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RESEARCH PAPER · Journal of Solid State Chemistry · 1985

Structure determination of Ca2MnO4 and Ca2MnO3.5 by X-ray and neutron methods

Michael E. Leonowicz, Kenneth Reinhard Poeppelmeier, John M. Longo

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Structure determination of Ca2MnO4 and Ca2MnO3.5 by X-ray and neutron methodsOriginalLaSrCuAlO5: A new oxygen-deficient perovskite structure25New phases induced by hydrogen reduction and by subsequent oxidation of L2 CuO4 (L=La,Pr,Nd,Sm,Eu,Gd)50Reduction chemistry of platinum group metal perovskites22X-ray structural study of calcium manganese oxide by rietveld analysis at high temperatures [Ca2MnO4.00]35Physical properties and high resolution electron microscope study of barium neodymium manganese tetra oxide [BaNdMnO4]6Structural and magnetic studies of Sr 2 IrO 4407Features of structural phase transitions in Ca2−xSmxMnO44Superconductivity, Magnetism and Metal-Insulator Transitions in Some Ternary and Pseudoternary 3d-, 4d-, and 5d-Metal Oxides3Physical properties and electron microscopy study of BaPrMnO41Solid phase reactivity of sodium oxosalts of manganese9A quantum mechanical investigation of the electronic and magnetic properties of perovskite34Decomposition oxygen partial pressures of Ln1−Sr MnO3 (Ln=La, Nd and Dy)11Structure, Magnetism, and Properties of Ruddlesden−Popper Calcium Manganates Prepared from Citrate Gels119Sr3Mn2O7: Mn4+Parent Compound of then=2 Layered CMR Manganites70A two-step ion exchange route to the new metastable double-layered perovskite, (Rb,Na)1−xCax/2LaNb2O7 (x ≈ 0.9)24Structural Chemistry and Electronic Properties of the n = 3 Ruddlesden−Popper Phases Ca4Mn2FeO9.75 and Sr4Mn2FeO9.8030Layered manganites: Magnetic structure at extreme doping levels28Crystal Structures and Magnetic Properties of Ca2−xSrxMnO435Site-Specific Vanadates Co4Fe3.33(VO4)6 and Mn3Fe4(VO4)629Features of Microstructure in Ca2MnO4-δ1Anion Vacancy Distribution and Magnetism in the New Reduced Layered Co(II)/Co(I) Phase LaSrCoO3.5-x101MnK-edge XANES studies of La1−xAxMnO3 systems (A=Ca, Ba, Pb)104Impact of Oxygen Partial Pressure on the Ruddlesden−Popper Series Nd2-2xSr1+2xMn2O7: Oxygen Vacancy Formation and Ordering11Enthalpies of Oxidation of CaMnO3-δ, Ca2MnO4-δ and SrMnO3-δ Deduced Redox Properties76Charge Ordering in a 2D Manganite, Pr0.25Ca1.75MnO420Nuclear and Magnetic Structures of K2NiF4-type Iron(III) Oxide Halides0A Mixed Oxide-Hydride Perovskite18Synthesis and Characterization of the Reduced Single-Layer Manganite Sr2MnO3.5+x31Synthesis and structure of Sr2MnGaO5+δ brownmillerites with variable oxygen content15Crystal growth and structure of a new manganese vanado-antimonate MnVSbO65Structural investigation of Ca2MnO4 by neutron powder diffraction and electron microscopy45Coexistence of ferromagnetism and antiferromagnetism in the L0.08Ca1.92MnO4 series5Ab initio investigation of the magnetic states of Ca2MnO4 and Ca2MnO3.513Dielectric response in the charge-ordered Ca2−xPrxMnO4 phases23Orthorhombic distortion in Ca2−xGdxMnO475.1.6.14 References for 5.1.60Figs. 1 - 9, Table 11Figs. 10 - 14, Table 20Structural and Magnetic Properties of Topotactically Reduced YSr2Mn2O7-x (0 < x < 1.5)33Synthesis and structural properties of n= 1 Ruddlesden–Popper manganites Nd1−Ca1+MnO47Synthesis and characterization of the K2NiF4 phases La1+xSr1−xCo0.5Fe0.5O4−δ (x=0, 0.2)40Crystal structure of Ce-doped CaMnO3 perovskite10In situ neutron diffraction study of the high-temperature redox chemistry of Ln3−xSr1+xCrNiO8−δ (Ln = La, Nd) under hydrogen20Topotactic reduction as a synthetic route for the preparation of low-dimensional Mn(II) oxide phases: The structure and magnetism of LaAMnO4-x (A = Sr, Ba)30Synthesis and characterization of La1+Sr2−CoMnO7− (x=0,0.2; δ=0,1)10Topochemical Manipulation of Perovskites: Low‐Temperature Reaction Strategies for Directing Structure and Properties151Low Temperature Synthesis of Oxygen Deficient Perovskites2Structural and Magnetic Studies of Ca2−x Sm x MnO Compounds (x=0–0.4)17Synthesis and characterization of Sr2Ir1−xMxO4 (M=Ti, Fe, Co) solid solutions26Structure and Magnetism of the Topotactically Reduced Oxychloride Sr4Mn3O6.5Cl211Ruddlesden-Popper Phases and Derivatives: Homologous Series of Transition Metal Oxides2Soft Chemistry Synthesis of Oxides39Reduction of Sr2MnO4 Investigated by High Temperature in Situ Neutron Powder Diffraction under Hydrogen Flow17Fluorine intercalation in the n=1 and n=2 layered manganites Sr2MnO3.5+x and Sr3Mn2O66Crystal-Chemistry Guidelines for Noncentrosymmetric A 2 BO 4 Ruddlesden−Popper Oxides88Growth of Ca2MnO4 Ruddlesden-Popper structured thin films using combinatorial substrate epitaxy17Crystal structure and physical properties of Cr and Mn oxides with 3d 3 electronic configuration and a K 2 NiF 4 -type structure7Magnetic Structures5Topotactic Solid-State Metal Hydride Reductions of Sr2MnO416Preferential orientation relationships in Ca2MnO4 Ruddlesden-Popper thin films8Effects of Lattice Defects and Niobium Doping on Thermoelectric Properties of Calcium Manganate Compounds for Energy Harvesting Applications24High-pressure and high-temperature synthesis and physical properties of Ca2CrO4 solid5Structural stability of calcium-manganate based CaO(CaMnO3)m (m = 1, 2, 3, ∞) compounds for thermoelectric applications26Dependence of electrical transport properties of CaO(CaMnO3)m (m = 1, 2, 3, ∞) thermoelectric oxides on lattice periodicity16Study of Ruddlesden-Popper manganites RExA2-xMnO4 (RE : La, Nd and A : Sr, Ca) with potential application as electrode materials in Solid Oxide Fuel Cells (SOFC)0Topotactic Reduction toward a Noncentrosymmetric Deficient Perovskite Tb0.50Ca0.50Mn0.96O2.37 with Ordered Mn Vacancies and Piezoelectric Behavior8Citric acid auto-combustion synthesis of Ti-containing perovskites via aqueous precursors12Synthesis and preliminary study of NdxAE2-xMnO4±δ (AE: Ca, Sr) for symmetrical SOFC electrodes17On the origin of vibrational properties of calcium manganate based thermoelectric compounds26Tailoring electronic and thermal transport properties of CaO(CaMnO3)m-based (m=1 and m=∞) composites for thermoelectric power generation25Improvement of near-infrared (NIR) reflectivity and black color tone by doping Zn 2+ into the Ca 2 Mn 0.85 Ti 0.15 O 4 structure35Na 2 Fe 2 OS 2 , a new earth abundant oxysulphide cathode material for Na-ion batteries22Enhanced Charge Transport in Ca2MnO4-Layered Perovskites by Point Defect Engineering19Structural and Magnetic Characterizations of Ruddlesden–Popper Family (Ca2-xNdxMnO4) Compound Synthesized by Ceramic Route5Dysprosium doping of Ca2MnO4: Effect on crystal structure at room temperature and thermal behavior5Elucidation of the redox activity of Ca2MnO3.5 and CaV2O4 in calcium batteries using operando XRD: charge compensation mechanism and reversibility26Raman Spectroscopic Investigation and Electronic State Calculation for Ca2(Mn,Ti)O4 Black Pigments with High Near-Infrared (NIR) Reflectivity16Karlleuite Ca2MnO4 – a first mineral with the Ruddlesden-Popper type structure from Bellerberg volcano, Germany1Interplay between A-site and oxygen-vacancy ordering, and mixed electron/oxide-ion conductivity in n = 1 Ruddlesden–Popper perovskite Sr 2 Nd 2 Zn 2 O 77Structure and ionic dynamics of Mn- and Fe-based Ca-ion battery electrode materials from molecular simulations0Molten salt route to Ruddlesden-Popper calcium manganites0Electronic Structure and Defect-Induced Properties of Oxygen-Deficient CaMnO 3−δ : Insights from First-Principles Calculations3Tunable Hidden Altermagnetic Spin Splitting in Layered Ruddlesden–Popper Oxides2High-Sensitivity and High-Precision Near-Infrared Luminescence Thermometry Using Mn5+-Activated Sr5(VO4)3Cl and Ba5(VO4)3Cl-Based Phosphors0

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  1. LaSrCuAlO5: A new oxygen-deficient perovskite structure

    Journal of Solid State Chemistry · 1990-09-01

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  2. New phases induced by hydrogen reduction and by subsequent oxidation of L2 CuO4 (L=La,Pr,Nd,Sm,Eu,Gd)

    Physical review. B, Condensed matter · 1990-10-01

    F. C. Chou, J.H. Cho, L. L. Miller, D. C. Johnston

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  3. Reduction chemistry of platinum group metal perovskites

    Materials Research Bulletin · 1991-11-01

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  4. X-ray structural study of calcium manganese oxide by rietveld analysis at high temperatures [Ca2MnO4.00]

    Materials Research Bulletin · 1993-06-01

    Junichi Takahashi, Naoki Kamegashira

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  5. Physical properties and high resolution electron microscope study of barium neodymium manganese tetra oxide [BaNdMnO4]

    Materials Research Bulletin · 1994-02-01

    Naoki Kamegashira, Shu Ueno, H. Saito-Nakano, K. Énami

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  6. Structural and magnetic studies of Sr 2 IrO 4

    Physical review. B, Condensed matter · 1994-04-01

    M. K. Crawford, Mas A. Subramanian, R. L. Harlow, Jaime A. Fernandez-Baca, ZR Wang, D. C. Johnston

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  7. Features of structural phase transitions in Ca2−xSmxMnO4

    Physica C Superconductivity · 1994-12-01

    Hirokazu Saito, Yasuhide Inoue, Fumio Munakata, M. Yamanaka, J. Takahashi, Naoki Kamegashira, Yasuhito Koyama

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  8. Superconductivity, Magnetism and Metal-Insulator Transitions in Some Ternary and Pseudoternary 3d-, 4d-, and 5d-Metal Oxides

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    D. C. Johnston, T. Ami, F. Borsa, M. K. Crawford, Jaime A. Fernandez-Baca, Kyung Hyun Kim, R. L. Harlow, A. V. Mahajan, L. L. Miller, Mas A. Subramanian, David R. Torgeson, Z. R. Wang

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  9. Physical properties and electron microscopy study of BaPrMnO4

    Materials Chemistry and Physics · 1995-11-01

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  10. Solid phase reactivity of sodium oxosalts of manganese

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  11. A quantum mechanical investigation of the electronic and magnetic properties of perovskite

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  12. Decomposition oxygen partial pressures of Ln1−Sr MnO3 (Ln=La, Nd and Dy)

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  13. Structure, Magnetism, and Properties of Ruddlesden−Popper Calcium Manganates Prepared from Citrate Gels

    Chemistry of Materials · 1998-10-09

    Ian D. Fawcett, Sunstrom, M. Greenblatt, Mark Croft, K.V. Ramanujachary

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  14. Sr3Mn2O7: Mn4+Parent Compound of then=2 Layered CMR Manganites

    Journal of Solid State Chemistry · 1998-12-01

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  15. A two-step ion exchange route to the new metastable double-layered perovskite, (Rb,Na)1−xCax/2LaNb2O7 (x ≈ 0.9)

    Materials Research Bulletin · 1999-01-01

    Brian L. Cushing, John B. Wiley

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  16. Structural Chemistry and Electronic Properties of the n = 3 Ruddlesden−Popper Phases Ca4Mn2FeO9.75 and Sr4Mn2FeO9.80

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  17. Layered manganites: Magnetic structure at extreme doping levels

    Journal of Applied Physics · 1999-04-15

    John F. Mitchell, J. E. Millburn, Marisa Medarde, D. N. Argyriou, J. D. Jorgensen

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  18. Crystal Structures and Magnetic Properties of Ca2−xSrxMnO4

    Journal of Solid State Chemistry · 1999-07-01

    Keitaro Tezuka, Masaaki Inamura, Yukio Hinatsu, Yutaka Shimojo, Yukio Morii

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  19. Site-Specific Vanadates Co4Fe3.33(VO4)6 and Mn3Fe4(VO4)6

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    Xiandong Wang, Douglas A. Vander Griend, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  20. Features of Microstructure in Ca2MnO4-δ

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    Yasuhide Inoue, Y. Horibe, Yasumasa Koyama

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  21. Anion Vacancy Distribution and Magnetism in the New Reduced Layered Co(II)/Co(I) Phase LaSrCoO3.5-x

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  22. MnK-edge XANES studies of La1−xAxMnO3 systems (A=Ca, Ba, Pb)

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  23. Impact of Oxygen Partial Pressure on the Ruddlesden−Popper Series Nd2-2xSr1+2xMn2O7: Oxygen Vacancy Formation and Ordering

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  24. Enthalpies of Oxidation of CaMnO3-δ, Ca2MnO4-δ and SrMnO3-δ Deduced Redox Properties

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  25. Charge Ordering in a 2D Manganite, Pr0.25Ca1.75MnO4

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  26. Nuclear and Magnetic Structures of K2NiF4-type Iron(III) Oxide Halides

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  27. A Mixed Oxide-Hydride Perovskite

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  28. Synthesis and Characterization of the Reduced Single-Layer Manganite Sr2MnO3.5+x

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  29. Synthesis and structure of Sr2MnGaO5+δ brownmillerites with variable oxygen content

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  30. Crystal growth and structure of a new manganese vanado-antimonate MnVSbO6

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  31. Structural investigation of Ca2MnO4 by neutron powder diffraction and electron microscopy

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  33. Ab initio investigation of the magnetic states of Ca2MnO4 and Ca2MnO3.5

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  34. Dielectric response in the charge-ordered Ca2−xPrxMnO4 phases

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  35. Orthorhombic distortion in Ca2−xGdxMnO4

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  36. 5.1.6.14 References for 5.1.6

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  37. Figs. 1 - 9, Table 1

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  38. Figs. 10 - 14, Table 2

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  39. Structural and Magnetic Properties of Topotactically Reduced YSr2Mn2O7-x (0 < x < 1.5)

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  40. Synthesis and structural properties of n= 1 Ruddlesden–Popper manganites Nd1−Ca1+MnO4

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  41. Synthesis and characterization of the K2NiF4 phases La1+xSr1−xCo0.5Fe0.5O4−δ (x=0, 0.2)

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  42. Crystal structure of Ce-doped CaMnO3 perovskite

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  43. In situ neutron diffraction study of the high-temperature redox chemistry of Ln3−xSr1+xCrNiO8−δ (Ln = La, Nd) under hydrogen

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  44. Topotactic reduction as a synthetic route for the preparation of low-dimensional Mn(II) oxide phases: The structure and magnetism of LaAMnO4-x (A = Sr, Ba)

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  47. Low Temperature Synthesis of Oxygen Deficient Perovskites

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  48. Structural and Magnetic Studies of Ca2−x Sm x MnO Compounds (x=0–0.4)

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  49. Synthesis and characterization of Sr2Ir1−xMxO4 (M=Ti, Fe, Co) solid solutions

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  50. Structure and Magnetism of the Topotactically Reduced Oxychloride Sr4Mn3O6.5Cl2

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