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RESEARCH PAPER · Nano Letters · 2013

Imaging the Atomic Surface Structures of CeO2 Nanoparticles

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Imaging the Atomic Surface Structures of CeO2 NanoparticlesOriginalSynthesis of monocarboxylic acid-modified CeO 2 nanoparticles using supercritical water47Electron-induced Ti-rich surface segregation on SrTiO3 nanoparticles15Morphology-dependent surface chemistry and catalysis of CeO 2 nanocrystals244Direct Observation of Atomic Surface Structures of CeO2 Nanoparticles0The effects of bimetallic Co–Ru nanoparticles on Co/RuO 2 /Al 2 O 3 catalysts for the water gas shift and methanation22Surface sites on Pt–CeO 2 mixed oxide catalysts probed by CO adsorption: a synchrotron radiation photoelectron spectroscopy study27Catalytic activities of CeO2(110)–2 × 1 reconstructed surface33Ceria Nanocrystals Exposing Wide (100) Facets: Structure and Polarity Compensation59Applications of Electron Microscopy in Heterogeneous Catalysis1Ceria Nanoshapes—Structural and Catalytic Properties21Morphology-dependent interplay of reduction behaviors, oxygen vacancies and hydroxyl reactivity of CeO 2 nanocrystals133Quantitative depth profiling of Ce 3+ in Pt/CeO 2 by in situ high-energy XPS in a hydrogen atmosphere102The Characterization and Structure-Dependent Catalysis of Ceria with Well-Defined Facets10Transmission electron microscopy finds plenty of room on the surface22Facet‐Dependent Effect of Well‐Defined CeO 2 Nanocrystals on the Adsorption and Dephosphorylation of Phosphorylated Molecules39The surface chemistry of cerium oxide687Spectroscopic Investigation of Surface-Dependent Acid–Base Property of Ceria Nanoshapes209Effect of Oxygen Defects on the Catalytic Performance of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol125Critical Influence of Nanofaceting on the Preparation and Performance of Supported Gold Catalysts67Surface-Dependence of Defect Chemistry of Nanostructured Ceria87Photochemical Deposition of Highly Dispersed Pt Nanoparticles on Porous CeO2 Nanofibers for the Water‐Gas Shift Reaction86Surface-Structure Sensitivity of CeO2 Nanocrystals in Photocatalysis and Enhancing the Reactivity with Nanogold190Structural and chemical characterization of novel NixZn1−xGa2O4 nanocatalysts at atomic resolution1Adhesion and Atomic Structures of Gold on Ceria Nanostructures: The Role of Surface Structure and Oxidation State of Ceria Supports114Activity versus Selectivity of the Methanol Oxidation at Ceria Surfaces: A Comparative First-Principles Study33Three-Dimensional Ordered CeO2 Hollow Spheres (3DOHSs-CeO2) from Polymethylmethacrylate/CeO2 Core/Shell Microsphere Colloidal Crystals2Surface Structure Dependence of SO 2 Interaction with Ceria Nanocrystals with Well-Defined Surface Facets42Real-Time Observation of Reconstruction Dynamics on TiO2(001) Surface under Oxygen via an Environmental Transmission Electron Microscope127Oxidation-state sensitive imaging of cerium dioxide by atomic-resolution low-angle annular dark field scanning transmission electron microscopy15Enhanced Hydroxyl Radical Scavenging Activity by Doping Lanthanum in Ceria Nanocubes98Ceria-Based Materials in Catalysis58Shape dependence of nanoceria on complete catalytic oxidation of o-xylene83Nanoparticle shape, thermodynamics and kinetics306Segregation and Migration of the Oxygen Vacancies in the Σ3 (111) Tilt Grain Boundaries of Ceria21Application of the surface potential data to elucidate interfacial equilibrium at ceria/aqueous electrolyte interface17Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach263Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis61Catalytic combustion of toluene with La0.8Ce0.2MnO3 supported on CeO2 with different morphologies83Basic Research Needs for Innovation and Discovery of Transformative Experimental Tools6Achieve atomic resolution in in situ S/TEM experiments to examine complex interface structures in nanomaterials24Atomic Surface Structures of Oxide Nanoparticles with Well-defined Shapes0When does atomic resolution plan view imaging of surfaces work?4Structure–Activity Map of Ceria Nanoparticles, Nanocubes, and Mesoporous Architectures58Probing Surface Structures of CeO 2 , TiO 2 , and Cu 2 O Nanocrystals with CO and CO 2 Chemisorption194Controlling the Formation and Structure of Nanoparticle Superlattices through Surface Ligand Behavior12Performance of DFT+ U Approaches in the Study of Catalytic Materials236Entropic contributions enhance polarity compensation for CeO2(100) surfaces121Synergistic degradation of antimicrobial agent ciprofloxacin in water by using 3D CeO2/RGO composite as cathode in electro-Fenton system53Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture36Oberflächenfacettierung und Rekonstruktion von Ceroxid‐ Nanopartikeln18Surface Faceting and Reconstruction of Ceria Nanoparticles268Oxygen-vacancy-promoted catalytic wet air oxidation of phenol from MnO x –CeO 255Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst65Publisher's Note3Transfer hydrogenation over sodium-modified ceria: Enrichment of redox sites active for alcohol dehydrogenation23Nanoscale Cobalt–Manganese Oxide Catalyst Supported on Shape-Controlled Cerium Oxide: Effect of Nanointerface Configuration on Structural, Redox, and Catalytic Properties58In Situ STEM Determination of the Atomic Structure and Reconstruction Mechanism of the TiO2 (001) (1 × 4) Surface54Structure and chemistry of epitaxial ceria thin films on yttria-stabilized zirconia substrates, studied by high resolution electron microscopy31Fast MAS 1H NMR Study of Water Adsorption and Dissociation on the (100) Surface of Ceria Nanocubes: A Fully Hydroxylated, Hydrophobic Ceria Surface43Inhibitory effects of water vapor on elemental mercury removal performance over cerium-oxide-modified semi-coke59Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?789In situ TEM observations of Oxygen Surface Dynamics in CeO2 Cubes3Variations in the surface chemistry of methanol with CeO2(100) at low and elevated pressures5Shape-Controlled CeO2 Nanoparticles: Stability and Activity in the Catalyzed HCl Oxidation Reaction144Visualizing atomic-scale redox dynamics in vanadium oxide-based catalysts75Atomic layer reversal on CeO2 (100) surface20Predicting NOx Catalysis by Quantifying Ce3+ from Surface and Lattice Oxygen24Photoaktivierung von Cerdioxid: die Rolle von Defekten4Rendering Photoreactivity to Ceria: The Role of Defects54Control synthesis of CeO2 nanomaterials supported gold for catalytic oxidation of carbon monoxide59Hollow Structure and Electron Promotion Effect of Mesoporous Pd/CeO2 Catalyst for Enhanced Catalytic Hydrogenation40Oxygen vacancy clusters essential for the catalytic activity of CeO2 nanocubes for o-xylene oxidation154Designed synthesis of thin CeO2 nanowires-supported Pt electrocatalysts with pore-interconnected structure and its high catalytic activity for methanol oxidation21Fabricated CeO2 nanopowders as a novel sensing platform for advanced forensic, electrochemical and photocatalytic applications28Oxygen adatoms and vacancies on the (110) surface of CeO220Direct Visualization and Control of Atomic Mobility at {100} Surfaces of Ceria in the Environmental Transmission Electron Microscope63Controllable Synthesis and Growth Mechanism of Ceria Nanocubes by Template‐Free Hydrothermal Method17Unveiling the Atomic Structures of the Minority Surfaces of TiO2 Nanocrystals28Effect of Ceria on redox-catalytic property in mild condition: A solvent-free route for imine synthesis at low temperature80A review on modification methods of adsorbents for elemental mercury from flue gas185Investigation of magnetic properties for Hf4+ substituted CeO2 nanoparticles for spintronic applications21Dependency of structural change and polishing efficiency of meso-silica/ceria core/shell composite abrasives on calcination temperatures17Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions18Selective allylic oxidation of cyclohexene over a novel nanostructured CeO2–Sm2O3/SiO2 catalyst18Design of Waterborne Nanoceria/Polymer Nanocomposite UV-Absorbing Coatings: Pickering versus Blended Particles30Identification of Rapid Oxygen Exchange Through Site-Dependent Cationic Displacements on CeO2 Nanoparticles4The effect of support morphology on CoOX/CeO2 catalysts for the reduction of NO by CO41In situ oxidation and reduction of cerium dioxide nanoparticles studied by scanning transmission electron microscopy18Protecting Ceria Nanocatalysts─The Role of Sacrificial Barriers11Atomic‐Scale Valence State Distribution inside Ultrafine CeO2 Nanocubes and Its Size Dependence125Subsurface reconstruction and saturation of surface bonds19Understanding CeO2‐Based Nanostructures through Advanced Electron Microscopy in 2D and 3D36A DFT+ U revisit of reconstructed CeO 2 (100) surfaces: structures, thermostabilities and reactivities43Atomic-Level Analysis of Oxygen Exchange Reactions on Ceria-based Catalysts0Controlling the {111}/{110} Surface Ratio of Cuboidal Ceria Nanoparticles47Enhanced photocatalytic reduction of CO2 by fabricating In2O3/CeO2/HATP hybrid multi-junction photocatalyst48Ceria nanocube with reactive {100} exposure planes: Simple and controllable synthesis under moderate conditions13Surface Reconstructions of Metal Oxides and the Consequences on Catalytic Chemistry225Multiscale Modeling of Agglomerated Ceria Nanoparticles: Interface Stability and Oxygen Vacancy Formation14Atomic Mechanism in Layer-by-Layer Growth via Surface Reconstruction15Wavelength‐Selective Photoreduction of Colloidal CeO2–x Nanocrystals7Surface chemistry and catalysis of oxide model catalysts from single crystals to nanocrystals146Can the environmental TEM confirm atomistic models of adsorbed molecules at surfaces of solids?0Reverse Monte Carlo modeling for low-dimensional systems8Dissociation de H2 sur des surfaces d’oxydes de cérium : étude de la réductibilité0A solid-state chemist’s eye for the development of materials science in China5Atomically dispersed platinum on low index and stepped ceria surfaces: phase diagrams and stability analysis28Composite particles with dendritic mesoporous-silica cores and nano-sized CeO2 shells and their application to abrasives in chemical mechanical polishing38Preparation, characterization, and application of dendritic silica-supported samarium-doped ceria nanoparticles in ultra-precision polishing for silica films17Cationic ion-driven surface control of one-dimensional CeO2 nanocrystals to enhance catalytic performance of CO oxidation12Properties, preparation methods and use of cerium nanooxide5Coordination Polymer to Atomically Thin, Holey, Metal‐Oxide Nanosheets for Tuning Band Alignment36Controllable design, synthesis and characterization of nanostructured rare earth metal oxides21A review of sample thickness effects on high-resolution transmission electron microscopy imaging29Clarifying the impacts of surface hydroxyls on CO oxidation on CeO 2 (100) surfaces: a DFT+ U study29Formation mechanism and size control of ceria nanocubes32Strongly Bound Surface Water Affects the Shape Evolution of Cerium Oxide Nanoparticles47Visualizing Anisotropic Oxygen Diffusion in Ceria under Activated Conditions35Effect of Ag-CeO2 interface formation during one-spot synthesis of Ag-CeO2 composites to improve their catalytic performance for CO oxidation34Efficiency and mechanism of pollutant degradation and bromate inhibition by faceted CeO2 catalyzed ozonation: Experimental and theoretical study61Dispersion of copper oxide species on nanostructured ceria37Ruthenium-loaded cerium dioxide nanocomposites with rich oxygen vacancies promoted the highly sensitive electrochemical detection of Hg(II)62Investigating the wetting phenomena and fabrication of sticky, para-hydrophobic cerium oxide coating10Flexible Cation Distribution for Stabilizing a Spinel Surface12Surface termination and stoichiometry of LaAlO3(001) surface studied by HRTEM15Oxygen Vacancy-Related Cathodoluminescence Quenching and Polarons in CeO235Surface Refaceting Mechanism on Cubic Ceria81Synthesis, Structure and Catalytic Properties of Faceted Oxide Crystals17Dynamic observation of manganese adatom mobility at perovskite oxide catalyst interfaces with water27Design strategies for ceria nanomaterials: untangling key mechanistic concepts73g-C3N4 quantum dots-modified mesoporous CeO2 composite photocatalyst for enhanced CO2 photoreduction14Theoretical and Experimental Studies of Structural Defects in CeO2 Nanoparticles6Recent Progresses on Structural Reconstruction of Nanosized Metal Catalysts via Controlled-Atmosphere Transmission Electron Microscopy: A Review118Metastable Ce-terminated (1 1 1) surface of ceria12Fe doped CeO2 nanocubes with the exposure of active (100) facets for photocatalytic ozonation of 4‐chlorophenol under solar irradiation18Atomic Scale Characterization of Fluxional Cation Behavior on Nanoparticle Surfaces: Probing Oxygen Vacancy Creation/Annihilation at Surface Sites52Unraveling the physical chemistry and materials science of CeO2-based nanostructures200Crystal plane effect of ceria on supported copper catalyst for liquid-phase hydrogenation of unsaturated aldehyde21Self-assembled dendrite-like 3D-CeO2 nanostructures for non-enzymatic vitamin B2 sensor18Graphene and Spherical CeO 2 -ZrO 2 Support Pt Nanoparticles as Anode Catalysts for Direct Methanol Fuel Cells6Shape control of exposed planes in ceria-zirconia based electrocatalysts for methanol oxidation14Tailoring CO2 adsorption and activation properties of ceria nanocubes by coating with nanometre-thick yttria layers4Enhanced Artificial Enzyme Activities on the Reconstructed Sawtoothlike Nanofacets of Pure and Pr-Doped Ceria Nanocubes19In Situ Resolving the Atomic Reconstruction of SnO2 (110) Surface38Vibrational Spectroscopies4Facet-Dependent selectivity of CeO2 nanoparticles in 2-Propanol conversion62Enhancing nitrobenzene reduction to azoxybenzene by regulating the O-vacancy defects over rationally tailored CeO2 nanocrystals19Exploring the effect of morphology and surface properties of nanoshaped Pd/CeO2 catalysts on CO2 hydrogenation to methanol53High Dispersion of CeO2 on CeO2/MgO Prepared under Dry Conditions and Its Improved Redox Properties4Surface potentials of acceptor- and donor-doped CeO 2 thin films and their relation to oxygen surface exchange13

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  1. Synthesis of monocarboxylic acid-modified CeO 2 nanoparticles using supercritical water

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  2. Electron-induced Ti-rich surface segregation on SrTiO3 nanoparticles

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  3. Morphology-dependent surface chemistry and catalysis of CeO 2 nanocrystals

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  4. Direct Observation of Atomic Surface Structures of CeO2 Nanoparticles

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  5. The effects of bimetallic Co–Ru nanoparticles on Co/RuO 2 /Al 2 O 3 catalysts for the water gas shift and methanation

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  6. Surface sites on Pt–CeO 2 mixed oxide catalysts probed by CO adsorption: a synchrotron radiation photoelectron spectroscopy study

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  7. Catalytic activities of CeO2(110)–2 × 1 reconstructed surface

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  8. Ceria Nanocrystals Exposing Wide (100) Facets: Structure and Polarity Compensation

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  11. Morphology-dependent interplay of reduction behaviors, oxygen vacancies and hydroxyl reactivity of CeO 2 nanocrystals

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  12. Quantitative depth profiling of Ce 3+ in Pt/CeO 2 by in situ high-energy XPS in a hydrogen atmosphere

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  14. Transmission electron microscopy finds plenty of room on the surface

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  15. Facet‐Dependent Effect of Well‐Defined CeO 2 Nanocrystals on the Adsorption and Dephosphorylation of Phosphorylated Molecules

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  17. Spectroscopic Investigation of Surface-Dependent Acid–Base Property of Ceria Nanoshapes

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  18. Effect of Oxygen Defects on the Catalytic Performance of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

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  20. Surface-Dependence of Defect Chemistry of Nanostructured Ceria

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  21. Photochemical Deposition of Highly Dispersed Pt Nanoparticles on Porous CeO2 Nanofibers for the Water‐Gas Shift Reaction

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  25. Activity versus Selectivity of the Methanol Oxidation at Ceria Surfaces: A Comparative First-Principles Study

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  34. Segregation and Migration of the Oxygen Vacancies in the Σ3 (111) Tilt Grain Boundaries of Ceria

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  35. Application of the surface potential data to elucidate interfacial equilibrium at ceria/aqueous electrolyte interface

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  36. Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach

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  37. Shape Engineering of Oxide Nanoparticles for Heterogeneous Catalysis

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  38. Catalytic combustion of toluene with La0.8Ce0.2MnO3 supported on CeO2 with different morphologies

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  45. Controlling the Formation and Structure of Nanoparticle Superlattices through Surface Ligand Behavior

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  47. Entropic contributions enhance polarity compensation for CeO2(100) surfaces

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  48. Synergistic degradation of antimicrobial agent ciprofloxacin in water by using 3D CeO2/RGO composite as cathode in electro-Fenton system

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  49. Controlled Growth of Ceria Nanoarrays on Anatase Titania Powder: A Bottom-up Physical Picture

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  50. Oberflächenfacettierung und Rekonstruktion von Ceroxid‐ Nanopartikeln

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