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RESEARCH PAPER · Journal of Materials Chemistry · 2008

Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesis

R. Srinivasan, Benoit Chavillon, Charlotte Doussier, Laurent Cario, Michaël Paris, Éric Gautron, Philippe Deniard, Fabrice Odobel, Stéphane Jobic

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Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesisOriginalSynthesis of light‐coloured nanoparticles of wide band gap p‐type semiconductors CuGaO2 and LaOCuS by low temperature hydro/solvothermal processes10Oxide Nanomaterials: Synthetic Developments, Mechanistic Studies, and Technological Innovations366Oxidische Nanomaterialien: Von der Synthese über den Mechanismus zur technologischen Innovation25First-principles study of structural, mechanical, electronic and optical properties of 3R- and 2H-CuGaO215P-Type Nitrogen-Doped ZnO Nanoparticles Stable under Ambient Conditions128CuGaO2: a promising alternative for NiO in p-type dye solar cells120Hydrothermally synthesized LiFePO4 crystals with enhanced electrochemical properties: simultaneous suppression of crystal growth along [010] and antisite defect formation156p-Type Dye-Sensitized Solar Cells Based on Delafossite CuGaO2 Nanoplates with Saturation Photovoltages Exceeding 460 mV165A facile arrested precipitation method for synthesis of pure wurtzite Cu2ZnSnS4 nanocrystals using thiourea as a sulfur source19Hydrothermal synthetic strategies of inorganic semiconducting nanostructures548Enhanced Performance of p‐Type Dye‐Sensitized Solar Cells Based on Ultrasmall Mg‐Doped CuCrO2 Nanocrystals78Hierarchically structured copper gallium spinels through microwave hydrothermal methods10Photoinduced Electron Transfer Dynamics of Cyclometalated Ruthenium (II)–Naphthalenediimide Dyad at NiO Photocathode52Three-Dimensional Mesoscale Heterostructures of ZnO Nanowire Arrays Epitaxially Grown on CuGaO2 Nanoplates as Individual Diodes40Origin of the Black Color of NiO Used as Photocathode in p-Type Dye-Sensitized Solar Cells83Hole conductivity and acceptor density of p-type CuGaO2 nanoparticles determined by impedance spectroscopy: The effect of Mg doping48Remarkable photocurrent of p-type dye-sensitized solar cell achieved by size controlled CuGaO 2 nanoplates103Impact of Mg Doping on Performances of CuGaO2 Based p-Type Dye-Sensitized Solar Cells50Controllable synthesis of high-performance LiMnPO 4 nanocrystals by a facile one-spot solvothermal process64Cu(i)-based delafossite compounds as photocathodes in p-type dye-sensitized solar cells127Mechanisms in the solution growth of free-standing two-dimensional inorganic nanomaterials67A facile novel synthesis of delafossite CuFeO2 powders47Synthesis and Characterization of CuAlO2 and AgAlO2 Delafossite Oxides through Low-Temperature Hydrothermal Methods85Understanding the Crystallization Mechanism of Delafossite CuGaO2 for Controlled Hydrothermal Synthesis of Nanoparticles and Nanoplates82Structural and electrical properties of Cu2Zn(Sn1−xSix)S4 (x=0, x=0.5) materials for photovoltaic applications18Impact of Fe doping on performances of CuGaO2 p-type dye-sensitized solar cells39Investigations on the Hydrothermal Synthesis of Pure and Mg-Doped Nano-CuCrO21Solution Synthesized p-Type Copper Gallium Oxide Nanoplates as Hole Transport Layer for Organic Photovoltaic Devices70Wurtzite-derived ternary I–III–O 2 semiconductors40Preparation of p-type AgCrO2 nanocrystals through low-temperature hydrothermal method and the potential application in p-type dye-sensitized solar cell412H-CuScO2Prepared by Low-Temperature Hydrothermal Methods and Post-Annealing Effects on Optical and Photoelectrochemical Properties32Effect of Al Doping on Performance of CuGaO2 p-Type Dye-Sensitized Solar Cells18Copper borate as a photocathode in p-type dye-sensitized solar cells46Low temperature hydrothermal synthesis mechanism and thermal stability of p-type CuMnO 2 nanocrystals45Optical Study of Cuprous Oxide and Ferric Oxide Based Materials for Applications in Low Cost Solar Cells5Photoluminescence and photocatalytic properties of rhombohedral CuGaO2 nanoplates60Structure and optical properties of Sn doped delafossite oxides CuGaO2by hydrothermal method2High photovoltages of CuFeO2 based p-type dye-sensitized solar cells33Synthesis, characterization and electrocatalytic properties of delafossite CuGaO267Sol – gel synthesis, structural characterization and bifunctional catalytic activity of nanocrystalline delafossite CuGaO2 particles46Dielectric, optical and enhanced photocatalytic properties of CuCrO 2 nanoparticles67Sub-micron-sized delafossite CuCrO2 with different morphologies synthesized by nitrate–citric acid sol–gel route4Solution‐Growth Strategy for Large‐Scale “CuGaO2 Nanoplate/ZnS Microsphere” Heterostructure Arrays with Enhanced UV Adsorption and Optoelectronic Properties32Electrocatalytic Properties of Cuprous Delafossite Oxides for the Alkaline Oxygen Reduction Reaction13CuGaS 2 nanoplates: a robust and self-healing anode for Li/Na ion batteries in a wide temperature range of 268–318 K57An ab initio study of Cu-based delafossites as an alternative to nickel oxide in photocathodes: effects of Mg-doping and surface electronic features31Dependence of (Photo)electrochemical Properties on Geometry Factors of Hydrothermally Synthesized Delafossite Copper Gallium Oxide CuGaO2toward Oxygen Evolution Reaction16Soft Chemistry Synthesis and Characterization of Nano p-Type Transparent Semiconducting Delafossite Oxides of Type A+B3+O2Where A = Cu; B = Al, Ga, and Cr3Employing surfactant-assisted hydrothermal synthesis to control CuGaO2 nanoparticle formation and improved carrier selectivity of perovskite solar cells49Interface State Luminescence and Sub‐Bandgap Absorption Based on CuGaO2 Nanoplates/ZnO Nanowires Heterostructure Arrays8Solution‐Processed Metal Oxide Nanocrystals as Carrier Transport Layers in Organic and Perovskite Solar Cells139Evidence and Influence of Copper Vacancies in p-Type CuGaO2 Mesoporous Films41Developing photocathode materials for p-type dye-sensitized solar cells70Investigation of the structural, optical and electrical properties of Ca 2+ doped CuCoO 2 nanosheets34Hydrothermal synthesis and photocatalytic properties of CuGaO2/ZnO hexagonal platelet hybrids15Use of ultrasound-assisted co-precipitation route to obtain CuMnO2 semiconductor nanomaterials8Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides92Molecular Design of Photocathode Materials for Hydrogen Evolution and Carbon Dioxide Reduction0Hydrothermal synthesis of 3D hierarchical flower‐like CuGaO 2 with high surface area for dye‐sensitised solar cell5Localized Surface Plasmon Resonance Absorption Generated by Free Carriers in Zn‐Doped CuGa1−xZnxO2 Nanoplates4High-Throughput Screening Delafossite CuMO2 (M = IIIA, 3d, 4d, 5d, and RE) Optoelectronic Functional Materials Based on First-Principles Calculations44In situ growth of monocrystal p-CuGaO 2 nanosheet as a hole transfer layer in a photoelectrode for solar hydrogen production6Recent Progress in Inorganic Hole Transport Materials for Efficient and Stable Perovskite Solar Cells98Insight into the Humidity Dependent Pseudo-n-Type Response of p-CuScO2 toward Ammonia18Stable all-fiber passively Q-switched erbium-doped fiber laser based on plasmonic Zn doped CuGaO2 nanoplates4Delafossite CuGaO 2 as promising visible-light-driven photocatalyst: synthesize, properties, and performances42Study on photoluminescence characteristics and whispering gallery mode resonance from Cr doped CuGaO2 nanoplates4Facile CuFeO2 microcrystal synthesis for lithium ion battery anodes via microwave heating13Stable passively Q-switched erbium-doped fiber laser based on CuCrO2 nanoparticles saturable absorber16Hydrothermal synthesis of new CuVO2 delafossite hexagonal nanoplates2Estimation of delafossite p-type CuGaO2/ZnO hybrids as semiconductor photocatalyst by controlling particle size15Hydrothermal Method for Synthesis of Materials18Hybrid 3D Nanostructure-Based Hole Transport Layer for Highly Efficient Inverted Perovskite Solar Cells14Bismuth Vacancy-Induced Efficient CO2 Photoreduction in BiOCl Directly from Natural Air: A Progressive Step toward Photosynthesis in Nature168Study on the optoelectronic properties of Zn and Mg doped CuGaO2 nanoplates7Nanocrystals of CuCoO 2 derived from MOFs and their catalytic performance for the oxygen evolution reaction22A review on the p-type transparent Cu–Cr–O delafossite materials67Highly‐Exposed Single‐Interlayered Cu Edges Enable High‐Rate CO2‐to‐CH4 Electrosynthesis59Micro-Raman and X-ray Photoemission Spectroscopic Investigations of Heterojunction Between Delafossite CuGaO2 and Wurtzite ZnO Obtained by Hydrothermal Method2CuGaO2 Nanosheets and CuCrO2 Nanoparticles Mixed with Spiro-OMeTAD as the Hole-Transport Layer in Perovskite Solar Cells17Formation of a p‐n heterojunction photocatalyst by the interfacing of graphitic carbon nitride and delafossite CuGaO22X-ray Diffraction, Micro-Raman and X-ray Photoemission Spectroscopic Investigations for Hydrothermally Obtained Hybrid Compounds of Delafossite CuGaO2 and Wurtzite ZnO10Microwave-assisted synthesis of nanocrystallite Cu2O particles and estimation of their microstructural parameters using Williamson–Hall method19CuGaO2 delafossite as a high-surface area model catalyst for Cu+-activated reactions6Boosting carrier separation and transport in CuGaO2 photocathodes by coupled effects of surface polarization and facet-junction12Insights into spray-coated p-type Li-doped ZnO thin films: An examination of structural, chemical, optical, and electrical characteristics2Combined experimental and first-principles investigation of the delafossite structure AgCoO215Delafossite CuGaO2-Based Chemiresistive Sensor for Sensitive and Selective Detection of Dimethyl Disulfide19Fe-Doped CuGaO₂ Nanoparticles-Based Gas Sensor for Sub-ppm Triethylamine Detection8Synergy of photoluminescence emission and antibacterial activity of Ag-Cu2O nanocomposite4Influence of Synthesis pH and Post-Synthetic Annealing on the Hole Density of CuGaO2 Mesoporous Films1Defect-driven optoelectronic and magnetic properties of Delafossite materials for photocatalytic, energy, and biomedical applications2Fast Synthesis of Nanosized CuGaO 2 Particles as a p-Type Semiconductor for Photocathodes: Preliminary Investigation in DSSCs0Highly efficient dual-absorber BaZrS3/CaZrSe3 chalcogenide perovskite solar cells: A SCAPS-1D simulation study1

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  1. Synthesis of light‐coloured nanoparticles of wide band gap p‐type semiconductors CuGaO2 and LaOCuS by low temperature hydro/solvothermal processes

    physica status solidi (a) · 2010-05-31

    Benoit Chavillon, Laurent Cario, Charlotte Doussier, R. Srinivasan, Loïc Le Pleux, Yann Pellegrin, Errol Blart, Fabrice Odobel, Stéphane Jobic

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  2. Oxide Nanomaterials: Synthetic Developments, Mechanistic Studies, and Technological Innovations

    Angewandte Chemie International Edition · 2010-11-25

    Greta Ricarda Patzke, Ying Zhou, Roman Kontic, Franziska Conrad

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  3. Oxidische Nanomaterialien: Von der Synthese über den Mechanismus zur technologischen Innovation

    Angewandte Chemie · 2010-11-25

    Greta Ricarda Patzke, Ying Zhou, Roman Kontic, Franziska Conrad

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  4. First-principles study of structural, mechanical, electronic and optical properties of 3R- and 2H-CuGaO2

    Physica B Condensed Matter · 2011-06-18

    Qi‐Jun Liu, Zheng‐Tang Liu, Jichao Chen, Liping Feng, Hao Tian

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  5. P-Type Nitrogen-Doped ZnO Nanoparticles Stable under Ambient Conditions

    Journal of the American Chemical Society · 2011-11-17

    Benoit Chavillon, Laurent Cario, Adèle Renaud, Franck Tessier, François Cheviré, Mohammed Boujtita, Yann Pellegrin, Errol Blart, Amanda L. Smeigh, Leif Hammarström, Fabrice Odobel, Stéphane Jobic

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  6. CuGaO2: a promising alternative for NiO in p-type dye solar cells

    Journal of Materials Chemistry · 2012-01-01

    Adèle Renaud, Benoit Chavillon, Loïc Le Pleux, Yann Pellegrin, Errol Blart, Mohammed Boujtita, Thierry Pauporté, Laurent Cario, Stéphane Jobic, Fabrice Odobel

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  7. Hydrothermally synthesized LiFePO4 crystals with enhanced electrochemical properties: simultaneous suppression of crystal growth along [010] and antisite defect formation

    Physical Chemistry Chemical Physics · 2012-01-01

    Xue Qin, Jiemin Wang, Jie Xie, Fangzhi Li, Lei Wen, Xiaohui Wang

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  8. p-Type Dye-Sensitized Solar Cells Based on Delafossite CuGaO2 Nanoplates with Saturation Photovoltages Exceeding 460 mV

    The Journal of Physical Chemistry Letters · 2012-04-10

    Mingzhe Yu, Gayatri Natu, Zhiqiang Ji, Yiying Wu

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  9. A facile arrested precipitation method for synthesis of pure wurtzite Cu2ZnSnS4 nanocrystals using thiourea as a sulfur source

    Materials Research Bulletin · 2012-08-16

    Chunya Li, Enna Ha, Wing‐Leung Wong, Cuiling Li, Kam‐Piu Ho, Kwok‐Yin Wong

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  10. Hydrothermal synthetic strategies of inorganic semiconducting nanostructures

    Chemical Society Reviews · 2013-01-01

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  11. Enhanced Performance of p‐Type Dye‐Sensitized Solar Cells Based on Ultrasmall Mg‐Doped CuCrO2 Nanocrystals

    ChemSusChem · 2013-06-21

    Dehua Xiong, Wenjun Zhang, Xianwei Zeng, Zhen Xu, Wei Chen, Jin Tao Cui, Mingkui Wang, Licheng Sun, Yi‐Bing Cheng

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  12. Hierarchically structured copper gallium spinels through microwave hydrothermal methods

    Solid State Sciences · 2013-07-12

    Franziska Conrad, Matthias Bauer, S. Weyeneth, Ying Zhou, Kathrin Hametner, Detlef Günther, Greta Ricarda Patzke

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  13. Photoinduced Electron Transfer Dynamics of Cyclometalated Ruthenium (II)–Naphthalenediimide Dyad at NiO Photocathode

    The Journal of Physical Chemistry C · 2013-08-09

    Zhiqiang Ji, Yiying Wu

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  14. Three-Dimensional Mesoscale Heterostructures of ZnO Nanowire Arrays Epitaxially Grown on CuGaO2 Nanoplates as Individual Diodes

    ACS Nano · 2013-08-16

    Audrey Forticaux, Salih Hacialioglu, John P. DeGrave, Rafal M. Dziedzic, Song Jin

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  15. Origin of the Black Color of NiO Used as Photocathode in p-Type Dye-Sensitized Solar Cells

    The Journal of Physical Chemistry C · 2013-10-04

    Adèle Renaud, Benoit Chavillon, Laurent Cario, Loïc Le Pleux, Nadine Szuwarski, Yann Pellegrin, Errol Blart, Éric Gautron, Fabrice Odobel, Stéphane Jobic

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  16. Hole conductivity and acceptor density of p-type CuGaO2 nanoparticles determined by impedance spectroscopy: The effect of Mg doping

    Electrochimica Acta · 2013-10-12

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  17. Remarkable photocurrent of p-type dye-sensitized solar cell achieved by size controlled CuGaO 2 nanoplates

    Journal of Materials Chemistry A · 2013-11-26

    Zhen Xu, Dehua Xiong, Huan Wang, Wenjun Zhang, Xianwei Zeng, Liqun Ming, Wei Chen, Xiaobao Xu, Jin Tao Cui, Mingkui Wang, Satvasheel Powar, Udo Bach, Yi‐Bing Cheng

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  18. Impact of Mg Doping on Performances of CuGaO2 Based p-Type Dye-Sensitized Solar Cells

    The Journal of Physical Chemistry C · 2013-12-11

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  19. Controllable synthesis of high-performance LiMnPO 4 nanocrystals by a facile one-spot solvothermal process

    Journal of Materials Chemistry A · 2014-01-01

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  20. Cu(i)-based delafossite compounds as photocathodes in p-type dye-sensitized solar cells

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  21. Mechanisms in the solution growth of free-standing two-dimensional inorganic nanomaterials

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  22. A facile novel synthesis of delafossite CuFeO2 powders

    Journal of Materials Science Materials in Electronics · 2014-02-21

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  23. Synthesis and Characterization of CuAlO2 and AgAlO2 Delafossite Oxides through Low-Temperature Hydrothermal Methods

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  24. Understanding the Crystallization Mechanism of Delafossite CuGaO2 for Controlled Hydrothermal Synthesis of Nanoparticles and Nanoplates

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  25. Structural and electrical properties of Cu2Zn(Sn1−xSix)S4 (x=0, x=0.5) materials for photovoltaic applications

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  26. Impact of Fe doping on performances of CuGaO2 p-type dye-sensitized solar cells

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  27. Investigations on the Hydrothermal Synthesis of Pure and Mg-Doped Nano-CuCrO2

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  28. Solution Synthesized p-Type Copper Gallium Oxide Nanoplates as Hole Transport Layer for Organic Photovoltaic Devices

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  29. Wurtzite-derived ternary I–III–O 2 semiconductors

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  30. Preparation of p-type AgCrO2 nanocrystals through low-temperature hydrothermal method and the potential application in p-type dye-sensitized solar cell

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  31. 2H-CuScO2Prepared by Low-Temperature Hydrothermal Methods and Post-Annealing Effects on Optical and Photoelectrochemical Properties

    Inorganic Chemistry · 2015-05-13

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  32. Effect of Al Doping on Performance of CuGaO2 p-Type Dye-Sensitized Solar Cells

    Journal of Materials Engineering and Performance · 2015-12-08

    Daniel Ursu, Nicolae Vaszilcsin, Radu Bănică, Marinela Miclau

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  33. Copper borate as a photocathode in p-type dye-sensitized solar cells

    RSC Advances · 2015-12-18

    Tengfei Jiang, Martine Bujoli‐Doeuff, Yoann Farré, Errol Blart, Yann Pellegrin, Éric Gautron, Mohammed Boujtita, Laurent Cario, Fabrice Odobel, Stéphane Jobic

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  34. Low temperature hydrothermal synthesis mechanism and thermal stability of p-type CuMnO 2 nanocrystals

    New Journal of Chemistry · 2016-01-01

    Dehua Xiong, Qingqing Zhang, Zijuan Du, Santosh Kumar Verma, Hong Li, Xiujian Zhao

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  35. Optical Study of Cuprous Oxide and Ferric Oxide Based Materials for Applications in Low Cost Solar Cells

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    Thi Cuc Than, Bao Thoa Bui, Benjamin Wegmuller, Minh Hieu Nguyen, Lam Huong Hoang Ngoc, Van Diep Bui, Quoc Hung Nguyen, Chi Hieu Hoang, Thuat Nguyen-Tran

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  36. Photoluminescence and photocatalytic properties of rhombohedral CuGaO2 nanoplates

    Scientific Reports · 2016-02-18

    Linlin Shi, Fei Wang, Yunpeng Wang, Dengkui Wang, Bin Zhao, Ligong Zhang, Dongxu Zhao, Dezhen Shen

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  37. Structure and optical properties of Sn doped delafossite oxides CuGaO2by hydrothermal method

    Integrated ferroelectrics · 2016-06-01

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  38. High photovoltages of CuFeO2 based p-type dye-sensitized solar cells

    Journal of Alloys and Compounds · 2016-06-25

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  39. Synthesis, characterization and electrocatalytic properties of delafossite CuGaO2

    Journal of Solid State Chemistry · 2016-07-05

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  40. Sol – gel synthesis, structural characterization and bifunctional catalytic activity of nanocrystalline delafossite CuGaO2 particles

    Journal of Alloys and Compounds · 2016-07-10

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  41. Dielectric, optical and enhanced photocatalytic properties of CuCrO 2 nanoparticles

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  42. Sub-micron-sized delafossite CuCrO2 with different morphologies synthesized by nitrate–citric acid sol–gel route

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  43. Solution‐Growth Strategy for Large‐Scale “CuGaO2 Nanoplate/ZnS Microsphere” Heterostructure Arrays with Enhanced UV Adsorption and Optoelectronic Properties

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  44. Electrocatalytic Properties of Cuprous Delafossite Oxides for the Alkaline Oxygen Reduction Reaction

    ChemCatChem · 2017-06-22

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  45. CuGaS 2 nanoplates: a robust and self-healing anode for Li/Na ion batteries in a wide temperature range of 268–318 K

    Journal of Materials Chemistry A · 2017-12-06

    Yun Ho Song, Yanmei Li, Lin Zhong Zhu, Zhichang Pan, Yinchang Jiang, Pei Wang, Yong‐Ning Zhou, Fang Fang, Linfeng Hu, Dalin Sun

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  46. An ab initio study of Cu-based delafossites as an alternative to nickel oxide in photocathodes: effects of Mg-doping and surface electronic features

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  47. Dependence of (Photo)electrochemical Properties on Geometry Factors of Hydrothermally Synthesized Delafossite Copper Gallium Oxide CuGaO2toward Oxygen Evolution Reaction

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  48. Soft Chemistry Synthesis and Characterization of Nano p-Type Transparent Semiconducting Delafossite Oxides of Type A+B3+O2Where A = Cu; B = Al, Ga, and Cr

    Materials Today Proceedings · 2018-01-01

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  49. Employing surfactant-assisted hydrothermal synthesis to control CuGaO2 nanoparticle formation and improved carrier selectivity of perovskite solar cells

    Materials Today Energy · 2018-03-09

    Ioannis T. Papadas, Achilleas Savva, Apostolos Ioakeimidis, Polyvios Eleftheriou, Gerasimos S. Armatas, Stelios A. Choulis

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  50. Interface State Luminescence and Sub‐Bandgap Absorption Based on CuGaO2 Nanoplates/ZnO Nanowires Heterostructure Arrays

    physica status solidi (b) · 2018-09-27

    Yingtian Xu, Guanghui Ma, Guanxin Wang, Linlin Shi, He Zhang, Liang Jin, Xiaohui Ma, Yonggang Zou, Jingzhi Yin, Ying Li

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