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RESEARCH PAPER · Coordination Chemistry Reviews · 2019

The utility of the template effect in metal-organic frameworks

Xiuxiu Guo, Shubo Geng, Mingjing Zhuo, Yao Chen, Michael John Zaworotko, Peng Cheng, Zhenjie Zhang

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The utility of the template effect in metal-organic frameworksOriginalA Zn( ii ) metal–organic framework based on bimetallic paddle wheels as a luminescence indicator for carcinogenic organic pollutants: phthalate esters8Template-Directed Synthesis of Photocatalyst-Encapsulating Metal–Organic Frameworks with Boosted Photocatalytic Activity75Tetraphenylethylene-Decorated Metal–Organic Frameworks as Energy-Transfer Platform for the Detection of Nitro-Antibiotics and White-Light Emission171Selective Detection of Aromatic Nitrophenols by a Metal–Organic Framework-Based Fluorescent Sensor83Structural elucidation of microcrystalline MOFs from powder X-ray diffraction82Tuneable solvent adsorption and exchange by 1D bispidine-based Mn( ii ) coordination polymers via ligand design10Organic Counteranion Co-assembly Strategy for the Formation of γ-Cyclodextrin-Containing Hybrid Frameworks45Metalloporphyrinic metal-organic frameworks: Controlled synthesis for catalytic applications in environmental and biological media59Exploring the Scope of Macrocyclic “Shoe-last” Templates in the Mechanochemical Synthesis of RHO Topology Zeolitic Imidazolate Frameworks (ZIFs)9Trends in polymers functionalized nanostructures for analysis of environmental pollutants58Solid-phase microextraction coatings based on the metal-organic framework ZIF-8: Ensuring stable and reusable fibers56Solvent Templating and Structural Dynamics of Fluorinated 2D Cu-Carboxylate MOFs Derived from the Diffusion-Controlled Process33A periodic table of metal-organic frameworks121Zeolitic Tetrazolate–Imidazolate Frameworks with SOD Topology for Room Temperature Fixation of CO2 to Cyclic Carbonates31Template-Assisted, Seed-Mediated Synthesis of Hierarchically Mesoporous Core–Shell UiO-66: Enhancing Adsorption Capacity and Catalytic Activity through Iterative Growth26Hierarchically porous metal–organic frameworks: synthesis strategies, structure(s), and emerging applications in decontamination135Assembly, structure and properties of three new multifunctional complexes derived from the naphthalene-based bis(pyridyl)-bis(amide) and benzenetricarboxylic acid1Syntheses, structures and properties of two Ni(II) coordination polymers based on an anionic ligand deprotonated 5-((3-carboxyphenoxy)methyl)benzene-1,3-dioic acid and different neutral ligands4Preparation of copper based metal organic framework materials and its effective adsorptive removal of ceftazidime from aqueous solutions47Rational design and synthesis of ultramicroporous metal-organic frameworks for gas separation218A Functional Electrocatalyst of Coordination Polymer Derived from Di-nuclear Nickel(II)-Glycine Cations and Wells–Dawson Polyoxoanions2Highly dynamic 1D coordination polymers for adsorption and separation applications90From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis, Crystal Structures, Inclusion, and Emission Properties11Assembly, photocatalytic and fluorescence properties of three new coordination complexes of zinc(II) and nickel(II) with two kinds of flexible bis(pyridyl)-bis(amide) ligands0Template‐Mediated Control over Polymorphism in the Vapor‐Assisted Formation of Zeolitic Imidazolate Framework Powders and Films32Template‐Mediated Control over Polymorphism in the Vapor‐Assisted Formation of Zeolitic Imidazolate Framework Powders and Films3Crystal engineering of porous coordination networks for C3 hydrocarbon separation66Indium metal–organic frameworks based on pyridylcarboxylate ligands and their potential applications30Optimizing the metal ion release and antibacterial activity of ZnO@ZIF-8 by modulating its synthesis method38Synthesis of a new ATN-type zeolitic imidazolate framework through cooperative effects of N , N -dipropylformamide and n -butylamine9Synthesis, structure and properties of a novel Cu(II)-MOF {[Cu2L(OH)]·DMF}n based on a semi-rigid polycarboxylic acid ligand10Transition metal-based metal–organic frameworks for environmental applications: a review118Recent advances in luminescent metal–organic frameworks (LMOFs) based fluorescent sensors for antibiotics216Cage‐Like Porous Materials with Simultaneous High C2H2Storage and Excellent C2H2/CO2Separation Performance28Cage‐Like Porous Materials with Simultaneous High C2H2Storage and Excellent C2H2/CO2Separation Performance171Insights into the role of cross-linking agents on polymer template effect: A case study of anionic imprinted polymers41Selective Photodimerization in a Cyclodextrin Metal–Organic Framework77A multi-responsive luminescent indicator based on a Zn(II) metal-organic framework with “Turn on” sensing of pyridine and “Turn off” sensing of Fe3+, Cr2O72− and antibiotics in aqueous media24Relationships between Changes in Guest Ion Properties and in the Host Framework Topology in Ionic Coordination Polymers2Research progress of metal organic frameworks and their derivatives for adsorption of anions in water: A review75Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour16Apport des cyclodextrines à la synthèse hydrothermale de MOFs de la famille UiO-660Metal–organic framework (MOF)-derived hollow hybrid Cu 2 O/Cu/Au for non-enzymatic H 2 O 2 sensing5MOF-enabled confinement and related effects for chemical catalyst presentation and utilization386MOFs for solar photochemistry applications1Modifying HKUST-1 Crystals for Selective Ethane Adsorption Using Ionic Liquids as Synthesis Media14Different Topologies of Hg(II)‐Bispidine 1D Coordination Polymers: Dynamic Behavior in Solvent Adsorption and Exchange Processes10Three-step post-synthetic modification metal-organic framework as a ratiometric fluorescent probe for the detection of creatinine17Metal–organic framework on porous TiO2 thin film-coated alumina beads for fractional distillation of plant essential oils2A Microporous Potassium‐Organic Framework for Efficient C 2 H 2 /CO 2 Separation2Hierarchically Porous MOFs Synthesized by Soft-Template Strategies253A Metal‐Organic Framework with Nonpolar Pore Surfaces for the One‐Step Acquisition of C 2 H 4 from a C 2 H 4 and C 2 H 6 Mixture129A Metal‐Organic Framework with Nonpolar Pore Surfaces for the One‐Step Acquisition of C2H4from a C2H4and C2H6Mixture11Biocatalysts Synthesized with Lipase from Pseudomonas cepacia on Glycol-Modified ZIF-8: Characterization and Utilization in the Synthesis of Green Biodiesel6Ferrimagnetic behavior in a naphthalene templated manganese(II) 1,1-cyclohexanediacetate compound1Chiral templated synthesis of homochiral metal-organic frameworks54Enhanced regenerability of metal-organic frameworks adsorbents: Influence factors and improved methods38Microporous Metal‐Phosphonates with a Novel Orthogonalized Linker and Complementary Guests: Insights for Trivalent Metal Complexes from Divalent Metal Complexes15MOF-assisted synthesis of mesoporous zirconium phosphate for enhanced cadmium removal from water16Polarity‐Evolution Control and Luminescence Regulation in Multiple‐Site Hydrogen‐Bonded Organic Frameworks15Layer-by-layer assembly of metal-organic framework thin films: Fabrication and advanced applications64In situ single-crystal synchrotron X-ray diffraction studies of biologically active gases in metal-organic frameworks17Recent progress of MOF/MXene-based composites: Synthesis, functionality and application2512D Coordination Polymers Based on Isoquinoline‐5‐Carboxylate and Cu(II)0Recent advances in tailoring zeolitic imidazolate frameworks (ZIFs) and their derived materials based on hard template strategy for multifunctional applications123Heterostructured Ag@MOF-801/MIL-88A(Fe) Nanocomposite as a Biocompatible Photocatalyst for Degradation of Reactive Black 5 under Visible Light32Solvent‐Directed Construction of a Nanoporous Metal‐Organic Framework with Potential in Selective Adsorption and Separation of Gas Mixtures Studied by Grand Canonical Monte Carlo Simulations12Templated synthesis of ZnO quantum dots via double solvents method inside MOF-801 as emerging photocatalyst for photodegradation of Acid Blue 25 under UV light28Research progress in structural regulation and applications of HKUST-1 and HKUST-1 based materials100Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect15Recent progress in bimetallic-organic framework materials and their derivatives for supercapacitors16Synthesis and Applications of Metal Organic Frameworks in Photodynamic Therapy0Unveiling the unique mechanism of UV-sensitive phosphonate-based metal–organic frameworks2A roadmap of recent advances in MXene@MOF hybrids, its derived composites: Synthesis, properties, and their utilization as an electrode for supercapacitors, rechargeable batteries and electrocatalysis86In Situ Single-crystal X-ray Diffraction Studies of Physisorption and Chemisorption of SO2 within a Metal–Organic Framework and Its Competitive Adsorption with Water53Subtle Structural Variations within Solvent-Free D–A-Type Organic Crystals for Tuning Emission Wavelength up to 47 nm Shift4Facile construction of hierarchically porous CPO-27-Ni by mixed ligand strategy towards enhanced adsorption desulfurization from fuels12Brain-specific targeted delivery of therapeutic agents using metal–organic framework-based nanomedicine23Synthesis and applications of metal organic frameworks in photodynamic therapy8Template Role of Long Alkyl-Chain Amides in the Synthesis of Zeolitic Imidazolate Frameworks3Metal‐Organic Frameworks (MOFs): Classification, Synthesis, Modification, and Biomedical Applications131Degradation of acid blue 41 with carbon quantum dots@MOF-808 nanocomposite as a biocompatible photocatalyst under visible light22Harnessing the potential of MOF/Fe2O3 nanocomposite within polypyrrole matrix for enhanced hydrogen evolution5Encapsulation of carvacrol in β-cyclodextrin metal-organic frameworks: Improved solubility, stability, antioxidant capacity and controlled release of carvacrol30Exploring the Syntheses, Structures, and Properties of Two 3D Porous Metal–Organic Frameworks Based on Aromatic Polyacid Ligands4Design and synthesis of a homostructured MUT-16/MUT-17 nanocomposite via the epitaxial growth method as a photocatalyst for the degradation of Acid Red 33 under visible light0Introduction0Structure-Property/Activity Correlations of Coordination Compounds, Supramolecular Molecular Assemblies and Materials, with Possible Industrial and Biological Applications0Sensitive detection of ciprofloxacin in the livestock manure by a portable smartphone platform based on Eu-MOFs@hydrogel composites5Functionalized interfaces in MXOF: Bridging high-performance energy storage and pollutant degradation6Metal-organic frameworks as therapeutic chameleons: revolutionizing the cancer therapy employing novel nanoarchitectonics4Morphology Engineering of Aggregation-Induced Emission-Based Metal–Organic Frameworks Templated with Cellulose Nanocrystals for Lactic Acid Detection8A Shape‐Complementarity Approach to Inducing Short Au(III)···Au(III) Contacts in Tetracyanoaurate(III) Salts7Shaping Metal–Organic Frameworks Toward Practical Applications: From 0D to 3D2Electrodeposition of ultra-low amount of Ru on FeCo-MOF/NF to enhance hydrogen production and methanol electroreforming performance2Zeolitic Imidazolate Framework-93 and Its Derivatives: Synthesis, Properties, and Applications3Proton etching-driven synthesis of MIL-101(Fe)-templated Cu-Fe LDH nanocatalysts: Synergistic Z-scheme heterojunction with Cu/Fe dual-metal redox cycling for high-efficiency photocatalytic degradation of tetracycline7Adsorption Materials toward Highly‐Efficient Lithium Extraction from Non‐Conventional Lithium Sources121Sorting polymerization in a bichannel metal-organic framework6Innovative synthesis methods and the role of green solvents on improved structural and adsorption properties of MOFs11Transition metal carbides/nitrides meet metal-organic frameworks: synergistic effects in supercapacitor electrodes11Mechanically interlocked crystalline frameworks: Synthesis, structural design, and applications3PVD/HVOF composite architecture triggering in situ amorphous-nanocrystalline composite layer for high-temperature wear resistance7Sequestered Aerial CO 2 and Phosphate-Assisted Formation of 2D Nanosheets1Template directed strategy of green energetic metal–organic frameworks for enhancing oxygen balance and near infrared laser initiation5Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants4Alumina supported Cu nanoparticles derived from MOF crystallites for CO 2 hydrogenation1Templated synthesis of a Zr-formate zeolite - like metal organic framework0Tailoring metal–organic frameworks: From morphological control to superstructure assembly17Investigating the Effect of Defect Engineering via Soft Templating on the Water Adsorption Behavior of Metal–Organic Frameworks2Defect-engineered interfaces via methyl gallate–modified ZIF-8 for plasticization-resistant propylene/propane separation membranes4Reprogramming Porosity: The Synthetic Evolution of Pore Engineering in Metal–Organic Frameworks9Metal-organic-framework derived Co/CeO2-PBA catalyst with enhanced Co-CeO2 interaction for efficient NH3 decomposition2A porous Cu(II) metal–organic framework based on 6-methyl-4-(1H-1,2,4-triazol-1-yl)pyridine carboxylic acid with efficient and selective dye adsorption0The synthesis, structural characterization, and visible-light photocatalytic performance of a novel Nd(III) MOF containing 4,4′-sulfoyldiphthalhydrazidate anion based on hydrothermal in situ acylation reaction0The phase and energy-level evolutions in seven distinct sequential states and their hierarchical memory effect of isomeric MOFs2

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  48. Three-step post-synthetic modification metal-organic framework as a ratiometric fluorescent probe for the detection of creatinine

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  49. Metal–organic framework on porous TiO2 thin film-coated alumina beads for fractional distillation of plant essential oils

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  50. A Microporous Potassium‐Organic Framework for Efficient C 2 H 2 /CO 2 Separation

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