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RESEARCH PAPER · Journal of the American Chemical Society · 2025

A Deep-Ultraviolet Transparent Nonlinear Optical Hydrogen-Bonded Organic Framework

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A Deep-Ultraviolet Transparent Nonlinear Optical Hydrogen-Bonded Organic FrameworkOriginalRegulating KBBF-like structures via a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals0Synergistic Enhancement of Birefringence in Metal Benzoxazolium Complexes by π-Conjugated [C 9 H 10 NO] + and Triangular [HgI 3 ] − Motifs3An Ultraviolet Transparent Nonlinear Optical Crystal Assembled from a Polarizable Tetrahedral Unit1Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property1Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides0Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals2Synthesis, growth, characterization and DFT studies of a new third-order nonlinear optical single crystal: (E)-4(4-(diethylamino) styryl)-1-methylpyridin-1-ium tosylate monohydrate1Advances in porous organic frameworks as signal amplification scaffolds for immunosensing of food contaminants0Growth, Structural Characterization, and Nonlinear Optical Properties of L-Lysinium Hydrogen Adipate Single Crystals: An Integrated Experimental and DFT Study0Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0Record Second-Harmonic Generation and Exceptional Optical Anisotropy in High-Symmetry 1D Polar Perovskites1A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation0A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation0The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal0Redefining the Minimal Editable Unit of Supramolecular Synthons: A 1→2 Lattice‐Editing Strategy in Ternary Multicomponent Crystals0Fluorinated substituent engineering in naphthyl chalcone crystals for enhanced second-order nonlinear optical responses and measurable terahertz emission0An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy0Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response0Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence0

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  1. Regulating KBBF-like structures via a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals

    Chemical Science · 2026-01-01

    Mingshu Zhang, Shuya Zhao, Zhen‐Cheng Wu, Yue Yin, Zheyu Zhang, Jiafeng Chen, Sheng‐Ping Guo, Yan Zhou

    Read original paper ↗ ·
  2. Synergistic Enhancement of Birefringence in Metal Benzoxazolium Complexes by π-Conjugated [C 9 H 10 NO] + and Triangular [HgI 3 ] − Motifs

    Inorganic Chemistry · 2026-03-19

    Bin Li, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Ning Ye

    Read original paper ↗ ·
  3. An Ultraviolet Transparent Nonlinear Optical Crystal Assembled from a Polarizable Tetrahedral Unit

    Inorganic Chemistry · 2026-03-20

    Ning Yang, Li Shen, Zhiyong Bai, Xitong Song

    Read original paper ↗ ·
  4. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, C L Zhang, Chao Wu

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  5. K 3 Mg 2 [K 6 MgCl 3 ][Ga 20 S 36 ]: A Diamond-like Framework Based on Mixed-Type Supertetrahedra for Excellent Nonlinear Optical Property

    Chemistry of Materials · 2026-04-22

    Jun-Long Chen, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo-Cong Guo

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  6. Positional Isomerism Controls Polarity and Nonlinear Optical Properties in One‐Dimensional Hybrid Germanium Halides

    Angewandte Chemie · 2026-04-29

    Shaohua Xiao, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, C L Zhang

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  7. Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals

    Advanced Science · 2026-05-11

    Lingli Wu, Chensheng Lin, Bo Li, Huixin Fan, Lingfei Lv, Shunda Yang, Tao Yan, Min Luo

    Read original paper ↗ ·
  8. Synthesis, growth, characterization and DFT studies of a new third-order nonlinear optical single crystal: (E)-4(4-(diethylamino) styryl)-1-methylpyridin-1-ium tosylate monohydrate

    Materials Science and Engineering B · 2026-05-23

    S.V. Baageshri Vasan, B. Sahaya Infant Lasalle, Boobalan Maria Susai, Muthu Senthil Pandian, Priyadharshini Suresh Babu, S. Alfred Cecil Raj

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  9. Advances in porous organic frameworks as signal amplification scaffolds for immunosensing of food contaminants

    TrAC Trends in Analytical Chemistry · 2026-07-07

    Lihong Su, Lei Zhao, Huan Liu, Lu Liu, Ibrahim Ali Darwish, Daohong Zhang

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  10. Growth, Structural Characterization, and Nonlinear Optical Properties of L-Lysinium Hydrogen Adipate Single Crystals: An Integrated Experimental and DFT Study

    International Research Journal of Multidisciplinary Technovation · 2026-07-27

    Thirumurugan R, Srirengaraj Vijayaram, E. Shobhana, Mohanraj V

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  11. Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates

    Inorganic Chemistry · 2026-08-04

    Xiuying Zhang, Yebiao Wu, Qiya Huang, Lehui Liu, Peican Chen, Hongming Liu

    Read original paper ↗ ·
  12. Record Second-Harmonic Generation and Exceptional Optical Anisotropy in High-Symmetry 1D Polar Perovskites

    Journal of the American Chemical Society · 2026-08-12

    Shaohua Xiao, Xingxing Jiang, Xiaotian Zhang, Chunbo Jiang, Wenzhi Song, Yukang Fan, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  13. A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation

    Angewandte Chemie · 2026-08-20

    Xiaotian Zhang, Xingxing Jiang, Shaohua Xiao, Wenzhi Song, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, Chi Zhang

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  14. A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2026-08-20

    Xiaotian Zhang, Xingxing Jiang, Shaohua Xiao, Wenzhi Song, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, Chi Zhang

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  15. The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-08-27

    Xiaofan Tong, Zuju Ma, Yulu Wu, Ruibiao Fu, Wenjing Yang, Jiacheng Chen, Qian Zeng

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  16. Redefining the Minimal Editable Unit of Supramolecular Synthons: A 1→2 Lattice‐Editing Strategy in Ternary Multicomponent Crystals

    Advanced Science · 2026-09-03

    Zheng Lin, Honglei Xia, Min Li, Ruihui Wang, Ying Wang, Xiaoyu Feng, Mingjing Tang, Yuan Zhang, Qinghua Zhang

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  17. Fluorinated substituent engineering in naphthyl chalcone crystals for enhanced second-order nonlinear optical responses and measurable terahertz emission

    Journal of Molecular Structure · 2026-09-09

    Qi Chu, Fanghao Xuan, Shoubo Wang, Jinkang Ma, Weiting Wang, Yukang Liang, Dongwei Zhai, Lifeng Cao, Bing Teng

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  18. An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy

    Energy & environment materials · 2026-09-15

    Xiliang Jiang, Hongyuan Sha, Xieming Xu, Chenrui Wang, Luying Zheng, Haotian Tian, Binwen Liu, Shuai‐Hua Wang, Guo‐Cong Guo

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  19. Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance

    Coordination Chemistry Reviews · 2026-09-17

    Bo Zhao, Yaozu Li, Danyang Dou, Wenjing Zhang, Huiyi Zhang, Bingbing Zhang, Ying Wang

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  20. A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-09-21

    Ning Yang, Li Shen, Wenting Lin, Zhenchao Bai, Xitong Song

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  21. Halogen‐Bond Dimensionality Controls π–π Packing to Unlock Ultrahigh Second‐Harmonic Generation and Giant Birefringence

    Small · 2026-10-04

    Jin Chen, Yun‐Xia Hu, Huai‐Yu Wu, Jia‐Min Lian, Jinyu Luo, Yiru Fu, Ke‐Zhao Du

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