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RESEARCH PAPER · Applied Clay Science · 2014

Intercalation of drugs in layered double hydroxides and their controlled release: A review

V. Rives, Margarita del Arco, C. Dianne Martin

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Intercalation of drugs in layered double hydroxides and their controlled release: A reviewOriginalPoly-vinyl alcohol (PVA) and malachite green: a new reagent system for the microdetermination of phosphate in water and wastewater.7Clay nanomaterial thin film electrodes for electrochemical energy storage applications25Development of a Highly Biocompatible Antituberculosis Nanodelivery Formulation Based on Para-Aminosalicylic Acid—Zinc Layered Hydroxide Nanocomposites22Reactivity and applications of layered silicates and layered double hydroxides116Redox properties of LDH microcrystals coated with a catechol-bearing phosphonate derived from dopamine5Layered Double Hydroxide-Based Nanocarriers for Drug Delivery249Alternating Misfit Layered Transition/Alkaline Earth Metal Chalcogenide Ca3Co4O9 as a New Class of Chalcogenide Materials for Hydrogen Evolution80MTX/LDHs hybrids synthesized from reverse microemulsions: Particle control and bioassay study41Fabrication of high-performance poly(vinyl alcohol)/MgAl-layered double hydroxide nanocomposites28Synthesis and Characterization of Layered Double Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite5The preparation and characterization of lactone form of 10-hydroxycamptothecin-layered double hydroxide nanohybrids2Layered double hydroxides as a nanocontainer for encapsulating marine natural product antifoulant: Intercalation and tunable controlled release of cinnamate10Raman spectroscopy — Useful tool for studying the catalysts derived from Mo and V-oxyanion-intercalated layered double hydroxides32A molecular dynamic study of layered hydroxide induced depletion of mobile anions within the extracellular medium0Controlled synthesis of monodisperse silver nanoparticles supported layered double hydroxide catalyst22Curcumin intercalated layered double hydroxide nanohybrid as a potential drug delivery system for effective photodynamic therapy in human breast cancer cells46Hierarchical coated metal hydroxide nanoconstructs as potential controlled release carriers of photosensitizer for skin melanoma34Nanoscale phase separation in laponite–polypyrrole nanocomposites. Application to electrodes for energy storage16Size-tunable LDH–protein hybrids toward the optimization of drug nanocarriers19Stable UV absorption material synthesized by intercalation of squaric acid anion into layered double hydroxides4Synthesis, Characterization, and In Vitro Drug Delivery Capabilities of (Zn, Al)-Based Layered Double Hydroxide Nanoparticles20Synthesis of Cu–Al layered double hydroxide nanofluid and characterization of its thermal properties83CO 2 Adsorption on Modified Mg–Al-Layered Double Hydroxides13Solution combustion synthesis of calcium phosphate particles for controlled release of bovine serum albumin10Structural and physicochemical aspects of drug release from layered double hydroxides and layered hydroxide salts55On the synthesis of layered double hydroxides (LDHs) by reconstruction method based on the “ memory effect ”123Dual-site polydopamine spheres/CoFe layered double hydroxides for electrocatalytic oxygen reduction reaction41Synthesis and controlled release properties of β-naphthoxyacetic acid intercalated Mg–Al layered double hydroxides nanohybrids16A facile and simple synthetic strategy for the preparation of modified NiAl-layered double hydroxide as nanofiller for L-phenylalanine containing poly(amide-imide)s based nanocomposites5Intracrystalline structure and release pattern of ferulic acid intercalated into layered double hydroxide through various synthesis routes38Layered double hydroxide nanoparticles for biomedical applications: Current status and recent prospects258Optimisation of the synthesis parameters of mechanochemically prepared CaAl-layered double hydroxide53Nanocomposites Based on Thermoplastic Polymers and Functional Nanofiller for Sensor Applications95Multi-laminated metal hydroxide nanocontainers for oral-specific delivery for bioavailability improvement and treatment of inflammatory paw edema in mice43Layered Double Hydroxides as Nanofillers of Composites and Nanocomposite Materials Based on Polyethylene2Methotrexate intercalated layered double hydroxides with the mediation of surfactants: Mechanism exploration and bioassay study30Structure, molecular simulation, and release of a spirin from intercalated Zn–Al-layered double hydroxides41Magnetic hydrotalcites as solid basic catalysts for cellulose hydrolysis30Starch Biocatalyst Based on α-Amylase-Mg/Al-Layered Double Hydroxide Nanohybrids19Structural Characterisation of Complex Layered Double Hydroxides and TGA‐GC‐MS Study on Thermal Response and Carbonate Contamination in Nitrate‐ and Organic‐Exchanged Hydrotalcites72Epigallocatechin Gallate/Layered Double Hydroxide Nanohybrids: Preparation, Characterization, and In Vitro Anti-Tumor Study39Hydrogel-swelling driven delivery device for corrosion resistance of metal in water1Inorganic nanolayers: structure, preparation, and biomedical applications83Self-assemblies of plasmonic gold/layered double hydroxides with highly efficient antiviral effect against the hepatitis B virus33Alternative Inorganic Systems for Controlled Release Applications3Novel Nanostructured Solid Materials for Modulating Oral Drug Delivery from Solid-State Lipid-Based Drug Delivery Systems71Synthesis of methotrexatum intercalated layered double hydroxides by different methods: Biodegradation process and bioassay explore26Ultrasound-assisted reconstruction and delamination studies on CaAl layered double hydroxides32Two‐Dimensional Nanomaterials for Biomedical Applications: Emerging Trends and Future Prospects880Factors Affecting MoO 4 2– Inhibitor Release from Zn 2 Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings104Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis25Dysprosium-containing layered double hydroxides nanoparticles intercalated with biologically active species as an approach for theranostic systems16Evaluation of Controlled-Release Property and Phytotoxicity Effect of Insect Pheromone Zinc-Layered Hydroxide Nanohybrid Intercalated with Hexenoic Acid25Mechanochemical approaches to synthesize layered double hydroxides: a review184In-vitro evaluation of layered double hydroxide–Fe 3 O 4 magnetic nanohybrids for thermo-chemotherapy49Intercalation of Norfloxacin into Layered Double Hydroxides by Delamination/Restacking Process and its Controlled-Release Property15Synthesis of methotrexatum intercalated zinc–aluminum-layered double hydroxides and the corresponding cell studies8Dexketoprofen and aceclofenac release from layered double hydroxide and SBA-15 ordered mesoporous material8Luminescence properties of lanthanide-containing layered double hydroxides27Determination and reduction of Fe(III) incorporated into Mg–Fe layered double hydroxide structures12Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts72Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts46Effect of the protein corona on the colloidal stability and reactivity of LDH-based nanocarriers67Efficient antibacterial activity via protein degradation of a 3D layered double hydroxide–reduced graphene oxide nanohybrid22Halloysite for Controllable Loading and Release45Intercalation of n-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane0Layered double hydroxide and sulindac coiled and scrolled nanoassemblies for storage and drug release59Pancreatic cancer therapy using an injectable nanobiohybrid hydrogel60Effects of lamellar reconstruction routes in the release of molybdate encapsulated in Mg–Al layered double hydroxides23Energy and structure of bonds in the interaction of organic anions with layered double hydroxide nanosheets: A molecular dynamics study61Layered double hydroxides: Efficient fillers for waterborne nanocomposite films26Effect of anion addition on the syntheses of Ca–Al layered double hydroxide via a two-step mechanochemical process44Preparation and characterization of magnetic thermosensitive fluorouracil micelles5Improvement of zeolite adsorption capacity for cephalexin by coating with magnetic Fe3O4 nanoparticles180Preparation and characterization of magnetic Fe3O4@sulfonated β-cyclodextrin intercalated layered double hydroxides for methylene blue removal39Intercalation of tetracycline in nano sheet layered double hydroxide: An insight into UV/VIS spectra analysis98Electrospun layered double hydroxide/poly (ε-caprolactone) nanocomposite scaffolds for adipogenic differentiation of adipose-derived mesenchymal stem cells53Polymeric Nanohybrids as a New Class of Therapeutic Biotransporters23Preparation and optimization of a drug delivery system based on berberine chloride-immobilized MgAl hydrotalcite37CaAl-layered double hydroxide as a drug delivery system: effects on solubility and toxicity of the antiretroviral efavirenz29MgAl- Layered Double Hydroxide Nanoparticles for controlled release of Salicylate48Synthesis, characterization, and efficacy of antituberculosis isoniazid zinc aluminum-layered double hydroxide based nanocomposites23Layered Double Hydroxide as a Vehicle to Increase Toxicity of Gallate Ions against Adenocarcinoma Cells11Precursor Preparation to Promote the Adsorption of Mg‐Al Layered Double Hydroxide25Tuning Colloidal Stability of Layered Double Hydroxides: From Monovalent Ions to Polyelectrolytes69Accessing the biocompatibility of layered double hydroxide by intramuscular implantation: histological and microcirculation evaluation100A Nanoscale Interface Promoting Molecular and Functional Differentiation of Neural Cells41Modified drug release system based on Sulindac and layered double hydroxide: An in vivo Raman investigation20Magnesium, zinc and calcium aluminium layered double hydroxide-drug nanohybrids: A comprehensive study80Delaminating and restacking MgAl-layered double hydroxide monitored and characterized by a range of instrumental methods14Functionalization of Surfaces in Layered Double Hydroxides and Hydroxide Salt Nanoparticles5Carborane-layered double hydroxide nanohybrids for potential targeted- and magnetically targeted-BNCT applications34Manganese-iron layered double hydroxide: a theranostic nanoplatform with pH-responsive MRI contrast enhancement and drug release103NIR absorbing Au nanoparticle decorated layered double hydroxide nanohybrids for photothermal therapy and fluorescence imaging of cancer cells30Opportunities and challenges in the use of layered double hydroxide to produce hybrid polymer composites7Polymeric Microparticles and Inorganic Micro/Nanoparticulate Drug Carriers: An Overview and Pharmaceutical Application12Nanoparticle decoration with surfactants: Molecular interactions, assembly, and applications608Sustained Release of Brimonidine from a New Composite Drug Delivery System for Treatment of Glaucoma101Ultrafast cooling of a hot steel plate using Cu-Al layered double hydroxide nanofluid jet22Antimicrobial activity of 2-mercaptobenzothiazole released from environmentally friendly nanostructured layered double hydroxides33Risedronate functionalized layered double hydroxides nanoparticles with bone targeting capabilities19Betamethasone dipropionate intercalated layered double hydroxide and the composite with liposome for improved water dispersity25Engineering of (10-hydroxycamptothecin intercalated layered double hydroxide)@liposome nanocomposites with excellent water dispersity21Design of nucleic acid-layered double hydroxide nanohybrids14Topotactic Synthesis of Porous Cobalt Ferrite Platelets from a Layered Double Hydroxide Precursor and Their Application in Oxidation Catalysis41Layered Double Hydroxides: Potential Release-on-Demand Fertilizers for Plant Zinc Nutrition41Layered double hydroxide nanoparticles customization by polyelectrolyte adsorption: mechanism and effect on particle aggregation26Solvothermal Synthesis of Cs0.33WO3/LDHs Composite as a Novel Visible‐Light‐Driven Photocatalyst9Improving the Carprofen Solubility: Synthesis of the Zn2Al-LDH Hybrid Compound33Nanoparticules d’hydroxydes doubles lamellaires élaborées à partir de micelles complexes de copolymères hydrosolubles : Synthèse directe en milieu aqueux et étude de la croissance et de la stabilisation0Effects of different milling techniques on the layered double hydroxides final properties19Reverse microemulsion synthesis of layered gadolinium hydroxide nanoparticles11Mechanochemical synthesis of dodecyl sulfate anion (DS − ) intercalated Cu-Al layered double hydroxide15Studies on drug release kinetics and antibacterial activity against drug-resistant bacteria of cefotaxime sodium loaded layered double hydroxide–fenugreek nanohybrid35Layered double hydroxide and zirconium phosphate as ion exchangers for the removal of ‘black crusts’ from the surface of ancient monuments12Tailoring Hybrid Layered Double Hydroxides for the Development of Innovative Applications320In situ synthesis of magnesium hydroxides modified with tripodal ligands in an organic medium13Layered double hydroxides: A brief review from fundamentals to application as evolving biomaterials930The use of Zn-Ti layered double hydroxide interlayer spacing property for low-loading drug and low-dose therapy. Synthesis, characterization and release kinetics study39Enhanced adsorption of potassium nitrate with potassium cation on H 3 PO 4 modified kaolinite and nitrate anion into Mg-Al layered double hydroxide38Interaction study between 3,4,5-trihydroxy benzoic acid-modified Mg/Al-hydrotalcite with Au ions on the adsorption process of AuCl4−1Intercalation of metformin into montmorillonite60Layered gadolinium hydroxides for simultaneous drug delivery and imaging44Structural and morphological aspects of (fluoro)quinolone delivery by layered double hydroxide nanoparticles4Synthesis of layered double hydroxide/poly( N -isopropylacrylamide) nanocomposite hydrogels with excellent mechanical and thermoresponsive performances44Building Up Functional Bionanocomposites from the Assembly of Clays and Biopolymers37Synthesis of carboxymethyl cellulose-g-poly(acrylic acid)/LDH hydrogel for in vitro controlled release of vitamin B 1263Layered Double Hydroxides (LDHs): Versatile and Powerful Hosts for Different Applications34SEM study of the surface morphology and chemical composition of the MgAl- and MgGa-layered hydroxides in different steps of platinum catalysts Pt/Mg(Al, Ga)O x synthesis24Controlled drug delivery vehicles for cancer treatment and their performance2161Nitrate-intercalated Mg 1−x Al x -Layered Double Hydroxides with different layer charges ( x ): Preparation, characterization, and study by impedance spectroscopy43Controlled Release of Nitrate and Molybdate Intercalated in Zn-Al-Layered Double Hydroxide Nanocontainers towards Marine Anticorrosion Applications66Effects of molar ratio and calcination temperature on the adsorption performance of Zn/Al layered double hydroxide nanoparticles in the removal of pharmaceutical pollutants77Controlled release of organic–inorganic nanohybrid:cefadroxil intercalated Zn–Al-layered double hydroxide41Dual role of layered double hydroxide nanocomposites on antibacterial activity and degradation of tetracycline and oxytetracyline35Evaluation of antioxidant potencial of novel CaAl and NiAl layered double hydroxides loaded with olanzapine11Formation of Arrested States in Natural Di- and Trioctahedral Smectite Dispersions Compared to Those in Synthetic Hectorite — A Macro- and Microrheological Study9Intercalation of hydrophilic antibiotic into the interlayer space of the layered silicate magadiite25Mg–Fe layered double hydroxide assembled on biochar derived from rice husk ash: facile synthesis and application in efficient removal of heavy metals68Highly efficient degradation of 2-chlorophenol and methylene blue with Rb 0.27 WO 3 /NiFe-CLDH composites under visible light irradiation23Controlling the Synthesis Conditions for Tuning the Properties of Hydrotalcite-Like Materials at the Nano Scale26L'élaboration des nouveaux (Bio)-matériaux et leurs applications dans le domaine médical0Two‐Dimensional Materials for Antimicrobial Applications: Graphene Materials and Beyond145Ibuprofen Intercalation and Release From Different Layered Double Hydroxides21Stability of Calcium–Alumino Layered-Double-Hydroxide Nanocomposites in Aqueous Electrolytes8Cinnamate intercalated-layered yttrium hydroxide: A potential hybrid UV filter7An improvised method for the synthesis of ZnAl2O4/ZnO nanocomposite and its use as a photocatalyst6Photodynamic treatment with anionic nanoclays containing curcumin on human triple‐negative breast cancer cells: Cellular and biochemical studies51Mefenamic Acid-Layered Zinc Hydroxide Nanohybrids: A New Platform to Elaborate Drug Delivery Systems15Composite Nanoparticles Based on Hydrotalcite as High Performance Lubricant Additives31

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  1. Poly-vinyl alcohol (PVA) and malachite green: a new reagent system for the microdetermination of phosphate in water and wastewater.

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  3. Development of a Highly Biocompatible Antituberculosis Nanodelivery Formulation Based on Para-Aminosalicylic Acid—Zinc Layered Hydroxide Nanocomposites

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  4. Reactivity and applications of layered silicates and layered double hydroxides

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  5. Redox properties of LDH microcrystals coated with a catechol-bearing phosphonate derived from dopamine

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  7. Alternating Misfit Layered Transition/Alkaline Earth Metal Chalcogenide Ca3Co4O9 as a New Class of Chalcogenide Materials for Hydrogen Evolution

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  10. Synthesis and Characterization of Layered Double Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite

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  11. The preparation and characterization of lactone form of 10-hydroxycamptothecin-layered double hydroxide nanohybrids

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  13. Raman spectroscopy — Useful tool for studying the catalysts derived from Mo and V-oxyanion-intercalated layered double hydroxides

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  35. Layered Double Hydroxides as Nanofillers of Composites and Nanocomposite Materials Based on Polyethylene

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  36. Methotrexate intercalated layered double hydroxides with the mediation of surfactants: Mechanism exploration and bioassay study

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  37. Structure, molecular simulation, and release of a spirin from intercalated Zn–Al-layered double hydroxides

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  38. Magnetic hydrotalcites as solid basic catalysts for cellulose hydrolysis

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  39. Starch Biocatalyst Based on α-Amylase-Mg/Al-Layered Double Hydroxide Nanohybrids

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  40. Structural Characterisation of Complex Layered Double Hydroxides and TGA‐GC‐MS Study on Thermal Response and Carbonate Contamination in Nitrate‐ and Organic‐Exchanged Hydrotalcites

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  44. Self-assemblies of plasmonic gold/layered double hydroxides with highly efficient antiviral effect against the hepatitis B virus

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  45. Alternative Inorganic Systems for Controlled Release Applications

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  46. Novel Nanostructured Solid Materials for Modulating Oral Drug Delivery from Solid-State Lipid-Based Drug Delivery Systems

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  47. Synthesis of methotrexatum intercalated layered double hydroxides by different methods: Biodegradation process and bioassay explore

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  48. Ultrasound-assisted reconstruction and delamination studies on CaAl layered double hydroxides

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  49. Two‐Dimensional Nanomaterials for Biomedical Applications: Emerging Trends and Future Prospects

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  50. Factors Affecting MoO 4 2– Inhibitor Release from Zn 2 Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

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