared by combining two-step deposition and post-annealing techniques17Bulk defect chemistry and surface electronic behavior of Zn,Sn codoped In2O3 transparent conducting oxides14Effects of Mg doping on structural, optical, and electrical properties of CuScO2(0001) epitaxial films12Acceptor Levels in p -Type Cu2O : Rationalizing Theory and Experiment303Understanding the p-Type Conduction Properties of the Transparent Conducting Oxide CuBO2: A Density Functional Theory Analysis112Room temperature ozone sensing properties of p-type CuCrO2 nanocrystals84Zn-doped CuAlS2 transparent p-type conductive thin films deposited by pulsed plasma deposition10(Cu 2 S 2 )(Sr 3 Sc 2 O 5 )−A Layered, Direct Band Gap, p-Type Transparent Conducting Oxychalcogenide: A Theoretical Analysis.85Understanding conductivity in SrCu 2 O 2 : stability, geometry and electronic structure of intrinsic defects from first principles44Understanding conductivity anomalies in CuI-based delafossite transparent conducting oxides: Theoretical insights116Improving the electrical conductivity of CuCrO2 thin film by N doping43Growth Strategy and Physical Properties of the High Mobility P-Type CuI Crystal226First principles study of CuAlO2 doping with S16Ternary and Multinary Materials: Crystal/Defect Structure–Property Relationships5Semiconducting Oxides to Facilitate the Conversion of Solar Energy to Chemical Fuels106Combined Jonker and Ioffe Analysis of Oxide Conductors and Semiconductors41Conductivity Limits in CuAlO2 from Screened-Hybrid Density Functional Theory132Copper doped nickel oxide transparent p-type conductive thin films deposited by pulsed plasma deposition52Band gap anomalies of the ZnM2IIIO4 (MIII = Co, Rh, Ir) spinels67Indium-doped molybdenum oxide as a new p-type transparent conductive oxide58Understanding the p-type defect chemistry of CuCrO2214Effect of Ca-doping on the structural and electrical properties of CuY1−xCaxO2 (0≤x≤0.10) ceramics10Highly enhanced p-type electrical conduction in wide band gap Cu1+xAl1−xS2 polycrystals32Chemical bonding in copper-based transparent conducting oxides: CuMO2(M = In, Ga, Sc)38Density functional theory study on transparent conductive oxide CuScO22On the possibility of p-type SnO2180Structural, electronic band transition and optoelectronic properties of delafossite CuGa1−xCrxO2 (0 ≤ x ≤ 1) solid solution films grown by the sol–gel method71Transparent conductive p-type lithium-doped nickel oxide thin films deposited by pulsed plasma deposition26Recent Developments of ZnO-Based P-Type Transparent Conductive Oxide Thin Films0Enhanced Performance of p‐Type Dye‐Sensitized Solar Cells Based on Ultrasmall Mg‐Doped CuCrO2 Nanocrystals78Electronic transition and electrical transport properties of delafossite CuCr1−xMgxO2 (0 ≤ x ≤ 12%) films prepared by the sol-gel method: A composition dependence study40Structural, mechanical, electronic, optical properties and effective masses of CuMO2 (M = Sc, Y, La) compounds: First-principles calculations16Structural, elastic and electronic properties of CuYO2 from first-principles study10Strong temperature-dependent crystallization, phase transition, optical and electrical characteristics of p-type CuAlO 2 thin films19Ternary chalcogenides Cs2Zn3Se4 and Cs2Zn3Te4 : Potential p -type transparent conducting materials11Structural and electronic properties of transparent conducting delafossite: a comparison between the AgBO 2 and CuBO 2 families (B = Al, Ga, In and Sc, Y)38Enhancing the Performance of a Robust Sol–Gel‐Processed p‐Type Delafossite CuFeO 2 Photocathode for Solar Water Reduction2622H-CuScO2Prepared by Low-Temperature Hydrothermal Methods and Post-Annealing Effects on Optical and Photoelectrochemical Properties32Sol–gel synthesis and characterization of the delafossite CuAlO237Effect of annealing temperature on structural, optoelectronic properties and interband transitions of CuCrO2 nanocrystalline films prepared by the sol–gel method29Transparent conductive CuCrO 2 thin films deposited by pulsed injection metal organic chemical vapor deposition: up-scalable process technology for an improved transparency/conductivity trade-off88Investigation of structural, morphological, optical, and electrical properties of CuCrO2 films prepared by sol–gel method13Electrical and optical properties of Cu–Cr–O thin films fabricated by chemical vapour deposition32High photovoltages of CuFeO2 based p-type dye-sensitized solar cells33P -type transparent conducting oxides412N–Mg dual-acceptor co-doping in CuCrO2 studied by first-principles calculations12Engineering Valence Band Dispersion for High Mobility p-Type Semiconductors98Valence band modification of Cr 2 O 3 by Ni-doping: creating a high figure of merit p-type TCO60Photovoltaic Performance of Co-doped CuCrO2 for p-type Dye-sensitized Solar Cells Application23Invisible electronics: Metastable Cu-vacancies chain defects for highly conductive p-type transparent oxide44Graphene-Anchored p-Type CuBO2Nanocrystals for a Transparent Cold Cathode12High figure-of-merit p -type transparent conductor, Cu alloyed ZnS via radio frequency magnetron sputtering27Room-temperature fabrication of a delafossite CuCrO 2 hole transport layer for perovskite solar cells108Transition from mobility-activated small polaron to carrier density-activated conduction of sol-gel-derived highly-oriented CuAlO2 thin film and enhanced thermoelectric properties12Rapid combustion synthesis of Cu2Y2O5 as a precursor for CuYO2 delafossite12Inorganic p‐Type Semiconductors as Hole Conductor Building Blocks for Robust Perovskite Solar Cells35Enhanced carrier concentration of Fe doped delafossite CuAlO2 by double-effect: Divalent metal ions doping and excess oxygen20Evidence and Influence of Copper Vacancies in p-Type CuGaO2 Mesoporous Films42Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides92The role of phase impurities and lattice defects on the electron dynamics and photochemistry of CuFeO2 solar photocathodes42Effects of iron doping on the oxidation/reduction properties of delafossite CuAlO2 synthesized via a solid-state reaction3Soft chemical deintercalation of silver from delafossites AgFeO2, and AgCrO21Fermi Energy Limitation at β‑CuGaO2 Interfaces Induced by Electrochemical Oxidation/Reduction of Cu7P-type transparent conducting characteristics of delafossite Ca doped CuScO 2 prepared by hydrothermal synthesis16Hybrid Electrolytes Based on Optimized Ionic Liquid Quantity Tethered on ZrO2 Nanoparticles for Solid-State Lithium-Ion Conduction11Investigating the existence of oxygen interstitial in CuCr1xMgxO2 [0.00 X 0.30] thermoelectric materials by X-Ray photoelectron spectroscopy [XPS]1Visible light driven and magnetically separable high performance photocatalyst CuFe0.9Ti0.1O2/GO10A review on the p-type transparent Cu–Cr–O delafossite materials67Stabilizing p-type conductivity in CuYO2 by co-doping: A first-principles study2Fundamental insight into the interaction between a lithium salt and an inorganic filler for ion mobility using a synergic theoretical-experimental approach6Anion Photoelectron Spectroscopy and Quantum Chemical Calculations of Bimetallic Oxide Clusters YCu2On–/0 (n = 2–5)2Recent Progress in Transparent Conductive Materials for Photovoltaics31Mixed ionic-electronic transport in Na2O doped glassy electrolytes: Promising candidate for new generation sodium ion battery electrolytes26Structural and physical properties of Mg-doped CuCoO2 delafossite thin films9The impact of thickness-related grain boundary migration on hole concentration and mobility of p-type transparent conducting CuI films13Tuning optical and electrical characteristics through Cu doping in spray pyrolysis fabricated Cr2O3 thin films12Surface-enhanced p-type transparent conducting CuI−Ga2O3 films with high hole transport performance and stability4Critical Review of Cu‐Based Hole Transport Materials for Perovskite Solar Cells: From Theoretical Insights to Experimental Validation29On the charge transport models in high intrinsic defect doped transparent and conducting p-type Cu–Cr–O delafossite thin films7Structural, vibrational and electronic properties of LiScO2: A joint experimental and theoretical study0Extrinsic dopants as growth modifiers in Cu–Cr–O delafossites: a study of incorporation limits and film properties2Defect-driven optoelectronic and magnetic properties of Delafossite materials for photocatalytic, energy, and biomedical applications2

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  1. Point defects and transport mechanisms in transparent conducting oxides of intermediate conductivity

    Thin Solid Films · 2005-02-02

    Brian J. Ingram, Mariana I. Bertoni, Kenneth Reinhard Poeppelmeier, Thomas O. Mason

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  2. Transport and Defect Mechanism in Cuprous Delafossites. Part 2. CuScO2 and CuYO2.

    ChemInform · 2005-03-02

    Brian J. Ingram, Bryan J. Harder, Nikolas W. Hrabe, Thomas O. Mason, Kenneth Reinhard Poeppelmeier

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  3. First-principles study of Sn and Ca doping in CuInO2

    Physical Review B · 2005-09-07

    Li Liu, Kewu Bai, Hao Gong, Ping Wu

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  4. Crystal chemistry and electrical properties of the delafossite structure

    Thin Solid Films · 2005-09-29

    Meagen A. Marquardt, Nathan A. Ashmore, David P. Cann

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  5. First-Principles Study of Bipolar Dopability in the CuInO2 Transparent Semiconductor

    Chemistry of Materials · 2005-10-04

    Li Liu, Bai, Hao Gong, Ping Wu

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  6. Preparation of delafossite CuFeO2 thin films by rf-sputtering on conventional glass substrate

    Materials Letters · 2006-04-07

    Antoine Barnabé, Emmanuelle Mugnier, Lionel Presmanes, Philippe Tailhades

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  7. Syntheses, crystal and electronic structure, and some optical and transport properties of LnCuOTe (Ln=La, Ce, Nd)

    Journal of Solid State Chemistry · 2006-09-25

    Min Ling Liu, Li Wu, Fu Qiang Huang, Lidong Chen, James A. Ibers

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  8. p -type transparent conductor: Zn-doped CuAlS2

    Applied Physics Letters · 2007-02-12

    Minling Liu, Fuqiang Huang, Lidong Chen, Yaoming Wang, Ying‐Hua Wang, Gui-Feng Li, Qun Zhang

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  9. Effects of Postannealing on Orientation and Crystallinity of P-Type Transparent Conducting CuScO2 Thin Films

    Japanese Journal of Applied Physics · 2007-07-01

    Yoshiharu Kakehi, Kazuo Satoh, Tsutom Yotsuya, Keiichiro Masuko, Atsushi Ashida

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  10. Electrical and optical properties of excess oxygen intercalated CuScO2(0001) epitaxial films prepared by oxygen radical annealing

    Thin Solid Films · 2007-10-30

    Yoshiharu Kakehi, Kazuo Satoh, Tsutom Yotsuya, Atsushi Ashida, Takeshi Yoshimura, Norifumi Fujimura

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  11. Optical and electrical properties study on p-type conducting CuAlS2+x with wide band gap

    Scripta Materialia · 2007-11-14

    Minling Liu, Yaoming Wang, Fuqiang Huang, Lidong Chen, Wendeng Wang

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  12. A promising p-type transparent conducting material: Layered oxysulfide [Cu2S2][Sr3Sc2O5]

    Journal of Applied Physics · 2007-12-01

    Minling Liu, Libin Wu, Fuqiang Huang, Lidong Chen, I‐Wei Chen

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  13. ZnO and Its Applications

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    K. Ellmer, Andreas Klein

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  14. The Optical and Electrical Properties of Zn-Doped CuAlO[sub 2] Thin Films Deposited by RF Magnetron Sputtering

    Journal of The Electrochemical Society · 2008-01-01

    Peiming Dong, Ming Zhang, Guobo Dong, Xueping Zhao, Hui Yu Yan

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  15. Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesis

    Journal of Materials Chemistry · 2008-01-01

    R. Srinivasan, Benoit Chavillon, Charlotte Doussier‐Brochard, Laurent Cario, Michaël Paris, Éric Gautron, Philippe Deniard, Fabrice Odobel, Stéphane Jobic

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  16. p-Type electrical conduction and wide optical band gap in Mg-doped CuAlS2

    Scripta Materialia · 2008-02-01

    Minling Liu, Fuqiang Huang, Lidong Chen

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  17. P-Type Transparent Conductivity of Cu1-xAlS2 (x = 0 ~ 0.08)

    Key engineering materials · 2008-02-01

    Min Ling Liu, Fu Qiang Huang, Lidong Chen

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  18. Silver Delafossite Oxides

    Inorganic Chemistry · 2008-02-13

    William C. Sheets, Evan S. Stampler, Mariana I. Bertoni, Makoto Sasaki, Tobin Jay Marks, Thomas O. Mason, Kenneth Reinhard Poeppelmeier

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  19. First-principle study of extrinsic defects in CuScO2 and CuYO2

    Physics Letters A · 2008-03-05

    Zhi‐Jie Fang, Lijie Shi

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  20. Syntheses, Crystal Structures, and Physical Properties of La5Cu6O4S7 and La5Cu6.33O4S7

    Inorganic Chemistry · 2008-04-23

    George Chan, Ming-Ling Liu, Lidong Chen, Fuqiang Huang, Daniel E. Bugaris, Daniel M. Wells, John R. Ireland, Mark C. Hersam, Richard P. Van Duyne, James A. Ibers

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  21. Band structure and thermopower of doped YCuO2

    Physical Review B · 2008-05-29

    D. J. Singh

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  22. Structure and optoelectronic properties of spray deposited Mg doped p-CuCrO2 semiconductor oxide thin films

    Journal of Applied Physics · 2008-07-15

    A. C. Rastogi, S. H. Lim, Seshu B. Desu

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  23. First-principles study of p-type transparent conductive oxides CuXO2 (X=Y, Sc, and Al)

    Journal of Applied Physics · 2008-10-01

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  24. First-principle study of native defects in CuScO 2 and CuYO 2

    Chinese Physics B · 2008-11-01

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  25. Optical and electrical properties of CuScO2 epitaxial films prepared by combining two-step deposition and post-annealing techniques

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  26. Bulk defect chemistry and surface electronic behavior of Zn,Sn codoped In2O3 transparent conducting oxides

    Physical Chemistry Chemical Physics · 2009-01-01

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  27. Effects of Mg doping on structural, optical, and electrical properties of CuScO2(0001) epitaxial films

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  28. Acceptor Levels in p -Type Cu2O : Rationalizing Theory and Experiment

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    David O. Scanlon, Benjamin J. Morgan, Graeme W. Watson, Aron Walsh

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  29. Understanding the p-Type Conduction Properties of the Transparent Conducting Oxide CuBO2: A Density Functional Theory Analysis

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  30. Room temperature ozone sensing properties of p-type CuCrO2 nanocrystals

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  31. Zn-doped CuAlS2 transparent p-type conductive thin films deposited by pulsed plasma deposition

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  32. (Cu 2 S 2 )(Sr 3 Sc 2 O 5 )−A Layered, Direct Band Gap, p-Type Transparent Conducting Oxychalcogenide: A Theoretical Analysis.

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  33. Understanding conductivity in SrCu 2 O 2 : stability, geometry and electronic structure of intrinsic defects from first principles

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  34. Understanding conductivity anomalies in CuI-based delafossite transparent conducting oxides: Theoretical insights

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  35. Improving the electrical conductivity of CuCrO2 thin film by N doping

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  36. Growth Strategy and Physical Properties of the High Mobility P-Type CuI Crystal

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  37. First principles study of CuAlO2 doping with S

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  38. Ternary and Multinary Materials: Crystal/Defect Structure–Property Relationships

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  39. Semiconducting Oxides to Facilitate the Conversion of Solar Energy to Chemical Fuels

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  40. Combined Jonker and Ioffe Analysis of Oxide Conductors and Semiconductors

    Journal of the American Ceramic Society · 2010-09-27

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  41. Conductivity Limits in CuAlO2 from Screened-Hybrid Density Functional Theory

    The Journal of Physical Chemistry Letters · 2010-10-21

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  42. Copper doped nickel oxide transparent p-type conductive thin films deposited by pulsed plasma deposition

    Thin Solid Films · 2010-12-12

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  43. Band gap anomalies of the ZnM2IIIO4 (MIII = Co, Rh, Ir) spinels

    Physical Chemistry Chemical Physics · 2011-01-01

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  44. Indium-doped molybdenum oxide as a new p-type transparent conductive oxide

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  45. Understanding the p-type defect chemistry of CuCrO2

    Journal of Materials Chemistry · 2011-01-01

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  46. Effect of Ca-doping on the structural and electrical properties of CuY1−xCaxO2 (0≤x≤0.10) ceramics

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  47. Highly enhanced p-type electrical conduction in wide band gap Cu1+xAl1−xS2 polycrystals

    Solar Energy Materials and Solar Cells · 2011-06-25

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  48. Chemical bonding in copper-based transparent conducting oxides: CuMO2(M = In, Ga, Sc)

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  49. Density functional theory study on transparent conductive oxide CuScO2

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  50. On the possibility of p-type SnO2

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