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RESEARCH PAPER · Journal of Solid State Chemistry · 1982

CaMnO2.5 and Ca2MnO3.5: New oxygen-defect perovskite-type oxides

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CaMnO2.5 and Ca2MnO3.5: New oxygen-defect perovskite-type oxidesOriginalStructure determination of CaMnO3 and CaMnO2.5 by X-ray and neutron methods354Preparative solid state chemistry. Recent developments9Elements of group 26Calcium mangano-ferrites (CaMO3)mCaMO2 □, M = Fe, Mn, with an oxygen-defect perovskite structure related to brownmillerite electron microscopy investigation15Crystal chemistry and magnetic properties of layered metal oxides possessing the K2NiF4 or related structures286The oxygen defect perovskite Ca3Mn1.35Fe1.65O8.02: A highly frustrated antiferromagnet24Superstructures formed by the ordering of vacancies in a selective oxidation catalyst: grossly defective CaMnO3105Microdomain formation in the CaFexMn1−xO3−y ferrites28Reversible topotactic reduction of perovskite-related calcium manganese oxides11Sr2Mn2O5, an oxygen-defect perovskite with Mn(III) in square pyramidal coordination90Structure determination of Ca2MnO4 and Ca2MnO3.5 by X-ray and neutron methods84Notiz über einen Perowskit der Zusammensetzung BaInO2,522Thermal analysis as a tool for investigations in metal oxide chemistry6Mössbauer study of vacancy ordering in the system SrTi1−xFexO3−y (0.50 ≤ x ≤ 0.70)21Novel metal oxides prepared by ingenious synthetic routes44Rhombohedral Sr2Co2O5: A new A2M2O5 phase52Ferroelectric properties of oxygen deficient PbTiO3-related phases3The oxygen defect perovskite Sr2Mn2O5: HREM study22Einflüsse struktureller Gegebenheiten auf den Verlauf von heterogenen Festkörperreaktionen12Reversible Reduktions‐ und Reoxidationsprozesse des Typs ABO3 ⇆ ABO3‐X an Perovskitischen Metalloxiden16Oxygen deficient perovskites :8Magnetic properties of Ca2F2-xMnxO51BaLa4Cu5O13+δ, an oxygen-deficient perovskite built up from corner-sharing CuO6 octahedra and CuO5 pyramids92Synthesis of complex metal oxides by novel routes63Nonstoichiometry and structural intergrowth in the CaFexMn1−xO3−y (0 ≤ x ≤ 1) system17Oxygen vacancy ordering and non stoichiometry in the Ba 2 YCu 3 O 7−x superconductors73Chapter 6 Reduction of Oxides6Oxygen Stoichiometry and Ordering in HTSC and Other Perovskite-Like Solids0An electron diffraction study of new phases in the LaNiO3−x system40Structural Relations between Metal Hydrides and Superconducting Oxides Ba2YCu3O9−x*2A study of the ordering of oxygen vacancies in the nonstoichiometric perovskite Sr2LaFe3O8+y by Mössbauer spectroscopy and a comparison with SrFeO3−y81Oxygen vacancy distribution in 6HBaFeO3−y (0.20 ≤ y ≤ 0.35)30Nickel/Lanthanum Ordering in YBa2Cu3O7-δ0New phases induced by hydrogen reduction and by subsequent oxidation of L2 CuO4 (L=La,Pr,Nd,Sm,Eu,Gd)50Nonstoichiometry in the perovskite-type oxides: an evolution from the classical Schottky-Wagner model to the recent high Tc superconductors27NON STOICHIOMETRY IN PEROVSKITE-TYPE OXIDES. INFLUENCE OF THE ELECTRONIC CONFIGURATION ON FORMATION OF EXTENDED DEFECTS1Local environment of iron in heavy ion-irradiated amorphous magnetic oxides by Mössbauer and X-ray absorption spectroscopy23Structural investigation of oxygen-deficient perovskite CaMnO2.7524Reduction chemistry of platinum group metal perovskites22Cation Ordering in Brownmillerite-Perovskite Intergrowth Structures1Oxygen Ion Conductivity in a New Class of Layered Bismuth Oxide Compounds14Cation coordination and oxygen vacancies in mixed oxide perovskites5Eine perowskitstapelvariante mit geordneter metallverteilung: Ba6Al2Rh2Ho2O1514Structural similarities among cuprate superconductors1Reinterpretation of the magnetic structures of the perovskites SrFeO2.710 and Sr2LaFe3O8.41716Phases on the ?Perovskite Line? in the La-Sr-Cu-O System2Estabilización estructural y caracterización eléctrica de materiales basados en CaMnO30Absence of superconductivity in the doped antiferromagnetic spin-ladder compound (La,Sr)CuO2.5188Solid phase reactivity of sodium oxosalts of manganese9Computer simulation of the oxygen mobility in CaMnO3-x8A New Series of Layered Cuprates (ACuO2.5)2(ATiO3)m: Dy2Ba2Ca2Cu2Ti4O17, m = 425Synthesis and Structure of LaSr2CuTiO6.5: A New Oxygen-Deficient Ruddlesden−Popper Phase9The nonstoichiometry and physical properties of the Nd1−xCa1+xFeO4−y system2Double-exchange interaction in electron-doped CaMnO3−δ perovskites84Chapter 1 Normal-state magnetic properties of single-layer cuprate high-temperature superconductors and related materials25Sr2Mn2O5 magnetic structure31Control on the Copper Valence and Properties by Oxygen Content Adjustment in the LaCuO3−System (0≤y≤0.5)32Decomposition oxygen partial pressures of Ln1−Sr MnO3 (Ln=La, Nd and Dy)11On new mixed conductors of Bi4V2 − xMnxO11 − δ formulation18The electronic structure of CaMnOx with 2.66 ≤ x ≤ 3.0021Synthesis, structure, electrical and magnetic properties of the new non-stoichiometric perovskite phase, Ca2MnNbOγ9Electronic structure of CaMnOx with 2.66<~x<~3.00 studied with photoemission and x-ray-absorption spectroscopy45A Multistep Topotactic Route to the New Mixed-Valence Titanate, Na2-x+yCax/2La2Ti3O10. Electron Localization Effects in a Triple-Layered Perovskite26Charge ordering in electron-doped manganates9Phase Equilibrium Diagrams of the Binary Systems LaMnO3-SrMnO3 and LaMnO3-CaMnO30Kondo Effect in the Resistivity of CaRu1-xMnxO315Effect of oxygen content on the magnetic state of La0.5Ca0.5MnO3−γ perovskites37Infrared-active phonons of LaMnO3 and CaMnO386Site-Specific Vanadates Co4Fe3.33(VO4)6 and Mn3Fe4(VO4)629Continuous symmetry measures of penta-coordinate molecules: Berry and non-Berry distortions of the trigonal bipyramid †173Structural and Magnetotransport Transitions in the Electron-Doped Pr1-xSrxMnO3 (0.85 ≤ x ≤ 1) Manganites27Phase diagram studies in the quasi binary systems LaMnO3–SrMnO3 and LaMnO3–CaMnO321Phase‐Diagram Studies in the La 2 O 3 –SrO–CaO–Mn 3 O 4 System at 1200°C in Air18Phase behavior in the system LaxSr1−xMnO(5+x)/2 (x=0.8–1.0) with trivalent state of manganese ion24Effect of oxygen content on magnetization and magnetoresistance properties of CMR manganites42Synthesis and characterisation of CaMn1−Cr O3− phases4Enthalpies of Oxidation of CaMnO3-δ, Ca2MnO4-δ and SrMnO3-δ Deduced Redox Properties77Enthalpies of Formation of La1−xAxMnO3±δ (A=Ca and Sr) Measured by High-Temperature Solution Calorimetry29Investigation of magnetic phase transformations in a system of Nd1−x BaxMnO3−δ (0≤x≤0.50) depending on the conditions of preparation38Phase Transitions in the La0.50Ca0.50MnO3?? Manganites6Oxygen stoichiometry and structural properties of La1 – xAxMnO3 ± δ (A = Ca or Sr and 0 ≤ x ≤ 1)130A Mixed Oxide-Hydride Perovskite18Smart Perovskites2The influence of oxygen deficiency on the magnetic and electric properties of La0.70Ba0.30MnO3 −γ (0≤γ≤0.30) manganite with a perovskite structure119Magnetic State of Ba-Doped Manganites Depending on the Oxygen Vacancy Concentration3Evolution of magnetic state in the La1−xCaxMnO3−γ (x=0.30, 0.50) manganites depending on the oxygen content125Transport Properties of Ca1 – x MnO3 – δ + xCeO2(0 < x ≤ 0.15) Mixtures10Magnetic properties of anion-deficient La1−x BaxMnO3−x/2 (0≤x≤0.30) manganites114Rare earth – manganese perovskites37Multiple magnetic phases of La2CoMnO6−δ (0<~δ<~0.05)454Magnetic and magnetotransport properties of La1–xBaxMnO3–x/2 perovskite manganites146Magnetic phase transitions in the anion-deficient La1 xBaxMnO3 x/2(0 x 0.50) manganites100A redox-stable efficient anode for solid-oxide fuel cells1209Synthesis and structure of Sr2MnGaO5+δ brownmillerites with variable oxygen content15Oxygen stoichiometry, ferromagnetism, and transport properties of La2−xNiMnO6+δ392Magnetic phase diagram of the manganites Bi1−xSrxMnO328Structure, nonstoichiometry and magnetic properties of the perovskites Sr1−xCaxMnO3−δ31Insulator–metal transition and magnetoresistance of oxygen deficient La0.35Ca0.65MnOy3Influence of oxygen vacancies on the magnetic and electrical properties of La $\mathsf{_{1-x}}$ Sr $\mathsf{_{x}}$ MnO $\mathsf{_{3-x/2}}$ manganites124Electronic structure and polarons in CaMnO3−δ single crystals: Optical data54Ab initio investigation of the magnetic states of Ca2MnO4 and Ca2MnO3.513Transmission electron microscopy and structural phase transitions in anion-deficient perovskite-based oxides22Order in the disordered state: local structural entities in the fast ion conductor Ba2In2O544Peculiarities of the magnetic state in the system La0.70Sr0.30MnO3−γ (0 ≤ γ ≤ 0.25)143Magnetic properties of the nonstoichiometric Sr‐doped manganites89Morphological and magnetic study of CaMnO3−x oxides obtained from different routes35Studies on surface composition and chemical states of calcium manganites12Magnetic and Electrotransport Properties of the Anion-Deficient Manganites with Perovskite Structure12Ordering of oxygen vacancies in a CaMnO3 − δ perovskite single crystal13Entropy of oxidation and redox energetics of CaMnO41Synthesis and Structure of (Ca,Sr)-Substituted Lanthanum Manganite3Oxygen-deficient perovskites: linking structure, energetics and ion transport1715.1.11.12 References for 5.1.110Table 105.1.6.11 Infrared data05.1.6.14 References for 5.1.605.1.6.9 Electrical resistivities0Figs. 1 - 9, Table 11Figs. 10 - 14, Table 20Figs. 15 - 250Sr and Ga substituted Ba2In2O5: Linking ionic conductivity and the potential energy surface22Studies of Oxygen Deficient Complex Cobaltates with Perovskite Related Structures2The dielectric behavior of perovskite-related manganese oxides with stretched bonds or multiferroic properties1Disruption of extended defects in solid oxide fuel cell anodes for methane oxidation402Influence of oxygen nonstoichiometry on the crystal structure and magnetic properties of the cation-deficient manganites Pr0.9MnOx (2.85<x<2.90)2Magnetic structure of a CaMnO2.75 crystal with ordered oxygen vacancies8Phase relations in alkaline earth-manganese-oxygen systems: Equilibrium and metastable states15A new anode for solid oxide fuel cells with enhanced OCV under methane operation40Multiphase magnetic state of Ca1 − x La x MnO3 − δ single crystals (x = 0.03, 0.05, 0.07) containing oxygen vacancies8Magnetic susceptibility and electrical resistivity of LaMnO3 , CaMnO3 , and La1−xSrxMnO3 (0.13⩽x⩽0.45) in the temperature range 300–900K43Phase equilibria in the CaO-CuO-Cu2O-MnO-MnO2 system at 900–1400°C in air0Structural and Magnetic Properties of a New Type of Ordered Oxygen-Deficient Perovskite, KMnVO417High Pressure and High Temperature Oxidation in the IrSr2RECu2O8 Family of Cuprates: The Disordered Multiple Perovskite (A1/3 A′2/3)(B1/3 B′2/3)O3−x Phases1Ba2Mn2O4Cu0.9S: A layered Oxysulfide with a New Perovskite-Related Manganese Oxide Fragment17Oxygen Ordered Phases in LaxSr1−xMnOy (0 ≤ x ≤ 0.2, 2.5 ≤ y ≤ 3): An In situ Neutron Powder Diffraction Study23Charge ordering melting in CaMnO3−δ single crystals with ordered oxygen vacancies18Chemistry and Structure of Anion‐Deficient Perovskites with Translational Interfaces41Influence of defects on structural and magnetic properties of multifunctional La2NiMnO6 thin films121Modular Construction of Oxide Structures—Compositional Control of Transition Metal Coordination Environments12Phase conversions in calcium manganites with changing Ca/Mn ratios and their influence on the electrical transport properties14CaMn1−x NbxO3 (x ≤ 0.08) Perovskite-Type Phases As Promising New High-Temperature n-Type Thermoelectric Materials234Non-adiabatic polaron hopping conduction in CaMn1−xCrxO3 (0⩽x⩽0.3)12Perovskite Oxide Anodes for SOFCs24Synthesis, Structural, Magnetic, and Electrical Study of BaSrCo2O5, a Highly Disordered Cubic Perovskite12Quest for new materials: Inorganic chemistry plays a crucial role5Non- d0 Mn-driven ferroelectricity in antiferromagnetic BaMnO3187Ordered Rock-Salt Related Nanoclusters in CaMnO223Infrared study of the phonon modes in PrMnO3 and CaMnO325High-temperature stability, structure and thermoelectric properties of CaMn 1 - x Nb x O 3 phases78Charge state of manganese ions and the nonstoichiometry of Ca1 − x La y MnO3 − δ single crystals14

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  2. Preparative solid state chemistry. Recent developments

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  3. Elements of group 2

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  4. Calcium mangano-ferrites (CaMO3)mCaMO2 □, M = Fe, Mn, with an oxygen-defect perovskite structure related to brownmillerite electron microscopy investigation

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  5. Crystal chemistry and magnetic properties of layered metal oxides possessing the K2NiF4 or related structures

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  6. The oxygen defect perovskite Ca3Mn1.35Fe1.65O8.02: A highly frustrated antiferromagnet

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  7. Superstructures formed by the ordering of vacancies in a selective oxidation catalyst: grossly defective CaMnO3

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  8. Microdomain formation in the CaFexMn1−xO3−y ferrites

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  9. Reversible topotactic reduction of perovskite-related calcium manganese oxides

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  10. Sr2Mn2O5, an oxygen-defect perovskite with Mn(III) in square pyramidal coordination

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  12. Notiz über einen Perowskit der Zusammensetzung BaInO2,5

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  14. Mössbauer study of vacancy ordering in the system SrTi1−xFexO3−y (0.50 ≤ x ≤ 0.70)

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  17. Ferroelectric properties of oxygen deficient PbTiO3-related phases

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  19. Einflüsse struktureller Gegebenheiten auf den Verlauf von heterogenen Festkörperreaktionen

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  30. Structural Relations between Metal Hydrides and Superconducting Oxides Ba2YCu3O9−x*

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  37. Local environment of iron in heavy ion-irradiated amorphous magnetic oxides by Mössbauer and X-ray absorption spectroscopy

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  41. Oxygen Ion Conductivity in a New Class of Layered Bismuth Oxide Compounds

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  44. Structural similarities among cuprate superconductors

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  45. Reinterpretation of the magnetic structures of the perovskites SrFeO2.710 and Sr2LaFe3O8.417

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  49. Solid phase reactivity of sodium oxosalts of manganese

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