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RESEARCH PAPER · Advanced Materials · 2025

3D Chiral Perovskitoid‐to‐Perovskite Reconstructive Phase Transition Designed Molecular Ferroelectric Thin‐Film with out‐of‐Plane Polarization

Huan‐Huan Chen, Yan Fang Qin, Yao Zhang, Hui‐Peng Lv, Xian‐Jiang Song, Wei‐Qiang Liao, Ren‐Gen Xiong, Xiao‐Gang Chen

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3D Chiral Perovskitoid‐to‐Perovskite Reconstructive Phase Transition Designed Molecular Ferroelectric Thin‐Film with out‐of‐Plane PolarizationOriginalEpimeric cation stereocontrol enables tunable phase transition enthalpy and polar ferroelectric frameworks3Linking and tuning of charge-transfer photoluminescence and dielectric relaxation in supramolecular perovskite materials based on cyclometalated Rh( iii ) and Ir( iii ) complexes0Neutral X‐Site ABX 3 ‐Type Perovskites1Neutral X‐Site ABX 3 ‐Type Perovskites0Reconstructive Phase Transition Enabled Second Harmonic Generation and Switchable Photoluminescence of a Hybrid Metal Halide for Temperature Sensing and Anticounterfeiting4Metal–Organic Framework Goes Perovskite: A Self-Healing Neutral X-Site Perovskite Ferroelastic Crystal1H/F substitution strategy for molecular ferroelectrics: From design principles to emerging materials0Water‐Triggered Domino‐Like Phase Transition in a Molecular Ferroelectric1Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures0Exploiting Bulk Photovoltaic Effect in a Polar Hybrid Perovskite Towards Self‐Powered Detection of Weak Ultraviolet Polarized Light0High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules0High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules0HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability0HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability0A Type-II Bismuth Iodide Ferroelectric for Sensitive X-ray Detection and Single-Pixel Imaging0

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  1. Epimeric cation stereocontrol enables tunable phase transition enthalpy and polar ferroelectric frameworks

    Inorganic Chemistry Frontiers · 2026-01-01

    Zheng-Hui Hu, Chang‐Chun Fan, Hongfei Zhao, Ze-Yu Jia, Ting Hai, Yu‐Hui Tan, Dong-Lan Zhang, Chao Yi Shi

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  2. Linking and tuning of charge-transfer photoluminescence and dielectric relaxation in supramolecular perovskite materials based on cyclometalated Rh( iii ) and Ir( iii ) complexes

    Materials Chemistry Frontiers · 2026-01-01

    Kinga Szczecińska, Jan Rzepiela, Mikołaj Żychowicz, Tomasz Charytanowicz, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorąży

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  3. Neutral X‐Site ABX 3 ‐Type Perovskites

    Angewandte Chemie International Edition · 2026-05-07

    Xiao‐Gang Chen, Yan Qin, Yan‐Ran Weng, Xian‐Jiang Song, Hui‐Peng Lv, Wei‐Qiang Liao, Ren‐Gen Xiong

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  4. Neutral X‐Site ABX 3 ‐Type Perovskites

    Angewandte Chemie · 2026-05-08

    Xiao‐Gang Chen, Yan Qin, Yan‐Ran Weng, Xian‐Jiang Song, Hui‐Peng Lv, Wei‐Qiang Liao, Ren‐Gen Xiong

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  5. Reconstructive Phase Transition Enabled Second Harmonic Generation and Switchable Photoluminescence of a Hybrid Metal Halide for Temperature Sensing and Anticounterfeiting

    Inorganic Chemistry · 2026-05-12

    Yi-Fan Guo, Hao-Jin Xu, W L Wang, Ya-Si Fang, Zhilin Liao, Hui‐Peng Lv, Yong Ai, Xiao‐Gang Chen, Yuan‐Yuan Tang, Yan Qin

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  6. Metal–Organic Framework Goes Perovskite: A Self-Healing Neutral X-Site Perovskite Ferroelastic Crystal

    Journal of the American Chemical Society · 2026-05-26

    Xiao‐Gang Chen, Yan Qin, Hui‐Peng Lv, Xian‐Jiang Song, Wei‐Qiang Liao, Ren‐Gen Xiong

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  7. H/F substitution strategy for molecular ferroelectrics: From design principles to emerging materials

    Coordination Chemistry Reviews · 2026-06-13

    H Y Chen, Yuqin Susan Xiong, Hailong Zhang

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  8. Water‐Triggered Domino‐Like Phase Transition in a Molecular Ferroelectric

    Advanced Materials · 2026-06-18

    Chen‐Kai Yang, Yong Ai, Xian‐Jiang Song, Huan‐Huan Chen, Xiao‐Gang Chen, Yuan‐Yuan Tang, Yao Zhang, Juanxia Wu, Bing Han, Liming Xie, Ren‐Gen Xiong

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  9. Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures

    Inorganic Chemistry · 2026-07-02

    Yiwen Xu, Juan Cheng, Gangji Yi, Yingjie Wang, Guohong Zou, Jintong Song, Zhien Lin

    Read original paper ↗ ·

  10. Exploiting Bulk Photovoltaic Effect in a Polar Hybrid Perovskite Towards Self‐Powered Detection of Weak Ultraviolet Polarized Light

    Advanced Science · 2026-07-23

    Xi Zhang, Jianbo Wu, Wai‐Yeung Wong

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  11. High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules

    Angewandte Chemie International Edition · 2026-08-25

    Mengxiang Luo, Xiao Sun, Yanlin LAI, Yang Si, Lin Zhou, Xiuli You, Wenjing Guo, Zhenhong Wei, Hu Cai

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  12. High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules

    Angewandte Chemie · 2026-08-25

    Mengxiang Luo, Xiao Sun, Yanlin LAI, Yang Si, Lin Zhou, Xiuli You, Wenjing Guo, Zhenhong Wei, Hu Cai

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  13. HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability

    Angewandte Chemie · 2026-09-08

    Wenting Liu, xin zeng, Wenkai Zhao, Hebin Wang, Haolin Lu, Xinyi Niu, Zhaoyu Wang, Tianyin Shao, Sehrish Gull, Bing Sun, Hao‐Li Zhang, Xinfeng Liu, Yongsheng Chen, Guankui Long

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  14. HSAB‐Guided Design of Chiral Osmium Halides With Both Efficient Nonlinear Optical Properties and High Stability

    Angewandte Chemie International Edition · 2026-09-08

    Wenting Liu, xin zeng, Wenkai Zhao, Hebin Wang, Haolin Lu, Xinyi Niu, Zhaoyu Wang, Tianyin Shao, Sehrish Gull, Bing Sun, Hao‐Li Zhang, Xinfeng Liu, Yongsheng Chen, Guankui Long

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  15. A Type-II Bismuth Iodide Ferroelectric for Sensitive X-ray Detection and Single-Pixel Imaging

    Inorganic Chemistry · 2026-09-21

    Kaizhou An, Mingli Liang, Weigui Li, Yulong Wang, Xiuwen Xu, Sasa Wang, Qiang Zhao

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