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RESEARCH PAPER · Coordination Chemistry Reviews · 2025

Review and perspective on the rational design and structural modulation of transition metal phosphides for efficient electrocatalytic water splitting

Bohan An, Xin Li, Linping Li, Zhixin Dai, Ning Li, Yangqin Gao, Lei Ge

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Review and perspective on the rational design and structural modulation of transition metal phosphides for efficient electrocatalytic water splittingOriginalHeterojunction construction and phosphorus doping engineering of a CeO 2 /NiCoFeO x -P@NF bifunctional electrocatalyst for efficient overall water splitting0Hierarchical NC/Ni–CoP nanoarrays supported on nickel foam: synergistic electronic modulation and surface reconstruction for high-efficiency ethanol oxidation3Phosphorus-vacancy density regulation in cobalt phosphide for efficient bifunctional urea-assisted energy-saving hydrogen production2Rare-earth-based materials for exchange membrane water electrolysis: from rational design to device applications12Synergistic microenvironment electrocatalysis: Cooperative Fe sites and S-vacancy nanoarchitectonics with an efficient interface for hydrogen evolution on Ni3S24Transition Metal Phosphides for Seawater Electrolysis: Dynamic Reconstruction, Synergistic Mechanisms and Design Paradigms24NiCo-LDH@NiCoP composite as bifunctional catalyst exhibiting excellent full water splitting performance5Crystalline-amorphous NiFeP alloy as an efficient bifunctional self-supporting electrode for alkaline overall water splitting1Synthesis of sea urchin-like porous Fe-doped CoP nanostructures for efficient hydrogen evolution reaction5MOF-derived in situ carbon-coated NiCoP/Ti3C2Tx with interfacial coupling for high-performance overall water splitting4Construction of CoP/Co2P heterojunctions on hollow carbon rods as efficient bifunctional electrocatalysts for overall water splitting0Unlocking synergistic Co-Fe phosphide nanocubes from MOFs as trifunctional electrocatalysts for water splitting and urea electrolysis1V-doped Ni12P5 nanoflowers boost alkaline hydrogen evolution0Optimizing band alignment in rock-salt/spinel high-entropy oxide heterostructures for efficient oxygen evolution3Synergistic promotion of charge transfer and CO2 activation over CoS1.097/ZnIn2S4 heterojunction for photocatalytic CO2 reduction8Engineering built-in electric fields through p-n heterojunction construction for enhanced dual-functional water electrolysis in Co2P/Fe2P systems3Multimetallic FeNiMoZnP enabling efficient oxygen evolution reaction via heterostructure and Zn-enriching entropy regulation0Achieving 99% selective photocatalytic conversion of CO2 to CH4 via built-in electric field guided S-scheme charge transfer in UiO-66/CuS heterojunction6A MOF-Derived Trimetallic Phosphide Bifunctional Electrocatalyst for Efficient Overall Water Splitting3Cutting‐Edge Advances in Metal Phosphides: Rational Synthesis to Dynamic Reconstruction for Electrochemical Water Splitting3A novel high-entropy selenide (Mn0.2Fe0.2Ni0.2Cu0.2Zn0.2)Co2Se4 electrocatalyst for advanced oxygen evolution reaction0Recent advances in graphene-semiconductor-based composites for water splitting and environmental remediation3Cadmium Sulfide‐Based Nanostructures for Next‐Generation Multifunctional Applications: Design Strategies, Decoding Performance Limitations, and Recent Advances4Porous CoP nanowire arrays on industrial stainless steel for efficient overall water splitting0Ru‐Doped Bimetallic Phosphide: A High‐Performance Air‐Breathing Electrode for Zn‐Air Batteries and an Efficient Electrocatalyst for Overall Water Splitting1Synergistic promotion of proton relay and *CO hydrogenation in Cu-Zn tandem catalysts for highly efficient electrocatalytic CO 2 -to-CH 4 conversion0From platinum-like to platinum-beyond: transition metal carbide electrocatalysts breaking the catalytic bottlenecks for hydrogen and oxygen related reactions3Hollow Tubular Engineering and Electronic Structure Modulation of Vanadium-Incorporated MoP for Boosting Alkaline Hydrogen Evolution0NiP/NFF Nanosheet Arrays as an Efficient Bifunctional Electrocatalyst for Water Splitting0Nanorod-like molybdenum/nickel-copper-doped iron phosphide as highly active electrocatalysts for enhanced hydrogen evolution reaction1Efficient electrosynthesis of ammonium formate from nitrate and PET waste over a Cu-doped CoP1Fundamental understanding of reaction mechanism and modulation strategy in carbon-based bifunctional oxygen electrocatalysts towards high-performance zinc-air batteries1Ascorbic acid-induced carbon-doped CoP2/CoNiP nanoparticles for wide pH range hydrogen evolution0Unraveling the role of pyrolysis duration to nitrogen speciation in Co-N-C catalysts for bifunctional energy conversion applications0Operation-induced reconstruction of self-supported nickel–tungsten–copper phosphides into hydroxide–metal working interfaces for high-current alkaline hydrogen evolution0Coordination Engineering of Dual-Atom Catalysts for Overall Water Splitting: Mechanistic Insights from Constant-Potential First-Principles and Machine Learning0Transition metal phosphides for seawater electrolysis: From activity enhancement to adaptive durability engineering0Construction of Gd–Mg–Ni-based superlattice alloys with excellent hydrogen storage performance from stable AB2 structures0Recent advances in MOF-based non-precious metal materials for oxygen evolution reaction electrocatalysis0Functional zoning strategy drives the construction of NiFeP@NiFeOOH as an excellent electrocatalyst for oxygen evolution reaction0Noble-metal free transition metal phosphides for hydrogen evolution reaction: Synergizing computational and experimental studies0Structural design and performance optimization of advanced electrocatalysts for industrial water electrolysis hydrogen production0Recent advances and future directions of prussian blue analogues-derived trifunctionality electrocatalysts for HER, OER, and ORR in alkaline electrolyte0Yttrium doping-induced electronic structure and interfacial water modulation for alkaline hydrogen evolution0Superwetting interface engineering for electrocatalytic water splitting: Construction strategies and mass-transfer mechanisms of nickel foam-based self-supported electrodes0Crystalline‐Amorphous Heterointerfaces Enable Elastic Peracetic Acid Activation for Resilient Remediation of Hypersaline Wastewater0Facile Electrodeposition of Ni-Mo-W Coating on Vanadium-Based Alloys as Hydrogen Evolution Electrocatalyst0

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  1. Heterojunction construction and phosphorus doping engineering of a CeO 2 /NiCoFeO x -P@NF bifunctional electrocatalyst for efficient overall water splitting

    CrystEngComm · 2026-01-01

    Ping Yang, Yao Jiang, Ziyan Sun, Siying Wu, Dawen Zhang

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  2. Hierarchical NC/Ni–CoP nanoarrays supported on nickel foam: synergistic electronic modulation and surface reconstruction for high-efficiency ethanol oxidation

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  3. Phosphorus-vacancy density regulation in cobalt phosphide for efficient bifunctional urea-assisted energy-saving hydrogen production

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  4. Rare-earth-based materials for exchange membrane water electrolysis: from rational design to device applications

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  5. Synergistic microenvironment electrocatalysis: Cooperative Fe sites and S-vacancy nanoarchitectonics with an efficient interface for hydrogen evolution on Ni3S2

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  6. Transition Metal Phosphides for Seawater Electrolysis: Dynamic Reconstruction, Synergistic Mechanisms and Design Paradigms

    Advanced Functional Materials · 2026-02-11

    Tengyu Gui, Zhu Lian Wu, Jin Li, Zhongyuan Qiao, Zhuotao Zheng, Longchao Zhuo, Yanhong Feng, Imran Shakir, Yinghong Wu, Ligang Feng, Xijun Liu

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  7. NiCo-LDH@NiCoP composite as bifunctional catalyst exhibiting excellent full water splitting performance

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  8. Crystalline-amorphous NiFeP alloy as an efficient bifunctional self-supporting electrode for alkaline overall water splitting

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  9. Synthesis of sea urchin-like porous Fe-doped CoP nanostructures for efficient hydrogen evolution reaction

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  10. MOF-derived in situ carbon-coated NiCoP/Ti3C2Tx with interfacial coupling for high-performance overall water splitting

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    Lichan Wu, Liuyan Zhang, Yidong Huang, Zeyi Guan, Renyu Zhou, Yan Pan, Danting Wu, Gengzhe Shen, Yanmei Zhang

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  11. Construction of CoP/Co2P heterojunctions on hollow carbon rods as efficient bifunctional electrocatalysts for overall water splitting

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    Jinli Yao, Lingfei Li, H. B. Liu, Kaili Wang, Shu‐Qi Deng, Wei Yan, Jiujun Zhang

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  12. Unlocking synergistic Co-Fe phosphide nanocubes from MOFs as trifunctional electrocatalysts for water splitting and urea electrolysis

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    Wenyuan Wang, Qifan You, Dui Ma, Dewei Yu, Can Xiao, Yong Liao, Zhiqiang Xiong, Meilan Xie, Hongbo Huang, Fanyan Zeng, Cailing Liu, Xuefeng Qian, Xiao Liang

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  13. V-doped Ni12P5 nanoflowers boost alkaline hydrogen evolution

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  14. Optimizing band alignment in rock-salt/spinel high-entropy oxide heterostructures for efficient oxygen evolution

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    Yuanxia Lao, Yongchao Ge, Haiyan Deng, Yuanyuan Li, Chunyuan Ou, Fangfang Mao, Wei Ping Jiang

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  15. Synergistic promotion of charge transfer and CO2 activation over CoS1.097/ZnIn2S4 heterojunction for photocatalytic CO2 reduction

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  16. Engineering built-in electric fields through p-n heterojunction construction for enhanced dual-functional water electrolysis in Co2P/Fe2P systems

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  17. Multimetallic FeNiMoZnP enabling efficient oxygen evolution reaction via heterostructure and Zn-enriching entropy regulation

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  18. Achieving 99% selective photocatalytic conversion of CO2 to CH4 via built-in electric field guided S-scheme charge transfer in UiO-66/CuS heterojunction

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  19. A MOF-Derived Trimetallic Phosphide Bifunctional Electrocatalyst for Efficient Overall Water Splitting

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  20. Cutting‐Edge Advances in Metal Phosphides: Rational Synthesis to Dynamic Reconstruction for Electrochemical Water Splitting

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  21. A novel high-entropy selenide (Mn0.2Fe0.2Ni0.2Cu0.2Zn0.2)Co2Se4 electrocatalyst for advanced oxygen evolution reaction

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  22. Recent advances in graphene-semiconductor-based composites for water splitting and environmental remediation

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  23. Cadmium Sulfide‐Based Nanostructures for Next‐Generation Multifunctional Applications: Design Strategies, Decoding Performance Limitations, and Recent Advances

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  25. Ru‐Doped Bimetallic Phosphide: A High‐Performance Air‐Breathing Electrode for Zn‐Air Batteries and an Efficient Electrocatalyst for Overall Water Splitting

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  26. Synergistic promotion of proton relay and *CO hydrogenation in Cu-Zn tandem catalysts for highly efficient electrocatalytic CO 2 -to-CH 4 conversion

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  28. Hollow Tubular Engineering and Electronic Structure Modulation of Vanadium-Incorporated MoP for Boosting Alkaline Hydrogen Evolution

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  29. NiP/NFF Nanosheet Arrays as an Efficient Bifunctional Electrocatalyst for Water Splitting

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  30. Nanorod-like molybdenum/nickel-copper-doped iron phosphide as highly active electrocatalysts for enhanced hydrogen evolution reaction

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  31. Efficient electrosynthesis of ammonium formate from nitrate and PET waste over a Cu-doped CoP

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  33. Ascorbic acid-induced carbon-doped CoP2/CoNiP nanoparticles for wide pH range hydrogen evolution

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  36. Coordination Engineering of Dual-Atom Catalysts for Overall Water Splitting: Mechanistic Insights from Constant-Potential First-Principles and Machine Learning

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  37. Transition metal phosphides for seawater electrolysis: From activity enhancement to adaptive durability engineering

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  38. Construction of Gd–Mg–Ni-based superlattice alloys with excellent hydrogen storage performance from stable AB2 structures

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  39. Recent advances in MOF-based non-precious metal materials for oxygen evolution reaction electrocatalysis

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  40. Functional zoning strategy drives the construction of NiFeP@NiFeOOH as an excellent electrocatalyst for oxygen evolution reaction

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