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RESEARCH PAPER · Chemistry of Materials · 2004

Assembly of Hybrid Inorganic−Organic Materials from Octahedral Nb6 Clusters and Metal Complexes

Huajun Zhou, Cynthia Secaur Day, Abdessadek Lachgar

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Assembly of Hybrid Inorganic−Organic Materials from Octahedral Nb6 Clusters and Metal ComplexesOriginalNickel(II) and iron(II) mononuclear complexes with 1-methylimidazole-2-aldoximate: New building units for molecule-assembled magnetic materials11Supramolecular π–π assembly of a neutral [Cu(salen)] complex via the templating effect of an ionic inorganic complex Na2[Cu(mnt)2] forming a framework type material having well-defined channels4Synthesis and Characterization of Prussian Blue Analogues Incorporating the Edge-Bridged Octahedral [Zr 6 BCl 12 ] 2+ Cluster Core40Supramolecular Assemblies Built of [Nb6Cl12(CN)6]4-Octahedral Metal Clusters and [Mn(acacen)]+Complexes21Superexpanded Prussian-Blue Analogue with [Fe(CN)6]4-, [Nb6Cl12(CN)6]4-, and [Mn(salen)]+as Building Units90Octahedral Metal Clusters [Nb 6 Cl 12 (CN) 6 ] 4– as Molecular Building Blocks: From Supramolecular Assemblies to Coordination Polymers32Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences75Directed Assembly of Cluster‐Based Supramolecules into One‐Dimensional Coordination Polymers54Directed Assembly of Cluster‐Based Supramolecules into One‐Dimensional Coordination Polymers12Inorganic Crystal Engineering through Cation Metathesis: One-, Two-, and Three-Dimensional Cluster-Based Coordination Polymers29Magnetic assemblies based on Mn(III) salen analogues382Metal–Ligand Directed Assembly of Layered Cluster-Based Coordination Polymer and Its Solvent-Mediated Structural Transformations36Material Applications for Salen Frameworks289Materialanwendungen für Salenstrukturen45Solvent‐Mediated Ion Exchange and Structural Transformations of Cluster‐Based Coordination Polymers24Expanded Prussian Blue Analogue Based on Octahedral {Nb6} Clusters and {K2} Dimers as Nodes8New Cluster Complexes with Octahedral Cores of Niobium Atoms: Syntheses, Structures, and Properties of [K(18-crown-6)]2[K(18-crown-6)(H2O)2]2[Nb6Cl12(CN)6] · 2CH3CN and [(C6H5)4P]4[Nb6Cl12(NCS)6] · 0.94CH3OH13Novel compounds based on [Re6Q8(L)6]4− (Q = S, Se, Te; L = CN, OH) and their applications51Self‐Assembly of Cluster‐Based Nanoscopic Supramolecules into One‐Dimensional Coordination Polymers4Supramolecular Heteropentamers As Building Blocks for Metal Organic Materials: Synthesis and Characterization of 1D and 2D 2-Fold Interpenetrated Frameworks9Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand10Self-Assembly of a New 1D Coordination Polymer Built of [Nb6Cl12(CN)6]4− and Mn(III) Complexes2Self-assembly and solvent-mediated structural transformation of one-dimensional cluster-based coordination polymer21Syntheses, Structures, and Properties of New Niobium Cluster Complexes with Terminal Formate Ligands: [AI(CH3OH)n]4[Nb6Cl12(OCHO)6] (AI = Na, K, Rb, Cs; n = 1, 2)5Octahedral Metal Clusters as Building Blocks of Trimetallic Superexpanded Prussian Blue Analogues22Assemblies Based on Schiff Base Chemistry9Discrete Neutral Niobium Cluster Units in Compounds of the Type [Nb6Cl14L4] with L = O or N Donor Ligand11Nb Complexes2Structural and electronic properties of the metal cluster‐based compounds including high concentration of solvent molecules5Organometallic Complexes of Group 5 With π-Acidic Ligands2The double cluster compound [Nb6Cl14(MeCN)4][Nb6Cl14(pyz)4]·6MeCN (Me: methyl, pyz: pyrazine) with a layered structure resulting from weak intermolecular interactions1Hydrogen-bonded frameworks based on hetero-trimers and -tetramers of octahedral cluster unit [Ta6Cl12(CN)6]3− and Mn complexes0Neutral Supramolecular Cluster-Based Nanorods from Direct Assembly of Three Building Units0

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  1. Nickel(II) and iron(II) mononuclear complexes with 1-methylimidazole-2-aldoximate: New building units for molecule-assembled magnetic materials

    Inorganica Chimica Acta · 2005-06-20

    Hitoshi Miyasaka, Ayumi Saitoh, Sayaka Yanagida, C. Kachi-Terajima, Ken-ichi Sugiura, Masahiro Yamashita

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  2. Supramolecular π–π assembly of a neutral [Cu(salen)] complex via the templating effect of an ionic inorganic complex Na2[Cu(mnt)2] forming a framework type material having well-defined channels

    Inorganic Chemistry Communications · 2005-10-20

    Vedichi Madhu, Samar K. Das

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  3. Synthesis and Characterization of Prussian Blue Analogues Incorporating the Edge-Bridged Octahedral [Zr 6 BCl 12 ] 2+ Cluster Core

    Inorganic Chemistry · 2005-12-08

    Laurance G. Beauvais, Jeffrey R. Long

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  4. Supramolecular Assemblies Built of [Nb6Cl12(CN)6]4-Octahedral Metal Clusters and [Mn(acacen)]+Complexes

    Crystal Growth & Design · 2006-09-19

    Huajun Zhou, Abdessadek Lachgar

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  5. Superexpanded Prussian-Blue Analogue with [Fe(CN)6]4-, [Nb6Cl12(CN)6]4-, and [Mn(salen)]+as Building Units

    Journal of the American Chemical Society · 2006-12-19

    Jianjun Zhang, Abdessadek Lachgar

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  6. Octahedral Metal Clusters [Nb 6 Cl 12 (CN) 6 ] 4– as Molecular Building Blocks: From Supramolecular Assemblies to Coordination Polymers

    European Journal of Inorganic Chemistry · 2007-02-13

    Huajun Zhou, Abdessadek Lachgar

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  7. Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

    Progress in Solid State Chemistry · 2007-03-31

    Mercouri G. Kanatzidis, Kenneth Reinhard Poeppelmeier, Svilen Bobev, Arnold M. Guloy, Shiou Jyh Hwu, Abdessadek Lachgar, Susan E. Latturner, Raymond, E. Schaak, Dong‐Kyun Seo, Slavi Christov Sevov, Andreas Stein, B. Dąbrowski, John E. Greedan, M. Greenblatt, Clare P. Grey, Allan J. Jacobson, Douglas A. Keszler, Jing Li, Mas A. Subramanian, Younan Xia, Tahir Cagin B, Ulrich Häußermann, Timothy R. Hughbanks, S. D. Mahanti, Dane D. Morgan, Dong‐Kyun Seo, Nicola A. Spaldin, William E. Buhro, Daniel E. Giammar, Jennifer Ann Hollingsworth, David C. Johnson, Arthur J. Nozik, Xiaogang Peng, Robert L. Bedard, Nathaniel E. Brese, Guang Cao, Sandeep S. Dhingra, Cherie R. Kagan, David B. Mitzi, Margret J. Geselbracht, George C. Lisensky, Michael W. Lufaso, Paul A. Maggard, M. O’Keeffe, Angus Paul Wilkinson, Hans‐Conrad zur Loye, T. Egami, John E. Greedan, Jason P. Hodges, James D. Martin, John B. Parise, Brian H. Toby, Terrell A. Vanderah, Peter Carman Burns, Julia Y. Chan, Anne E. Meyer, Christopher B. Murray, Arthur P. Ramirez, Michael D. Ward, Lian Yu, Miguel Ángel Alario Franco, Peter D. Battle, Thomas Bein, Christopher L. Cahill, P. Shiv Halasyamani, Antoine Maignan, Ram Seshadri

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  8. Directed Assembly of Cluster‐Based Supramolecules into One‐Dimensional Coordination Polymers

    Angewandte Chemie International Edition · 2007-04-05

    Jianjun Zhang, Huajun Zhou, Abdessadek Lachgar

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  9. Directed Assembly of Cluster‐Based Supramolecules into One‐Dimensional Coordination Polymers

    Angewandte Chemie · 2007-04-05

    Jianjun Zhang, Huajun Zhou, Abdessadek Lachgar

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  10. Inorganic Crystal Engineering through Cation Metathesis: One-, Two-, and Three-Dimensional Cluster-Based Coordination Polymers

    Chemistry of Materials · 2007-04-07

    Huajun Zhou, K.C. Strates, Miguel‐Ángel Muñoz‐Hernández, Kevin J. Little, Daniel M. Pajerowski, Mark W. Meisel, Daniel R. Talham, Abdessadek Lachgar

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  11. Magnetic assemblies based on Mn(III) salen analogues

    Coordination Chemistry Reviews · 2007-08-23

    Hitoshi Miyasaka, Ayumi Saitoh, Satoshi Abe

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  12. Metal–Ligand Directed Assembly of Layered Cluster-Based Coordination Polymer and Its Solvent-Mediated Structural Transformations

    Crystal Growth & Design · 2007-12-14

    Jianjun Zhang, Yue Zhao, Sergio Aarón Gamboa, Abdessadek Lachgar

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  13. Material Applications for Salen Frameworks

    Angewandte Chemie International Edition · 2008-02-27

    Sander J. Wezenberg, Arjan W. Kleij

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  14. Materialanwendungen für Salenstrukturen

    Angewandte Chemie · 2008-02-27

    Sander J. Wezenberg, Arjan W. Kleij

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  15. Solvent‐Mediated Ion Exchange and Structural Transformations of Cluster‐Based Coordination Polymers

    European Journal of Inorganic Chemistry · 2008-05-28

    Jianjun Zhang, Yue Zhao, Sergio Aarón Gamboa, Miguel‐Ángel Muñoz‐Hernández, Abdessadek Lachgar

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  16. Expanded Prussian Blue Analogue Based on Octahedral {Nb6} Clusters and {K2} Dimers as Nodes

    Journal of Chemical Crystallography · 2008-05-29

    Jianjun Zhang, Jochen Gläser, Sergio Aarón Gamboa, Abdessadek Lachgar

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  17. New Cluster Complexes with Octahedral Cores of Niobium Atoms: Syntheses, Structures, and Properties of [K(18-crown-6)]2[K(18-crown-6)(H2O)2]2[Nb6Cl12(CN)6] · 2CH3CN and [(C6H5)4P]4[Nb6Cl12(NCS)6] · 0.94CH3OH

    Journal of Cluster Science · 2008-11-18

    Anke Flemming, A. Bernsdorf, Martin Köckerling

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  18. Novel compounds based on [Re6Q8(L)6]4− (Q = S, Se, Te; L = CN, OH) and their applications

    Journal of Materials Chemistry · 2009-01-01

    Youngmee Kim, Vladimir E. Fedorov, Sung‐Jin Kim

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  19. Self‐Assembly of Cluster‐Based Nanoscopic Supramolecules into One‐Dimensional Coordination Polymers

    Advances in Materials Science and Engineering · 2009-01-01

    Jianjun Zhang, Sergio Aarón Gamboa, Barry J. Davis, Abdessadek Lachgar

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  20. Supramolecular Heteropentamers As Building Blocks for Metal Organic Materials: Synthesis and Characterization of 1D and 2D 2-Fold Interpenetrated Frameworks

    Crystal Growth & Design · 2009-01-13

    Jianjun Zhang, Cynthia Secaur Day, Mark D. Harvey, G.T. Yee, Abdessadek Lachgar

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  21. Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand

    Inorganica Chimica Acta · 2010-07-07

    Xiaoyan Tu, Huong Truong, Gary S. Nichol, Zhiping Zheng

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  22. Self-Assembly of a New 1D Coordination Polymer Built of [Nb6Cl12(CN)6]4− and Mn(III) Complexes

    Journal of Chemical Crystallography · 2010-07-07

    Huajun Zhou, Jianjun Zhang, Abdessadek Lachgar

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  23. Self-assembly and solvent-mediated structural transformation of one-dimensional cluster-based coordination polymer

    CrystEngComm · 2010-08-27

    Jianjun Zhang, Cynthia Secaur Day, Abdessadek Lachgar

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  24. Syntheses, Structures, and Properties of New Niobium Cluster Complexes with Terminal Formate Ligands: [AI(CH3OH)n]4[Nb6Cl12(OCHO)6] (AI = Na, K, Rb, Cs; n = 1, 2)

    Zeitschrift für anorganische und allgemeine Chemie · 2015-01-08

    Tao Xie, Martin Köckerling

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  25. Octahedral Metal Clusters as Building Blocks of Trimetallic Superexpanded Prussian Blue Analogues

    Inorganic Chemistry · 2015-01-15

    Jianjun Zhang, Abdessadek Lachgar

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  26. Assemblies Based on Schiff Base Chemistry

    Elsevier eBooks · 2016-12-18

    Janusz Lewiński, Daniel Prochowicz

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  27. Discrete Neutral Niobium Cluster Units in Compounds of the Type [Nb6Cl14L4] with L = O or N Donor Ligand

    Zeitschrift für anorganische und allgemeine Chemie · 2019-02-05

    Eric Sperlich, Jonas König, Daniel Holger Weiß, Florian Schröder, Martin Köckerling

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  28. Nb Complexes

    Elsevier eBooks · 2020-09-29

    Takashi Kurogi, Daniel J. Mindiola

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  29. Structural and electronic properties of the metal cluster‐based compounds including high concentration of solvent molecules

    Zeitschrift für anorganische und allgemeine Chemie · 2021-02-08

    Norio Saito, Pierric Lemoine, Stéphane Cordier, Yoshitaka Matsushita, Takeo Ohsawa, Fabien Grasset, Jeffrey S. Cross, Naoki Ohashi

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  30. Organometallic Complexes of Group 5 With π-Acidic Ligands

    Elsevier eBooks · 2021-02-26

    Fabio Marchetti, Guido Pampaloni

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  31. The double cluster compound [Nb6Cl14(MeCN)4][Nb6Cl14(pyz)4]·6MeCN (Me: methyl, pyz: pyrazine) with a layered structure resulting from weak intermolecular interactions

    Zeitschrift für Naturforschung B · 2023-02-24

    Eric Sperlich, Martin Köckerling

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  32. Hydrogen-bonded frameworks based on hetero-trimers and -tetramers of octahedral cluster unit [Ta6Cl12(CN)6]3− and Mn complexes

    Polyhedron · 2024-04-27

    Jianjun Zhang, Huajun Zhou, Abdessadek Lachgar

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  33. Neutral Supramolecular Cluster-Based Nanorods from Direct Assembly of Three Building Units

    Journal of Chemical Crystallography · 2025-03-25

    Jianjun Zhang, Huajun Zhou, Ted Grant, Abdessadek Lachgar

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