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RESEARCH PAPER · Chemical Communications · 2014

A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO 2 adsorption selectivity at room temperature

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A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO 2 adsorption selectivity at room temperatureOriginalA family of coordination polymers assembled with a flexible hexacarboxylate ligand and auxiliary N-donor ligands: syntheses, structures, and physical properties22Three sra topological lanthanide–organic frameworks built from 2,2′-dimethoxy-4,4′-biphenyldicarboxylic acid21Structural Diversity Modulated by the Ratios of a Ternary Solvent Mixture: Syntheses, Structures, and Luminescent Properties of Five Zinc(II) Metal–Organic Frameworks36Solvent-Induced Change of Electronic Spectra and Magnetic Susceptibility of CoII Coordination Polymer with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine22Structural Features in Metal–Organic Nanotube Crystals That Influence Stability and Solvent Uptake335‐(3′,4′‐Dicarboxylphenoxy)isophthalate/5‐(2′,3′‐Dicarboxylphenoxy)isophthalate‐Based 3D Cadmium(II) Coordination Polymers: Synthesis, Structure, and Sensing of Nitrobenzene16Guest-triggered assembly of zinc( ii ) supramolecular isomers with accompanying dimensional change and reversible single-crystal-to-single-crystal transformation25Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu 2+ ions119Water-triggered macroscopic structural transformation of a metal–organic framework10Assembly and Selective Photocatalysis of Two Multifunctional Copper(II) Complexes Derived From a Bis-Pyridyl-Bis-Amide and Two Dicarboxylates1Synthesis and Functionalization of Oriented Metal–Organic‐Framework Nanosheets: Toward a Series of 2D Catalysts254LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations16Synthesis and Structural Characterization of a Two‐Dimensional Magnesium Acetate, Mg7(OH)2(OAc)12(H2O)4·4H2O, a Precursor to Three‐Dimensional Porous Magnesium Acetate2Solvent-Controlled Assembly of Ionic Metal–Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties50Spatio‐Design of Multidimensional Prickly Zn‐Doped CuO Nanoparticle for Efficient Bacterial Killing42New Solid-Base Cu–MgO for CO2 Capture at 473 K and Removal of Nitrosamine33Effect of Coordinated Solvent Molecules on Metal Coordination Sphere and Solvent-Induced Transformations63A Cd mixed-ligand MOF showing ligand-disorder induced breathing behaviour at high temperature and stepwise, selective carbon dioxide adsorption at low temperature19A nanoporous Ag( i ) coordination polymer for selective adsorption of carcinogenic dye Acid Red 2678Thermal decomposition pathways of nitro-functionalized metal–organic frameworks13Water-Stable In(III)-Based Metal–Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH490Syntheses, Structures and Characterization of Four Metal-Organic Frameworks constructed by 2,2′,6,6′-Tetramethoxy-4,4′-biphenyldicarboxylic Acid4Synthesis, crystal structures and photoluminescence studies of three mixed ligand silver(I) coordination polymers7Molecular transport through mixed matrix membranes: A time‐dependent density functional approach9Highly Water Stable Lanthanide Metal–Organic Frameworks Constructed from 2,2′-Disulfonyl-4,4′-biphenyldicarboxylic Acid: Syntheses, Structures, and Properties30Metal–Organic Framework Mediated Synthesis of Small‐Sized γ‐Alumina as a Highly Active Catalyst for the Dehydration of Glycerol to Acrolein18A windmill-like Zn3L2 cage exhibiting conformational change imparted sensing for DMA and highly selective naked-eye detection of Co2+ ion by dynamic quenching19Guest exchange in a porous cucurbit[6]uril-based metal–organic rotaxane framework probed by NMR and X-ray crystallography20Topological identification of the first uninodal 8-connected lsz MOF built from 2,2′-difluorobiphenyl-4,4′-dicarboxylate pillars and cadmium(II)–triazolate layers7Large Pore Isoreticular Strontium-Organic Frameworks: Syntheses, Crystal Structures, and Thermal and Luminescent Properties11Three novel topologically different metal–organic frameworks built from 3-nitro-4-(pyridin-4-yl)benzoic acid6The utility of the template effect in metal-organic frameworks116Stable fluorinated 3D isoreticular nanotubular triazole MOFs: synthesis, characterization and CO2 separation4Molecular Sieving and Direct Visualization of CO2 in Binding Pockets of an Ultramicroporous Lanthanide Metal–Organic Framework Platform31Two topologically different 3D CuII metal–organic frameworks assembled from the same ligands: control of reaction conditions8Syntheses, structures, and magnetic properties of three supramolecular isomeric Cu( ii ) square grid networks: solvents effect on the ligand linkages7The effect of coordinated solvent molecules on metal coordination environments in single-crystal-to-single-crystal transformations29Time-Resolved in Situ Polymorphic Transformation from One 12-Connected Zr-MOF to Another24Quest for Zeolite‐like Supramolecular Assemblies: Self‐Assembly of Metal–Organic Squares via Directed Hydrogen Bonding26Quest for Zeolite‐like Supramolecular Assemblies: Self‐Assembly of Metal–Organic Squares via Directed Hydrogen Bonding6Creative Construction of a Series of Chiral 3D Indium–Organic Frameworks with a umy Topology11Efficient and selective removal of Pb 2+ from aqueous solution by using an O − functionalized metal–organic framework11Metal–Organic Frameworks for CO 2 Separation from Flue and Biogas Mixtures132Metal-organic frameworks derived from chalcone dicarboxylic acid: New topological characters and initial catalytic properties4Epitaxial transformations of metal–organic frameworks into orientated superparticles15Solvent-oriented structural diversity, sequential SCSC and low-temperature transformation in Cd-coordination polymers: unique turn-on–off sensing of Fe 3+3A novel topological indium–organic framework for reversible ammonia uptake under mild conditions and catalysis11Design and Synthesis of Bismuth-based Metal-Organic Frameworks for Photothermal Energy Conversion9Proton Conducting Metal‐Organic Frameworks (MOFs) via Post Synthetic Transmetallation and Water Induced Structural Transformations14Undulated 1D Polymeric Chains of Ag(I) Turning into a 3D Network by Carboxylate Ions and Water Molecules: Hirshfeld Surface Analysis, Insights from DFT Applications and Study of Cytotoxicity, Oxidative Stress in HLCs and MCF-7 Cells6Synthesis of Two Structurally Distinct Cu-MOFs Regulated by Imidazole and Their Proton Conducting Properties7CIF2MOFNet : A deep learning model with multi‐dimensional coordinate features to accelerate MOF screening for CO 2 capture2Asymmetric carboxylate/hydroxamate bifunctional ligand to build robust 3D MOFs with a novel uod topology0Simultaneous Pore Formation and Nitrogen Doping in Isomeric Indium-Isophthalate-Derived Carbon Nanostrips for Enhanced CO 2 Sorption2Hydration-regulated structural transformation and luminescent behaviors of three benzothiadiazole-based MOF isomers1Dramatic Structural Upheavals of 3D Lanthanide-Organic Frameworks Triggered by Moisture-Induced Single-Crystal-to-Single-Crystal Transformation1High-Throughput Topological Analysis of Rod Metal–Organic Frameworks0

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  2. Three sra topological lanthanide–organic frameworks built from 2,2′-dimethoxy-4,4′-biphenyldicarboxylic acid

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  3. Structural Diversity Modulated by the Ratios of a Ternary Solvent Mixture: Syntheses, Structures, and Luminescent Properties of Five Zinc(II) Metal–Organic Frameworks

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  4. Solvent-Induced Change of Electronic Spectra and Magnetic Susceptibility of CoII Coordination Polymer with 2,4,6-Tris(4-pyridyl)-1,3,5-triazine

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  5. Structural Features in Metal–Organic Nanotube Crystals That Influence Stability and Solvent Uptake

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  6. 5‐(3′,4′‐Dicarboxylphenoxy)isophthalate/5‐(2′,3′‐Dicarboxylphenoxy)isophthalate‐Based 3D Cadmium(II) Coordination Polymers: Synthesis, Structure, and Sensing of Nitrobenzene

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  7. Guest-triggered assembly of zinc( ii ) supramolecular isomers with accompanying dimensional change and reversible single-crystal-to-single-crystal transformation

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  8. Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu 2+ ions

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  10. Assembly and Selective Photocatalysis of Two Multifunctional Copper(II) Complexes Derived From a Bis-Pyridyl-Bis-Amide and Two Dicarboxylates

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  11. Synthesis and Functionalization of Oriented Metal–Organic‐Framework Nanosheets: Toward a Series of 2D Catalysts

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  12. LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations

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  13. Synthesis and Structural Characterization of a Two‐Dimensional Magnesium Acetate, Mg7(OH)2(OAc)12(H2O)4·4H2O, a Precursor to Three‐Dimensional Porous Magnesium Acetate

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  14. Solvent-Controlled Assembly of Ionic Metal–Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties

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  15. Spatio‐Design of Multidimensional Prickly Zn‐Doped CuO Nanoparticle for Efficient Bacterial Killing

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  16. New Solid-Base Cu–MgO for CO2 Capture at 473 K and Removal of Nitrosamine

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  17. Effect of Coordinated Solvent Molecules on Metal Coordination Sphere and Solvent-Induced Transformations

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  18. A Cd mixed-ligand MOF showing ligand-disorder induced breathing behaviour at high temperature and stepwise, selective carbon dioxide adsorption at low temperature

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  19. A nanoporous Ag( i ) coordination polymer for selective adsorption of carcinogenic dye Acid Red 26

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  20. Thermal decomposition pathways of nitro-functionalized metal–organic frameworks

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  21. Water-Stable In(III)-Based Metal–Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4

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  22. Syntheses, Structures and Characterization of Four Metal-Organic Frameworks constructed by 2,2′,6,6′-Tetramethoxy-4,4′-biphenyldicarboxylic Acid

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  23. Synthesis, crystal structures and photoluminescence studies of three mixed ligand silver(I) coordination polymers

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  24. Molecular transport through mixed matrix membranes: A time‐dependent density functional approach

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  29. Topological identification of the first uninodal 8-connected lsz MOF built from 2,2′-difluorobiphenyl-4,4′-dicarboxylate pillars and cadmium(II)–triazolate layers

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