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RESEARCH PAPER · Journal of Materials Chemistry C · 2012

Synthesis and photoluminescence of Eu 3+ -activated double perovskite NaGdMg(W, Mo)O 6 – a potential red phosphor for solid state lighting

Le Zhang, Lu Zhou, Pengde Han, Lixi Wang, Qitu Zhang

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Synthesis and photoluminescence of Eu 3+ -activated double perovskite NaGdMg(W, Mo)O 6 – a potential red phosphor for solid state lightingOriginalCrystal Structure and Photoluminescence Properties of CaSr2Al2O6:Eu3+Phosphors7Synthesis, structure and photoluminescence properties of europium-, terbium-, and thulium-doped Ca3Bi(PO4)3 phosphors96Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs55A new red-emitting phosphor of Eu3+-doped Sr2MgMoxW1−xO6 for solid state lighting47Photoluminescence studies of red-emitting Y 5 Mo 2 O 12 : Eu 3+ , Sm 3+ as a near-UV convertible phosphor23Analysis of Energy Transfer and Concentration Quenching in Sm3+-Activated Borate GdB3O6Phosphors by Means of Fluorescence Dynamics12Co‐luminescence properties of terbium ions–benzoic acid–phen complexes doped with europium ions38A red phosphor BaTiF 6 :Mn 4+ : reaction mechanism, microstructures, optical properties, and applications for white LEDs105Hydrothermal synthesis and photoluminescence properties of red phosphor BaSiF6:Mn4+ for LED applications161Enhanced novel orange red emission in Ca3(PO4)2:Sm3+ by charge compensation62Luminescence properties of Eu3+ in gadolinium molybdate β′-Gd2Mo3O12 phosphors18Color-Tunable Luminescence and Energy Transfer Properties of Ca 9 Mg(PO 4 ) 6 F 2 :Eu 2+ , Mn 2+ Phosphors for UV-LEDs174Gd3B(W,Mo)O9: Eu3+ red phosphor: From structure design to photoluminescence behavior and near-UV white-LEDs performance48Luminescence properties of red‐emission Mg4Nb2O9:Eu3+ phosphor10Crystal Structure, Electronic Structure, and Photoluminescence Properties of La3BW1–xMoxO9:Eu3+ Red Phosphor68A novel red-emitting phosphor Ca9Bi(PO4)7:Eu3+ for near ultraviolet white light-emitting diodes45Enhanced novel white emission in Ca3(PO4)2:Dy3+ single-phase full-color phosphor by charge compensation33Photoluminescence of Sr 2 P 2 O 7 :Sm 3+ Phosphor as Reddish Orange Emission for White Light‐Emitting Diodes26Synthesis and luminescence of Eu3+‐doped in triple phosphate Ca8MgBi(PO4)7 with whitlockite structure11Energy transfer and luminescence properties of Sr[1−3(x+y)/2]Al2B2O7:xEu3+, yBi3+ phosphor12Synthesis and structure investigation of ternary oxides based on molybdenum and lanthanum1Dual-channel enhanced luminescence of double perovskite NaGdMgWO6:Eu3+ phosphor based on alternative excitation and delayed quenching89Interfacial reaction and failure mode analysis of the solder joints for flip-chip LED on ENIG and Cu-OSP surface finishes18Sr2CaWxMo1−xO6:Eu3+, Li+: An emission tunable phosphor through site symmetry and excitation wavelength30Luminescence properties of α-Sr2P2O7:Sm3+ phosphor without and with co-doping charge compensation agents9Synthesis and photoluminescence properties of novel CaB6O10:RE3+ (RE=Ce, Tb, Dy, Eu) phosphors under ultraviolet excitation17Enhanced luminescence and structure evolution of double perovskite (K, Na)LaMgWO6:Eu3+ phosphor for white LEDs36A red-emitting perovskite-type SrLa(1−)MgTaO6:xEu3+ for white LED application58Enhanced photoluminescence of K2Ba(WO4)2:Eu3+ by Cl− co-doping1Enhanced luminous efficiency in Pr3+ activated Ca0.5La(MoO4)2 red phosphor with blue excitation for WLED applications5High-brightness Eu3+-doped La0.67Mg0.5W0.5O3 red phosphor for NUV light-emitting diodes application15Failure mode analysis for the solder joints for the flip-chip light emitting diodes1Co‐precipitation synthesis and luminescence properties of K2TiF6:Mn4+ red phosphors for warm white light‐emitting diodes38Novel layered perovskite Sr 3 Ti 2 O 7 :Eu 3+ phosphor with high-efficiency luminescence enhanced by charge compensation46Deep red MGe 4 O 9 :Mn 4+ (M = Sr, Ba) phosphors: structure, luminescence properties and application in warm white light emitting diodes141Extensive studies of host lattices and activators in lanthanide phosphors based on efficient synthesis12Enhanced luminescence of a Eu3+-activated double perovskite (Na, Li)LaMgWO6 phosphor based on A site inducing energy transfer47Structure evolution and delayed quenching of the double perovskite NaLaMgWO6:Eu3+ phosphor for white LEDs128Luminescence enhancement in the Sr2ZnW1−xMoxO6:Eu3+,Li+ phosphor for near ultraviolet based solid state lighting57Optical properties and energy transfers of Ce3+ and Mn2+ in Ca9LiGd0.667(PO4)75Broadly tuning Sm3+ emission via crystal field micro-modulation in CdMoO4 for white-LEDs6Effect of NH4Cl flux used to synthesize double perovskite BaLaMgSbO6:Eu3+ phosphor by solid-state reaction method6Double perovskite LiLaMgWO6:Eu3+ novel red-emitting phosphors for solid sate lighting: Synthesis, structure and photoluminescent properties185Improved full-color emission and switched luminescence in single Ca3(PO4)2: Dy3+, Eu3+ phosphors for white LEDs48Influence of Alkali Metal Ions on Luminescence Behaviour of Ca0.5R1-x(MoO4)2:xLn3+ (R = Y, La), (Ln = Eu, Tb, Dy) Pulsed Laser Deposited Thin Phosphor Films2Photoluminescence properties of novel BaGd 2 Si 3 O 10 :RE 2+/3+ (RE = Eu or Ce) phosphors with trichromatic emission for white LEDs15Tailoring photoluminescence stability in double perovskite red phosphors A 2 BAlF 6 :Mn 4+ (A = Rb, Cs; B = K, Rb) via neighboring-cation modulation80Unusual, broad red emission of novel Ce 3+ -activated Sr 3 Sc 4 O 9 phosphors under visible-light excitation81Synthesis and luminescence properties of La0.67Mg0.5W0.5O3:Tb3+ green phosphors3The impact of local structure variation on thermal quenching of luminescence in Ca3MoxW1−xO6:Eu3+ solid solution phosphors28Photoluminescence of a novel red emitting phosphor LiLaMgWO6 : Eu3+5Structure and luminescence properties of Eu 3+ -doped trigonal double-perovskite Ba 2 Lu 0.667 WO 611The design and synthesis of new double perovskite (Na,Li)YMg(W,Mo)O 6 :Eu 3+ red phosphors for white light-emitting diodes108Luminescence properties of novel double perovskite Gd2MgTiO6:Eu3+ phosphors prepared by solid state method14Structural modification and photoluminescence studies of Eu in lamellar fluorphlogopite by the adjustment of layer charge7First‐Principles Calculation of Phase/Size Characteristic in Yb 3+ /Tm 3+ /ZnO Upconversion Nanoparticles through Metal Ga 3+ Doping6Mo^6+ substitution induced band structure regulation and efficient near-UV-excited red emission in NaLaMg(W,Mo)O_6:Eu phosphor19Color-tunable luminescence and energy transfer properties of Dy3+/Eu3+ codoped Sr3Sc(PO4)3 eulytite-type orthophosphate phosphors for NUV-LEDs17Synthesis and luminescence properties of new red phosphor YBiW2O9:Eu3+6Eu3+-doped double perovskite-based phosphor-in-glass color converter for high-power warm w-LEDs91Significant promotion of porous architecture and magnetic Fe 3 O 4 NPs inside honeycomb-like carbonaceous composites for enhanced microwave absorption63Crystal structure, electronic structure and photoluminescence properties of KLaMgWO6:Eu3+ phosphors44Tuneable colour-emitting Ce3+, Eu3+/K+ and Ce3+/Tb3+ doped BaSiF6 phosphors via charge compensation and energy transfer4Synthesis and photoluminescence properties of red-emitting NaLaMgWO6:Sm3+,Eu3+ phosphors for white LED applications80A novel dazzling Eu 3+ ‐doped whitlockite‐type phosphate red‐emitting phosphor for white light‐emitting diodes60Synthesis and luminescence properties of single‐component Ca 5 ( PO 4 ) 3 F:Dy 3+ , Eu 3+ white‐emitting phosphors24Molybdenum substitution simultaneously induced band structure modulation and luminescence enhancement in LiLaMg(W, Mo)O6: Eu3+ red-emitting phosphor for near ultraviolet excited white light diodes38Photoluminescence enhancement of novel K(Y,Lu)CaWO6: Eu3+ red phosphor prepared by controllable citrate-EDTA complexing method11Preparation, band-structure and luminescence of double perovskite Ba2MgMoO6:Eu3+ orange-red phosphor for white LEDs56Second-order John-Teller distortion in the thermally stable Li(La, Gd)MgWO6:Eu3+ phosphor with high quantum efficiency40Analysis of high-temperature aging and microstructure of FC LED solder joints of a silver conductive layer bonded using SAC solder1Crystal structure, luminescence enhancement and white LEDs application of NaZnPO4:Eu3+ red phosphors19Effect of Different Welding Methods on Flip-Chip LED (FC-LED) Filament Properties2Crystal Structure and Site Symmetry of Undoped and Eu3+ Doped Ba2LaSbO6 and BaLaMSbO6 Compounds (M=Mg,Ca): Tuning Europium Site Occupancy to Develop Orange and Red Phosphor27Enhancement of the red emission in Ba3(PO4)2:Eu3+ by addition of charge compensator Na+3Novel emission bands of Na2TiF6:Mn4+ phosphors induced by the cation exchange method35Insights into the structure, photoluminescence and Judd-Ofelt analysis of red emitting SrLaLiTeO6: Eu3+ phosphors82Hydrothermal synthesis and crystal structure of new red phosphors, KNaMF7:Mn4+ (M: Nb, Ta)21Synthesis and photoluminescence properties of CaMTiO3:0.12Eu3+ (M = Mg, Sm) red phosphors for lighting application1Implementation of high color quality, high luminous warm WLED using efficient and thermally stable Rb3AlF6:Mn4+ as red color converter40Enhancement of zero phonon line for Na2TiF6:Mn4+, Li+ phosphors induced by Li+13CaYGaO4 olivine-based green and red downconversion phosphors17Intense red emission from Sr4Nb2O9:Eu3+ phosphor by introducing with SrF2 as flux and charge compensator14Sol-gel synthesis, crystal structure and luminescence properties of Eu3+ doped double perovskite molybdates NaCaBi1−xEuxMoO6 (x = 0–0.27)4Expanding the Doubly Cation Ordered AA′BB′O6 Perovskite Family: Structural Complexity in NaLaInNbO6 and NaLaInTaO621Exploring the intricacies in the conduction mechanism of the perovskite series Ba2HoSb1−Ru O6: A conductivity scaling approach2Probing crystal structure and site‐selective photo‐physical properties of various Eu 3+ ‐doped niobates30Structure and calorimetric study of complex oxides based on lanthanum, tungsten, and alkaline earth elements MeLa2WO7 (Me = Mg, Ca, Sr, Ba)7Structure, energy transfer, and luminescence properties of NaLaMgWO6: Tb3+,Eu3+ phosphors for solid-state lighting16Site Occupation and Luminescence of Novel Orange-Red Ca3M2Ge3O12:Mn2+,Mn4+ (M = Al, Ga) Phosphors106Luminescence and energy transfer in BaY2(MoO4)4:Tb3+,Eu3+ phosphors and bifunctional applications in thermometry and light emitting diodes35A new mixed-anion phosphate Cs2Bi2Sr(P2O7)(PO4)2: Synthesis, characterization, structure and its Eu3+-activated luminescence11Role of energy band structure on the luminescence performance of double perovskite La2LiMO6:Eu3+ (M=Sb, Ta, Nb) red emitting phosphors16Multi-color emission of Dy3+/Eu3+ co-doped LiLuF4 single crystals for white light-emitting devices37Eu3+-activated Ln2TeO6 (Ln = La, Y) as a novel red-emitting phosphor for warm white LEDs4Deep-red photoluminescence from enhanced 5D0-7F4 transition in Eu3+ doped Ca2Ga2GeO7 phosphors36Luminescence Properties of Rare Earth–Doped Cubic Double Perovskite Tungstate Ba2(1−x)(Na,RE)xZnWO6 (RE = Ce3+, Eu3+ and Dy3+) Phosphors9Investigation on thermal quenching of Eu3+ luminescence in Sr2Ca(Mo/W)O6, Gd3B(Mo/W)O9 and Ca(Mo/W)O411Red luminescence properties of Te4+-doped CaYAlO4 phosphors17New narrow orange-emitting phosphors in 1:2 B-site cation ordered Eu3+ doped triple perovskite Ba3CaNb2O92Enhanced luminescence performance in double perovskite Na4/5Gd16/15-MgWO6: xEu3+ red-emitting phosphors for white LEDs through cation modification11Excellent Red Phosphors of Eu3+ Activated Double Perovskite Structured Series NaSrBi1-xEuxMoO6 (x = 0.0-0.24) Prepared by Citrate-Gel Method0Structural and spectral investigation of a near-UV-converted LiSrP3O9:Dy3+ phosphor for white light-emitting diodes16Sol-gel synthesized double perovskite Na(1-)Gd(0.95+/3)MgWO6: 5% Eu3+ (0 ≤ x ≤ 0.5) phosphors with incommensurately modulated structure: Microstructures and luminescence properties15Luminescence enhancement and tunable color emission in Eu/Dy/Sm codoped CaW1- xMoxO4 phosphor13New red-emitting phosphor of Eu3+-doped Ba2Gd0.67W1−xMoxO6 for solid state lighting0Synthesis, dielectric, magnetic, and photoluminescence properties of two new hybrid rare-earth double perovskites6Improved thermal stability of the red-emitting Gd3+ - Modulated La2LiSbO6:Eu3+ phosphors for WLED10Color tunability of NaLaMgWO6:Mn4+, Tb3+ phosphor and its potential application in temperature sensor and wavelength detector7Protocol for Dy3+-modified NaCaVO4 nanophosphors in solid-state lighting applications: structural and luminescence investigations6Synthesis of an excellent red phosphor and photo luminescence studies of Eu 3+ activated double perovskite phosphors NaSrBi 1- x Eu x WO 6 ( x = 0.0–0.24)2Octahedral modulation of W 6+ /Mo 6+ in Ba 2 MgTeO 6 for smart lighting and anti-counterfeiting0Chemical unit substitution at B/B′ site enables efficient red emission and high thermal stability in NaGdMgWO6:Eu3+ for white light-emitting diodes application3Influence of the A site order–disorder transition on the photoluminescence properties of LiLa(Ca, Mg)(W, Mo)O6:Eu3+ red phosphor1Multifunctional Eu3+- activated Na0.5Li0.5Gd(WO4)2 phosphor: Applications in solid-state lighting, fingerprint identification and dye degradation3

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  14. Luminescence properties of red‐emission Mg4Nb2O9:Eu3+ phosphor

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  31. High-brightness Eu3+-doped La0.67Mg0.5W0.5O3 red phosphor for NUV light-emitting diodes application

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  32. Failure mode analysis for the solder joints for the flip-chip light emitting diodes

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  33. Co‐precipitation synthesis and luminescence properties of K2TiF6:Mn4+ red phosphors for warm white light‐emitting diodes

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  35. Deep red MGe 4 O 9 :Mn 4+ (M = Sr, Ba) phosphors: structure, luminescence properties and application in warm white light emitting diodes

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  36. Extensive studies of host lattices and activators in lanthanide phosphors based on efficient synthesis

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  37. Enhanced luminescence of a Eu3+-activated double perovskite (Na, Li)LaMgWO6 phosphor based on A site inducing energy transfer

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  38. Structure evolution and delayed quenching of the double perovskite NaLaMgWO6:Eu3+ phosphor for white LEDs

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  39. Luminescence enhancement in the Sr2ZnW1−xMoxO6:Eu3+,Li+ phosphor for near ultraviolet based solid state lighting

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  42. Effect of NH4Cl flux used to synthesize double perovskite BaLaMgSbO6:Eu3+ phosphor by solid-state reaction method

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  43. Double perovskite LiLaMgWO6:Eu3+ novel red-emitting phosphors for solid sate lighting: Synthesis, structure and photoluminescent properties

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  44. Improved full-color emission and switched luminescence in single Ca3(PO4)2: Dy3+, Eu3+ phosphors for white LEDs

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  45. Influence of Alkali Metal Ions on Luminescence Behaviour of Ca0.5R1-x(MoO4)2:xLn3+ (R = Y, La), (Ln = Eu, Tb, Dy) Pulsed Laser Deposited Thin Phosphor Films

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  46. Photoluminescence properties of novel BaGd 2 Si 3 O 10 :RE 2+/3+ (RE = Eu or Ce) phosphors with trichromatic emission for white LEDs

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