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RESEARCH PAPER · Advanced Science · 2026

Halogen‐Bond Coupled Halogenated‐π‐Conjugation Enables Giant Birefringence in Hydrogen‐Bonded Organic Frameworks

Miao‐Bin Xu, Yun‐Xia Hu, Ming‐Chang Wang, Jia‐jia Li, Jia‐Min Lian, Jin Chen, Ke‐Zhao Du

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Halogen‐Bond Coupled Halogenated‐π‐Conjugation Enables Giant Birefringence in Hydrogen‐Bonded Organic FrameworksOriginalAchieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution0Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide5Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide0Physicochemical properties on 2, 4-dimethyl –N-(E)-3, 4-dimethoxybenzylidene aniline (DDA) single crystal: an efficient organic material for optoelectronic applications0Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals1Birefringence and anisotropic nonlinear-optical effects in flexible organic microstructures0From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates0Recent Advances in Luminescent Hydrogen‐Bonded Organic Frameworks (HOFs): Linker Design, Phosphorescence, and Smart Responsiveness0Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides1Dual‐Role BF 3 Anchoring Enables Giant Birefringence in Short‐Wave UV‐Transparent Fluoroborates0Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence0

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  1. Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution

    Chemical Science · 2026-01-01

    Yan-Zhen Xie, Hai-Yan Jiang, Yi Zhang, Hui‐Ping Xiao, Qing‐Yan Liu, Yu‐Ling Wang

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  2. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

    Read original paper ↗ ·

  3. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  4. Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide

    Angewandte Chemie International Edition · 2026-05-26

    Yun‐Xia Hu, Huai Yu Wu, Jia‐jia Li, Ming‐Chang Wang, Jia‐Min Lian, Jin Yu Luo, Yiru Fu, Zi‐Yan Chen, Yang‐Hang Guo, Jin Chen, Ke‐Zhao Du

    Read original paper ↗ ·

  5. Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide

    Angewandte Chemie · 2026-05-26

    Yun‐Xia Hu, Huai Yu Wu, Jia‐jia Li, Ming‐Chang Wang, Jia‐Min Lian, Jin Yu Luo, Yiru Fu, Zi‐Yan Chen, Yang‐Hang Guo, Jin Chen, Ke‐Zhao Du

    Read original paper ↗ ·

  6. Physicochemical properties on 2, 4-dimethyl –N-(E)-3, 4-dimethoxybenzylidene aniline (DDA) single crystal: an efficient organic material for optoelectronic applications

    Journal of Materials Science Materials in Electronics · 2026-06-01

    Vijayan Munuswamy, Ramalingam Tamilarasan, Thiyagarajan Maadhu, Chedharla Balaji Sarath Kumar, T. U. Jeevitha, Parthipan Govindasamy

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  7. Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals

    Advanced Functional Materials · 2026-06-01

    Hangwei Jia, Yaqi Jin, Muhammad Arif, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  8. Birefringence and anisotropic nonlinear-optical effects in flexible organic microstructures

    Laser Physics Letters · 2026-07-01

    I. A. Kolmychek, V. B. Novikov, Melchi Chosenyah, Rajaram Swaraj, Rajadurai Chandrasekar, T. V. Murzina

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  9. From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates

    Small · 2026-08-03

    Chunjie Shen, Junwei Feng, Zhihua Yang, Shilie Pan, Feng Zhang

    Read original paper ↗ ·

  10. Recent Advances in Luminescent Hydrogen‐Bonded Organic Frameworks (HOFs): Linker Design, Phosphorescence, and Smart Responsiveness

    Information & Functional Materials · 2026-08-14

    Heng Wu, Fengqi Wang, Zhuoyan Dong, Yuanchao Lv, Zhangjing Zhang

    Read original paper ↗ ·

  11. Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides

    Crystal Growth & Design · 2026-08-21

    Jia-Wei Li, Zi-Feng Cao, Jun-Pu Wang, Wen-Pei Jia, Zi-Lin Yang, Yongyan Xu, Kai Zhang, Song-Xue Luo, Hui-Li Zheng, Jian-Qiang Zhao

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  12. Dual‐Role BF 3 Anchoring Enables Giant Birefringence in Short‐Wave UV‐Transparent Fluoroborates

    Advanced Functional Materials · 2026-09-30

    Jin Chen, Jia‐Min Lian, Huai‐Yu Wu, Yun‐Xia Hu, Jinyu Luo, Yiru Fu, Cai‐Yi Liu, Ke‐Zhao Du

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  13. Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence

    Small · 2026-10-04

    Jin Chen, Yun‐Xia Hu, Huai‐Yu Wu, Jia‐Min Lian, Jinyu Luo, Yiru Fu, Ke‐Zhao Du

    Read original paper ↗ ·
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