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RESEARCH PAPER · Chemical Communications · 2008

PF6− Hydrolysis as a route to unique uranium phosphate materials

Nicholas P. Deifel, K.T. Holman, Christopher L. Cahill

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PF6− Hydrolysis as a route to unique uranium phosphate materialsOriginalChemInform Abstract: PF6‐ Hydrolysis as a Route to Unique Uranium Phosphate Materials.1A new crystal modification of diammonium hydrogen phosphate, (NH4)2(HPO4)3Hydrogen-Bonded Quartz-type Network of Diprotonated Tetrakis(4-pyridyl)methane Dications8A Cubic, 12-Connected, Microporous Metal−Organometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes57A straightforward and convenient pathway for the synthesis of functional bismacrocyclic ligands7Bifunctional Ionic Liquid Catalyst Containing Sulfoacid Group and Hexafluorotitanate for Room Temperature Sulfoxidation of Sulfides to Sulfoxides Using Hydrogen Peroxide33Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Ionothermal synthesis of uranyl compounds that incorporate imidazole derivatives14An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols12Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl)cyanurate32,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Morphotropy and Temperature-Driven Polymorphism in A2Th(AsO4)2 (A = Li, Na, K, Rb, Cs) Series19Synthesis and characterization of a trans-1 hexakis-fullerene linker that forms crystalline polymers with silver salts8Mild hydrothermal crystal growth of new uranium(IV) fluorides, Na3.13Mg1.43U6F30 and Na2.50Mn1.75U6F30: Structures, optical and magnetic properties12Hexafluoridophosphate partial hydrolysis leading to the one-dimensional coordination polymer [{Cu(xantphos)(μ-PO2F2)} ]6Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials45o-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands1Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption64Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO2)4F13][Sr3(H2O)8](NO3)·H2O6Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Phosphate–phosphate oligomerization drives higher order co-assemblies with stacks of cyanostar macrocycles86Complex Inorganic Actinide Materials1Semirigid Tripodal Ligand Based Uranyl Coordination Polymer Isomers Featuring 2D Honeycomb Nets33Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange37Uranyl Compounds Involving a Weakly Bonded Pseudorotaxane Linker: Combined Effect of pH and Competing Ligands on Uranyl Coordination and Speciation33Optimization of the synthesis of UiO-66(Zr) in ionic liquids25Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth13Solubilité et fluoration d’oxydes d’uranium en milieu liquide ionique0A unique uranyl framework containing uranyl pentamers as secondary building units: synthesis, structure, and spectroscopic properties25Highly efficient absorption of methyl tert-butyl ether with ionic liquids18Features of Uranium Stereochemistry in Uranyl Oxofluorides6New Barium Fluorosuccinato and Fluoroglutarato Uranylates2New Barium Fluorosuccinato and Fluoroglutarato Uranylates2Improving the Mg Sacrificial Anode in Tetrahydrofuran for Synthetic Electrochemistry by Tailoring Electrolyte Composition20Uranyl-Tc( vii )/Tc( v ) hybrid clusters5Alkaline Metal Fluorooxalatouranilates: Structures and Selected Properties2Lithium, Sodium, and Strontium Fluoroglutaratouranylates: Structure and Some Properties1A new uranyl silicate sheet derived from phosphuranylite topology in the structure of Cs4[(UO2)5(SiO3OH)2O2F4]1Alkaline Metal Fluoroxalatouranylates: Structure and Some Properties0Lithium, sodium and strontium fluoroglutaratouranylates: structure and some properties0

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  1. ChemInform Abstract: PF6‐ Hydrolysis as a Route to Unique Uranium Phosphate Materials.

    ChemInform · 2009-02-13

    Nicholas P. Deifel, K.T. Holman, Christopher L. Cahill

    Read original paper ↗ ·

  2. A new crystal modification of diammonium hydrogen phosphate, (NH4)2(HPO4)

    Acta Crystallographica Section E Structure Reports Online · 2010-03-19

    Peter C. Kunz, Corinna Wetzel, Bernhard Spingler

    Read original paper ↗ ·

  3. Hydrogen-Bonded Quartz-type Network of Diprotonated Tetrakis(4-pyridyl)methane Dications

    Crystal Growth & Design · 2010-06-03

    Kouzou Matsumoto, Daisuke Inokuchi, Yasukazu Hirao, Hiroyuki Kurata, Takashi Kubo

    Read original paper ↗ ·

  4. A Cubic, 12-Connected, Microporous Metal−Organometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes

    Journal of the American Chemical Society · 2011-01-19

    Sayon A. Kumalah Robinson, Marion-Vincent L. Mempin, Amy Cairns, K.T. Holman

    Read original paper ↗ ·

  5. A straightforward and convenient pathway for the synthesis of functional bismacrocyclic ligands

    Tetrahedron Letters · 2011-02-02

    Pascal Kadjane, Nikos K. Logothetis, Goran Angelovski

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  6. Bifunctional Ionic Liquid Catalyst Containing Sulfoacid Group and Hexafluorotitanate for Room Temperature Sulfoxidation of Sulfides to Sulfoxides Using Hydrogen Peroxide

    ACS Catalysis · 2012-01-02

    Sasa Wang, Ling Wang, Marijana Đaković, Zora Popović, Haihong Wu, Ye Liu

    Read original paper ↗ ·

  7. Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures

    Chemical Reviews · 2012-08-10

    Michael B. Andrews, Christopher L. Cahill

    Read original paper ↗ ·

  8. Ionothermal synthesis of uranyl compounds that incorporate imidazole derivatives

    Journal of Solid State Chemistry · 2012-08-28

    Ernest M. Wylie, Megan K. Dustin, Jeremy S. Smith, Peter Carman Burns

    Read original paper ↗ ·

  9. An ionic compound containing Ru(III)-complex cation and phosphotungstate anion as the efficient and recyclable catalyst for clean aerobic oxidation of alcohols

    Catalysis Communications · 2012-08-29

    Sasa Wang, Jing Zhang, Chengliang Zhou, Giang Vo‐Thanh, Ye Liu

    Read original paper ↗ ·

  10. Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

    Inorganic Chemistry · 2012-12-07

    P. Thuéry

    Read original paper ↗ ·

  11. Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl)cyanurate

    Inorganica Chimica Acta · 2013-05-13

    Tae Hwan Noh, Haeri Lee, Young‐A Lee, Ok‐Sang Jung

    Read original paper ↗ ·

  12. 2,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids

    European Journal of Inorganic Chemistry · 2013-07-05

    P. Thuéry

    Read original paper ↗ ·

  13. Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties

    Journal of Inorganic and Organometallic Polymers and Materials · 2013-10-05

    Andrew T. Kerr, S.A. Kumalah, K.T. Holman, Ray John Butcher, Christopher L. Cahill

    Read original paper ↗ ·

  14. Morphotropy and Temperature-Driven Polymorphism in A2Th(AsO4)2 (A = Li, Na, K, Rb, Cs) Series

    Inorganic Chemistry · 2014-10-02

    Na Yu, Vladislav V. Klepov, Giuseppe Modolo, Dirk Bosbach, Evgeny V. Suleimanov, Thorsten M. Gesing, Lars Robben, Evgeny V. Alekseev

    Read original paper ↗ ·

  15. Synthesis and characterization of a trans-1 hexakis-fullerene linker that forms crystalline polymers with silver salts

    Dalton Transactions · 2015-01-01

    Chia‐Hsiang Chen, Amineh Aghabali, Alejandro J. Metta‐Magaña, Marilyn M. Olmstead, Alan L. Balch, Luis A. Echegoyen

    Read original paper ↗ ·

  16. Mild hydrothermal crystal growth of new uranium(IV) fluorides, Na3.13Mg1.43U6F30 and Na2.50Mn1.75U6F30: Structures, optical and magnetic properties

    Journal of Solid State Chemistry · 2015-05-04

    Jeongho Yeon, Mark D. Smith, Joshua H. Tapp, Angela Möller, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  17. Hexafluoridophosphate partial hydrolysis leading to the one-dimensional coordination polymer [{Cu(xantphos)(μ-PO2F2)} ]

    Inorganic Chemistry Communications · 2015-06-07

    Sarah Keller, Fabian Brunner, Alessandro Prescimone, Edwin C. Constable, Catherine E. Housecroft

    Read original paper ↗ ·

  18. Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials

    European Journal of Inorganic Chemistry · 2015-12-14

    Korey Prescott Carter, Mark Kalaj, Christopher L. Cahill

    Read original paper ↗ ·

  19. o-, m-, and p-Pyridyl isomer effects on construction of 1D loop-and-chains: Silver(I) coordination polymers with Y-type tridentate ligands

    Journal of Molecular Structure · 2016-05-31

    Jeong Gyun Kim, Yoonjung Cho, Haeri Lee, Young‐A Lee, Ok‐Sang Jung

    Read original paper ↗ ·

  20. Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

    Crystal Growth & Design · 2016-07-18

    Kong‐Qiu Hu, Liu-Zheng Zhu, Cong‐Zhi Wang, Lei Mei, Yunhai Liu, Zengqiang Gao, Zhifang Chai, Wei‐Qun Shi

    Read original paper ↗ ·

  21. Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption

    Chemistry - A European Journal · 2016-11-02

    Kong‐Qiu Hu, Xiang Jiang, Cong‐Zhi Wang, Lei Mei, Zhen‐ni Xie, Wuqing Tao, Xiao‐Lin Zhang, Zhifang Chai, Wei‐Qun Shi

    Read original paper ↗ ·

  22. Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO2)4F13][Sr3(H2O)8](NO3)·H2O

    Inorganic Chemistry · 2016-11-17

    Laurent J. Jouffret, Jean-Michel Hiltbrunner, Murielle Rivenet, Nicolas Sergent, S. Obbade, Daniel Avignant B, Marc Dubois

    Read original paper ↗ ·

  23. Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation

    Inorganic Chemistry · 2017-11-01

    Chao Liu, Fangyuan Chen, Hong‐Rui Tian, Jing Ai, Weiting Yang, Qing‐Jiang Pan, Zhong‐Ming Sun

    Read original paper ↗ ·

  24. Phosphate–phosphate oligomerization drives higher order co-assemblies with stacks of cyanostar macrocycles

    Chemical Science · 2018-01-01

    Elisabeth Maria Fatila, Maren Pink, Eric B. Twum, Jonathan A. Karty, Amar H. Flood

    Read original paper ↗ ·

  25. Complex Inorganic Actinide Materials

    Unknown journal · 2018-01-12

    Matthew L. Marsh, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  26. Semirigid Tripodal Ligand Based Uranyl Coordination Polymer Isomers Featuring 2D Honeycomb Nets

    Inorganic Chemistry · 2018-04-04

    Xiaolin Zhang, Kong‐Qiu Hu, Lei Mei, Yubao Zhao, Yitong Wang, Zhifang Chai, Wei‐Qun Shi

    Read original paper ↗ ·

  27. Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange

    Inorganic Chemistry · 2018-11-27

    Chao Liu, Chao Wang, Zhong‐Ming Sun

    Read original paper ↗ ·

  28. Uranyl Compounds Involving a Weakly Bonded Pseudorotaxane Linker: Combined Effect of pH and Competing Ligands on Uranyl Coordination and Speciation

    Inorganic Chemistry · 2019-02-11

    Li Fei, Lei Mei, Kong‐Qiu Hu, Shu‐wen An, Si Wu, Ning Liu, Zhifang Chai, Wei‐Qun Shi

    Read original paper ↗ ·

  29. Optimization of the synthesis of UiO-66(Zr) in ionic liquids

    Microporous and Mesoporous Materials · 2019-06-18

    Florian Joly, Philippe Devaux, Thierry Loiseau, Mehdi Arab, Bertrand Morel, Christophe Volkringer

    Read original paper ↗ ·

  30. Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth

    Frontiers in Chemistry · 2019-08-21

    Christian A. Juillerat, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  31. Solubilité et fluoration d’oxydes d’uranium en milieu liquide ionique

    Unknown journal · 2019-10-31

    Florian Joly

    Read original paper ↗ ·

  32. A unique uranyl framework containing uranyl pentamers as secondary building units: synthesis, structure, and spectroscopic properties

    Dalton Transactions · 2019-12-02

    Yugang Zhang, Lanhua Chen, Jingwen Guan, Xia Wang, Shuao Wang, Juan Diwu

    Read original paper ↗ ·

  33. Highly efficient absorption of methyl tert-butyl ether with ionic liquids

    Separation and Purification Technology · 2021-11-10

    Min Chen, Chengna Dai, Gangqiang Yu, Ning Liu, Ruinian Xu, Ning Wang, Biaohua Chen

    Read original paper ↗ ·

  34. Features of Uranium Stereochemistry in Uranyl Oxofluorides

    Radiochemistry · 2022-08-01

    В. Н. Сережкин, Д. В. Пушкин, Л. Б. Сережкина

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  35. New Barium Fluorosuccinato and Fluoroglutarato Uranylates

    Russian Journal of Physical Chemistry A · 2023-04-01

    В. Н. Сережкин, Mikhail S. Grigoriev, М. V. Sukacheva, Л. Б. Сережкина

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  36. New Barium Fluorosuccinato and Fluoroglutarato Uranylates

    Журнал физической химии · 2023-04-01

    В. Н. Сережкин, Mikhail S. Grigoriev, М. V. Sukacheva, Л. Б. Сережкина

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  37. Improving the Mg Sacrificial Anode in Tetrahydrofuran for Synthetic Electrochemistry by Tailoring Electrolyte Composition

    JACS Au · 2023-07-28

    Wendy Zhang, Chaoxuan Gu, Yi Wang, Skyler D. Ware, Lingxiang Lu, Song Lin, Yue Qi, Kimberly A. See

    Read original paper ↗ ·

  38. Uranyl-Tc( vii )/Tc( v ) hybrid clusters

    Chemical Communications · 2024-01-01

    Mohammad Shohel, May Nyman

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  39. Alkaline Metal Fluorooxalatouranilates: Structures and Selected Properties

    Russian Journal of Inorganic Chemistry · 2024-02-01

    В. Н. Сережкин, Mikhail S. Grigoriev, М. V. Sukacheva, V. Yu. Losev, Л. Б. Сережкина

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  40. Lithium, Sodium, and Strontium Fluoroglutaratouranylates: Structure and Some Properties

    Radiochemistry · 2024-04-01

    В. Н. Сережкин, Mikhail S. Grigoriev, М. V. Sukacheva, Д. В. Пушкин, Л. Б. Сережкина

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  41. A new uranyl silicate sheet derived from phosphuranylite topology in the structure of Cs4[(UO2)5(SiO3OH)2O2F4]

    Zeitschrift für Kristallographie - Crystalline Materials · 2024-04-16

    Еvgeny V. Nazarchuk, Oleg I. Siidra, Dmitri O. Charkin, Yana G. Tagirova

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  42. Alkaline Metal Fluoroxalatouranylates: Structure and Some Properties

    Журнал неорганической химии · 2024-07-28

    В. Н. Сережкин, Mikhail S. Grigoriev, М. V. Sukacheva, V. Yu. Losev, Л. Б. Сережкина

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  43. Lithium, sodium and strontium fluoroglutaratouranylates: structure and some properties

    Radiokhimiya (U.S.S.R.) For English translation see Sov. Radiochem. (Engl. Transl.) · 2024-09-13

    В. Н. Сережкин, Mikhail S. Grigoriev, М. V. Sukacheva, Д. В. Пушкин, Л. Б. Сережкина

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