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RESEARCH PAPER · Chemistry of Materials · 2004

Transport and Defect Mechanisms in Cuprous Delafossites. 1. Comparison of Hydrothermal and Standard Solid-State Synthesis in CuAlO2

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Transport and Defect Mechanisms in Cuprous Delafossites. 1. Comparison of Hydrothermal and Standard Solid-State Synthesis in CuAlO2OriginalTransport and Defect Mechanisms in Cuprous Delafossites. Part 1. Comparison of Hydrothermal and Standard Solid‐State Synthesis in CuAlO2.0Preparation and physical properties of the solid solutions Cu1+xMn1−xO2 ()53Electrical and structural characteristics of non-stoichiometric Cu-based delafossites24Crystal chemistry and electrical properties of the delafossite structure384Syntheses, crystal and electronic structure, and some optical and transport properties of LnCuOTe (Ln=La, Ce, Nd)68Pressure and temperature dependence of the lattice dynamics of CuAlO2 investigated by Raman scattering experiments andab initiocalculations111Preparation and physical properties of CuAl1−xMnxO2 (0≤x≤0.2) delafossites13Optical and Structural Properties of Single Phase Epitaxial p‐Type Transparent Oxide Thin Films66Optical and electrical properties study on p-type conducting CuAlS2+x with wide band gap25A promising p-type transparent conducting material: Layered oxysulfide [Cu2S2][Sr3Sc2O5]55Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesis94Effect of oxygen intercalation on properties of sputtered CuYO2 for potential use as p-type transparent conducting films26Silver Delafossite Oxides97Chemical spray pyrolysis deposition and characterization of p-type CuCr1−xMgxO2 transparent oxide semiconductor thin films81Hydrothermal synthesis of CuAlO2 with the delafossite structure in supercritical water31Preparation of p-type conducting transparent CuCrO2 and CuAl0.5Cr0.5O2 thin films by sol–gel processing54Synthesis and Thermostructural Studies of a CuFe1−xCrxO2 Delafossite Solid Solution with 0 ≤ x ≤ 173Group-IIIA versus IIIB delafossites: Electronic structure study81Acceptor Levels in p -Type Cu2O : Rationalizing Theory and Experiment303Understanding the p-Type Conduction Properties of the Transparent Conducting Oxide CuBO2: A Density Functional Theory Analysis112Room temperature ozone sensing properties of p-type CuCrO2 nanocrystals84Origin of p -type conduction in single-crystal CuAlO2183(Cu 2 S 2 )(Sr 3 Sc 2 O 5 )−A Layered, Direct Band Gap, p-Type Transparent Conducting Oxychalcogenide: A Theoretical Analysis.85Understanding conductivity in SrCu 2 O 2 : stability, geometry and electronic structure of intrinsic defects from first principles44Structural and physical effects of Mg-doping on p-type CuCrO2 and CuAl0.5Cr0.5O2 thin films61The Effect of (Ag, Ni, Zn)-Addition on the Thermoelectric Properties of Copper Aluminate61Understanding conductivity anomalies in CuI-based delafossite transparent conducting oxides: Theoretical insights116p ‐Type Wide‐Band‐Gap Semiconductors for Transparent Electronics4Growth Strategy and Physical Properties of the High Mobility P-Type CuI Crystal226Reactivity of Copper(I) Halides CuCl, CuI with Double Alkoxides MAl(iOPr)4 (M = Na, K)2Ternary and Multinary Materials: Crystal/Defect Structure–Property Relationships5Conductivity Limits in CuAlO2 from Screened-Hybrid Density Functional Theory132Effect of Cr doping on the optical–electrical property of CuAlO2 thin films derived by chemical solution deposition18Band gap anomalies of the ZnM2IIIO4 (MIII = Co, Rh, Ir) spinels67Understanding the p-type defect chemistry of CuCrO2214Chemical bonding in copper-based transparent conducting oxides: CuMO2(M = In, Ga, Sc)38Synthesis of delafossite CuAlO2 p-type semiconductor with a nanoparticle-based Cu(I) acetate-loaded boehmite precursor25Mg substitution in CuCrO2 delafossite compounds45Spin 1/2 Delafossite Honeycomb Compound Cu5SbO636On the possibility of p-type SnO2180Properties of CuAlO2 thin films deposited by polyacrylamide gel route17Investigation of the promising thermoelectric compound CuAlO2 by the method of nuclear quadrupole resonance in Cu7Sol–gel synthesis and characterization of wide band gap p-type nanocrystalline CuBO227Formation of AgFeO2, α-FeOOH, and Ag2O from mixed Fe(NO3)3–AgNO3 solutions at high pH25Cupric Oxide Thin Films for Photovoltaic Applications0Dellafossite CuAlO2 film growth and conversion to Cu–Al2O3 metal ceramic composite via control of annealing atmospheres12Transparent Conducting Oxides11Characterization of transparent conductive delafossite-CuCr1−xO2 films45Synthesis of the p-type semiconducting ternary oxide CuAlO2 using the Pechini method17Enhanced Performance of p‐Type Dye‐Sensitized Solar Cells Based on Ultrasmall Mg‐Doped CuCrO2 Nanocrystals78Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53Rapid synthesis and electrical transition in p-type delafossite CuAlO 224The luminescent properties of CuAlO 223Theoretical Modeling of Oxide-Photocatalysts for PEC Water Splitting2Scalable synthesis of delafossite CuAlO2 nanoparticles for p-type dye-sensitized solar cells applications81Synthesis and Characterization of CuAlO2 and AgAlO2 Delafossite Oxides through Low-Temperature Hydrothermal Methods86Theoretical insights into structural–electronic relationships and relative stability of the Cu-, Al- and O-terminated CuAlO2(0001) surfaces16Effects of chalcogen substitution on electronic properties and chemical bondings of delafossite CuAlO213Rectifying structure with high voltage operation based on CuBO 2 as an UV photocatalyst16p ‐Type Optoelectronic and Transparent Conducting Oxide Properties of Delafossite CuAl 1/2 Fe 1/2 O 212Structures and characteristics of delafossite CuCr 1− x O 2 thin films prepared by pulsed laser deposition7Ternary chalcogenides Cs2Zn3Se4 and Cs2Zn3Te4 : Potential p -type transparent conducting materials11Structural and electronic properties of transparent conducting delafossite: a comparison between the AgBO 2 and CuBO 2 families (B = Al, Ga, In and Sc, Y)38Epitaxial growth of highly infrared-transparent and conductive CuScO 2 thin film by polymer-assisted-deposition method14p-Type conducting transparent characteristics of delafossite Mg-doped CuCrO 2 thin films prepared by RF-sputtering105Enhancing the Performance of a Robust Sol–Gel‐Processed p‐Type Delafossite CuFeO 2 Photocathode for Solar Water Reduction262Preparation of p-type AgCrO2 nanocrystals through low-temperature hydrothermal method and the potential application in p-type dye-sensitized solar cell412H-CuScO2Prepared by Low-Temperature Hydrothermal Methods and Post-Annealing Effects on Optical and Photoelectrochemical Properties32Synthesis of CuAlO2 from chemically precipitated nano-sized precursors13Microstructural and electrical properties of CuAlO2 ceramic prepared by a novel solvent-free ester elimination process20A novel organic pollutants gas sensing material p-type CuAlO 2 microsphere constituted of nanoparticles for environmental remediation47Delafossite Nanoparticle as New Functional Materials: Advances in Energy, Nanomedicine and Environmental Applications75The role of annealing conditions on the low temperature photoluminescence properties of CuAlO211Effect of Al Doping on Performance of CuGaO2 p-Type Dye-Sensitized Solar Cells18Influences of S, Se, Te and Po substitutions on structural, electronic and optical properties of hexagonal CuAlO 2 using GGA and B3LYP functionals15Low temperature hydrothermal synthesis mechanism and thermal stability of p-type CuMnO 2 nanocrystals45Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Transparent conductive CuCrO 2 thin films deposited by pulsed injection metal organic chemical vapor deposition: up-scalable process technology for an improved transparency/conductivity trade-off88Control of p-type conduction in Mg doped monophase CuCrO 2 thin layers25Crystal structural, optical properties and mott-schottky plots of p-type Ca doped CuFeO 2 nanoplates67P -type transparent conducting oxides412Engineering Valence Band Dispersion for High Mobility p-Type Semiconductors98The effect of Mg-doping and Cu nonstoichiometry on the photoelectrochemical response of CuFeO 258Stability and electronic properties of CuAlO2 ( 11 2 − 0 ) surfaces14P-type transparent LaCuOS semiconductor synthesized via a novel two-step solid state reaction and sulfurization process14Vacancy defects in delafossite СuАlO2: First-principles calculations1Enhancing the electrical conductivity and thermoelectric figure of merit of the p-type delafossite CuAlO2 by Ag2O addition29Thermoelectric and Transport Properties of Delafossite CuCrO2:Mg Thin Films Prepared by RF Magnetron Sputtering61Invisible electronics: Metastable Cu-vacancies chain defects for highly conductive p-type transparent oxide44Thermoelectric properties of 2H-CuGaO2 for device applications: A first principle TB-mBJ potential study9Effect of starch addition on structural, electrical and thermal properties of delafossite CuAl 0.9 Fe 0.1 O 24An ab initio study of Cu-based delafossites as an alternative to nickel oxide in photocathodes: effects of Mg-doping and surface electronic features32Tuning the Electronic and Magnetic Properties of CuAlO2 Nanocrystals Using Magnetic Dopants16Achievement of highly conductive p-type transparent NdCuOS film with Cu deficiency and effective doping11Etude de couches minces à base de delafossite CuCr1-xFexO2(0 ≤ x ≤ 1) dopées au Mg déposées par pulvérisation cathodique radiofréquence en vue d'optimiser leurs propriétés thermoélectriques0Synergetic improvement strategy on thermoelectric performance of CuAlO2 compacts10Evidence and Influence of Copper Vacancies in p-Type CuGaO2 Mesoporous Films42Surface oxygen vacancy defect engineering of p-CuAlO 2 via Ar&H 2 plasma treatment for enhancing VOCs sensing performances38Transparent p-Type Semiconductors: Copper-Based Oxides and Oxychalcogenides92Solution‐Processed Ternary Oxides as Carrier Transport/Injection Layers in Optoelectronics53Highly Conducting p-Type Transparent LnCuOS (Ln = La and Nd) and p–n Junction by Using Ink11Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency82A New Highly Conductive Direct Gap p-Type Semiconductor La 1– x Y x CuOS for Dual Applications: Transparent Electronics and Thermoelectricity24Etude expérimentale et modélisation thermodynamique de systèmes de delafossites à base de cuivre0Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit2Soft chemical deintercalation of silver from delafossites AgFeO2, and AgCrO21Fermi Energy Limitation at β‑CuGaO2 Interfaces Induced by Electrochemical Oxidation/Reduction of Cu7Bipolar conductivity in amorphous Cu–Al–O thin films prepared by r.f. magnetron sputtering5Surface analysis and electrical property of oxygen- and Ga-doped CuAlO21A member of p-type TCO family: Sn2TaxNb2-xO7 with a tunable band gap and controllable hole mobility8Low-Frequency Dynamics of Charge Carriers in CuAlO2 Semiconductor According to NMR Data2Multifunctional delafossite CuFeO2 as water splitting catalyst and rhodamine B sensor29A review on the p-type transparent Cu–Cr–O delafossite materials67Doping‐Dependent Phase Fractions in Hydrothermally Synthesized Mn‐Doped CuFeO23Solution-processed metal-oxide based hole transport layers for organic and perovskite solar cell: A review49Effect of Sintering Temperature on the Properties of CuAlO2 Synthesized from Nanosized Precursors for Application in Smart Infrastructure Systems1P-Type α-CuGaO2Electronics: A Study on Gap States and Fermi Level Pinning and a Solution to Schottky to Ohmic Transition for Electronic Applications11A Novel laser scanning method for metallization of alumina substrate by copper11Magnetism and hyperfine interactions in the hexagonal polymorph of delafossite CuFeO 24Substrate-Induced Anisotropic Growth of CuAlO2 Platelets in a Liquid–Solid Reaction2Device engineering of p-CuAlO2/β-Ga2O3 interface: A staggered-gap band-alignment15A comprehensive review on the preparation and applications of delafossite CuAlO2 optoelectronic functional materials25Tailoring structure and nanoscale surface topography in Mg–N doped CuCrO 2 thin films via post deposition annealing for optothermoelectric application5Charge-carrier engineering of staggered-gap p-CuAlO2/β-Ga2O3 bipolar heterojunction for self-powered photodetector with exceptional linear dynamic range and stability42Electrical properties of strained off-stoichiometric Cu–Cr–O delafossite thin films5Critical Review of Cu‐Based Hole Transport Materials for Perovskite Solar Cells: From Theoretical Insights to Experimental Validation29Structural, Electronic Structure, and Electrical Properties of Pure and Vanadium-Doped CuCrO2 Thin Films2On the charge transport models in high intrinsic defect doped transparent and conducting p-type Cu–Cr–O delafossite thin films7On some distinct characteristics of reactive and normal flash sintering: A case study using low-temperature synthesized p-type cuprous delafossite, CuCrO22Spin entropy enhancement and valence band convergence for augmenting thermoelectric performance of Mg-N co-doped CuCrO2 thin films4Insights into the enhanced degradation of phenolic pollutants via the heterogeneous Fenton process over nitrogen-doped CuAlO2: The critical role of nitrogen doping1Delafossite CuFeO 2 photocathodes for photoelectrochemical water splitting: fundamental properties, synthesis, and modification strategies1Multiscale Insights into Ceria-Based Catalysts for Soot Oxidation: Structural and Electrical Properties, Catalytic Performance, Coupled with Data-Driven and Thermo-Mechanical Analysis0Defect-driven optoelectronic and magnetic properties of Delafossite materials for photocatalytic, energy, and biomedical applications2Fermi level pinning effect investigation on delafossite CuGaO2/β-Ga2O3 heterojunction: application in UV-photodetectors1

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  1. Transport and Defect Mechanisms in Cuprous Delafossites. Part 1. Comparison of Hydrothermal and Standard Solid‐State Synthesis in CuAlO2.

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  2. Preparation and physical properties of the solid solutions Cu1+xMn1−xO2 ()

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  4. Crystal chemistry and electrical properties of the delafossite structure

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  5. Syntheses, crystal and electronic structure, and some optical and transport properties of LnCuOTe (Ln=La, Ce, Nd)

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  6. Pressure and temperature dependence of the lattice dynamics of CuAlO2 investigated by Raman scattering experiments andab initiocalculations

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  7. Preparation and physical properties of CuAl1−xMnxO2 (0≤x≤0.2) delafossites

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  8. Optical and Structural Properties of Single Phase Epitaxial p‐Type Transparent Oxide Thin Films

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  10. A promising p-type transparent conducting material: Layered oxysulfide [Cu2S2][Sr3Sc2O5]

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  11. Tuning the size and color of the p-type wide band gap delafossite semiconductor CuGaO2 with ethylene glycol assisted hydrothermal synthesis

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  12. Effect of oxygen intercalation on properties of sputtered CuYO2 for potential use as p-type transparent conducting films

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  14. Chemical spray pyrolysis deposition and characterization of p-type CuCr1−xMgxO2 transparent oxide semiconductor thin films

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  16. Preparation of p-type conducting transparent CuCrO2 and CuAl0.5Cr0.5O2 thin films by sol–gel processing

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  17. Synthesis and Thermostructural Studies of a CuFe1−xCrxO2 Delafossite Solid Solution with 0 ≤ x ≤ 1

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  37. Synthesis of delafossite CuAlO2 p-type semiconductor with a nanoparticle-based Cu(I) acetate-loaded boehmite precursor

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  38. Mg substitution in CuCrO2 delafossite compounds

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  39. Spin 1/2 Delafossite Honeycomb Compound Cu5SbO6

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  42. Investigation of the promising thermoelectric compound CuAlO2 by the method of nuclear quadrupole resonance in Cu

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  48. Characterization of transparent conductive delafossite-CuCr1−xO2 films

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  49. Synthesis of the p-type semiconducting ternary oxide CuAlO2 using the Pechini method

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