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RESEARCH PAPER · Inorganic Chemistry · 2010

Novel Bismuth and Lead Coordination Polymers Synthesized with Pyridine-2,5-Dicarboxylates: Two Single Component “White” Light Emitting Phosphors

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Novel Bismuth and Lead Coordination Polymers Synthesized with Pyridine-2,5-Dicarboxylates: Two Single Component “White” Light Emitting PhosphorsOriginalNew 3D bismuth-oxo coordination polymers containing terephthalate-based ligands: observation of Bi 2 O 2 -layer and Bi 4 O 3 -chain motifs83Novel tin supramolecular compounds and coordination polymers: Influence of aromatic dicarboxylates on the crystal structures19A new Kagomé lattice coordination polymer based on bismuth and pyridine-2,5-dicarboxylate: structure and photoluminescent properties89Nitrogen, phosphorus, arsenic, antimony and bismuth2Luminescent Functional Metal–Organic Frameworks5697Structural Diversity of Metal–Organic Materials Containing Bismuth(III) and Pyridine-2,5-Dicarboxylate63Structural motifs in phenylbismuth heterocyclic carboxylates – secondary interactions leading to oligomers31Synthesis and Crystal Structures of the Coordination Polymers Pb(PYTAC)2 and Pb2(PYTAC)3(NO3) (PYTAC = 2-(pyridin-4-yl)thiazole-5-carboxylate)5White Light Emission and Second Harmonic Generation from Secondary Group Participation (SGP) in a Coordination Network159Bismuth–ferrocene carboxylates: synthesis and structure19N-oxide-4,4′-bipyridine, a forgotten ligand in coordination chemistry: structure–photoluminescence property relationships in 2D and 1D lead-coordination polymers19In Situ Formed White-Light-Emitting Lanthanide–Zinc–Organic Frameworks118Intrinsic Broad-Band White-Light Emission by a Tuned, Corrugated Metal–Organic Framework320Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties31Coordination chemistry of the nitro-terephthalate molecule, highlighting two new main group complexes3Dual-Emission from a Single-Phase Eu–Ag Metal–Organic Framework: An Alternative Way to Get White-Light Phosphor244Solvent-Dependent Formation of Cd(II) Coordination Polymers Based on a C2-Symmetric Tricarboxylate Linker138Copper(II)–lanthanide(III) coordination polymers constructed from pyridine-2,5-dicarboxylic acid: Preparation, crystal structure and photoluminescence15Incorporating different secondary building units of {Bi 2 }, {Bi 8 } and {Bi 10 } to construct diversity of luminescent bismuth–organic frameworks22Luminescent 2D bismuth–cadmium–organic frameworks with tunable and white light emission by doping different lanthanide ions37Luminescent Properties and Applications of Metal-Organic Frameworks21Mixed Cu(ii)–Bi(iii) metal organic framework with a 2D inorganic subnetwork and its catalytic activity34White light emission based on a single component Sm( iii ) framework and a two component Eu( iii )-doped Gd( iii ) framework constructed from 2,2′-diphenyl dicarboxylate and 1 H -imidazo[4,5- f ][1,10]-phenanthroline108White photoluminescent material based on a functional polysiloxane complex with lanthanide ions (Eu3+ and Dy3+)9N‐Methyl‐4,4′‐bipyridinium and N‐Methyl‐N′‐oxide‐4,4′‐bipyridinium Bismuth Complexes – Photochromism and Photoluminescence in the Solid State82In(SAr)3 As a Building Block for 3D and Helical Coordination Polymers14Bismuth Carboxylates with Brucite- and Fluorite-Related Structures: Synthesis Structure and Properties32Mercury Bismuth Chalcohalides, Hg3Q2Bi2Cl8 (Q = S, Se, Te): Syntheses, Crystal Structures, Band Structures, and Optical Properties21Syntheses, molecular and crystalline architectures, and luminescence behaviour of terephthalate bridged heptacoordinated dinuclear lead(II) complexes containing a pentadentate N-donor Schiff base4Bismuth Tri‐ and Tetraarylcarboxylates: Crystal Structures, In Situ X‐ray Diffraction, Intermediates and Luminescence82Syntheses, structures, and luminescence behavior of terephthalate bridged lead(II) complexes with tetradentate N-donor Schiff bases15Enhancing photoluminescent behavior of 2-(naphthalen-1-yl)-1,4,5-triphenyl-1H-imidazole by ZnO and Bi2O333A Bismuth(III) Coordination Polymer With Pyridine-2,3-dicarboxylic Acid as Precursor for Preparation of Bi2O3 Nanoparticles via Thermal Decomposition16Spectroscopic and structural investigation of 2,5-dicarboxy-1-methylpyridinium inner salt1Synthesis, structures and properties of the first series of Sr II –M II (M = Cu, Co, Ni and Zn) coordination polymers based on pyridine-2,5-dicarboxylic acid21A white-light-emitting LnMOF with color properties improved via Eu3+ doping: an alternative approach to a rational design for solid-state lighting72Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal–Organic Frameworks222Anionic porous metal–organic framework with novel 5-connected vbk topology for rapid adsorption of dyes and tunable white light emission119Tuning electronic and optical properties of a new class of covalent organic frameworks38Unexpected transfer of phenyl from a phenylbismuth complex to iridium in [Cp*IrCl2]26A Novel Bismuth‐Based Metal–Organic Framework for High Volumetric Methane and Carbon Dioxide Adsorption80Hemi- and holo-directed lead( ii ) complexes in a soft ligand environment35Coordination polymers for energy transfer: Preparations, properties, sensing applications, and perspectives418Hydrothermal syntheses and crystal structure of a novel one-dimensional Pb(II) coordination polymer with chenodeoxycholic acid ligand1Intercalation of lanthanide cations to a layer-like metal–organic framework for color tunable white light emission42A new strategy for achieving white-light emission of lanthanide complexes: effective control of energy transfer from blue-emissive fluorophore to Eu( iii ) centres54Color tunable and near white-light emission of two solvent-induced 2D lead( ii ) coordination networks based on a rigid ligand 1-tetrazole-4-imidazole-benzene33Color-tunable and white-light emission of one-dimensional l -di-2-thenoyltartaric acid mixed-lanthanide coordination polymers45Lanthanide coordination frameworks constructed from 1,3-benzenedicarboxylate, oxalate and 1,10-phenanthroline: crystal structure, multicolor luminescence and high-efficiency white light emission27Narrow bandgap covalent–organic frameworks with strong optical response in the visible and infrared21Photoluminescence and white-light emission in two series of heteronuclear Pb( ii )–Ln( iii ) complexes23Semidirected versus holodirected coordination and single-component white light luminescence in Pb( ii ) complexes383D Microporous Lanthanide–Organic Frameworks Constructed from Left‐ and Right‐Handed Helical Chains: Synthesis, Crystal Structure, and Tunable Photoluminescence8Multistimuli‐responsive White Luminescent Fluids Using Hybrid Lanthanide Metal–Coordinate Complex Probes38Ten new predicted covalent organic frameworks with strong optical response in the visible and near infrared13Three new bismuth(III) pyridine-2,6-dicarboxylate compounds: Synthesis, characterization and crystal structures18The Lead Coordination Polymers Containing Pyrazine-2,3-Dicarboxylic Acid: Rapid Structural Transformations and Cation Exchange25A highly stable and white-light-emitting Eu( iii ) MOF29Tunable luminescence and white light emission of mixed lanthanide–organic frameworks based on polycarboxylate ligands142A bismuth based layer structured organic–inorganic hybrid material with enhanced photocatalytic activity27Hydrothermal synthesis of Bismuth(III) coordination polymer and its transformation to nano α-Bi2O3 for photocatalytic degradation40High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework59A new bismuth-based coordination polymer as an efficient visible light responding photocatalyst under white LED irradiation14Structural Diversity of Bismuth(III) Thiophenemonocarboxylates Isolated from Aqueous Solutions13A two-dimensional bismuth coordination polymer with tartaric acid: Synthesis, characterization and thermal decomposition to Bi 2 O 3 nanoparticles7Synthesis and crystal structures of three new lead(II) isonicotinoylhydrazone derivatives: Anion controlled nuclearity and dimensionality55Highly Efficient White-Light Emission and UV–Visible/NIR Luminescence Sensing of Lanthanide Metal–Organic Frameworks912D holodirected lead(II) halide coordination polymers based on rigid N,N′-bis(4-pyridylmethylidyne) phenylene-1,4-diamine ligand: Syntheses, crystal structures, NBO studies and luminescence properties12Synthesis, spectral and X-ray diffraction of two new 2D lead(II) coordination polymers formed by nicotinic acid N-oxide linkers26Ligand-Driven Coordination Sphere-Induced Engineering of Hybride Materials Constructed from PbCl2 and Bis-Pyridyl Organic Linkers for Single-Component Light-Emitting Phosphors78Sonochemical synthesis of a novel nanoscale 1D lead(II) [Pb2(L)2(I)4]n coordination Polymer, survey of temperature, reaction time parameters24Pure white light emission from a rare earth-free intrinsic metal–organic framework and its application in a WLED64Exploring physical and chemical properties in new multifunctional indium-, bismuth-, and zinc-based 1D and 2D coordination polymers26Bismuth( iii )-thiophenedicarboxylates as host frameworks for lanthanide ions: synthesis, structural characterization, and photoluminescent behavior20Facile preparation of a tetraphenylethylene-doped metal–organic framework for white light-emitting diodes28Pb[NC 5 H 3 (CO 2 ) 2 ]: a white light emitting single component coordination polymer revealing high quantum efficiency and thermal stability25Three Cd(II) MOFs with Different Functional Groups: Selective CO2 Capture and Metal Ions Detection97Bismuth Coordination Polymers with 2,4,6‐Pyridine Tricarboxylic Acid: High‐Throughput Investigations, Crystal Structures and Luminescence Properties18Preparation of monodispersed metal-based infinite coordination polymer nanostructures and their good capability for metal oxide preparation11Tridecanuclear CuII11Na2 Cagelike Silsesquioxanes25Nanostructured BiOI for air pollution control: Microwave-assisted synthesis, characterization and photocatalytic activity toward NO transformation under visible light irradiation25An alkaline metal–organic framework on white-light emission by two routes of ion–exchange with lanthanide metal ions2Multiparameter High-Throughput and in Situ X-ray Diffraction Study of Six New Bismuth Sulfonatocarboxylates: Discovery, Phase Transformation, and Reaction Trends25Single-Phase White-Light-Emitting and Photoluminescent Color-Tuning Coordination Assemblies567Near-White Light Emission from Lead(II) Metal–Organic Frameworks48Lead‐Based Organic Frameworks (Pb‐MOFs): Structural, Luminescence and Adsorption Aspects23Modulating photoelectronic performance of metal–organic frameworks for premium photocatalysis155Morphological, luminescence and gas adsorption studies of Pb(II)-MOFs2Effects of N -oxidation on the molecular and crystal structures and properties of isocinchomeronic acid, its metal complexes and their supramolecular architectures: experimental, CSD survey, solution and theoretical approaches22Significant enhancement of cathode-ray scintillation for a conductive Bi-SMOF via in situ partial rare earth ion replacement34An unusual four-nuclear Pb(II)-pyrrole-2-carboxylato polymer: The effect of the lone pair and non-covalent interactions on the supramolecular assembly and fluorescence properties31Three Silver Coordination Polymers with Diverse Architectures Constructed from Pyridine Carboxylic Hydrazide Ligands28Lead–Organic Frameworks Containing Trimesic Acid: Facile Dissolution–Crystallization and Near-White Light Emission15Sensing of Fe3+ and Cr2O72– in Water and White Light: Synthesis, Characterization, and Fluorescence Properties of a Crystalline Bismuth-1,3,5-benzenetricarboxylic Acid Framework67Color-Tuning and Near-Sunlight White Emission in Highly Stable Rod-Spacer MOFs with Defective Dicubane Based Lead(II)-Carboxyl Chains38Supramolecular architecture constructed from the hemidirected lead(II) complex with N'-(4-hydroxybenzylidene)isonicotinohydrazide49Lead( ii ) coordination polymers driven by pyridine-hydrazine donors: from anion-guided self-assembly to structural features35Synthesis and photoluminescence of three bismuth( iii )-organic compounds bearing heterocyclic N-donor ligands20A rht‐Type Luminescent Zn (II)‐MOF Constructed by Triazine Hexacarboxylate Ligand: Tunable Luminescent Performance and White‐light Emission Regulation through doping Eu3+/Tb3+12Room Temperature Synthesis and Characterization of Novel Bi(III) Complex with 2-Amino-3- Carbomethoxy-4,5,6,7-Tetrahydrobenzo[B]Thiophene as Potential Antimicrobial Agent7Second-Harmonic Generation and Photoluminescence Properties of Sn(II)- and Bi(III)-Based Lone Pair Cation–Pyridine Dicarboxylate Coordination Compounds17Lanthanide Contraction in Action: Structural Variations in 13 Lanthanide(III) Thiophene-2,5-dicarboxylate Coordination Polymers (Ln = La–Lu, Except Pm and Tm) Featuring Magnetocaloric Effect, Slow Magnetic Relaxation, and Luminescence-Lifetime-based Thermometry56Tetrel Bonding and Other Non-Covalent Interactions Assisted Supramolecular Aggregation in a New Pb(II) Complex of an Isonicotinohydrazide51Bi( iii ) MOFs: syntheses, structures and applications82Structural Insights into New Bi(III) Coordination Polymers with Pyridine-2,3-Dicarboxylic Acid: Photoluminescence Properties and Anti-Helicobacter pylori Activity24A different approach: highly encapsulating macrocycles being used as organic tectons in the building of CPs3Environmental pollution analysis based on the luminescent metal organic frameworks: A review94Blue- and white-light-emitting 2D-coordination polymers and their solid-state photodimerization reaction6Synthesis, structural characterization, and luminescence properties of heteroleptic bismuth-organic compounds8Applications of MOFs as Luminescent Sensors for Environmental Pollutants436Synthesis, Single‐Crystal Structure, Dielectric Properties of a New Phosphate K3Bi6.5(PO4)7.54Bismuth-based metal–organic frameworks and their derivatives: Opportunities and challenges149Metal-organic frameworks as functional materials for implantable flexible biochemical sensors41Recent Advances on the Applications of Luminescent Pb2+-Containing Metal–Organic Frameworks in White-Light Emission and Sensing14Polymeric lead(II) phosphor featuring cubane [Pb4] and [Pb8] units: Organic vs inorganic binding competition, colour regulation and white luminescence2A new bismuth coordination polymer with proton conductivity and orange-red photoluminescence6Structural insights into coordination polymers based on 6s2 Pb(II) and Bi(III) centres connected via heteroaromatic carboxylate linkers and their potential applications55Open for Bismuth: Main Group Metal-to-Ligand Charge Transfer40The effect of pH on the coordination sphere of Pb(II) ions and structural diversity of Pb(II) coordination polymers8Synthesis, structures and properties of lead coordination polymers based on pyridinedicarboxylate ligand6Harnessing Bismuth Coordination Chemistry to Achieve Bright, Long-Lived Organic Phosphorescence24Bismuth-Based Metal–Organic Frameworks Derived from Multi-Carboxylate Organic Linkers3Ψ-Polyhedral symbols for bismuth(III) with an active electron lone pair2Nanoarchitectonics of heterometallic compound Al4Bi4 for optical limiting2An overview of the synthesis and structures lead(II) and mercury(II) complexes with diamine-based bis-pyridine Schiff base ligands5Synthesis, Crystal Structures, Photophysics and Computational Study of a Series of Luminescent Pb2+ Compounds Bearing Various Functionalized Diimine Ligands3Two Bi-Mofs with Pyridylmulticarboxylate Ligands Showing Distinct Crystal Structures and Phosphorescence Properties0Two Bi-MOFs with pyridylmulticarboxylate ligands showing distinct crystal structures and phosphorescence properties8Synthesis, structures and properties of two lead halide coordination polymers based on pyridinedicarboxylate ligand4Multifunctional Luminescent Sensor Based on the Pb2+ Complex Containing a Tetrazolato Ligand17Tetrel bonding stabilization of a new coordination polymer constructed from lead( ii ) azide and 1-(pyridin-2-yl)ethylidenepicolinohydrazide16Strategies, Synthesis, and Applications of Metal-Organic Framework Materials0Efficient Europium Sensitization via Low-Level Doping in a 2-D Bismuth-Organic Coordination Polymer1Rapid Light Response of a Novel Bi‐Based Metal–Organic Framework for Bacterial Wound Infections Treatment10Bismuth trihalide based coordination polymers with the N‐donor cyanopyridine as source for charge transfer based luminescence4Unlocking Arene Phosphorescence in Bismuth–Organic Materials7Supramolecular lead(II) coordination polymers, obtained from polydonor N'-(amino(pyrazin-2-yl)methylene)thiosemicarbazide0Interaction of Lead(II) Perchlorate with N′-Isonicotinoylpicolinohydrazonamide and Its Sodium Salt in the Presence of Potassium Cyanide: Yellow Green Light Emitting Phosphors, Stabilized by Tetrel Bonds, and a System to Transform Methanol to Acetate10A structural versatility of the lead(II) coordination compounds with N′-(pyridin-2-ylmethylene)isonicotinohydrazide7Supramolecular coordination polymers, obtained from multidentate N′-benzoylpyrazine-2-carbohydrazonamide and a variety of salts PbX2 (X = Cl−, NO3−, NO2−, SCN−), derived from tetrel and other noncovalent bonds1A lead( ii ) supramolecular coordination polymer, obtained from polydonor N ′-(amino(pyrazin-2-yl)methylene)thiosemicarbazide, stabilized by tetrel bonds and other non-covalent interactions1Bismuth-based metal–organic materials: lone-pair-driven structures, single-crystal-mediated synthetic strategies, and emerging applications0Tetrel bonding stabilized supramolecular dimer versus coordination polymer, obtained from N'-benzoylpyrazine-2-carbohydrazonamide and lead(II) acetate2Bismuth based MOF for low concentration non-enzymatic histamine electrochemical detection0In Situ Confinement of 0D Halometallates Within Deep Eutectic Solvents: From Systematic Screening to Metal‐Tunable Luminescence for Anti‐Counterfeiting Eutectogels0Advances in Bi-MOF-based heterostructures for CO2 photoconversion: Mechanistic insights, charge dynamics, and structure-function correlations0

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